• Title/Summary/Keyword: CN-85

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Measurement of Detection Efficiency of Plastic Track Detector to ${\alpha}-particle$ (고체비적검출기의 알파선 검출효율 측정에 관한 연구)

  • Park, Young-Woong;Yang, Hyun-Soo
    • Journal of Radiation Protection and Research
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    • v.21 no.3
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    • pp.167-173
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    • 1996
  • The calibration method for the detection efficiency of solid state track detector to alpha is presented, and the detection efficiency of CN-85 and LEXAN to alpha is measured by this method. The results are 97% and 57% in CN-85 and LEXAN, respectively. The reason for a better result in CN-85 in not only the high sensitivity but also the low energy dependency with comparing for LEXAN. The peak detection efficiency is 3MeV and 1.8MeV in CN-85 and LEXAN, respectively.

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Detection of Alpha Tracks of Boron by Nuclear Reaction with Neutron (중성자 핵반응에 의한 보론의 알파트랙 검출)

  • Sohn, Se Chul;Pyo, Hyung Yeal;Park, Yong Jun;Jee, Kwang Yong;Kim, Won Ho
    • Analytical Science and Technology
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    • v.17 no.1
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    • pp.8-15
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    • 2004
  • The detection efficiencies of the several solid track detectors were investigated for the determination of boron content in aqueous solution by using the alpha muti-Radioisotope(RI) source. Polycarbonate (Lexan and CR-39) and cellulose nitrate (CN-85 and LR-115) were selected as materials for alpha track detection of boron. Alpha muti-RI source, uranium metal particles and boron standard solution were used for alpha emission. In this study, four solid track detectors(CN-85, LR-115, Lexan and CR-39) were characterized under various etching conditions as well as neutron irradiation conditions. As a result, the CN-85 was turned out to be best to provide good efficiency among the four detectors. The selected solid track detector was utilized for the determination of trace amount of boron in aqueous sample and its results were discussed in the text.

Improving Initial Abstraction Method of NRCS-CN for Estimating Effective Rainfall (유효우량 산정을 위한 NRCS-CN 모형의 초기손실량 산정방법 개선)

  • Park, Dong-Hyeok;Ajmal, Muhammad;Ahn, Jae-Hyun;Kim, Tae-Woong
    • Journal of Korea Water Resources Association
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    • v.48 no.6
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    • pp.491-500
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    • 2015
  • In order to improve the runoff estimation accuracy of the Natural Resources Conservation Service (NRCS) curve number (CN) model, this study incorporated rainfall and maximum potential retention as contributors for initial abstraction. The modification was proposed based on 658 rank-order data of rainfall and subsequent runoff from 15 watersheds. The NRCS-CN model (M1), one of its inspired modified model (M2), and the proposed model (M3) were analyzed employing different CN approaches. Using tabulated, calculated and least squares fitted CNs ($CN_T$, $CN_C$, $CN_{LSF}$, respectively), the models' performances were evaluated based on Root Mean Square Error (RMSE), Nash-Sutcliffe Efficiency (NSE), and Percent Bias (PBIAS). Applications of model M1, M2, and M3, respectively exhibited watershed cumulative mean [RMSE (23.60, 18.12, 16.04), NSE (0.54, 0.73, 0.79), and PBIAS (36.54, 20.25, 12.00)]. Similarly, using CNC (for M1 and M2 model) and $CN_{LSF}$ (for M3 model), the performance of three models respectively were assessed based on watershed cumulative mean [RMSE (17.17, 15.88, 13.82), NSE (0.76, 0.80, 0.85), and PBIAS (3.06, 4.47, 0.11)]. The proposed model (M3) that linked all of the NRCS-CN variants showed more statistically significant agreement between the observed and estimated data.

