• 한국농공학회논문집
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• 제53권5호
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• pp.9-16
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• 2011

Curve Numbers (CN) for the combination of land use and hydrologic soil group were regionalized at Imha Watershed using Long-term Hydrologic Impact Assessment (L-THIA) coupled with SCE-UA. The L-THIA was calibrated during 1991-2000 and validated during 2001-2007 using monthly observed direct runoff data. The Nash-Sutcliffe (NS) coefficients for calibration and validation were 0.91 and 0.93, respectively, and showed high model efficiency. Based on the criteria of model calibration, both calibration and validation represented 'very good' fit with observe data. The spatial distribution of direct surface runoff by L-THIA represented runoff from Thiessen pologen at Subi and Sukbo rain gage station much higher than other area due to the combination of poor hydrologic condition (hydrologic soil C and D group) and locality heavy rainfall. As a results of hydrologic condition and treatment for land use type based on calibrated CNs, forest is recommended to be hydrologically modelled dived into deciduous, coniferous, and mixed forest due to the hydrological difference. The CNs for forest and upland showed the poor hydrologic condition. The steep slope of forest and alpine agricultural field make high runoff rate which is the poor hydrologic condition because CN method can not consider field slope. L-THIA linded with SCE-UA could generated a regionalized CNs for land use type with minimized time and effort, and maximized model's accuracy.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.2995-3004
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• 2013

The structural, electronic, and optical properties of poly(3-hexylthiophene) (P3HT) have been comprehensively studied by density functional theory (DFT) to rationalize the experimentally observed properties. Rather, we employed periodic boundary conditions (PBC) method to simulate the polymer block, and calculated effective charge mass from the band structure calculation for describing charge transport properties. The simulated results of P3HT are consistent with the experimental results in band gaps, absorption spectra, and effective charge mass. Based on the same calculated methods as P3HT, a series of polymers have been designed on the basis of the two types of building blocks, furofurans and furofurans substituted with cyano (CN) groups, to investigate suitable polymers toward polymer solar cell (PSC) materials. The calculated results reveal that the polymers substituted with CN groups have good structural stability, low-lying FMO energy levels, wide absorption spectra, and smaller effective masses, which are due to their good rigidity and conjugation in comparison with P3HT. Besides, the insertion of CN groups improves the performance of PSC. Synthetically, the designed polymers PFF1 and PFF2 are the champion candidates toward PSC relative to P3HT.

• Geomechanics and Engineering
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• 제24권1호
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• pp.57-65
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• 2021

The effects of initial soil fabric and aspect ratio (AR) on the small-strain stiffness (G0) of granular soils are studied by employing discrete element method (DEM) numerical analysis. Elongated clumps composed of subspheres were adopted, and the G0 values were obtained by DEM simulations of drained triaxial tests under different densities and initial confining pressure (p0). The DEM simulations indicate that the initial soil fabric has an insignificant effect on G0. The effect of the AR on G0 is related to the initial density. Namely, for dense specimens, G0 first increases with increasing AR, reaching a plateau value when the AR ≥ 1.5. However, for loose specimens, G0 gradually increases as the AR increases. Microscopic examination reveals that G0 uniquely depends on the coordination number of the particles (CN-particle) rather than the subspheres (CN-sphere) at the particulate level for the effects of initial soil fabric and AR. Finally, Poisson's ratio ν0 is also determined by CN-particle. In addition, based on data in literature and this study, ν0 can be fitted as ν0 = 5.920(G0/(p0)1/3)-0.99, which can be used to predict ν0 of granular soils based on the measured G0.

