• Title/Summary/Keyword: CMPS

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Characteristics of Biodegradable Blends of PBAST and Chemically Modified Thermoplastic Starch (생분해성 PBAST와 변형 열가소성 전분 블렌드의 특성)

  • Shin, Boo-Young
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.580-585
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    • 2011
  • This article aims to enhance the biodegradability and environment-friendliness of petroleum based biodegradable poly(butylene adipate-co-succinate-co-terephthalate)(PBAST) by blending chemically modified thermoplastic starch(CMPS). CMPS is a kind of bio-based biodegradable resin which is manufactured by reacting starch with maleic anhydride(MA) in the presence of a plasticizer and a free radical initiator. The characteristic properties of PBAST/CMPS blends were investigated by observing their morphology, thermal, mechanical properties, and biodegradability. The good interfacial adhesion between the phases examined by SEM revealed that PBAST/CMPS blends were compatible blends. The tensile strength and elongation decreased with increasing CMPS content, while modulus increased. The biodegradability of the blends was much higher than that of pristine PBAST and increased with increasing CMPS contents.

Morphology and Rheology on the Blends of PLA/CMPS

  • Shin, Boo-Young;Jo, Gyu-Soon;Kang, Kyoung-Su;Lee, Tae-Jin;Kim, Bong-Shik;Lee, Sang-Il;Song, Jeong-Sup
    • Macromolecular Research
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    • v.15 no.4
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    • pp.291-301
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    • 2007
  • The rheological behaviors and morphologies of polylactide (PLA) and chemically modified plasticized starch (CMPS) blends were investigated. For this study, oscillatory shear flow measurements of the PLA, CMPS and their blends were performed. A scanning electron microscope (SEM) study was also conducted on the extracted extrudates of the blends. The morphology of the blend changed in relation to the composition: sphere-shaped CMPS disperse/continuous PLA, rod-like deformed CMPS phase/continuous PLA, a co-continuous structure with bridged CMPS long rods and PLA dispersed/continuous CMPS. The composition of the phase inversion could be estimated and closely coincided from the observed morphology experimental results. The rheological behavior of the blends, from oscillatory measurements, was found to vary in relation to the composition, and reflected the morphologies of the blends. PLA showed Newtonian flow behavior, while CMPS showed strong shear thinning behavior. The relationships between the morphology and rheological properties were observed in detail.

Morphology, Thermal and Mechanical Properties of Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)/CMPS Blends (Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)/CMPS 블렌드의 형태학, 열적 및 기계적 특성)

  • Kang, Kyoung-Soo;Kim, Bong-Shik;Jang, Woo-Yeul;Shin, Boo-Young
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.164-168
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    • 2009
  • The effects of chemically modified thermoplastic starch (CMPS) on the morphology, thermal and mechanical properties of the blends of poly (lactic acid)(PLA) and poly(butylene adipate-co-terephthalate)(PBAT) were studied. Blends of PLA/PBAT with the CMPS contents of 10, 20 and 30 wt% on the basis of PLA/PBAT weight were prepared by a twin screw extruder. The morphology, thermal and mechanical properties of the blends were examined by using scanning electron microscope (SEM), differential scanning calorimeter (DSC) and a tensile tester. The DSC study revealed that PLA/PBAT blends are thermodynamically immiscible, while the compatibility was much improved by addition of the CMPS.

Development of Compressible Three Phases Flow Simulator Based on Fractional Flow Approach (압축성을 고려한 분율 흐름 접근 방식에 근거한 삼상흐름모델 개발)

  • Suk, Hee-Jun;Ko, Kyung-Seok;Yeh, Gour-Tsyh
    • Economic and Environmental Geology
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    • v.41 no.6
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    • pp.731-746
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    • 2008
  • Most multiphase flow simulators following fractional flow approach assume incompressibility of fluid and matrix or consider only two phase flow (water and air, water and NAPL). However, in this study, mathematical governing equations were developed for fully compressible three-phase flow using fractional flow based approach. Also, fully compressible multiphase flow simulator (CMPS) considering compressibilities of matrix and fluid was developed using the mathematical governing equations. In order to verify CMPS, the CMPS were compared with analytical solution and the existing multiphase flow simulator, MPS, which had been developed for simulating incompressible multiphase flow (Suk and Yeh 2007; Suk and Yeh 2008). According to the results, solutions of CMPS and MPS and analytical solutions are well matched each other. Thus, it is found that CMPS has the capability of simulating compressible three phase flow phenomena assuming compressibilities of fluids and matrix.

