• Title/Summary/Keyword: CO/CO2 ratio

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Characteristics of Dissimilar CO2 Laser Welding for High Mn Steel and Low Carbon Steel (고Mn강과 저탄소강의 CO2 레이저 이종용접 특성)

  • Jeong, Bo-Young;Han, Tae-Kyo
    • Journal of Welding and Joining
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    • v.28 no.3
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    • pp.36-41
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    • 2010
  • High Mn steel has been developed for automotive applications since the steel has an excellent combination of strength and ductility. However, from the viewpoint of welding, high Mn steel has a few problems related to its chemical composition. This paper describes characteristics of dissimilar $CO_2$ laser welding for expanding application of high Mn steel. From this work it was cleared that dissimilar laser welded joint between high Mn steel and carbon steel had poor formability due to the formation of martensite within weld metal. In order to improve ductility of welded joint, the method of controlling the dilution ratio of high Mn steel was suggested.

Distribution Behavior of Ni between CaO-SiO2-Al2O3-MgO Slag and Cu-Ni Alloy (CaO-SiO2-Al2O3-MgO 슬래그와 Cu-Ni합금 사이의 Ni 분배거동)

  • Han, Bo-Ram;Sohn, Ho-Sang
    • Resources Recycling
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    • v.24 no.1
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    • pp.35-42
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    • 2015
  • To obtain the fundamental information on the dissolution of nickel into the slag in the pyrometallurgical processes for treatment of wasted PCB, the distribution ratios of nickel between CaO-$SiO_2-Al_2O_3$-MgO slag and copper-5 wt%Ni alloy were measured at 1623 K to 1823 K under a controlled $CO_2$-CO atmosphere. The distribution ratio of Ni increased linearly with increasing oxygen partial pressure. Therefore, the dissolution reaction of nickel into the slags could be described by the following equation; $$Ni(l)_{metal}+\frac{1}{2}O_2(g)NiO(l)_{slag}$$ The distribution ratio of Ni increased linearly with increasing content of basic oxides(CaO and MgO) in slag. However, the distribution ratio of Ni decreased linearly with increasing temperature. From these results, the empirical equation of distribution ratio of Ni was obtained by the following equation from the analysis of experimental conditions by multiple regression. $${\log}L_{Ni}=0.4000{\log}P_{O2}-5.1{\times}10^{-4}T+0.3375\(\frac{X_{CaO}+X_{MgO}}{X_{SiO2}}\)$$

Characteristics of PM10, PM2.5 and CO2 Concentration in Public Transportations and Development of Control Technology (대중교통수단에서 PM10, PM2.5 및 CO2의 농도 현황과 저감기술 개발에 관한 연구)

  • Park, Duck Shin;Kwon, Soon Bark;Cho, Young Min;Jang, Seong Ki;Jeon, Jae Sik;Park, Eun Young
    • Particle and aerosol research
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    • v.6 no.1
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    • pp.9-20
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    • 2010
  • This study examined the concentration level of the major air pollutants in public transportation. The study was conducted between February 2009 and March 2008 at Suwon-Yeosu line in Korea. $PM_{10}$ concentration level was $100{\mu}g/m^3$ on average. The $PM_{2.5}$ to PM10 ratio in transport is 0.37, which was lower than the results published by other researches. The result also demonstrated that outdoor $PM_{10}$ concentration was about 56~60% level compared to that of the cabin. $CO_2$ concentration level in the cabin was 1,359ppm, which does not exceed 2,000ppm, which is the guideline concentration level according to the Ministry of Environment. $CO_2$ concentration level in the cabin was $CO_2=23.4{\times}N+460.2$, and about 23.4ppm in $CO_2$ concentration level increased every time one passenger was added on. The experiment conducted on the train demonstrated that the average $PM_{10}$ concentration level was $100{\mu}g/m^3$ in case of the reference cabin while average $PM_{10}$ concentration level of the modified vehicle was $68{\mu}g/m^3$. Likewise, effect of the particle reduction device for the reduction of $PM_{10}$ concentration level was approximately 21%. Meanwhile there was almost no difference in the concentration level between reference and modified cabin in case of $PM_{2.5}$. Using zeolite as an adsorbent was made to reduce the $CO_2$ concentration level in the cabin. Number of passengers was factored in, to calculate the effect of the adsorption device, which demonstrated that about 36% of $CO_2$ concentration level was reduced in the modified cabin effect of the $CO_2$ reduction device. This research analyzed the current status concerning the quality of air in the public transportation and technologies were developed that reduces major air pollutants.

