• Journal of the Korean Mathematical Society
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• v.60 no.6
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• pp.1233-1254
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• 2023

We introduce two subclasses of abelian McCoy rings, so-called π-CN-rings and π-duo rings, and systematically study their fundamental characteristic properties accomplished with relationships among certain classical sorts of rings such as 2-primal rings, bounded rings etc. It is shown that a ring R is π-CN whenever every nilpotent element of index 2 in R is central. These rings naturally generalize the long-known class of CN-rings, introduced by Drazin [9]. It is proved that π-CN-rings are abelian, McCoy and 2-primal. We also show that, π-duo rings are strongly McCoy and abelian and also they are strongly right AB. If R is π-duo, then R[x] has property (A). If R is π-duo and it is either right weakly continuous or every prime ideal of R is maximal, then R has property (A). A π-duo ring R is left perfect if and only if R contains no infinite set of orthogonal idempotents and every left R-module has a maximal submodule. Our achieved results substantially improve many existing results.

• Korean Journal of Mathematics
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• v.21 no.1
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• pp.41-53
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• 2013

Antoine studied conditions which are connected to the question of Amitsur of whether or not a polynomial ring over a nil ring is nil, introducing the notion of nil-Armendariz rings. Hizem extended the nil-Armendariz property for polynomial rings onto power-series rings, say nil power-serieswise rings. In this paper, we introduce the notion of power-serieswise CN rings that is a generalization of nil power-serieswise Armendariz rings. Finally, we study the nil-Armendariz property for Ore extensions and skew power series rings.

• Bulletin of the Korean Chemical Society
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• v.7 no.3
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• pp.210-213
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• 1986

1,1-Dicyano-2-ethoxycyclobutane (1a) was prepared by [2 + 2] cycloaddition reaction of vinylidene cyanide with ethyl vinyl ether. 1,1-Dicyano-2-phenylcyclobutane (1b) was prepared by the reactions involving the reduction of cinnamyl alcohol, chlorination, cyanomethylation, bromination, and ring-closure reaction. Compound 1a was ring-opening polymerized with NaCN or n-butyllithium to give a low molecular weight polymer. The compound 1b however, failed to polymerize by either anionic or radical catalysts.

• Analytical Science and Technology
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• v.8 no.4
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• pp.649-654
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• 1995

The reactivity of superoxide ion($O{_2}^{-.}$) with halogenated substrates is investigated by cyclic voltammetry and rotated ring-disk electrode method in aprotic solvents. The more positive the reduction potential of the substituted nitrile, the more facile is nucleophilic displacement by $O{_2}^{-.}$. The reaction rates of halogenonitriles with $O{_2}^{-.}$ vary according to the leaving-group propensity of halide (Br>Cl>F). The relative reaction rates of other substituted nitriles are in the order of electron-withdrawing propensity of the substituent group (CN> $C(O)NH_2$ >Ph, $CH_2CN$). The reaction of $O{_2}^{-.}$ with dihalocarbons indicates that five-membered rings can be rapidly formed by the cyclization of substrate and $O{_2}^{-.}$, and the relative rates of cyclization depend on the number of methylenic carbons {$Br(CH_2)_nBr$, [n=1<2<3>4>5]}. Mechanisms are proposed for the reaction of $O{_2}^{-.}$ with halogenated substrates.

• Bulletin of the Korean Chemical Society
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• v.16 no.6
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• pp.528-533
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• 1995

Metallic iridium and rhodium powders prepared from the reactions of [M(COD)(PhCN)2]ClO4 (M=Ir(1), Rh(2); COD=1,5-cyclooctadiene) with hydrogen at room temperature in methylene chloride show catalytic activities for hydrogenation of arenes at room temperature under atmospheric pressure of hydrogen. Most substituents (CH3, COOH, NO2, CH2OH, CHO, OPh, OCH3, C=C, halogens and CH2Cl) on aromatic ring suppress the rate of the hydrogenation of the aromatic ring while the aromatic ring hydrogenation of phenol and 1,4-dihydroxobenzene is faster than that of benzene over these metallic powders. Hydrogenation of benzoic acid occurs only at the aromatic ring leaving the COOH group intact over iridium metal powders while benzoic acid is not hydrogenated at all over rhodium metal powders. Carbonyl, nitro, acetylenic and olefinic groups on an aromatic ring are hydrogenated prior to the aromatic ring hydrogenation. Hydrogenolysis of OH groups of phenol, benzyl alcohol and 1,4-dihydroxobenzene, and hydrodehalogenation of halobenzenes, benzyl halides and cinnamyl chloride also occur along with the hydrogenation of aromatic ring.

