• Title/Summary/Keyword: CO adsorption

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Production of Activated Carbon from Bamboo by Gas Activation Method (기상 활성화법에 의한 대나무 활성탄 제조)

  • 조광주;박영철
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.166-172
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    • 2004
  • The activated carbon was produced from Sancheong bamboo by steam and carbon dioxide gas activation methods. The carbonization of raw material was conducted at 90$0^{\circ}C$ and gas activation reactions were conducted with respect to various conditions. -activation temperature 750-90$0^{\circ}C$, the flow rate of steam 0.5-2g-$H_2O$/g-char$.$hr, the flow rate of carbon dioxide 5-30$m\ell$-$CO_2$/g-char-min and activation time 1-5 hr. The prepared activated carbons were measured yield, the adsorption capacity of iodine and methylene blue, BET specific surface area and pore size distribution. The adsorption capacity of iodine (680.5-1526.1 mg/g) and methylene blue (18.3-221.5 mg/g) increased with creasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the activation gas quantity in the range of 0.5-1.5g-$H_2O$/g-charㆍhr, 5-18.9$m\ell$-Co$_2$/g-charㆍmin. But those decreased over those range due to the pore shrinkage. The steam activation method was superior in efficiency to carbon dioxide activation method.

Preparation of Spherical Activated Carbon and Their Physicochemical Properties

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Zhang, Kan;Meng, Ze-Da
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.568-573
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    • 2009
  • In this study, we used coal based activated carbons as starting material and phenolic resin (PR) as a bonding agent to prepare spherical shaped activated carbons. The textural properties of SAC were characterized by BET surface area, XRD, SEM, iodine adsorption, strength intensity and pressure drop. According to the results, the spherical activated carbon prepared with activated carbon and PR at a ratio of 60:40 was found to have the best formation of spherical shape, which was found in sample SAC40. After activation, SAC40 has high BET surface area, iodine adsorption capability and strength value, and lowest pressure drop.

Preparation of Micro-/Macroporous Carbons and Their Gas Sorption Properties

  • Hwang, Yong-Kyung;Shin, Hye-Seon;Hong, Jin-Yeon;Huh, Seong
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.377-382
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    • 2014
  • Micro-/macroporous carbons (MMCs) were prepared using a hollow mesoporous silica capsule (HMSC) as a sacrificial hard template. The carbonization process after the infiltration of furfuryl alcohol into the template-free HMSC material afforded MMC materials in high yield. The hard template HMSC could be removed by HF etching without deteriorating the structure of MMC. The MMC materials were fully characterized by SEM, TEM, PXRD, XPS, and Raman spectroscopy. The replication processes were so successful that MMCs exhibited a hollow capsular structure with multimodal microporosity. Detailed textural properties of MMC materials were investigated by volumetric $N_2$ adsorption-desorption analysis at 77 K. To explore the gas sorption abilities of MMCs for other gases, $H_2$ and $CO_2$ sorption analyses were also performed at various temperatures. The multimodal MMC materials were found to be good sorbents for both $H_2$ and $CO_2$ at low pressure.

Sensing Characterization of Metal Oxide Semiconductor-Based Sensor Arrays for Gas Mixtures in Air

  • Jung-Sik Kim
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.195-204
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    • 2023
  • Micro-electronic gas sensor devices were developed for the detection of carbon monoxide (CO), nitrogen oxides (NOx), ammonia (NH3), and formaldehyde (HCHO), as well as binary mixed-gas systems. Four gas sensing materials for different target gases, Pd-SnO2 for CO, In2O3 for NOx, Ru-WO3 for NH3, and SnO2-ZnO for HCHO, were synthesized using a sol-gel method, and sensor devices were then fabricated using a micro sensor platform. The gas sensing behavior and sensor response to the gas mixture were examined for six mixed gas systems using the experimental data in MEMS gas sensor arrays in sole gases and their mixtures. The gas sensing behavior with the mixed gas system suggests that specific adsorption and selective activation of the adsorption sites might occur in gas mixtures, and allow selectivity for the adsorption of a particular gas. The careful pattern recognition of sensing data obtained by the sensor array made it possible to distinguish a gas species from a gas mixture and to measure its concentration.

A study on analysis of particle size distribution

  • Min, Shin-Hong
    • Archives of Pharmacal Research
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    • v.3 no.2
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    • pp.65-74
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    • 1980
  • Analysis of particle size distribution of a sample of fine aluminum hydroxide powder was carried out by four different methods, i. e., conductivity, air permeability, gas-adsorption and sedimentation. Each method was reproducible. The results obtained by Coulter counter and sedimentation balance were similar, and the data obtained by Lea and Nurse permeameter and Stroehlein areameter were also similar. But the results differ considerabley between the former and the latter. The advantages and disavantages of each method were discussed briefly and a means of comparing the results with those obtianed by surface area measurements was shown.

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Spatial Distribution of CO2 Absorption Derived from Land-Cover and Stock Maps for Jecheon, Chungbuk Province (토지피복도와 임상도를 이용한 제천시의 이산화탄소 분포 추정)

  • Jeon, Jeong-Bae;Na, Sang-Il;Yoon, Seong-Soo;Park, Jong-Hwa
    • Journal of Korean Society of Rural Planning
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    • v.19 no.2
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    • pp.121-128
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    • 2013
  • The greenhouse gas emission according to the energy consumption is the cause of global warming. With various climates, it is occurs the direct problems to ecosystem. The various studies are being to reduce the carbon dioxide, which accounts for more than 80% of the total greenhouse gas emissions. In this study, estimate the carbon usage using potential biomass extracted from forest type map according to land-use by satellite image, and estimate the amount of carbon dioxide, according to the energy consumption of urban area. The $CO_2$ adsorption is extracted by the amount of forest based on the direct absorption of tree, the other used investigated value. The $CO_2$ emission in Jecheon was 3,985,900 $TCO_2$ by energy consumption. At the land cover classification, the forest is analyzed as 624,085ha and the farmland is 148,700ha. The carbon dioxide absorption was estimated at 1,834,850 Tons from analyzed forest. In case of farmland, it was also estimated at 706,658 Tons.

