• 한국재료학회지
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• 제25권6호
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• pp.300-304
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• 2015

Nanorod ZnO and spherical nano ZnO for gas sensors were prepared by hydrothermal reaction method and hydrazine method, respectively. The nano-ZnO gas sensors were fabricated by a screen printing method on alumina substrates. The gas sensing properties were investigated for hydrocarbon gas. The effects of Co concentration on the structural and morphological properties of the nano ZnO:Co were investigated by X-ray diffraction and scanning electron microscope (SEM), respectively. XRD patterns revealed that nanorod and spherical ZnO:Co with a wurtzite structure were grown with (100), (002), (101) peaks. The sensitivity of nanorod and spherical ZnO:Co sensors was measured for 5 ppm $CH_4$ and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in target gases. The highest sensitivity to the $CH_4$ and $CH_3CH_2CH_3$ gas of spherical nano ZnO:Co sensors was observed at Co 6 wt%. The spherical nano ZnO:Co sensor exhibited a higher sensitivity to hydrocarbon gas than nanorod ZnO.

• 한국산학기술학회논문지
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• 제19권3호
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• pp.624-629
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• 2018

본 논문은 NDIR(Non Dispersive Infra Red) 방식을 적용하여 $CO_2$ 및 $CH_4$의 두 가지 가스를 하나의 휴대용 장치에서 측정이 가능하도록 제작된 복합 가스 측정 장치에 대한 연구이다. 측정 장치의 구성은 적외선램프에서 적외선이 방출되면 방출된 파장이 광학창을 거치면서 흡수로 인하여 빛이 줄어들게 되고 이 감소량(흡수도)을 검출기에서 검출하고 이를 전기적 신호로 변환 증폭하여(3.5V~6V) 정확한 측정이 가능함을 보여준다. 기존의 Single Sensor 방식은 적외선에서 특수파장을 흡수하여 상대 측정량을 검출하는 방식으로 가스의 경우 $4.26{\mu}m$파장의 빛만을 검출하여 측정하는 방식으로 센서의 값을 보정할 수 있는 기준센서가 없어 오차가 발생하는 문제가 발생하였다. 본 연구에 적용된 Dual Sensor 방식은 다른 가스의 영향을 받지 않는 $3.91{\mu}m$의 기준치와 가스의 $4.26{\mu}m$의 두 파장을 검출하여 비교측정 함으로써 오차가 적어 신뢰도가 높은 방식으로, 휴대형으로 소형화하여 저 전력화가 가능하며, $CO_2$ 및 $CH_4$의 2가지 가스농도를 복합적으로 측정 할 수 있다는 특징이 있다. 측정 범위는 $CO_2$의 경우 0ppm~5,000ppm이고 $CH_4$의 경우는 0~5%의 부피 농도로 실내 공기량 1,000ppm을 측정 할 수 있도록 제작되어 휴대용이나 주택의 Home automation과 연동하여 소화연동이 가능함으로 화재예방에 매우 효과적일 것으로 확인하였다.

• 한국전기전자재료학회논문지
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• 제24권7호
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• pp.589-593
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• 2011

[ $SnO_2$ ]nano powders were prepared by solution reduction method using tin chloride($SnCl_2{\cdot}2H_2O$), hydrazine($N_2H_4$) and NaOH. The $SnO_2$ thick films for gas sensors were fabricated by screen printing method on alumina substrates and annealed at $300^{\circ}C$ in air, respectively. XRD patterns of the $SnO_2$ nano powders showed the tetragonal structure with (110) dominant orientation. The particle size of $SnO_2$ nano powders at the ratio of $SnCl_2:N_2H_4$+NaOH= 1:6 was about 60 nm. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box. Sensitivity of $SnO_2$ gas sensor to 5 ppm $CH_4$gas and 5 ppm $CH_3CH_2CH_3$ gas was investigated for various $SnCl_2:N_2H_4$+NaOH proportion. The highest sensitivity to $CH_4$ gas and $CH_3CH_2CH_3$ gas of $SnO_2$ sensors was observed at the $SnCl_2:N_2H_4$+NaOH= 1:8 and $SnCl_2:N_2H_4$+NaOH= 1:6, respectively. Response and recovery times of $SnO_2$ gas sensors prepared by $SnCl_2:N_2H_4$+NaOH= 1:6 was about 40 s and 30 s, respectively.

• 센서학회지
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• 제27권3호
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• pp.199-203
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• 2018

In this study, we develop a methane sensor module that can detect low concentrations below 5,000 ppm and measure up to the detection limit of 50 ppm with the NDIR method, with a long lifetime and high accuracy. Methane ($CH_4$) is one of a representative greenhouse gas, which is very explosive. Thus, it is important to quickly and accurately measure methane concentration in the air. To adjust the methane sensor for industrial field applications, a NDIR-based small sensor was implemented and characterized, where its volume was $4cm{\times}4cm{\times}2cm$ and its response time ($T_{90}$) was less than 30 sec. These results demonstrate that the proposed sensor is commercially available for low-concentration measurement, low volume, and fast response application, such as IoT sensor nodes and portable devices.

