• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.5
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• pp.9-16
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• 2011

Curve Numbers (CN) for the combination of land use and hydrologic soil group were regionalized at Imha Watershed using Long-term Hydrologic Impact Assessment (L-THIA) coupled with SCE-UA. The L-THIA was calibrated during 1991-2000 and validated during 2001-2007 using monthly observed direct runoff data. The Nash-Sutcliffe (NS) coefficients for calibration and validation were 0.91 and 0.93, respectively, and showed high model efficiency. Based on the criteria of model calibration, both calibration and validation represented 'very good' fit with observe data. The spatial distribution of direct surface runoff by L-THIA represented runoff from Thiessen pologen at Subi and Sukbo rain gage station much higher than other area due to the combination of poor hydrologic condition (hydrologic soil C and D group) and locality heavy rainfall. As a results of hydrologic condition and treatment for land use type based on calibrated CNs, forest is recommended to be hydrologically modelled dived into deciduous, coniferous, and mixed forest due to the hydrological difference. The CNs for forest and upland showed the poor hydrologic condition. The steep slope of forest and alpine agricultural field make high runoff rate which is the poor hydrologic condition because CN method can not consider field slope. L-THIA linded with SCE-UA could generated a regionalized CNs for land use type with minimized time and effort, and maximized model's accuracy.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.2995-3004
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• 2013

The structural, electronic, and optical properties of poly(3-hexylthiophene) (P3HT) have been comprehensively studied by density functional theory (DFT) to rationalize the experimentally observed properties. Rather, we employed periodic boundary conditions (PBC) method to simulate the polymer block, and calculated effective charge mass from the band structure calculation for describing charge transport properties. The simulated results of P3HT are consistent with the experimental results in band gaps, absorption spectra, and effective charge mass. Based on the same calculated methods as P3HT, a series of polymers have been designed on the basis of the two types of building blocks, furofurans and furofurans substituted with cyano (CN) groups, to investigate suitable polymers toward polymer solar cell (PSC) materials. The calculated results reveal that the polymers substituted with CN groups have good structural stability, low-lying FMO energy levels, wide absorption spectra, and smaller effective masses, which are due to their good rigidity and conjugation in comparison with P3HT. Besides, the insertion of CN groups improves the performance of PSC. Synthetically, the designed polymers PFF1 and PFF2 are the champion candidates toward PSC relative to P3HT.

• Geomechanics and Engineering
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• v.24 no.1
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• pp.57-65
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• 2021

The effects of initial soil fabric and aspect ratio (AR) on the small-strain stiffness (G0) of granular soils are studied by employing discrete element method (DEM) numerical analysis. Elongated clumps composed of subspheres were adopted, and the G0 values were obtained by DEM simulations of drained triaxial tests under different densities and initial confining pressure (p0). The DEM simulations indicate that the initial soil fabric has an insignificant effect on G0. The effect of the AR on G0 is related to the initial density. Namely, for dense specimens, G0 first increases with increasing AR, reaching a plateau value when the AR ≥ 1.5. However, for loose specimens, G0 gradually increases as the AR increases. Microscopic examination reveals that G0 uniquely depends on the coordination number of the particles (CN-particle) rather than the subspheres (CN-sphere) at the particulate level for the effects of initial soil fabric and AR. Finally, Poisson's ratio ν0 is also determined by CN-particle. In addition, based on data in literature and this study, ν0 can be fitted as ν0 = 5.920(G0/(p0)1/3)-0.99, which can be used to predict ν0 of granular soils based on the measured G0.

• Journal of Korea Water Resources Association
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• v.50 no.11
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• pp.759-767
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• 2017

Two main parameters of NRCS-CN method are curve numbers and intial loss ratio. They are generally selected according to the guideline of US National Engineering Handbook, however, they might cause errors on estimated runoff in Korea because there are differences between soil types and hydrological characteristics of Korean watersheds and those of United States. In this study, applying asymptotic CN regression method, we suggested eight modified NRCS-CN models to decide optimum runoff estimation model for Korean watersheds. RSR (RMSE-observations standard deviation ratio) and NSE (Nash-Sutcliffe efficiency) were used to evaluate model performance, consequently M6 for gauged basins (Avg. RSR was 0.76, Avg. NSE was 0.39) and M7 for ungauged basins (Avg. RSR was 0.82, Avg. NSE was 0.31) were selected. Furthermore it was observed that initial loss ratios ranging from 0.01 to 0.10 were more adequate than the fixed ${\lambda}=0.20$ in most of basins.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1774-1777
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• 1996

In this paper, applicability of SI-PD(switching impulse - partial discharge) testing method was put on an attempt as a newly proposed diagnostic method for the underground distribution power cable system in Korea. For this purpose, SI-PD testing equipment was designed, and tests were performed using artificial needle-type defects integrated into the 22.9 kV CN/CV cables in drder to prove its reliability. As a result, arc noises, generated from spark gap, were considerably decreased by use of a pneumatic switch immersed into oil, and artificial needle-type defects were well detected with impulse voltage level under $2U_0$. These results imply that it is likely possible to apply SI-PD measurement method as a the nondistructive test for the 22.9 kV CN/CV cable system in Korea.

