• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.26 no.2
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• pp.71-76
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• 2020

CO₂ concentration in kimchi package has emerged recently as a potential index of product ripening to be monitored or sensed in intelligent packaging. Considering that addition of CO₂ absorber into the flexible kimchi package changes behavior of its CO₂ concentration, ripening of kimchi in total acidity, package CO₂ concentration in partial pressure (P_CO2) and package volume at 10℃ were estimated by mathematical model for two size packages included with different CO₂ absorbers. In small size package containing 0.5 kg of kimchi, relatively less gas permeable low density polyethylene (LDPE) sachet of the absorber was found to give rise of P_CO2 linearly correlated with acidity at acceptable conditions of absorber amount and size. The levels of P_CO2 at optimum ripening were different with absorber amount. However, highly gas permeable microporous spunbonded film (Tyvek) sachet did not show the linear relationship except a condition of 1.5 g of CO₂ absorbent. In large size package containing 2.0 kg, absorber sachets of LDPE and Tyvek could give the linear relationship between product acidity and package P_CO2 but at different levels (P_CO2 of package with LDPE sachet: 0.46~0.79 bar, P_CO2 of package with Tyvek sachet: 0.00~0.75 bar). The P_CO2 at optimal ripening was found to be less variable with LDPE sachets than with Tyvek ones. Use of package CO₂ concentration as an indicator of kimchi ripening was shown to be possible on the limited conditions where the linear relationship between them is established or confirmed.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.26 no.2
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• pp.105-112
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• 2020

As sprout vegetables of interest growing, its maintaining the quality of the technology was needed to solve the problem of increasing growth and maintain quality after harvest. This experiment proved that the quality of radish sprout vegetable was affected by CO₂ treatment during cultivation. Thus, the effect of CO₂ treatment during cultivation on postharvest quality of radish sprout vegetable was investigated in terms of the quality changes in weight loss, gas partial pressure, SPAD, hue angle external appearance during storage at polypropylene film (thickness 30 ㎛) at 10℃. CO₂ treatment used the way to gas with 700 ppm or carbonated water with 700 ppm and 1,400 ppm. The study revealed that growths on CO₂ treated plant were more than those of non-treatment on stem length. After harvesting, the CO₂ treated plant and control growing little different characteristics on fresh weight, plant length and so on. However, there were no differences between the CO₂ treated plant and control on the Fv/Fm and SOD (superoxide dismutase). In gas partial pressure, the O₂ consumption and CO₂ accumulation of the CO₂ treated plant tended to be more than that of non-treated plant. This study also checked that after packaging, the effects of CO₂ treatment during cultivation on the quality of radish sprout vegetable was not significant. However, there were tended to CO₂ treatments were lower value compared to control on SPAD, hue angle and general appearance. CO₂ treatments of radish sprouting vegetable before harvest were improve growth of stem length, but ones were not improving the maintain of quality on radish sprout vegetable during shelf-life period. The results indicated that CO₂ treatment only affected stem elongation until radish sprout vegetable its growth.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.77-83
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• 2023

Energy consumption is increased by rapid industrialization. As a result, climate change is accelerating due to the increase in CO₂ concentration in the atmosphere. Therefore, a shift in the energy paradigm is required. Hydrogen is in the spotlight as a part of that. Currently 95% of hydrogen is fossil fuel-based reforming hydrogen which is accompanied by CO₂ emissions. This is called gray hydrogen, if the CO₂ is captured and emission of CO₂ is reduced, it can be converted into blue hydrogen. There are 3 technologies to capture CO₂: absorption, adsorption and membrane technology. In order to select CO₂ capture technology, the analysis of the exhaust gas should be carried out. The concentration of CO₂ in the flue gas from the hydrogen production process is higher than 20%if water is removed as well as the emission scale is classified as small and medium. So, the application of the membrane technology is more advantageous than the absorption. In addition, if LNG cold energy can be used for low temperature CO₂ capture system, the CO₂/N₂ selectivity of the membrane is higher than room temperature CO₂ capture and enabling an efficient CO₂ capture process. In this study, we will analyze the flue gas from hydrogen production process and discuss suitable CO₂ capture technology for it.