Low-power heterogeneous uncore architecture for future 3D chip-multiprocessors

  • Dorostkar, Aniseh;Asad, Arghavan;Fathy, Mahmood;Jahed-Motlagh, Mohammad Reza;Mohammadi, Farah
    • ETRI Journal
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    • v.40 no.6
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    • pp.759-773
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    • 2018
  • Uncore components such as on-chip memory systems and on-chip interconnects consume a large amount of energy in emerging embedded applications. Few studies have focused on next-generation analytical models for future chip-multiprocessors (CMPs) that simultaneously consider the impacts of the power consumption of core and uncore components. In this paper, we propose a convex-optimization approach to design heterogeneous uncore architectures for embedded CMPs. Our convex approach optimizes the number and placement of memory banks with different technologies on the memory layer. In parallel with hybrid memory architecting, optimizing the number and placement of through silicon vias as a viable solution in building three-dimensional (3D) CMPs is another important target of the proposed approach. Experimental results show that the proposed method outperforms 3D CMP designs with hybrid and traditional memory architectures in terms of both energy delay products (EDPs) and performance parameters. The proposed method improves the EDPs by an average of about 43% compared with SRAM design. In addition, it improves the throughput by about 7% compared with dynamic RAM (DRAM) design.

The Preparation of Quaternary Ammonium Polysulfone and its Permeation Behavior (I) -Preparation of Quaternary Ammonium Polysulfone- (Quaternary Ammonium Polysulfone막의 제조 및 투과 특성 (I) - Quaternary Ammonium Polysulfone의 제조 -)

  • 현진호;전종영;김종호;탁태문
    • Membrane Journal
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    • v.6 no.2
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    • pp.72-78
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    • 1996
  • This paper was to investigate the preparation of quaternary ammonium polysulfone. The aminated polysullone (AMPS) as quaternary ammonium polysulfone was synthesized by two-step process. The first step involves the preparation of chloromethylated polysulfone (CMPS) which was produced by the introducion of chloromethyl group into polysulfone using chloromethyl methyl ether as a chloromethylation agent and zinc oxide as a catalyst. The second step, amination of CMPS was to give rise to AMPS using triethylamine.

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Magnetic Field Simulation for Circumferential Magnetic Phase Produced in Steam Generator Tube

  • Ryu, Kwon-Sang;Son, Derac;Park, Duck-Gun;Jung, Jae-Kap
    • Journal of Magnetics
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    • v.16 no.2
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    • pp.88-91
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    • 2011
  • Steam generator tubes (SGTs) in nuclear power plants (NPPs) are a boundary between the primary side generating heat by nuclear fission and the secondary side generating electric power by a turbine. The water inside the SGT is high temperature and high pressure. Therefore, defects and magnetic phases (MPs) are partly produced in non-magnetic SGT by high stresses and temperatures. This causes trouble regarding the safety of SGTs but it is difficult to detect the MP using the conventional eddy current technique (ECT). In particular, a circumferential defect (CD) and circumferential magnetic phase (CMP) cannot detected by ECT. Consequently, a new method is needed to detect CDs and CMPs in SGT. A new U-type yoke with two types of coils was designed and the reactance signal by the CMPs and CDs in the SGT material was simulated.

