• Title/Summary/Keyword: CO2 generation

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Characteristics of Chemical Reactions in Coal Gasification Processes (석탄가스화 화학반응의 기본 특성 분석 연구)

  • Baek, Seung-Chul;Sohn, Jeong-L.;Song, Seung-Jin
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3125-3130
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    • 2008
  • Coal is one of the most abundant and cheapest energy sources in the earth, but its typical combustion product, $CO_2$, is related with serious recent environmental issues such as global warming. The Integrated Coal Gasification Combined Cycle (IGCC) with $CO_2$ sequestration is one of the most promising options to produce electricity using a relatively cheap fuel (coal) with minimum impact on environment. In IGCC power generation systems, some chemical reactions are required to gasify coal to produce syngases such as $H_2$ and CO, which would be burnt in the combustor to produce heat for power generation, with a penalty of additional energy consumption. In this paper, several chemical reactions for the gasification of coal are considered and their characteristics are investigated.

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The development of expansion planning algorithm considering environmental constraints (환경 제약을 고려한 설비계획 방법론 개발)

  • Kim, Yang-Il;Chung, Koo-Hyung;Shin, Hye-Kyeong;Kim, Bal-Ho H.
    • Proceedings of the KIEE Conference
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    • 2006.11a
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    • pp.164-166
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    • 2006
  • Wien Automatic System Planning Package (WASP) which is used to draw out generation expansion planning applies Dynamic Programming in Korea power system panning. While this package has an advantage that computes annual capacity, it has a disadvantage that can't consider environmental constraints. With the effectuation of the Kyoto Protocol in February, 2005, it is expected that CO2 emission has a severe effect on Korean power system. Therefore, as the most important issue, the generation expansion planning considering environmental constraints is rising in power system. This paper develops a mathematic model including not only generation expansion planning but transmission planning and considering regional supply-demand and environmental constraints, especially CO2 emission, and verifies propriety through the case study.

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Development of a Highly Efficient Boiler System Using a Diesel Engine

  • Lee, D.-H;Lee, D.-Y;Jo, M.-C;Cho, H.-N;Kim, Y.-S
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.2
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    • pp.367-375
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    • 2004
  • We have developed a highly efficient boiler system using the 2,600cc Diesel engine. In this system, the co-generation concept is utilized in that the electric power is produced by the generator connected to the engine, and waste heat is recovered from both the exhaust gases and the engine itself by the shell-and-tube heat exchangers. The heat exchanger connected to the engine outlet is specially designed such that it not only recovers waste heat effectively from the exhaust gases, but significantly reduces an engine noise. It is found that the total efficiency(thermal efficiency plus electric power generation efficiency) of this system reaches maximum 96.3% which is about 15% higher than the typical Diesel engine boiler system currently being used worldwide.

Estimation of Emission and Development of Emission Factor on Greenhouse Gas (CO2) of the Combustion Facilities (연소시설의 온실가스(CO2) 배출량 산정 및 배출계수개발)

  • Kim, Hong-Rok;Jin, Byong-Bok;Yoon, Wan-Woo;Kwon, Young-Sung;Lee, Min-Young;Yoon, Young-Bong;Shin, Won-Geun
    • Journal of Environmental Impact Assessment
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    • v.16 no.4
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    • pp.277-283
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    • 2007
  • Since the Kyoto Protocol became into effect, Korea has been expected to be part of the Annex I countries performing the duty of GHG reduction in the phase of post-Kyoto. Therefore, it is necessary to develop emission factors appropriate to Korean circumstances. In order to develop emission factors this study utilized the CleanSYS, which is the real-time monitoring system for industrial smoke stacks to calculate the emission rate of $CO_2$ continuously. In this study, the main focus was on the power generation plants emitting the largest amount of $CO_2$ among the sectors of fossil fuel combustion. Also, an examination on the comparison of $CO_2$ emission was made among 3 generation plants using the different types of fuels such as bituminous coal and LNG; one for coal and others for LNG. The $CO_2$ concentration of the coal fired plant showed Ave. 13.85 %(10,384 ton/day). The LNG fired plants showed 3.16 %(1,031 ton/day) and 3.19 %(1,209 ton/day), respectably. Consequently, by calculating the emission factors using the above results, it was found that the bituminous coal fired power plant had the $CO_2$ emission factor average of 88,726 kg/TJ, and the LNG fired power plants had the $CO_2$ average emission factors of 56,971 kg/TJ and 55,012 kg/TJ respectably which were similar to the IPCC emission factor.

