• Korean Journal of Materials Research
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• v.25 no.6
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• pp.300-304
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• 2015

Nanorod ZnO and spherical nano ZnO for gas sensors were prepared by hydrothermal reaction method and hydrazine method, respectively. The nano-ZnO gas sensors were fabricated by a screen printing method on alumina substrates. The gas sensing properties were investigated for hydrocarbon gas. The effects of Co concentration on the structural and morphological properties of the nano ZnO:Co were investigated by X-ray diffraction and scanning electron microscope (SEM), respectively. XRD patterns revealed that nanorod and spherical ZnO:Co with a wurtzite structure were grown with (100), (002), (101) peaks. The sensitivity of nanorod and spherical ZnO:Co sensors was measured for 5 ppm $CH_4$ and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in target gases. The highest sensitivity to the $CH_4$ and $CH_3CH_2CH_3$ gas of spherical nano ZnO:Co sensors was observed at Co 6 wt%. The spherical nano ZnO:Co sensor exhibited a higher sensitivity to hydrocarbon gas than nanorod ZnO.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.624-629
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• 2018

The current study was conducted to develop a portable composite gas detector allowing the detection of both $CO_2$ and $CH_4$ gases by means of the Non Dispersive Infra-Red (NDIR) method. The gas detector is configured to radiate infrared waves using infrared lamps, where the wavelength of the infrared light is reduced due to absorption throughout the chamber, and this reduction (absorption) is detected by the absorption detector, before being converted and amplified to a 3.5V~6V electrical signal, providing as accurate a measurement as possible. The conventional singe sensor method measures the relative measurement by absorbing only specified wavelengths of infrared radiation, which in the case of gas detection leads to problems with accuracy due to the lack of a reference sensor when detecting light with a wavelength of only $4.26{\mu}m$. The dual sensor employed in this study provides a comparative measurement between the reference value derived from the wavelength of $3.91{\mu}m$, which is not influenced by other gas sources, and the measurement value derived from the wavelength of $4.26{\mu}m$, in order to reduce the errors and enhance the reliability, thereby allowing low power consumption for portable devices and multi-gas detection for both $CO_2$ and $CH_4$ gases. The portable composite gas detector developed herein provides a measurement rage of 0ppm~5,000ppm for $CO_2$ gas, and 0.5%vol for $CH_4$, which allows the determination of whether the $CO_2$ and $CH_4$ contents in indoor air are less than 1,000ppm or not. The current study established that the composite gas detector can be interlinked with firefighting appliances through portable devices or home automation, and is anticipated to be very effective in fire prevention.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.24 no.7
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• pp.589-593
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• 2011

[ $SnO_2$ ]nano powders were prepared by solution reduction method using tin chloride($SnCl_2{\cdot}2H_2O$), hydrazine($N_2H_4$) and NaOH. The $SnO_2$ thick films for gas sensors were fabricated by screen printing method on alumina substrates and annealed at $300^{\circ}C$ in air, respectively. XRD patterns of the $SnO_2$ nano powders showed the tetragonal structure with (110) dominant orientation. The particle size of $SnO_2$ nano powders at the ratio of $SnCl_2:N_2H_4$+NaOH= 1:6 was about 60 nm. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box. Sensitivity of $SnO_2$ gas sensor to 5 ppm $CH_4$gas and 5 ppm $CH_3CH_2CH_3$ gas was investigated for various $SnCl_2:N_2H_4$+NaOH proportion. The highest sensitivity to $CH_4$ gas and $CH_3CH_2CH_3$ gas of $SnO_2$ sensors was observed at the $SnCl_2:N_2H_4$+NaOH= 1:8 and $SnCl_2:N_2H_4$+NaOH= 1:6, respectively. Response and recovery times of $SnO_2$ gas sensors prepared by $SnCl_2:N_2H_4$+NaOH= 1:6 was about 40 s and 30 s, respectively.

• Journal of Sensor Science and Technology
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• v.27 no.3
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• pp.199-203
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• 2018

In this study, we develop a methane sensor module that can detect low concentrations below 5,000 ppm and measure up to the detection limit of 50 ppm with the NDIR method, with a long lifetime and high accuracy. Methane ($CH_4$) is one of a representative greenhouse gas, which is very explosive. Thus, it is important to quickly and accurately measure methane concentration in the air. To adjust the methane sensor for industrial field applications, a NDIR-based small sensor was implemented and characterized, where its volume was $4cm{\times}4cm{\times}2cm$ and its response time ($T_{90}$) was less than 30 sec. These results demonstrate that the proposed sensor is commercially available for low-concentration measurement, low volume, and fast response application, such as IoT sensor nodes and portable devices.

