• Title/Summary/Keyword: CI-이온

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The Correlation of Wavelengths with Heavy Metal Elements on the Circadian Rhythm Conidiation in Neurospora crassa (Neurospora crassa의 포자형성 주기에 미치는 빛파장과 중금속 이온의 영향 관계 조사)

  • 한상진
    • Environmental Analysis Health and Toxicology
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    • v.10 no.3_4
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    • pp.7-13
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    • 1995
  • The most periodlengths($\tau$) of conidiation of Neurospora were shortened in the medium with Li$^+$, Rb$^+$, and Cs$^+$ under the blue or green light. The higher the concentration of the heavy metal elements are, the shorter the circadian lengths are. The largest differences between the maxima- and minima circadian lengths showed in the medium with LiCI, RbCl, and CsCI under the blue lights at 150 Lux, while the little differences of circadian lengths presented in 1 mM heavy metal elements at the 270Lux blue light. Li$^+$ under the blue light effected extremely much and in the order of Rb$^+$ and Cs$^+$ on the conidiation of Neurospora. Under the green lights at 270Lux, the smallest changes of the circadian lengths are resulted in the medium with heavy metal elements. The other way at the green light 150Lux, the conidiation is stimulated by lmM LiCI or RbCl for the average 0.71h and 0.29h longer than the periodlength of control 28.34h. The medium with Li$^+$ under the green light has less effect on the conidiation rhythm of Neurospora than with Rb$^+$ or Cs$^+$.

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Isolation and Properties of a Cytoplasmic Metalloendoprotease in Escherichia coli (大腸菌 細胞質內 Metalloendoprotease의 抽出과 그 性質에 관하여)

  • Chung, Chin-Ha;Ha, Doo-Bong
    • The Korean Journal of Zoology
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    • v.27 no.4
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    • pp.199-212
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    • 1984
  • A cytoplasmic endoprotease, named protease Ci, has been partially purified by classical chromatographic procedures. This enzyme degrades insulin, glucagon and bovine growth hormone to trichloroacetic acid-soluble materials, but shows little or no hydrolysis of bovine serum albumin, casein or globin. It has a molecular weight of about 120,000 as determined by gel filtration on Sephadex G200, and it appears to be consisted of two identical subunits having molecular weight of 54,000 when estimated by polyacrylamide gel electrophoresis in the presence of sodium dodecyl sulfate. Protease Ci has an optimum pH of 7.5, and has an isoelectric point of 5.5. This enzyme is a metalloprotease, since it is inhibited by o-phenanthroline and can be activated by the addition of divalent metal cations, such as $Mn^++$ and $Co^++$. Protease ci is inhibited by p-hydroxymercuribenzoic acid, but not by either of leupeptin or Ep475 which are specific inhibitors of sulfhydryl protease. It is distinct from protease Pi, a perplasmic insulin degrading enzyme, since protease Ci is localized to the cytoplasm. The physiological function of protease Ci is presently unknown.

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The Study on the Fixation of Cs-137 Radionuclide in Clinoptillolite - The Fixation of Cesium in Clinoptillolite - (Clinoptillolite에 의(依)한 Cs-137 핵종(核種) 흡착(吸着)에 관(關)한 연구(硏究))

  • Lee, Sang-Hoon;Sung, Nak-June;Park, Won-Jong
    • Journal of Radiation Protection and Research
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    • v.3 no.1
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    • pp.1-5
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    • 1978
  • Investigation is carried out that low-level liquid radioactive wastes which is consisted of long half-life nuclides such as cesium can be treated by Korean clinoptillolite as a kind of zeolites. Column operation using a activated clinoptillolite shows good results in terms of break-through curves and comparing to clinoptillolite classified at WARD in U.S, Korean clinoptillolite shows a tailing phenomena longer than that of WARD. The fixation quantity of radioactivity in Korea clinoptillolite is to be about $75{\mu}Ci/100g$ using a $2.5{\times}10^{-3}{\mu}Ci/ml$ solution.

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Experimental Study of Microscopic Etching Shapes in the RIE Processes of Tungsten Silicide Films Using $SF_6$ Plasma ($SF_6$플라즈마를 이용한 텅스템 실리사이등 식각공정에서의 미세 식각형성 특성에 관한 연구)

  • 이창덕;박상규
    • Journal of the Korean Vacuum Society
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    • v.4 no.1
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    • pp.91-103
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    • 1995
  • SF6 플라즈마를 이용한 텅스템 실리사이드 식각공정에서 전력, 압력, 전극간 거리, 기판온도 등의 공정변수와 CI2 첨가 기체가 식각율, 이방성, RIE Lag 등의 식각특성에 미치는 영향을 살펴보았다. 입력 전력이 증가할수록 식각율이 증가하였고 RIE Lag는 감소하였다. 식각율은 150mtorr에서 최대가 되었는데 이는 이온과 반응성 라디칼의 공동작용효과가 가장 크게 나타나기 때문으로 생각된다. 또한 압력이 작아질수록 이온의 에너지가 증가하고 이온의 분산현상이 감소하여 RIE Lag이 감소되었다. 전극간 거리가 감소할수록 식각율은 증가하고 RIE Lag은 감소되었으나 이방성은 악화되는 것으로 나타났다. 기판 온도가 증가할수록 표면 반응이 활발해져 총 식각율은 증가하였으며 반응성 라디칼의 도랑 내부로의 확산이 용이하게 이루어져 RIE Lag가 감소하였으나 화학적 식각의 증가로 이방성은 악화되었다. 염소의 첨가량이 증가할수록 도랑 벽면에 보호막이 형성되어 식각율 및 RIE Lag은 감소하였으며 이방성은 향상되는 것으로 나타났다.

