• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.118-119
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• 2016

γ-C₂S is known as a kind of substance that it does not react with water at room temperature. However it could react with the CO₂ producing CaCO₃ and silica gel as the carbonation products. Thus γ-C₂S can be used as a mineral addition to improve the compressive strength and durability of concrete. On the other hand, the manufacture of γ-C₂S can give an effective utilization of industrial by-product with low energy consumption and low CO₂ emission. This paper aims to summarize the development situation on this field.

• Journal of Environmental Impact Assessment
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• v.16 no.4
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• pp.277-283
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• 2007

Since the Kyoto Protocol became into effect, Korea has been expected to be part of the Annex I countries performing the duty of GHG reduction in the phase of post-Kyoto. Therefore, it is necessary to develop emission factors appropriate to Korean circumstances. In order to develop emission factors this study utilized the CleanSYS, which is the real-time monitoring system for industrial smoke stacks to calculate the emission rate of $CO_2$ continuously. In this study, the main focus was on the power generation plants emitting the largest amount of $CO_2$ among the sectors of fossil fuel combustion. Also, an examination on the comparison of $CO_2$ emission was made among 3 generation plants using the different types of fuels such as bituminous coal and LNG; one for coal and others for LNG. The $CO_2$ concentration of the coal fired plant showed Ave. 13.85 %(10,384 ton/day). The LNG fired plants showed 3.16 %(1,031 ton/day) and 3.19 %(1,209 ton/day), respectably. Consequently, by calculating the emission factors using the above results, it was found that the bituminous coal fired power plant had the $CO_2$ emission factor average of 88,726 kg/TJ, and the LNG fired power plants had the $CO_2$ average emission factors of 56,971 kg/TJ and 55,012 kg/TJ respectably which were similar to the IPCC emission factor.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1207-1213
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• 2011

This study was conducted to assess $N_2O$ emissions in agricultural soils of Korea. According to 1996 and 2006 IPCC (Intergovernmental Panel on Climate Change) methodology, $N_2O$ emission was calculated the sum of direct emission ($N_2O_{DIRECT}$) and indirect emission ($N_2O_{INDIRECT}$). To calculate $N_2O$ emissions, emission factor was used default of IPCC and activity data was used the food, agricultural, forestry and fisheries statistical yearbook of MIFAFF (Ministry for Food, Agriculture, Forestry and Fisheries). It was emitted 8,608 $N_2O$ Mg resulted from direct emission by application of chemical fertilizer and animal manure, input in n-fixation crops and input of crop residues and emissions converted $N_2O$ into $CO_2$ equivalent was 2,668 $CO_2$-eq Gg. Indirect emission as $N_2O_{(G)}$ (atmospheric deposition of $NH_3$ and $NO_X$) and $N_2O_{(L)}$ (leaching and runoffs) were 4,567 and 6,013 $N_2O$ Mg and emissions converted $N_2O$ into $CO_2$ equivalent were 1,416 and 1,864 $CO_2$-eq Gg, respectively. Total $N_2O$ emission in Korea agricultural soil in 2009 was 5,948 $CO_2$-eq Gg.

• Atmosphere
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• v.31 no.5
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• pp.593-606
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• 2021

The Korea Meteorological Administration/National Institute of Meteorological Sciences (KMA/NIMS) has monitored atmospheric CO₂ at Anmyeondo (AMY) World Meteorological Organization (WMO) Global Atmosphere Watch Programme (GAW) regional station since 1999, and expanded its observations at Jeju Gosan Suwolbong station (JGS) in the South and at Ulleungdo-Dokdo stations in the East (ULD and DOK) since 2012. Due to a recent WMO CO₂ scale update and a new filter (NIMS) to select baseline levels at each station, the 22 years of CO₂ data are recalculated. After correction for the new CO₂ scale, we confirmed that those corrected records are reasonable within the compatibility goal (±0.1 ppm of CO₂) between KMA/NIMS and National Oceanic and Atmosphereic Administration (NOAA) flask-air measurements with the new scale. With the new NIMS filter, CO₂ baseline levels are now more representative of the large-scale background compared to previous values, which contained large CO₂ enhancements. Atmospheric CO₂ observed in South Korea is 4 to 8 ppm greater than the global average while the amplitude of seasonal variation is similar (10~13 ppm) to the amplitude averaged over a comparable latitude zone (30°N-60°N). Variations in CO₂ growth rate are also similar, increasing and decreasing similar to global values, as it reflects the net balance between terrestrial respiration and photosynthesis. In 2020, atmospheric CO₂ continued increasing despite the COVID-19 pandemic. Even though fossil emission was reduced (around -7% globally), we still emitted large amounts of anthropogenic CO₂. Overall, since CO₂ has large natural variations and its source was derived from not only fossil fuel but also biomass burning, the small fossil emission reduction could not affect the atmospheric level directly.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.5
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• pp.393-399
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• 2020