A Study on the Hydrocarbon Dew Point Prediction by the Compositions of the Fuel Gas Mixtures (연료용 혼합가스 조성에 따른 탄화수소 이슬점 예측)

  • Kim, Young-Gu;Choi, Seul-Gi;Ahn, Jung-Jin;Lee, Chang-Eon
    • Journal of the Korean Institute of Gas
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    • v.19 no.3
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    • pp.44-48
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    • 2015
  • The equations of hydrocarbon dew points(DT) of the fuel gas mixtures have been derived using the multiple regression analysis. In QSDR(Quantitative Structure Dew-point Relationship), the principal descriptors are CN(average carbon number) and BI(the ratio of the branched isomers). QSDRs studied by changing the pressures of the fuel gas mixtures in the range of 100 kPa ~ 500 kPa are as follows; $$DT(^{\circ}C)=-683.1+1224.98CN-898.01CN^2+308.58CN^3-49.56CN^4+3.02CN^5-12.42BI$$ (at 100 kPa, $$R_{adj}{^2}=0.99$$) (1) $$DT(^{\circ}C)=-745.2+1351.66CN-978.1CN^2+332.7CN^3-52.96CN^4+3.20CN^5-12.84BI$$ (at 200 kPa, $$R_{adj}{^2}=0.99$$) (2) $$DT(^{\circ}C)=-795.4+1457.1CN-1051.1CN^2+357.53CN^3-57.07CN^4+3.46CN^5-13.10BI$$ (at 300 kPa, $$R_{adj}{^2}=0.99$$) (3) $$DT(^{\circ}C)=-868.1+1608.4CN-1156.0CN^2+393.38CN^3-63.06CN^4+3.85CN^5-13.39BI$$ (at 500 kPa, $$R_{adj}{^2}=0.99$$) (4) As the average carbon numbers in the mixed fuel being reduced or the ratio of the branched isomers having a boiling point lower increase, The hydrocarbon dew point becomes lower, The differences between the hydrocarbon-dew points determined by the multiple regression and those calculated by the commercial program, VMGSim are negligible.

Estimating SCS-Curve Numbers of Paddy Fields in Yeongsan and Seomjin River Basins (영산강.섬진강 수계의 논 유출곡선지수(SCS-Curve Number)산정)

  • Jung, Jae-Woon;Yoon, Kwang-Sik;Choi, Woo-Jung;Choi, Woo-Young;Choi, Jin-Kyu;Kim, Young-Ju;Lee, Soo-Hyung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.775-780
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    • 2008
  • 유출곡선지수(SCS-CN)를 사용하는 유역수문모형의 정확도를 향상시키기 위해서는 토지이용별 유출곡선지수가 잘 정의되어야한다. 하지만 논의 경우에는 유출곡선지수가 잘 정의되어 있지않다. 현재까지 연구된 논 CN number로는 경기지역의 조건을 반영한다. 본 연구에서는 영산강 수계와 섬진강 수계에 대한 논의 CN값을 추정하기위해 수문모니터링을 실시하였다. 시험지구는 영산강 수계 내에 위치한 전라남도 함평군 엄다면 화양리 학야지구와 섬진강 수계 내에 위치한 전라북도 순창군 적성면 고원리 적성지구로 2004년부터 2007년 영농기(5월$\sim$9월)동안 모니터링을 실시하였다. 두 시험지구에서 각각 강우량과 유출량을 조사하여 강우-유출 관계식을 유도하여 CN값을 산정하였다. 그 결과 CN-I, CN-II, CN-III 값은 학야지구에서 각각 65, 85, 94로 나타났고, 적성지구에서 각각 69, 89, 97로 나타났다. 이는 기존의 연구와 비교하여 CN-II값이 더 높은 것으로 나타났다.

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Characteristics of Electrolytic Treatment for Chromium and Cyanide containing Wastewater (크롬과 시안이 공존하는 폐수의 전해처리 특성)

  • 정일현;윤용수
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.85-92
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    • 1998
  • In this study, the electrolytic treatment by one-stage electrolysis was investigated for electroplating wastewater containing $Cr^{6+}$ and $CN^{-}$. From the results, we concluded as follows : Optimum initial pH of wastewater was pH : 3. Amount of optimum addition of electroltyte(NaCl) was 0.1 wt%. Optimum potential for electrolysis was 5 volt. Concentration and removal efficiency for $Cr^{6+}$ and $CN^{-}$ were under 1 mg/L and above 99% at optimum conditions. And the feasibility of electrolytic treatment for electroplating wastewater containing $Cr^{6+}$ and $CN^{-}$ was certified.