Economic Evaluation of Alternatives for CO2 Reduction of Thermal Power Generation Companies using ROPM: Comparing CCS with RPS Implementation (실물옵션을 활용한 화력발전회사의 CO2 감축대안의 경제성 평가: CCS와 RPS 이행의 비교)

  • Lee, Dong Su;Jeong, Kiho
    • Environmental and Resource Economics Review
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    • v.20 no.1
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    • pp.61-98
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    • 2011
  • This study conducts economic evaluation of alternatives for $CO_2$ reduction of thermal power plants. Two alternatives in reducing $CO_2$ emission are considered for the evaluation under the RPS(Renewable Portfolio Standard) system; one is to perform renewable energy quotas and another is to construct green thermal power plants using CCS(Carbon Capture and Sequestration). As evaluation methods, DCF(Discount Cash Flow) and ROPM(Real Options Pricing Method) are employed. At a discount rate of 7.5% applied to the Electricity Supply and Demand Plan, it is shown that green thermal power generation has economic dominance under both evaluation methods.

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Analysis of Generation Explansion Planning Considering CO2 Emission Constraints and Emission Trading under using LP(Linear Programing) and MIP(Mixed Integer Programing) (정수계획법과 선형계획법을 이용한 CO2 배출량 제약과 배출권거래하의 설비계획 비교/ 분석)

  • Shin, Hye-Kyeong;Jung, Hee-Chung;Kang, Gong-Ju;Han, Seok-Man;Chung, Koo-Hyung;Kim, Balho-H.
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.816-817
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    • 2007
  • As UNFCC(United Nations Framework Convention on Climate Change) is enhanced, Korea will perform a CO2 reduction duty. The CO2 reduction duty will effect Korea power system because coal and oil thermal generations emit large CO2 form about 46% of total CO2 emission. Moreover various alternatives should be designed to comply with CO2 reduction duty. In this paper, we analysis resource planning considering CO2 emission constraints and emission trading. And we analysis resource planning under using LP(Linear Programing) and MIP(Mixed Integer Programing).

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Coal pyrolysis behaviors at supercritical CO2 conditions

  • Hakduck Kim;Jeongmin Choi;Heechang Lim;Juhun Song
    • Advances in Energy Research
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    • v.8 no.4
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    • pp.265-273
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    • 2022
  • In this study, a product gas yield and carbon conversion were measured during the coal pyrolysis. The pyrolysis process occurred under two different atmospheres such as subcritical (45 bar, 10℃) and supercritical CO2 condition (80 bar, 35℃). Under the same pressure (80 bar), the atmosphere temperature increased from 35℃ to 45℃ to further examine temperature effect on the pyrolysis at supercritical CO2 condition. For all three cases, a power input supplied to heating wire placed below coal bed was controlled to make coal bed temperature constant. The phase change of CO2 atmosphere and subsequent pyrolysis behaviors of coal bed were observed using high-resolution camcorder. The pressure and temperature in the reactor were controlled by a CO2 pump and heater. Then, the coal bed was heated by wire heater to proceed the pyrolysis under supercritical CO2 condition.

The performance evaluation for H2 reforming of the plate type hydrogen generation system (평판형 수소생산시스템의 수소개질 성능평가)

  • Heo, Su-Bin;Yun, Bong-Seock;Lee, Do-Hyung
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.602-608
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    • 2014
  • Hydrogen energy, a field of low-carbon substitute energy, can be produced by fossile fuel reforming and electrolysis of water etc. We developed 1kW class flat type reformer for PEM Fuel Cells. The PEMFC is highly sensitive to carbon monoxide because CO has detrimental effects on the performance of the fuel cell. Thus, reformed gas supplied to Fuel cell system, which maintained CO concentration below 10ppm. After applying optimum drive condition, reformed gas was measured with gas chromatography and could find out about each experimental condition of $H_2$ and CO concentration. As a results, The 1kW class plate type hydrogen generation system's optimum condition is A/F ratio ${\alpha}=1.3$, STR temperature 1023K, S/C ratio 3, and $PrOx1{\cdot}2$ 30cc/min. It turns out that installation of PrOx 2 stage is more efficient for reducing CO concentration.