• 한국수자원학회논문집
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• 제50권11호
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• pp.759-767
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• 2017

NRCS-CN 방법을 이용해서 유출량을 결정하는 과정에 가장 큰 영향을 주는 변수는 유출곡선지수와 초기손실률이다. 수자원 실무에서 유출곡선지수와 초기손실률은 대부분 미국 National Engineering Handbook의 지침에 따라 결정하지만, 우리나라 유역의 토양 및 수문학적 특성은 미국과 다르기 때문에 유출량을 과대 또는 과소 산정하게 된다. 따라서 본 연구에서는 우리나라 유역특성에 적합한 유효우량을 산정하기 위하여 점근유출곡선지수법을 이용하여 총 8개의 유효우량 산정 모형(M1~M8)을 제시하였다. RSR (RMSE-observations standard deviation ratio)과 NSE(Nash-Sutcliffe Efficiency)의 두 가지 지표를 이용하여 모형을 평가하였으며, 그 결과 계측 유역에서는 M6 (평균 RSR: 0.76, 평균 NSE: 0.39), 미계측 유역에서는 M7 (평균 RSR: 0.82, 평균 NSE: 0.31)이 최적의 모형으로 선정되었다. 또한 대부분의 유역에서 기존에 사용되고 있던 초기손실률 0.20보다 더 작은 값(0.01-0.10)을 적용할 때 더 좋은 결과를 나타내는 것을 확인하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1774-1777
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• 1996

In this paper, applicability of SI-PD(switching impulse - partial discharge) testing method was put on an attempt as a newly proposed diagnostic method for the underground distribution power cable system in Korea. For this purpose, SI-PD testing equipment was designed, and tests were performed using artificial needle-type defects integrated into the 22.9 kV CN/CV cables in drder to prove its reliability. As a result, arc noises, generated from spark gap, were considerably decreased by use of a pneumatic switch immersed into oil, and artificial needle-type defects were well detected with impulse voltage level under $2U_0$. These results imply that it is likely possible to apply SI-PD measurement method as a the nondistructive test for the 22.9 kV CN/CV cable system in Korea.

• 대한화학회지
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• 제68권3호
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• pp.139-145
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• 2024

This study aims to elucidate the mechanism involved in the hydrolysis of the hexacyanoferrate(III) complex ion (Fe(CN)₆^3-) and the mechanism leading to the formation of Prussian blue (Fe^III₄[Fe_II(CN)₆]₃·xH₂O, PB) in acidic aqueous solutions at moderately elevated temperatures. Hydrolysis constitutes a crucial step in generating PB through the widely used single-source or precursor method. Recent PB syntheses predominantly rely on the single-source method, where hexacyanoferrate(II/III) is the exclusive reactant, as opposed to the co-precipitation method employing bare metal ions and hexacyanometalate ions. Despite the widespread adoption of the single-source method, mechanistic exploration remains largely unexplored and speculative. Utilizing UV-vis spectrophotometry, negative-ion mode liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS), and a devised reaction, this study identifies crucial intermediates, including aqueous Fe^2+/3+ ions and hydrocyanic acid (HCN) in the solution. These two intermediates eventually combine to form thermodynamically stable PB. The findings presented in this research significantly contribute to understanding the fundamental mechanism underlying the acid-catalyzed hydrolysis of the hexacyanoferrate(III) complex ion and the subsequent formation of PB, as proposed in the sequential mechanism introduced herein. This finding might contribute to the cost-effective synthesis of PB by incorporating diverse metal ions and potassium cyanide.

• 대한화학회지
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• 제54권1호
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• pp.13-22
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• 2010

7 diethylaminocoumarin (DEAC) 레이저 염료의 광물리적 특성들을 다양한 용매에서 측정하였다. DEAC의 방출 스펙트럼은 양이온성(CTAC) 미셀과 음이온성(SDS) 미셀에서 측정하였고, 레이저 파라미터는 아세톤, 다이옥산, 에탄올 및 dimethylforamide (DMF)과 같은 여러 가지 용매에 대하여 계산하였다. DEAC의 광반응성은 366 nm 빛을 사용하여 $CCl_4$ 용매에서 연구하였고, 광화학 수득률 (${\Phi}_c$)과 속도 상수(k)도 결정하였다. picric acid (PA), tetracyanoethylene (TCNE), 7,7,8,8-tetracynoquinonedimethane (TCNQ)등의 유기 수용체와 DEAC의 상호 작용에 대한 연구는 acetonitrile ($CH_3CN$) 용액에서 형광을 측정하므로 써 수행하였다. DEAC의 전기화학적 연구는 백금 전극을 사용하여 0.1 mol/L tetrabutyl ammonium perchlorate (TBAP)/$CH_3CN$ 용액에서 순환 전류-전압법, convolutive voltammetry 및 디지털 시뮬레이션을 조합하여 수행하였고, 전기화학 파라미터도 결정하였다.