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Selective Deprotonation and Decarbonylation from Hydridocarbonyl-iridium(III) Compounds with Trimethylamine N-oxide

  • 천청식;오문현;원경식;조해연;신동찬
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.85-88
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    • 1999
  • Me3NO selectively abstracts the proton from [IrH(CO)(PPh3)2L(A)]0.1+,2+ (1) (A: -CCPh, Cl-, CH3CN and L: CH3CN, Cl-, C1O4-) to give the trans-elimination products, Ir(CO)(PPh3)2(A) (2). The reductive elimination of H+ and Cl- from Ir(H)Cl2(CO)(PPh3)2 (lb) to give IrCl(CO)(PPh3)2 (2b) is first order in both lb and Me3NO. The rate law d[2b]/dt=kobs[lb]=k2[lb][Me3NO] suggests the formation of (PPh3)2(CI)2(CO)Ir-H-ON+Me3 in the rate determining step (k2) followed by the fast dissociation of both H-ON+Me3 and the trans ligand Cl-. The rate significantly varies with the cis liaand A and the trans ligand L and is slower with both A and L being Cl- than other ligands. Me3NO selectively eliminates CO from [Ir(H)2(CO)(PPh3)2L]0,+ (3) (L=CH3CN, C1O4-) to produce [Ir(H)2(PPh3)2L'(CH3CN)]+ (4) (L'=CH3CN, PPh3) in the presence of L. Me3NO does not readily remove either H+ or CO from cis, trans- and trans, trans-lr(H)(-CCPh)2(CO)(PPh3)2 and cis, trans-Ir(H)2Cl(CO)(PPh3)2. The choice whether hydridocarbonyls, 1 and 3 undergo the deprotonation or decarbonylation may be understood mostly in terms of thermodynamic stability of the products and partly by kinetic preference of Me3NO on proton and CO.

Grain Refinement and Mechanical Properties of AM60 Mg Alloy by $CaCN_2$ Addition (Ca$CN_2$ 첨가에 의한 AM60 마그네슘 합금의 결정립 미세화 및 기계적 성질)

  • Eom, Jeong-Pil;Jeong, Seong-Kyu;Lim, Su-Geun;Shin, Hee-Taek;Jeong, Deuk-Soo
    • Journal of Korea Foundry Society
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    • v.18 no.4
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    • pp.383-388
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    • 1998
  • Effects of $CaCN_2$ addition on the grain refinement in the AM60 magnesium ingots were investigated. The effects of the $CaCN_2$ are estimated with different inoculation temperatures, inoculation contents, and holding time to find out the optimum condition. AM60 alloy was melted in the low carbon steel crucible by cylindrical electric furnace under an argon atmosphere. The melting and casting apparatus is specially designed for magnesium alloys. The grain size of AM60 magnesium alloy decreased significantly with an increase in $CaCN_2$ content and, at 0.8 wt% $CaCN_2$ or more, grain size becomes constant at about $85 {\mu}m$. The optimum condition was obtained in the 0.8 wt% $CaCN_2$ for holding molten metal of 30 min. at the temperature of $710^{\circ}C$. The tensile properties of AM60 magnesium alloys were improved due to grain refinement by addition of $CaCN_2$. In the optimum condition, the yield strength, tensile strength and elongation were ${\sigma}_{0.2}=107 MPa$, ${\sigma}_{T.S}=234 MPa$ and e=14.2%. The variation of stress with strain obeyed the relationship of the ${\sigma}=K{\varepsilon}^n$. The strain-hardening exponent, n and strength coefficient, K obtained in the 0.8 wt% $CaCN_2$ added AM 60 magnesium alloy were n=0.21 and K=390 MPa.