• Corrosion Science and Technology
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• v.22 no.2
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• pp.90-98
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• 2023

In this study, cobalt oxide (Co₃O₄) and cobalt-doped magnetite (CoFe₂O₄) nanoparticles were synthesized by a hydrothermal method. They were then used as corrosion inhibitors for corrosion protection of AA2024-T3 aluminum alloys. These obtained nanoparticles were characterized by x-ray diffraction, field-emission scanning electron microscopy, and Zeta potential measurements. Corrosion inhibition activities of Co₃O₄ and CoFe₂O₄ nanoparticles were determined by performing electrochemical measurements for bare AA2024-T3 aluminum alloys in 0.05 M NaCl + 0.1 M Na₂SO₄ solution containing Co₃O₄ or CoFe₂O₄ nanoparticles. Corrosion protection for AA2024-T3 aluminum alloys by a water-based epoxy with or without the synthesized Co₃O₄ or CoFe₂O₄ nanoparticles was investigated by electrochemical impedance spectroscopy during immersion in 0.1 M NaCl solution. The corrosion protection of epoxy coating deposited on the AA2024-T3 surface was improved by incorporating Co₃O₄ or CoFe₂O₄ nanoparticles in the coating. The corrosion protection performance of the epoxy coating containing CoFe₂O₄ was higher than that of the epoxy coating containing Co₃O₄.

• Membrane Journal
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• v.33 no.1
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• pp.23-33
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• 2023

In this study, a mixed matrix membrane was prepared by varying the contents of PEI-GO@ZIF-8 synthesized in PEBAX 2533, and the permeation characteristics of N₂ and CO₂ were studied. The N₂ permeability of the PEBAX/PEIGO@ZIF-8 mixed matrix membrane decreased as the PEI-GO@ZIF-8 content increased, and the CO₂ permeability showed different trends depending on the PEI-GO@ZIF-8 content. The CO₂ permeability increased in pure PEBAX membrane up to PEBAX/PEI-GO@ZIF-8 0.1 wt%, but decreased at the subsequent content. The PEI-GO@ZIF-8 0.1 wt% mixed matrix membrane had a CO₂ permeability of 221.9 Barrer and a CO₂/N₂ selectivity of 60.0, showing the highest permeation properties with improved CO₂ permeability and CO₂/N₂ selectivity among the prepared mixed matrix membrane and we obtained a result that reached the Robeson upper-bound. This is due to the -COOH, -O-, and -OH functional groups of GO and the amine group bonded to PEI, which interact friendly with CO₂, and the effect of ZIF-8, which causes gate-opening for CO₂ while the fillers are evenly dispersed in PEBAX.

• Membrane Journal
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• v.30 no.4
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• pp.269-275
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• 2020

In this study, CO₂ separation experiment was performed on a CH₄/CO₂ mixed gas using a ceramic hollow fiber membrane contactor (HFMC). In order to fabricate high-performance HFMC, experiments were conducted to manufacture high-permeability hollow fiber membranes, and the prepared hollow fiber membranes were evaluated through N₂ gas permeation experiments. HFMC for CH₄/CO₂ mixed gas separation was manufactured using the manufactured high-permeability hollow fiber membrane. In the experiment, mixed gas of CH₄/CO₂ (34.5% CO₂, CH₄ balance) and monoetanolamine (MEA) was used, and the effect of CO₂ removal efficiency on the flow rate of the absorbent was evaluated. The CO₂ removal efficiency increased as the liquid flow rate increased, and the CO₂ absorption flux also increased with the liquid flow rate.

• Journal of Soil and Groundwater Environment
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• v.21 no.1
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• pp.49-60
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• 2016

Distribution and behavior of baseline soil CO₂ were investigated in a candidate geologic CO₂ storage site in Pohang, with measuring CO₂ concentrations and carbon isotopes in the vadose zone as well as CO₂ fluxes and concentrations through ground surface. This investigation aimed to assess the baseline CO₂ levels and to build the CO₂ monitoring system before injecting CO₂. The gas in the vadose zone was collected using a peristaltic pump from the depth of 60 cm below ground surface, and stored at gas bags. Then the gas components (CO₂, O₂, N₂, CH₄) and δ¹³C_CO2 were analyzed using GC and CRDS (cavity ringdown spectroscopy) respectively in laboratory. CO₂ fluxes and CO₂ concentrations through ground surface were measured using Li-COR in field. In result, the median of the CO₂ concentrations in the vadose zone was about 3,000 ppm, and the δ¹³C_CO2 were in the wide range between −36.9‰ and −10.6‰. The results imply that the fate of CO₂ in the vadose zone was affected by soil property and vegetations. CO₂ in sandy or loamy soils originated from the respiration of microorganisms and the decomposition of C₃ plants. In gravel areas, the CO₂ concentrations decreased while the δ¹³C_CO2 increased because of the mixing with the atmospheric gas. In addition, the relation between O₂ and CO₂, N₂, and the relation between N₂/O₂ and CO₂ implied that the gases in the vadose zone dissolved in the infiltrating precipitation or the soil moisture. The median CO₂ flux through ground surface was 2.9 g/m²/d which is lower than the reported soil CO₂ fluxes in areas with temperate climates. CO₂ fluxes measured in sandy and loamy soil areas were higher (median 5.2 g/m²/d) than those in gravel areas (2.6 g/m²/d). The relationships between CO₂ fluxes and concentrations suggested that the transport of CO₂ from the vadose zone to ground surface was dominated by diffusion in the study area. In gravel areas, the mixing with atmospheric gases was significant. Based on this study result, a soil monitoring procedure has been established for a candidate geologic CO₂ storage site. Also, this study result provides ideas for innovating soil monitoring technologies.