• Journal of the Korean Chemical Society
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• v.68 no.3
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• pp.139-145
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• 2024

This study aims to elucidate the mechanism involved in the hydrolysis of the hexacyanoferrate(III) complex ion (Fe(CN)₆^3-) and the mechanism leading to the formation of Prussian blue (Fe^III₄[Fe_II(CN)₆]₃·xH₂O, PB) in acidic aqueous solutions at moderately elevated temperatures. Hydrolysis constitutes a crucial step in generating PB through the widely used single-source or precursor method. Recent PB syntheses predominantly rely on the single-source method, where hexacyanoferrate(II/III) is the exclusive reactant, as opposed to the co-precipitation method employing bare metal ions and hexacyanometalate ions. Despite the widespread adoption of the single-source method, mechanistic exploration remains largely unexplored and speculative. Utilizing UV-vis spectrophotometry, negative-ion mode liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS), and a devised reaction, this study identifies crucial intermediates, including aqueous Fe^2+/3+ ions and hydrocyanic acid (HCN) in the solution. These two intermediates eventually combine to form thermodynamically stable PB. The findings presented in this research significantly contribute to understanding the fundamental mechanism underlying the acid-catalyzed hydrolysis of the hexacyanoferrate(III) complex ion and the subsequent formation of PB, as proposed in the sequential mechanism introduced herein. This finding might contribute to the cost-effective synthesis of PB by incorporating diverse metal ions and potassium cyanide.

• Journal of the Korean Chemical Society
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• v.54 no.1
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• pp.13-22
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• 2010

The photophysical properties of 7-diethylaminocoumarin (DEAC) laser dye have been measured in different solvents. The emission spectrum of DEAC has also been measured in cationic (CTAC) and anionic (SDS) micelles. The laser parameters have been calculated in different solvents namely acetone, dioxane, ethanol and dimethylforamide(DMF). The photoreactivity of DEAC has been studied in $CCl_4$ solvent using 366 nm light. The values of photochemical yield (${\Phi}_c$) and rate constant (k) are determined. The interaction of organic acceptors such as picric acid (PA), tetracyanoethylene (TCNE) and 7,7,8,8-tetracynoquinonedimethane (TCNQ) with DEAC are also studied using fluorescence measurements in acetonitrile ($CH_3CN$). The electrochemical investigation of (DEAC) has been carried out using cyclic voltammetry and convolutive voltammetry combined with digital simulation technique at a platinum electrode in 0.1 mol $L^{-1}$ tetrabutyl ammonium perchlorate (TBAP) in $CH_3CN$ solvent. The electrochemical parameters of the investigated compound were determined using cyclic and convolutive voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation method.

• Journal of Sensor Science and Technology
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• v.29 no.4
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• pp.215-219
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• 2020

MnCo₂S₄/CoS₂ electrode with highly accessible electroactive sites is prepared using the hydrothermal method. The electrode exhibits an areal capacitance of 0.75 Fcm^-2 at 6 mAcm^-2 in 1 M KOH. The capacitance is further increased to 2.06 Fcm^-2 by adding K₃Fe(CN)₆ and K₄Fe(CN)₆ (a redox couple) to KOH. This increment is associated with the redox-active properties of cobalt and manganese transition metals, as well as the ion pair of [Fe(CN)₆]^-3/[Fe(CN)₆]^-4. The capacitance retention of the MnCo₂S₄/CoS₂ electrode is 87.5% for successive 4000 charge-discharge cycles at 10 mAcm^-2 in a composite electrolyte system of KOH and ferri/ferrocyanide. The capacitance enhancement is supported by the lowest equivalent series resistance (0.62 Ωcm^-2) of MnCo₂S₄/CoS₂ in the presence of redox additive couple compared with the bare KOH electrolyte.

• Journal of Magnetics
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• v.13 no.4
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• pp.149-152
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• 2008

In this report, we present the results of a study on the effects of the particle size on the properties of the Prussian blue (PB) analog $Na_xMn_y[Fe(CN){_6}]$. A novel synthesis method of the $Na_xMn_y[Fe(CN){_6}]$ nano-particles using an organic solvent, formamide, is employed. The size of the PB particles is found to be 100-150 nm for the samples prepared in the formamide solvent, which is much smaller than that of the samples prepared using water only. The broadening of the X-ray diffraction peaks of the nano-sized PB samples is attributed to the lattice disorder and a dramatic reduction in the particle size. The compositions of the samples are confirmed by an energy-dispersive X-ray analysis (EDAX), and the result proves that the samples are actually $Na_xMn_y[Fe(CN){_6}]$ Prussian blue. The UV-vis spectra show a broad intervalence charge-transfer (CT) band in the visible region between 400 and 700 nm, and the absorption decreases abruptly in the green region for the nano-sized PB sample. A divergence between the field cooled (FC) and zero field cooled (ZFC) magnetization curves is observed for the nano-sized PB sample at 11 K, indicating that nanoparticles in the sample are single domain superparamagnets with a blocking temperature of 11 K. Our results reveal that the nano-sized PB samples show significantly different optical and magnetic properties than those of the bulk PB samples.

• Journal of Korea Water Resources Association
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• v.36 no.4
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• pp.633-645
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• 2003

The techniques of GIS and remote sensing are being applied to hydrology, geomorphology and various field of studies are performed by many researcher, related those techniques. In this paper, curve number change detection is tested according to soil map and land cover in mountain area. Neural networks method is applied for land cover classification and GIS for curve number calculation. The first, sample area are selected and tested land cover classification, NN(84.1％) is superior to MLC(80.9％). So we selected NN with land cover classifier. The second, curve number from the land cover by neural network classifier(57) is compared with that(curve number) from the land cover by manual work(55). Two values are so similar. The third, curve number classified by NN in sample area was applied and tested to whole study area. As results of this study, it is shown that curve number is more exact and efficient by using NN and GIS technique than by (using) manual work.