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Estimation of Effective Rainfall Through Improving Initial Abstraction Method of NRCS-CN (NRCS-CN의 초기손실량 산정방법의 개선을 통한 유효우량 산정)

  • Park, Dong-Hyeok;Ajmal, Muhammad;Ahn, Jae-Hyun;Kim, Tae-Woong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.98-98
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    • 2015
  • 강우-유출 모형을 이용하여 직접유출량을 산정할 경우, 유역의 유효우량을 산정하기 위해 NRCS-CN(Natural Resources Conservation Service - curve number) 방법을 주로 사용한다. 그러나 NRCS-CN 방법은 초기손실량을 잠재보유수량의 20%로 가정하고 유효우량을 산정한다. 이는 초기손실량을 과대 추정하여 유효우량의 과소산정을 초래한다. 따라서 본 연구에서는 관측된 강우-유출사상을 바탕으로 초기손실량을 추정하는 방법을 보완하였다. 우리나라 홍수기 동안 강우-유출 자료를 확보한 15개의 유역에 대해 658개의 강우-유출사상에 대하여 NRCS-CN 방법을 기반으로, 초기손실량과 유효우량을 산정하고 이를 관측 직접유출량과 비교 분석하였다. 유효우량을 산정하는 방법으로는 NRCS-CN 방법(M1), NRCS-CN 방법에서 초기손실량계수를 감소시킨 방법(M2), 관측 강우-유출 관계를 바탕으로 본 연구에서 제안하는 방법(M3)을 적용하였다. 또한 USDA에서 제시하는 CN값(CNT)과 유역의 경사도를 고려하여 조정한 CN값(CNC)을 각 방법들에 적용하였다. 모형의 성과는 Root Mean Square Error (RMSE), Nash-Sutcliffe Efficiency (NSE), 그리고 Percent Bias (PBIAS) 등을 이용하여 평가되었다. 그 결과 CNT를 M1, M2, M3에 적용한 경우 각 유역에서 평균적으로 [RMSE(0.24, 18.12, and 16.04), NSE(0.54, 0.73, and 0.79), PBIAS(36.54, 20.25, and 12.00)]로 나타났으며. 이와 비슷하게 CNC를 M1, M2, M3에 적용하였을 경우의 각 유역에서 평균적으로 [RMSE(17.17, 15.88, and 13.82), NSE(0.76, 0.80, and 0.85), PBIAS(3.06, 4.47, and 0.11)]로 나타났다. 본 연구에서 제안된 M3방법을 사용하여 추정한 유효우량이 관측된 직접유출량과 통계학적으로 가장 가까운 값으로 나타났다.

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Separation and Purification of Angiotensin Converting Enzyme Inhibitory Peptides Derived from Goat's Milk Casein Hydrolysates

  • Lee, K.J.;Kim, S.B.;Ryu, J.S.;Shin, H.S.;Lim, J.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.5
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    • pp.741-746
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    • 2005
  • To investigate the basic information and the possibility of ACE-inhibitory peptides for antihypertension materials, goat's caisin (CN) was hydrolyzed by various proteolytic enzymes and ACE-inhibitory peptides were separated and purified. ACE-inhibition ratios of enzymatic hydrolysates of goat's CN and various characteristics of ACE-inhibitory peptides were determined. ACE-inhibition ratios of goat's CN hydrolysates were shown the highest with 87.84% by pepsin for 48 h. By Sephadex G-25 gel chromatograms, Fraction 3 from goat's CN hydrolysates by pepsin for 48 h was confirmed the highest ACE-inhibition activity. Fraction 3 g and Fraction 3 gh from peptic hydrolysates by RP-HPLC to first and second purification were the highest in ACE-inhibition activity, respectively. The most abundant amino acid was leucine (18.83%) in Fraction 3 gh of ACE-inhibitory peptides after second purification. Amino acid sequence analysis of Fraction 3 gh of ACE-inhibitory peptides was shown that the Ala-Tyr-Phe-Tyr, Pro-Tyr-Tyr and Tyr-Leu. IC$_{50}$ calibrated in peptic hydrolysates at 48 h, Fraction 3, Fraction 3 g and Fraction 3 gh from goat's CN hydrolysates by pepsin for 48 h were 29.89, 3.07, 1.85 and 0.87 g/ml, respectively. Based on the results of this experiment, goat's CN hydrolysates by pepsin were shown to have ACE-inhibitory activity.