• 센서학회지
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• 제29권4호
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• pp.215-219
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• 2020

MnCo₂S₄/CoS₂ electrode with highly accessible electroactive sites is prepared using the hydrothermal method. The electrode exhibits an areal capacitance of 0.75 Fcm^-2 at 6 mAcm^-2 in 1 M KOH. The capacitance is further increased to 2.06 Fcm^-2 by adding K₃Fe(CN)₆ and K₄Fe(CN)₆ (a redox couple) to KOH. This increment is associated with the redox-active properties of cobalt and manganese transition metals, as well as the ion pair of [Fe(CN)₆]^-3/[Fe(CN)₆]^-4. The capacitance retention of the MnCo₂S₄/CoS₂ electrode is 87.5% for successive 4000 charge-discharge cycles at 10 mAcm^-2 in a composite electrolyte system of KOH and ferri/ferrocyanide. The capacitance enhancement is supported by the lowest equivalent series resistance (0.62 Ωcm^-2) of MnCo₂S₄/CoS₂ in the presence of redox additive couple compared with the bare KOH electrolyte.

• Journal of Magnetics
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• 제13권4호
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• pp.149-152
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• 2008

In this report, we present the results of a study on the effects of the particle size on the properties of the Prussian blue (PB) analog $Na_xMn_y[Fe(CN){_6}]$. A novel synthesis method of the $Na_xMn_y[Fe(CN){_6}]$ nano-particles using an organic solvent, formamide, is employed. The size of the PB particles is found to be 100-150 nm for the samples prepared in the formamide solvent, which is much smaller than that of the samples prepared using water only. The broadening of the X-ray diffraction peaks of the nano-sized PB samples is attributed to the lattice disorder and a dramatic reduction in the particle size. The compositions of the samples are confirmed by an energy-dispersive X-ray analysis (EDAX), and the result proves that the samples are actually $Na_xMn_y[Fe(CN){_6}]$ Prussian blue. The UV-vis spectra show a broad intervalence charge-transfer (CT) band in the visible region between 400 and 700 nm, and the absorption decreases abruptly in the green region for the nano-sized PB sample. A divergence between the field cooled (FC) and zero field cooled (ZFC) magnetization curves is observed for the nano-sized PB sample at 11 K, indicating that nanoparticles in the sample are single domain superparamagnets with a blocking temperature of 11 K. Our results reveal that the nano-sized PB samples show significantly different optical and magnetic properties than those of the bulk PB samples.

• 한국수자원학회논문집
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• 제36권4호
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• pp.633-645
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• 2003

GIS기법과 원격탐사 기법은 수문학의 지형자료 구축과 응용 분야에 활발하게 이용되고 있으며 다방면에서 많은 연구가 진행 중이다. 본 연구에서는 산악지역에서 토양 특성과 토지 피복 상태에 따라 유출 특성이 어떻게 나타나는지를 CN값을 산정하여 평가 하였다. 토지 피복 분류에 신경망 기법을 사용하여 보다 적합한 분류 방법을 모색하고자 했고, CN값 산정을 위한 연산에 GIS기법출 사용하였다. 우선 샘플지역을 선정하여 토지 피복의 정확도를 평가하면, 기존의 최우도법(80.9%)과 신경망 기법(84.1%)에서 신경망 기법 분류 결과가 상대적으로 우수하므로 신경망 기법으로 토지 피복을 분류하였다. 그리고 SCS방법으로 토양도를 이용하여 AMC-II 조건하에서 CN값을 산정하면 수작업 토지이용도는 55, 신경망 분류 토지 피복도는 57로 비슷한 결과로 나타났다. 이를 토대로 전체 유역에 대해서 신경망 기법으로 분류한 토지 피복도를 사용하여 CN값을 산정하여 적용함으로써 타당성을 증명했다. 앞으로 신경망 기법을 이용한 토지 피복 분류와 GIS기법의 적용으로 보다 정확하고 신속한 CN값 산정이 가능할 것으로 사료된다.