• Journal of the Korean Institute of Gas
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• v.26 no.4
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• pp.9-17
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• 2022

This paper is the continuation of our previous paper, which we refer to as numerical analysis of phase behavior and flow properties in an injection tubing during gas phase CO₂ injection. Our study in this paper show the results during supercritcal CO₂ injection under the same project. Geological CO₂ storage technology is one of the most effective method to decrease climate change due to high injectivity and storage capacity and economics. A demonstration-scale CO₂ storage project was performed in a deep aquifer in the Pohang basin, Korea for a technological development in a large-scale CO₂ storage project. A problem to consider in the early stage design of the project was to analyze CO₂ phase change and flow characteristics during CO₂ injection. To solve this problem, injection conditions were decided by calculating injection rate, pressure, temperature, and thermodynamic properties. For this research, we simulated and numerically analyzed CO₂ phase change from liquid to supercritical phase and flow characteristics in injection tubing using OLGA program. Our results provide discharge pressure and temperature conditions of CO₂ injection combined with a pressure of an aquifer.

• Journal of Bio-Environment Control
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• v.32 no.4
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• pp.416-422
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• 2023

This study was aimed to determine the changes in CO₂ concentration according to the temperatures of daytime and nighttime in the CO₂ supplemental greenhouse, and to compare calculated supplementary CO₂ concentration during winter and spring cultivation seasons. CO₂ concentrations in experimental greenhouses were analyzed by selecting representative days with different average temperatures due to differences in integrated solar radiation at the growth stage of leaf area index (LAI) 2.0 during the winter season of 2022 and 2023 years. The CO₂ concentration was 459, 299, 275, and 239 µmol·mol^-1, respectively at 1, 2, 3, and 4 p.m. after the CO₂ supplementary time (10:00-13:00) under the higher temperature (HT, > 18℃ daytime temp. avg. 31.7, 26.8, 23.8, and 22.4℃, respectively), while it was 500, 368, 366, 364 µmol·mol^-1, respectively under the lower temperature (LT, < 18℃ daytime temp. avg. 22.0, 18.9, 15.0, and 13.7℃, respectively), indicating the CO₂ reduction was significantly higher in the HT than that of LT. During the nighttime, the concentration of CO₂ gradually increased from 6 p.m. (346 µmol·mol^-1) to 3 a.m. (454 µmol·mol^-1) in the HT with a rate of 11 µmol·mol^-1 per hour (240 tomatoes, leaf area 330m²), while the increase was very lesser under the LT. During the spring season, the CO₂ concentration measured just before the start of CO₂ fertilization (7:30 a.m.) in the CO₂ enrichment greenhouse was 3-4 times higher in the HT (>15℃ nighttime temperature avg.) than that of LT (< 15℃ nighttime temperature avg.), and the calculated amount of CO₂ fertilization on the day was also lower in HT. All the integrated results indicate that CO₂ concentrations during the nighttime varies depending on the temperature, and the increased CO₂ is a major source of CO₂ for photosynthesis after sunrise, and it is necessary to develop a model formula for CO₂ supplement considering the nighttime CO₂ concentration.

• Journal of the Microelectronics and Packaging Society
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• v.31 no.2
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• pp.78-84
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• 2024

The electrochemical reduction of carbon dioxide (CO₂) is gaining attention as an effective method for converting CO₂ into high-value carbon compounds. This paper reports a facile meth od for synth esizing and characterizing g-C₃N₄-modified porous Au (pAu) electrodes for electrochemical CO₂ reduction using e-beam deposition and anodization techniques. The fabricated pAu@g-C₃N₄ electrode (@ -0.9 VRHE) demonstrated superior electrochemical performance compared to the pAu electrode. Both electrodes exhibited a Faradaic efficiency (FE) of 100% for CO production. The pAu@g-C₃N₄ electrode achieved a maximum CO production rate of 9.94 mg/s, which is up to 2.2 times higher than that of the pAu electrode. This study provides an economical and sustainable approach to addressing climate change caused by CO₂ emissions and significantly contributes to the development of electrodes for electrochemical CO₂ reduction.