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A study on the apparent and partial molal volumes of n-Alkyl amine hydrochloride in water (n-Alkyl amine 鹽酸鹽의 水溶液 中에서의 apparent 및 partial molal volumes에 관한 硏究)

  • Yoon Sang Ki
    • Journal of the Korean Chemical Society
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    • v.13 no.2
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    • pp.121-129
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    • 1969
  • The apparent and partial molal volumes({\phi}\nu$and $V^{\circ}$) of a series of homologous n-alkylamine hydrochlorides $C_nH_{2n+1}NH_3^+Cl^-$, where n varies from zero to four, have been determined by means of a float method at 30$^{\circ}C$ to the fifth decimal place down to 0.01M in aqueous solutions. The experimental results indicate that the partial molal volumes of the salts are almost additive for successive homologues depending on the increment of molecular weight ($CH_2$). It has been observed that the concentration dependence of the ${\Phi}v$ are linear in general and limiting slopes are positive and relatively close to the theoretical values. Anionic partial molal volume of chlorides anion $V^{\circ}_{Cl^-}$ is found to be 18.6 ml $mole^{-1}$, which is in good agreement with the results of other workers. {\phi}\nu$ data also show that in solution the hydrophobic effect of ions are in competition with the charge effect, but the latter, that is, electrostriction seemed to be considerably predominant.

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Dry etching of polysiliconin high density plasmas of $CI_2$ (고밀도 플라즈마를 사용한 $CI_2$/ Poly-Si 건식 식각)

    • Journal of the Korean Vacuum Society
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    • v.8 no.1
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    • pp.63-69
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    • 1999
  • The characteristic parameters of high density plasma source (Helical Resonator) have been measured with Langmuir probe to get the plasma density electron temperature, ion current density, etc. Optical emission spectra of Si and SiCl have been analyzed in $Cl_2$$/poly-Si system to elucidate etching mechanism. In this system, the main reaction to remove silicon atoms on the surface is proceeding mostly through chemical reaction, not pure physical reaction. The emission intensity of SiCl (chemical etching product) increases much faster than Si (pure physical etching product) with increasing the concentration of impurities (P). This is due to the electron transfer from substrate to the surface via Si-Cl bond. As a result, Si-Cl bond becomes more ionic and mobile, therefore the Cl-containing etchant forms $SiCl_x$ with surface more easily. Consequently, for the removal of Si atom from poly silicon surface, the chemical etching is more favorable than physical etching with increasing P concentrations.

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Effects of Butanol Isomers on the Mixed Micellization of TTAB/Brij 35 Mixed Surfactant Systems (TTAB/Brij 35 혼합계면활성제의 미셀화에 미치는 부탄올 이성질체들의 효과)

  • Gil, Han-Nae;Lee, Byung-Hwan
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.111-117
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    • 2008
  • critical micelle concentration (CMC) and the counter ion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at 25oC in water and in aqueous solutions of butanol isomers were determined as a function of 1 (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The results say that the effects of butanol isomers on the micellization of TTAB/Brij 35 mixtures have been in the order of n-butanol>iso-butanol>t-butanol> water.

Effect of n-Butanol on the Micellization of DBS/Brij 35 Mixed Surfactant Systems (DBS/Brij 35 혼합계면활성제의 미셀화에 미치는 n-부탄올 효과)

  • Lee, Byeong-Hwan;Park, In-Jeong
    • Journal of the Korean Chemical Society
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    • v.50 no.5
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    • pp.355-361
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    • 2006
  • The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

Study on elemental analysis of metal and ceramic samples by using laser ablation ion trap mass spectrometry(LAITMS) (레이저 이온화 이온트랩 질량분석법을 이용한 금속 및 세라믹 시료의 원소분석에 관한 연구)

  • Song, Kyuseok;Park, Hyunkook;Cha, Hyungki;Lee, Sang Chun
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.7-14
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    • 2002
  • Laser ablation ion trap mass spectrometry (LAITMS) was developed for the analysis of metal and ceramic samples. For this study, XeCl excimer laser (308 nm) was used for ablating the samples and ITMS was used as a detector. Samples were introduced from outside of a ring electrode and this way of sample introduction was very effective for solid samples when laser ablation was employed. Helium gas was used as a buffer gas, and its effect on sensitivity and some parameters (buffer gas pressure, ion storage time, and cut-off RF voltage) were studied. The optimized conditions were $1{\times}10^{-4}$ Torr of buffer gas pressure, 100 ms of ion storage time and $1150V_{p-p}$ of cut-off RF voltage. From that results, copper (Cu) and molybdenum (Mo) metals were tested with LAITMS and the mass spectra of these pure metals were compared with the natural abundance of isotope ratio. We also examined ceramic samples ($Al_2O_3$, $ZrO_2$) and represented the result of elemental analysis.