• 센서학회지
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• 제13권4호
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• pp.298-302
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• 2004

Thick films of $LaNiO_{3}$ having perovskite structure impregnated with indium and bismuth oxides have been used as sensing material for acetonitrile ($CH_{3}CN$) gas. The sensor response for $CH_{3}CN$ is quite good with an excellent recovery for partial pressure from 3 ppm to 20 ppm between 200 and $250^{\circ}C$. $LaNiO_{3}$ alone has exhibited low response, but after impregnation of $In_{2}O_{3}$ and $Bi_{2}O_{3}$ have given increased sensitivity even with 3 ppm partial pressure of $CH_{3}CN$ at $200^{\circ}C$. It is assumed that $CH_{3}CN$ is undergoing oxidation reaction on surface of the film.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제8권4호
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• pp.1237-1255
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• 2014

In wireless sensor networks (WSNs), hierarchical clustering is an efficient approach for lower energy consumption and extended network lifetime. In cluster-based multi-hop communications, a cluster head (CH) closer to the sink is loaded heavier than those CHs farther away from the sink. In order to balance the energy consumption among CHs, we development a novel cluster-based routing protocol for corona-structured wireless sensor networks. Based on the relaying traffic of each CH conveys, adequate radius for each corona can be determined through nearly balanced energy depletion analysis, which leads to balanced energy consumption among CHs. Simulation results demonstrate that our clustering approach effectively improves the network lifetime, residual energy and reduces the number of CH rotations in comparison with the MLCRA protocols.

• Journal of Communications and Networks
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• 제15권4호
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• pp.422-429
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• 2013

Advances in wireless sensor network (WSN) technology have enabled small and low-cost sensors with the capability of sensing various types of physical and environmental conditions, data processing, and wireless communication. In the WSN, the sensor nodes have a limited transmission range and their processing and storage capabilities as well as their energy resources are limited. A triple umpiring system has already been proved for its better performance in WSNs. The clustering technique is effective in prolonging the lifetime of the WSN. In this study, we have modified the ad-hoc on demand distance vector routing by incorporating signal-to-noise ratio (SNR) based dynamic clustering. The proposed scheme, which is an efficient and secure routing protocol for wireless sensor networks through SNR-based dynamic clustering (ESRPSDC) mechanisms, can partition the nodes into clusters and select the cluster head (CH) among the nodes based on the energy, and non CH nodes join with a specific CH based on the SNR values. Error recovery has been implemented during the inter-cluster routing in order to avoid end-to-end error recovery. Security has been achieved by isolating the malicious nodes using sink-based routing pattern analysis. Extensive investigation studies using a global mobile simulator have shown that this hybrid ESRP significantly improves the energy efficiency and packet reception rate as compared with the SNR unaware routing algorithms such as the low energy aware adaptive clustering hierarchy and power efficient gathering in sensor information systems.

• 한국전기전자재료학회논문지
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• 제26권5호
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• pp.335-340
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• 2013

In this study, the plasma etching of the TaN thin film with $CH_4/BCl_3/Ar$ gas chemistries was investigated. The etch rate of the TaN thin film and the etch selectivity of TaN to $SiO_2$ was studied as a function of the process parameters, including the amount of $CH_4$. X-ray photoelectron spectroscopy (XPS) and Field-emission scanning electron microscopy (FE-SEM) was used to investigate the chemical states of the surface of the TaN thin film.

• 센서학회지
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• 제24권4호
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• pp.258-263
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• 2015

In order to prevent drink-driving by detecting concentration of alcohol from driver's exhale breath, twenty chemical sensors fabricated. The one of purposes for sensor array which consists of those sensors is to discriminate between target gas(alcohol) and interference gases($CH_3CH_2OH$, CO, NOx, Toluene, and Xylene). Wilks's lambda was presented to achieve above purpose and optimal sensors were selected using the method. In this paper, step-wise sensor elimination based on Euclidean distance was investigated for selecting optimal sensors and compared with a result of Wilks's lambda method. The selectivity and sensitivity of sensor array were used for comparing performance of sensor array as a result of two methods. The data acquired from selected sensor were analyzed by pattern analysis methods, principal component analysis and Sammon's mapping to analyze cluster tendency in the low space (2D). The sensor array by stepwise sensor elimination method had a better sensitivity and selectivity compared to a result of Wilks's lambda method.

• 한국재료학회지
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• 제21권4호
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• pp.232-235
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• 2011

ZnO nanorods for gas sensors were prepared by a hydrothermal method. The ZnO gas sensors were fabricated on alumina substrates by a screen printing method. The gas-sensing properties of the ZnO nanorods were investigated for $CH_4$ gas. The effects of growth time on the structural and morphological properties of the ZnO nanorods were investigated by X-ray diffraction and scanning electron microscope. The XRD patterns of the nanocrystallized ZnO nanorods showed a wurtzite structure with the (002) predominant orientation. The diameter and length of the ZnO nanorods increased in proportion to the growth time. The sensitivity of the ZnO sensors to 5 ppm $CH_4$ gas was investigated for various growth times. The ZnO sensors exhibited good sensitivity and rapid response-recovery characteristics to $CH_4$ gas, and both traits were dependent on the growth time. The highest sensitivity of the ZnO sensors to $CH_4$ gas was observed with the growth time of 7 h. The response and recovery times were 13 s and 6 s, respectively.