• Journal of the Korean Chemical Society
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• v.28 no.6
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• pp.384-392
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• 1984

Reaction of the Fe(II) complex of a fully saturated tetradentate macrocyclic ligand [Fe([14]aneN$_4)(CH_3CN)_2]^{2+}$, where [14]ane$N_4$ represents 1,4,8,11-tetraazacyclotetradecane, with $O_2$ has been investigated in acetonitrile solutions. [Fe([14]aneN$_4)(CH_3CN)_2]^{2+}$ reacts with oxygen to yield low spin Fe(III) species, [Fe([14]aneN$_4)(CH_3CN)_2]^{3+}$, which undergoes metal ion assisted oxidative dehydrogenation of the macrocyclic ligand to produce low spin Fe(II) complex, [Fe([14]tetraeneN$_4)(CH_3CN)_2]^{2+}$. The macrocyclic ligand in [Fe([14]tetraeneN$_4)(CH_3CN)_2]^{2+}$ is highly unsaturated and its double bonds are conjugated. [Fe([14]dieneN$_4)(CH_3CN)_2]^{2+}$ and [Fe([14]dieneN$_4)(CH_3CN)_2]^{3+}$ are isolated as the intermediates of the reaction. The Fe(II) complexes involved in this oxidative dehydrogenation reaction react with carbon monoxide to give respective carbon monoxide derivatives, [FeL$(CH_3CN)(CO)]^{2+}$ (where L = macrocyclic ligand). The values of $v_{CO}$ of [FeL$(CH_3CN)(CO)]^{2+}$, and the electrochemical oxidation potentials of Fe(II) ${\to}$ Fe(III) and the qualitative stability toward air-oxidation for [FeL(CH$_3CN_2)^{2+}$ increase as the degree of unsaturation of the macrocyclic ligands increase.

• Journal of the Korean Mathematical Society
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• v.53 no.2
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• pp.381-401
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• 2016

According to Jacobson [31], a right ideal is bounded if it contains a non-zero ideal, and Faith [15] called a ring strongly right bounded if every non-zero right ideal is bounded. From [30], a ring is strongly right AB if every non-zero right annihilator is bounded. In this paper, we introduce and investigate a particular class of McCoy rings which satisfy Property (A) and the conditions asked by Nielsen [42]. It is shown that for a u.p.-monoid M and ${\sigma}:M{\rightarrow}End(R)$ a compatible monoid homomorphism, if R is reversible, then the skew monoid ring R * M is strongly right AB. If R is a strongly right AB ring, M is a u.p.-monoid and ${\sigma}:M{\rightarrow}End(R)$ is a weakly rigid monoid homomorphism, then the skew monoid ring R * M has right Property (A).

• Journal of the Korean institute of surface engineering
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• v.25 no.4
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• pp.173-180
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• 1992

The effects of the stabilizing additives such as NaCN, 2-MBT and Thiourea on bath decom-position, plating rate and surface morphology have been studied. Bath stability was increased in the order of an additive-free bath, and NaCN-, 2-MBT-, and Thiourea-stabilized baths. The sta-bilizing effects may be attributed to the stability of Cu(II) -complexes. The plating rate is the re-verse order of the bath stability. Accelerative effect of 2-MBT in proper quantity(0.3mg/$\ell$) may be explained by visualizing it absorbed through benzene ring or sulfur atom on portions of the sub-strates. The strong bond of the complexing part of the molecule to nearby chelated copper ions would tend to accelerate plating by making it easier for the Cu2+ -ligand bond to be broken. Sur-face morphologies of copper deposits depend on the bath additives. Electroless copper deposits from the 2-MBT stabilized baths are finer than the deposits from the NaCN- and Thiourea- stabi-lized baths due to the strong adsorption on the substrates.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.16 no.2
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• pp.81-87
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• 2017

The pipe connection process using a clamping ring is used for joining small pipes in the refrigerator and air-conditioner industries instead of the brazing process, which induces inevitable thermal deformation in the pipes. However, few studies have been carried out on the process to select optimal parameters in joining pipes, and studies on the relation between the process parameters of the connection and connecting force of the joint have not been conducted. In this study, the connection process of pipes with the clamping ring was modeled using the finite element method (FEM) and analyzed to obtain the contact stress distribution between the pipes with which the connecting force of the joint was estimated. Considering the characteristics of pipe connection, the process was modeled and simulated in a two-dimensional axisymmetric solution domain. With the numerical model, the effect of ring shape on the connection was studied by adding a projection to the end of a ring or changing the length of a ring. The results of the analyses revealed that the contact stress distribution could be predicted with the suggested model. The effect of the ring shape was also presented. The effect of any combination of process parameters could be easily estimated through the related analyses.

• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.128-133
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• 2024

Although antisolvent-assisted crystallization is one of the promising processes to produce high-quality perovskite films, general antisolvents such as chlorobenzene (CB) have toxic and volatile properties. In addition, CB is not suitable to control the crystallization of perovskite in the atmospheric air. In this work, isopropyl acetate (IA) is used as an eco-friendly antisolvent to demonstrate air-processed perovskite solar cells, and ethyl-4-cyanocinnamate (E4CN) with a cyano group, carbonyl group, and aromatic ring is introduced in IA to improve the performance and stability of devices. Defects at the surface and grain boundaries of the perovskite layer, such as un-coordinated Pb²⁺ and iodine, can be decreased resulting from the interaction of E4CN and perovskite, and thus reduced recombination and enhanced carrier transport can be expected. As a result, the perovskite device with E4CN achieves a high maximum power conversion efficiency (PCE) of 18.89% and outstanding stability, maintaining 60% of the initial efficiency for 300 h in the air without any encapsulation.