A series of phosphors, SrWO₄:5 mol% Dy³⁺, SrWO₄:5 mol% Sm³⁺, and SrWO₄:5 mol% Dy³⁺:x Sm³⁺ (x＝1~15 mol%), were prepared using a facile co-precipitation. The crystal structure, morphology, photoluminescence properties, and application in anti-counterfeiting fields were investigated. The crystalline structures of the prepared phosphors were found to be tetragonal systems with the dominant peak occurring at the (112) plane. The excitation spectra of the Dy³⁺ singly-doped SrWO₄ phosphors were composed of an intense charge-transfer band centered at 246 nm in the range of 210~270 nm and two weak peaks at 351 nm and 387 nm due to the ⁶H_15/2→⁶P_7/2 and ⁶H_15/2→⁴I_13/2 transitions of Dy³⁺ ions, respectively. The wavelength of 246 nm was optimum for exciting the luminescence of Dy³⁺ and Sm³⁺ co-doped SrWO₄ phosphors. The emission spectra consisted of two intense blue and yellow emission bands at 480 nm and 573 nm corresponding to the ⁴F_9/2→⁶H_15/2 and ⁴F_9/2→⁶H_13/2 transitions of Dy³⁺, and two strong emission peaks at 599 nm and 643 nm originating from the ⁴G_5/2→⁶H_7/2 and ⁴G_5/2→⁶H_9/2 transitions of Sm³⁺, respectively. As the concentration of Sm³⁺ ions increased, the emission intensities of Dy³⁺ rapidly decreased, while the emission intensities of Sm³⁺ gradually increased. These results suggest that the color of the emission light can be tuned from yellow to white by changing the concentration of Sm³⁺ ions at a fixed 5 mol% Dy³⁺. Furthermore, the fluorescent security inks were synthesized for use in anti-counterfeiting applications.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.63-64
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• 2011

Recently, due to global warming, CO₂ emissions is one of the global issues over all areas including construction industry. In Korea, apartment housing has large ratio of building construction and its CO₂ emissions during the operation and maintenance has the most large amount of tatal life cycle of apartment housing. However, there are rare research related to this subject. So, this study investigates the CO₂ emissions of domestic apartment housing during the operation and maintenance. In the future, the results of this study can be utilized in further study to decrease CO₂ emissions strategy.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.23-24
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• 2014

Currently, cement and concrete industries have been contributing to the CO₂ emission worldwide. Because of that, the efforts to minimize CO₂ have been the subject of many researches. This study focus on the use of GGBFS and fly ash in mortar specimens as a patial replacement of cement. Because of the limitation of the initial compressive strength, the newly efforts to enhance the strength through CO₂ Curing was adapted. To accelerate the reaction with CO₂, MgO was replaced by percentage from 0 to 100%. Results showed that compressive strength values at 7 days with CO₂ curing done on specimens was higher than that with no CO₂ curing. Similar trend was observed at 14 days too. It is therefore appeared that CO₂ curing has an obvious effect on compressive strength development of mortar specimens.