Global Trend of CO2 Capture Technology Development (이산화탄소 포집기술 국외 기술개발 동향)

  • Baek, Jeom-In
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.2
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    • pp.143-165
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    • 2016
  • The amount of greenhouse gas emission reduction based on INDCs (Intended Nationally Determined Contributions) submitted to UN by each party is not sufficient to achieve the Paris Agreement's aim to "hold the increase in the global average temperature to well below $2^{\circ}C$ above pre-industrial levels and to pursue efforts to limit the temperature increase to $1.5^{\circ}C$" which was determined in the $21^{st}$ Conference of the Parties to the UNFCCC (COP 21). Accordingly, the emission reduction target of each party will be revised for the $2^{\circ}C$ goal. Among the several options to reduce the carbon emission, CCS (Carbon Capture and Storage) is a key option to curb $CO_2$ emissions from large emission sources such as fossil-based power plants, cement plants, and steel production plants. A large scale CCS demonstration projects utilizing $1^{st}$ generation $CO_2$ capture technologies are under way around the world. It is anticipated, however, that the deployment of those $1^{st}$ generation $CO_2$ capture technologies in great numbers without government support will be difficult due to the high capture cost and considerable increase of cost of electricity. To reduce the carbon capture cost, $2^{nd}$ and $3^{rd}$ generation technologies are under development in a pilot or a bench scale. In this paper, current status of large scale CCS demonstration projects and the $2^{nd}$ and $3^{rd}$ generation capture technologies are summarized. Novel capture technologies on wet scrubbing, dry sorbent, and oxygen combustion are explained in detail for all capture areas: post-combustion capture, pre-combustion capture, and new combustion technologies.

Bee Venom Enhanced Cytotoxic Effect of Natural Killer Cells on Human Lung Cancer Through Inducing Extrinsic Apoptosis

  • Kim, Jung Hyun;Song, Ho Sueb
    • Journal of Acupuncture Research
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    • v.31 no.1
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    • pp.111-119
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    • 2014
  • Objectives : I investigated whether Bee Venom can synergistically strengthen the cytotoxic effects of NK-92 cells, enhancing the inhibition of the growth of Lung Cancer Cells including A549 and NCI-H460 through induction of death receptor dependent extrinsic apoptosis and NO generation in the Nitro-oxide pathway. Methods : Bee Venom inhibited cell proliferation of A549 or NCI-H460 Human Lung Cancer Cells as well as NK-92 Cells. Moreover, when they were co-punctured with NK cells and concomitantly treated by 3 ${\mu}g/ml$ of Bee Venom, more influence was exerted on inhibition of proliferation of A549 or NCI-H460 Human Lung Cancer Cells than BV or NK cell co-culture alone. Results : The expression of Fas, TNFR2, DR3, DR6 in A549 Lung Cancer Cells was significantly increased by co-culture of NK-92 cells and treatment of 3 ${\mu}g/ml$ of Bee Venom, compared to co-culture of NK-92 cells alone, whereas the expression of Fas, TNFR2, DR6 in NCI-H460 Lung Cancer Cells was significantly increased by co-culture of NK-92 cells, representing no synergistic effects in the co-culture of NK-92 cell and concomitant treatment of 3 ${\mu}g/ml$ of Bee Venom. Coincidently, caspase-8, a expression of pro-apoptotic proteins in the extrinsic apoptosis pathway demonstrated same results as the above. Meanwhile, In NO generation, there is little change of NO generation in co-culture of NK-92 cells with A549 cells as well as the co-culture of NK-92 cell with them and concomitant treatment of 3 ${\mu}g/ml$ of Bee Venom, whereas increase of NO generation was shown in co-culture of NK-92 cells with NCI-H460 cells as well as the co-culture of NK-92 cell with them and concomitant treatment of 3 ${\mu}g/ml$ of Bee Venom, although synergistic effects by Bee Venom was not found. Conclusions : These present data provide that Bee Venom could be useful candidate compounds to enhance lung cancer growth inhibiting ability of NK-92 cells through DR expression and the related apoptosis.