Preparation of Activated Carbon Fiber Adsorbent for Enhancement of CO2 Capture Capacity (이산화탄소 포집능 향상을 위한 활성탄소 섬유 흡착제 제조)

  • Hwang, Su-Hyun;Park, Hyun-Soo;Kim, Dong-woo;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.6
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    • pp.538-547
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    • 2015
  • Test activated carbon fiber (ACF) was prepared from Polyacrylonirile (PAN) through oxidation and chemical activation. Immersion of ACF precursors in the aqueous KOH solution enhanced the surface structure, as examined by BET pore analysis. Specific surface area increased greatly from less than $70m^2/g$ to $1226m^2/g$ with 4 M KOH, and total pore volume also rose up to $0.483cm^3/g$. In particular, it was found that micropores favorable for $CO_2$ molecule capture occupied more than 95%. Maximum $CO_2$ adsorption capacity was 3.59 mmol/g at 298 K. Low depth of pores in the present ACF may facilitate the molecules' desorption for its regeneration.

Pproperties of formaldehyde and CO2 adsorption type matrix using TiO2 photocatalysis (광촉매를 활용한 흡착형 경화체의 포름알데히드 및 CO2 특성)

  • Lee, Won-Gyu;Pyeon, Su-Jeong;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.153-154
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    • 2018
  • As the air pollution progresses, the pollution degree of the indoor air quality is increased, and when the pollution degree of the indoor air quality is increased, it causes respiratory diseases and skin diseases. In addition, volatile organic compounds are released from the materials used for architectural interior decoration, and volatile organic compounds are the main cause of polluting indoor air quality. In order to improve indoor air quality, we tried to secure indoor air quality pollution by using photocatalyst which has the function of decomposing harmful substances. photocatalyst is a material that promotes chemical reaction by absorbing light. The photocatalyst used in the experiment was TiO2, In this study, an adsorption type hardener for reducing volatile organic compounds was prepared by photocatalytic reaction. the formaldehyde and CO2 concentrations of the cured products were analyzed according to the TiO2 content.

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Cobalt ferrite nanotubes and porous nanorods for dye removal

  • Girgis, E.;Adel, D.;Tharwat, C.;Attallah, O.;Rao, K.V.
    • Advances in nano research
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    • v.3 no.2
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    • pp.111-121
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    • 2015
  • $CoFe_2O_4$ nanotubes and porous nanorods were prepared via a simple one-pot template-free hydrothermal method and were used as an adsorbent for the removal of dye contaminants from water. The properties of the synthesized nanotubes and porous nanorods were characterized by electron diffraction, transmission electron microscopy and x-ray powder diffraction. The Adsorption characteristics of the $CoFe_2O_4$ were examined using polar red dye and the factors affecting adsorption, such as, initial dye concentration, pH and contact time were evaluated. The overall trend followed an increase of the sorption capacity reaching a maximum of 95% dye removal at low pHs of 2-4. An enhancement in the removal efficiency was also noticed upon increasing the contact time between dye molecules and $CoFe_2O_4$ nanoparticles. The final results indicated that the $CoFe_2O_4$ nanotubes and porous nanorods can be considered as an efficient low cost and recyclable adsorbent for dye removal with efficiency 94% for Cobalt ferrite nanotubes and for Cobalt ferrite porous nanorods equals 95%.

Adsorption and Dissociation Reaction of Carbon Dioxide on Pt(111) and Fe(111) Surface: MO-study

  • Jo, Sang Jun;Park, Dong Ho;Heo, Do Seong
    • Bulletin of the Korean Chemical Society
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    • v.21 no.8
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    • pp.779-784
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    • 2000
  • Comparing the adsorption properties and dissociation on a Pt(111) iththat ona Fe(111) surface, we have con-sidered seven coordination modes of the adsorbed binding site: $di-${\sigma}$${\Delta}$\mu\pi/\mu$, 1-fbld,2-fold, and 3-fbld sites. On the Pt(111) surface, t he adsorbed binding site of carbon dioxide was strongestat the1-fold site and weakest at the $\pi/\mu-site.$ The adsorbed binding site on the Fe(111) surface was strongest at the di-бsite and weakest at the 3-fold site. We have found that the binding energy at each site that excepted 3-fold on the Fe(111) surface was stronger than the binding energy on the Pt(111) surface and that chemisorbed $CO_2bends$ because of metal mixing with $2\piu${\rightarrow}$6a_1CO_2orbital.$, The dissociation reaction occured in two steps, with an intermediate com-plex composed of atomic oxygen and ${\pi}bonding$ CO forming. The OCO angles of reaction intermediate com-plex structure for the dissociation reaction $were115^{\circ}Con$ the Pt(111), and $117^{\circ}C$ on the Fe(111) surface. We have found that the $CO_2dissociation$ rea11) surface proceeds easily,with an activationenergy about 0.2 eV lower than that on the Pt(111) surface.