Microstructural and Wear Properties of WC-based and Cr3C2-based Cermet Coating Materials Manufactured with High Velocity Oxygen Fuel Process (고속 화염 용사 공정으로 제조된 WC계 및 Cr3C2계 Cermet 코팅 소재의 미세조직 및 마모 특성)

  • Kang, Yeon-Ji;Ham, Gi-Su;Kim, Hyung-Jun;Yoon, Sang-Hoon;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.408-414
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    • 2018
  • This study investigates the microstructure and wear properties of cermet (ceramic + metal) coating materials manufactured using high velocity oxygen fuel (HVOF) process. Three types of HVOF coating layers are formed by depositing WC-12Co, WC-20Cr-7Ni, and Cr3C2-20NiCr (wt.%) powders on S45C steel substrate. The porosities of the coating layers are $1{\pm}0.5%$ for all three specimens. Microstructural analysis confirms the formation of second carbide phases of $W_2C$, $Co_6W_6C$, and $Cr_7C_3$ owing to decarburizing of WC phases on WC-based coating layers. In the case of WC-12Co coating, which has a high ratio of $W_2C$ phase with high brittleness, the interface property between the carbide and the metal binder slightly decreases. In the $Cr_3C_2-20CrNi$ coating layer, decarburizing almost does not occur, but fine cavities exist between the splats. The wear loss occurs in the descending order of $Cr_3C_2-20NiCr$, WC-12Co, and WC-20Cr-7Ni, where WC-20Cr-7Ni achieves the highest wear resistance property. It can be inferred that the ratio of the carbide and the binding properties between carbide-binder and binder-binder in a cermet coating material manufactured with HVOF as the primary factors determine the wear properties of the cermet coating material.

Advanced Cell Structure for High Contrast Ratio in Charge Share S-PVA Monitors

  • Kim, Su-Jeong;Kim, Kwang-Hyun;Jung, Ji-Yoon;Heo, Jeong-Uk;Lee, Nam-Seok;Kim, Kyeong-Hyeon;Kim, Sang-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.288-291
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    • 2008
  • This paper describes a new S-PVA cell structure which achieves enhanced contrast ratio by adopting a step-like patterned common electrode between the high sub-pixel and low sub-pixel electrodes without loss of transmittance. A 24-inch panel was developed for monitor applications and measured contrast ratio and white luminance were over 2500:1 and 400cd/m2, respectively.

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Effects of elevated CO2 concentration and increased temperature on leaf related-physiological responses of Phytolacca insularis (native species) and Phytolacca americana (invasive species)

  • Kim, Hae-Ran;You, Young-Han
    • Journal of Ecology and Environment
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    • v.33 no.3
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    • pp.195-204
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    • 2010
  • In the study, the effects of elevated $CO_2$ and temperature on the photosynthetic characteristics, chlorophyll content, nitrogen content, carbon content, and C/N ratio of Phytolacca insularis and Phytolacca americana were examined under control (ambient $CO_2+$ ambient temperature) and treatment (elevated $CO_2+$ elevated temperature) for 2 years (2008 and 2009). The photosynthetic rate, transpiration rate and water use efficiency of two plant species were higher under the treatment than the under the control. The stomatal conductance of P. insularis was higher under the control, but that of P. americana was not significantly affected by $CO_2$ and temperature under the treatment. The chlorophyll contents of two species were decreased about 72.5% and 20%, respectively, by elevated $CO_2$ and temperature. The nitrogen contents of two species were not significantly altered by increase in $CO_2$ and temperature. The carbon contents of the two species were higher under the treatment than under the control. The C/N ratio of P. insularis was higher under the treatment but that of P. americana was not significantly affected by $CO_2$ and temperature. These results demonstrated that the physiological responses of P. insularis native plants might be more sensitively influenced by a $CO_2$-mediated global warming situation than those of the P. americana invasive plants.

Effect on the Formation of Fe3O4 with Ferrous Sulfate/Ferric Sulfate Molar Ratio (Fe3O4 생성에 미치는 황산제일철/황산제이철 몰비의 영향)