• Korean Journal of Materials Research
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• v.30 no.8
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• pp.406-412
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• 2020

SrMoO₄:RE³⁺ (RE=Dy, Sm, Tb, Eu, Dy/Sm) phosphors are prepared by co-precipitation method. The effects of the type and the molar ratio of activator ions on the structural, morphological, and optical properties of the phosphor particles are investigated. X-ray diffraction data reveal that all the phosphors have a tetragonal system with a main (112) diffraction peak. The emission spectra of the SrMoO₄ phosphors doped with several activator ions indicate different multicolor emissions: strong yellow-emitting light at 573 nm for Dy³⁺, red light at 643 nm for Sm³⁺, green light at 545 nm for Tb³⁺, and reddish orange light at 614 nm for Eu³⁺ activator ions. The Dy³⁺ singly-doped SrMoO₄ phosphor shows two dominant emission peaks at 479 and 573 nm corresponding to the ⁴F_9/2→⁶H_15/2 magnetic dipole transition and ⁴F_9/2→⁶H_13/2 electric dipole transition, respectively. For Dy³⁺ and Sm³⁺ doubly-doped SrMoO₄ phosphors, two kinds of emission peaks are observed. The two emission peaks at 479 and 573 nm are attributed to ⁴F_9/2→⁶H_15/2 and ⁴F_9/2→⁶H_13/2 transitions of Dy³⁺ and two emission bands centered at 599 and 643 nm are ascribed to ⁴G_5/2→⁶H_7/2 and ⁴G_5/2→⁶H_9/2 transitions of Sm³⁺. As the concentration of Sm³⁺ increases from 1 to 5 mol%, the intensities of the emission bands of Dy³⁺ gradually decrease; those of Sm³⁺ slowly increase and reach maxima at 5 mol% of Sm³⁺ ions, and then rapidly decrease with increasing molar ratio of Sm³⁺ ions due to the concentration quenching effect. Fluorescent security inks based on as-prepared phosphors are synthesized and designed to demonstrate an anti-counterfeiting application.

• Corrosion Science and Technology
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• v.22 no.2
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• pp.90-98
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• 2023

In this study, cobalt oxide (Co₃O₄) and cobalt-doped magnetite (CoFe₂O₄) nanoparticles were synthesized by a hydrothermal method. They were then used as corrosion inhibitors for corrosion protection of AA2024-T3 aluminum alloys. These obtained nanoparticles were characterized by x-ray diffraction, field-emission scanning electron microscopy, and Zeta potential measurements. Corrosion inhibition activities of Co₃O₄ and CoFe₂O₄ nanoparticles were determined by performing electrochemical measurements for bare AA2024-T3 aluminum alloys in 0.05 M NaCl + 0.1 M Na₂SO₄ solution containing Co₃O₄ or CoFe₂O₄ nanoparticles. Corrosion protection for AA2024-T3 aluminum alloys by a water-based epoxy with or without the synthesized Co₃O₄ or CoFe₂O₄ nanoparticles was investigated by electrochemical impedance spectroscopy during immersion in 0.1 M NaCl solution. The corrosion protection of epoxy coating deposited on the AA2024-T3 surface was improved by incorporating Co₃O₄ or CoFe₂O₄ nanoparticles in the coating. The corrosion protection performance of the epoxy coating containing CoFe₂O₄ was higher than that of the epoxy coating containing Co₃O₄.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.2
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• pp.158-168
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• 2007

The cement industry is one of the energy intensive industries such as petrochemical and steel industry. The energy efficiency of cement industry is high comparing to oversea's cement industries due to the enforcement of energy conservation policies. The purpose of this study is estimate emission factors for greenhouse gas ($CO_{2}$) in cement industry. The results of field study, quicklime contained quantity of five factories were $0.64{\sim}0.65$. Measurement emission (15,382 ton/day) is 40% higher than process emission (8,929 ton/day) on the IPCC Guidelines (1996). Add to combustion emission on the lines of IPCC Guidelines (1996) is similar to the emission of this study. The emission factor of greenhouse gas ($CO_{2}$) were as follows the emission factor between $9.01E-01{\sim}2.15E-01\;ton/ton$ for $CO_{2}$. The result of this study is higher than emission factor of IPCC (0.51) but it is similar to U.S. EPA's (0.952).