Hierarchical Multiplexing Interconnection Structure for Fault-Tolerant Reconfigurable Chip Multiprocessor

  • Kim, Yoon-Jin
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.11 no.4
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    • pp.318-328
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    • 2011
  • Stage-level reconfigurable chip multiprocessor (CMP) aims to achieve highly reliable and fault tolerant computing by using interwoven pipeline stages and on-chip interconnect for communicating with each other. The existing crossbar-switch based stage-level reconfigurable CMPs offer high reliability at the cost of significant area/power overheads. These overheads make realizing large CMPs prohibitive due to the area and power consumed by heavy interconnection networks. On other hand, area/power-efficient architectures offer less reliability and inefficient stage-level resource utilization. In this paper, I propose a hierarchical multiplexing interconnection structure in lieu of crossbar interconnect to design area/power-efficient stage-level reconfigurable CMP. The proposed approach is able to keep the reliability offered by the crossbar-switch while reducing the area and power overheads. Experimental results show that the proposed approach reduces area by up to 21% and power by up to 32% when compared with the crossbar-switch based interconnection network.

Retrospective clinical and radiographic evaluation of restored endodontically treated teeth

  • Paula Pontes Garcia ;Aline Cappoani ;Ricardo Susin Schelbauer ;Gisele Maria Correr ;Carla Castiglia Gonzaga
    • Restorative Dentistry and Endodontics
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    • v.45 no.4
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    • pp.49.1-49.11
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    • 2020
  • Objectives: The aim of this study was to perform a clinical and radiographic analysis of endodontically treated teeth (ETT) restored with cast metal posts (CMPs) or prefabricated glass fiber posts (GFPs) and crowns. Materials and Methods: Fifty ETT were restored with 25 CMPs and 25 GFPs at a private dental clinic between 2001 and 2016. The restorations consisted of 12 all-ceramic crowns, 31 metal-ceramic crowns, and 7 composite resin crowns. Demographic data, type of teeth, type of post-and-core system, time of placement, crown restorations, the number of proximal contacts, the type of antagonist, and reports of any complications after post-and-core placement were recorded for each patient. Assessments were performed at baseline (radiographic) and follow-up (radiographic and clinical). Data were analyzed by the McNemar test, the Pearson χ2 test, and Kaplan-Meier survival curves (α = 0.05). The mean follow-up was 67.6 months. Results: No significant difference was observed for any of the radiographic parameters when the baseline and final radiographs were compared. In the clinical evaluation, anatomical form (p = 0.009) and occlusion (p = 0.001) showed significant differences according to the type of crown restoration; specifically, metal-ceramic and all-ceramic crowns outperformed composite resin crowns. Conclusions: CMPs and GFPs showed favorable results for restoring ETT after 6 years of follow-up. All-ceramic and metal-ceramic crowns showed higher survival rates and better clinical outcomes.

Analytical Quality by Design Methodology Approach for Simultaneous Quantitation of Paeoniflorin and Decursin in Herbal Medicine by RP-HPLC Analysis

  • Kim, Min Kyoung;Park, Geonha;Hong, Seon-Pyo;Jang, Young Pyo
    • Natural Product Sciences
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    • v.27 no.4
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    • pp.264-273
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    • 2021
  • Simultaneous quantification of multiple marker compounds in herbal medicine by high performance liquid chromatography (HPLC) analysis is still a challenge due to the complexity in various parameters to be considered and co-existing multi-components. As a case study, a reliable HPLC method for simultaneous quantification of paeoniflorin from Paeoniae Radix and decursin from Angelicae Gigantis Radix in various commercial herbal medicine was developed based on analytical quality by design (AQbD) strategy. As a first step, risk assessment was performed to select the critical method parameters (CMPs) which were decided as organic mobile phase ratio and column oven temperature. In order to evaluate the effect of the CMPs on critical method attributes (CMAs) of peak resolution and tailing, central composite design (CCD) was employed. The final chromatographic conditions were optimized as follows: column- C18, 4.6 × 250 mm, 5 ㎛ particle size; mobile phase- A: acetonitrile, B: 0.1% acetic acid water; detection wavelength- 235 nm for paeoniflorin, 325 nm for decursin; column oven temperature- 25℃; flow rate- 1.0 mL/min; gradient mobile phase system as Time (min) : % A, 0:14, 25:14, 30:50, 60:50, 61:100, 65:100, 66:14, 75:14. The method was successfully validated according to the International Conference on Harmonization (ICH) guidelines and piloted for ten commercial herbal medicines.