  • Eom, Tae-Hyoung;Tuan, Huynh Thanh;Kim, Sam-Joong;An, Suk-Jin;Oh, Kyoung-Hwan;Suhr, Dong-Soo
    • Korean Journal of Materials Research
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    • v.21 no.4
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    • pp.225-231
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    • 2011
  • The effect of ferrous/ferric molar ratio on the formation of nano-sized magnetite particles was investigated by a co-precipitation method. Ferrous sulfate and ferric sulfate were used as iron sources and sodium hydroxide was used as a precipitant. In this experiment, the variables were the ferrous/ferric molar ratio (1.0, 1.25, 2.5 and 5.0) and the equivalent ratio (0.10, 0.25, 0.50, 0.75, 1.0, 2.0 and 3.0), while the reaction temperature ($25^{\circ}C$) and reaction time (30 min.) were fixed. Argon gas was flowed during the reactions to prevent the $Fe^{2+}$ from oxidizing in the air. Single-phase magnetite was synthesized when the equivalent ratio was above 2.0 with the ferrous/ferric molar ratios. However, goethite and magnetite were synthesized when the equivalent ratio was 1.0. The crystallinity of magnetite increased as the equivalent ratio increased up to 3.0. The crystallite size (5.6 to 11.6 nm), median particle size (15.4 to 19.5 nm), and saturation magnetization (43 to 71 $emu.g^{-1}$) changed depending on the ferrous/ferric molar ratio. The highest saturation magnetization (71 $emu.g^{-1}$) was obtained when the equivalent ratio was 3.0 and the ferrous/ferric molar ratio was 2.5.

A Prediction on the Flammability Limits of Biodiesel Fuel in the High Temperature and Pressure Conditions (고온·고압 조건에서 바이오디젤의 가연한계 예측)

  • Lim, Young Chan;Jung, Jun Woo;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.24 no.4
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    • pp.157-162
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    • 2019
  • This numerical study was analyzed to predict the flammability limits of biodiesel and diesel fuels in the high temperature and pressure conditions. To achieve this, the biodiesel fuel was simulated with the chemical species of n-heptane (n-C7H16), methyl decanoate (C11H22O2), and methyl-9-decenoate (C11H20O2), and the diesel fuel was substituted the chemical species of n-heptane. The closed 0-D homogeneous reactor model which was employed the 1100 K of ambient temperature and 35 atm of ambient pressure was used for the simulation of constant volume combustion, and the equivalence ratio was changed from 0.3 to 2.5 conditions. In addition, a comparative analysis study was conducted with the results of HCCI engine simulation and flammability limits according to the changes of equivalence ratio. The results of combustion temperature, pressure, and ignition delay were increased when the equivalence ratio elevated from 0.3 to 1.3 conditions because the increase in fuel oxidation rate affects the chemical reaction of the overall combustion process. Furthermore, the CO and NOX production under the rich combustion conditions are considered to have a trade off relationship since the OH radicals and O2 chemical species are greatly affected the CO and NOX production and oxidation processes.

Low Grade Coal-CO2 Catalytic Gasification Reaction for CO gas Synthesis (CO 합성을 위한 저급석탄-CO2 촉매 가스화 반응)

  • Lee, Ho Yong;Lee, Jong Dae
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.3
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    • pp.466-473
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    • 2016
  • In this study, the experiments on optimal CO gas synthesis were conducted using low grade coal-$CO_2$ catalyst gasification reaction. The characteristics of generated CO gas were investigated using the chemical activation method of KOH, $K_2CO_3$, $Na_2CO_3$ catalysts with Kideco and Shewha coal. The preparation process has been optimized through the analysis of experimental variables such as ratio between activating chemical agents and coal, the flow rate of gas and reaction temperature during $CO_2$ conversion reaction. The produced CO gas was analysed by Gas Chromatography (GC). The 98.6% $CO_2$ conversion for Kideco coal mixed with 20 wt% $Na_2CO_3$ and 98.9% $CO_2$ conversion for Shenhua coal mixed with 20 wt% KOH were obtained at the conditions of $T=950^{\circ}C$ and $CO_2$ flow rate of 100 cc/min. Also, the low grade coal-$CO_2$ catalytic gasification reaction showed the CO selectivities(97.8 and 98.8 %) at the same feed ratio and reaction conditions.

Development of Microwave-Matrix Reformer for Applying SOFC Stack (SOFC 스택 적용 마이크로웨이브-매트릭스 개질기 개발)

  • AN, JUNE;CHUN, YOUNG NAM
    • Journal of Hydrogen and New Energy
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    • v.32 no.6
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    • pp.534-541
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    • 2021
  • In this study, a novel microwave-matrix reformer was proposed to convert CH4, which is a major component, to a high quality hydrogen energy. And to identify this performance, it was investigated for O2/C ratio, steam feed amount and reformed gas recirculation which are affected for methane conversion and product gas yield. Through the parametric screening studies, optimal operating conditions were that O2/C ratio, steam feed amount and recirculation rate were 1.1, 10 mL/min and 30 L/min. In this conditions, CH4 conversion was 68.1%, H2 selectivity 77.2 and H2/CO ratio 2.62 which are possible applying SOFC stack for RPG (residential power generator).