• Journal of Sensor Science and Technology
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• v.13 no.4
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• pp.298-302
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• 2004

Thick films of $LaNiO_{3}$ having perovskite structure impregnated with indium and bismuth oxides have been used as sensing material for acetonitrile ($CH_{3}CN$) gas. The sensor response for $CH_{3}CN$ is quite good with an excellent recovery for partial pressure from 3 ppm to 20 ppm between 200 and $250^{\circ}C$. $LaNiO_{3}$ alone has exhibited low response, but after impregnation of $In_{2}O_{3}$ and $Bi_{2}O_{3}$ have given increased sensitivity even with 3 ppm partial pressure of $CH_{3}CN$ at $200^{\circ}C$. It is assumed that $CH_{3}CN$ is undergoing oxidation reaction on surface of the film.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.8 no.4
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• pp.1237-1255
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• 2014

In wireless sensor networks (WSNs), hierarchical clustering is an efficient approach for lower energy consumption and extended network lifetime. In cluster-based multi-hop communications, a cluster head (CH) closer to the sink is loaded heavier than those CHs farther away from the sink. In order to balance the energy consumption among CHs, we development a novel cluster-based routing protocol for corona-structured wireless sensor networks. Based on the relaying traffic of each CH conveys, adequate radius for each corona can be determined through nearly balanced energy depletion analysis, which leads to balanced energy consumption among CHs. Simulation results demonstrate that our clustering approach effectively improves the network lifetime, residual energy and reduces the number of CH rotations in comparison with the MLCRA protocols.

• Journal of Communications and Networks
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• v.15 no.4
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• pp.422-429
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• 2013

Advances in wireless sensor network (WSN) technology have enabled small and low-cost sensors with the capability of sensing various types of physical and environmental conditions, data processing, and wireless communication. In the WSN, the sensor nodes have a limited transmission range and their processing and storage capabilities as well as their energy resources are limited. A triple umpiring system has already been proved for its better performance in WSNs. The clustering technique is effective in prolonging the lifetime of the WSN. In this study, we have modified the ad-hoc on demand distance vector routing by incorporating signal-to-noise ratio (SNR) based dynamic clustering. The proposed scheme, which is an efficient and secure routing protocol for wireless sensor networks through SNR-based dynamic clustering (ESRPSDC) mechanisms, can partition the nodes into clusters and select the cluster head (CH) among the nodes based on the energy, and non CH nodes join with a specific CH based on the SNR values. Error recovery has been implemented during the inter-cluster routing in order to avoid end-to-end error recovery. Security has been achieved by isolating the malicious nodes using sink-based routing pattern analysis. Extensive investigation studies using a global mobile simulator have shown that this hybrid ESRP significantly improves the energy efficiency and packet reception rate as compared with the SNR unaware routing algorithms such as the low energy aware adaptive clustering hierarchy and power efficient gathering in sensor information systems.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.5
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• pp.335-340
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• 2013

In this study, the plasma etching of the TaN thin film with $CH_4/BCl_3/Ar$ gas chemistries was investigated. The etch rate of the TaN thin film and the etch selectivity of TaN to $SiO_2$ was studied as a function of the process parameters, including the amount of $CH_4$. X-ray photoelectron spectroscopy (XPS) and Field-emission scanning electron microscopy (FE-SEM) was used to investigate the chemical states of the surface of the TaN thin film.

• Journal of Sensor Science and Technology
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• v.24 no.4
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• pp.258-263
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• 2015

In order to prevent drink-driving by detecting concentration of alcohol from driver's exhale breath, twenty chemical sensors fabricated. The one of purposes for sensor array which consists of those sensors is to discriminate between target gas(alcohol) and interference gases($CH_3CH_2OH$, CO, NOx, Toluene, and Xylene). Wilks's lambda was presented to achieve above purpose and optimal sensors were selected using the method. In this paper, step-wise sensor elimination based on Euclidean distance was investigated for selecting optimal sensors and compared with a result of Wilks's lambda method. The selectivity and sensitivity of sensor array were used for comparing performance of sensor array as a result of two methods. The data acquired from selected sensor were analyzed by pattern analysis methods, principal component analysis and Sammon's mapping to analyze cluster tendency in the low space (2D). The sensor array by stepwise sensor elimination method had a better sensitivity and selectivity compared to a result of Wilks's lambda method.

• Korean Journal of Materials Research
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• v.21 no.4
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• pp.232-235
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• 2011

ZnO nanorods for gas sensors were prepared by a hydrothermal method. The ZnO gas sensors were fabricated on alumina substrates by a screen printing method. The gas-sensing properties of the ZnO nanorods were investigated for $CH_4$ gas. The effects of growth time on the structural and morphological properties of the ZnO nanorods were investigated by X-ray diffraction and scanning electron microscope. The XRD patterns of the nanocrystallized ZnO nanorods showed a wurtzite structure with the (002) predominant orientation. The diameter and length of the ZnO nanorods increased in proportion to the growth time. The sensitivity of the ZnO sensors to 5 ppm $CH_4$ gas was investigated for various growth times. The ZnO sensors exhibited good sensitivity and rapid response-recovery characteristics to $CH_4$ gas, and both traits were dependent on the growth time. The highest sensitivity of the ZnO sensors to $CH_4$ gas was observed with the growth time of 7 h. The response and recovery times were 13 s and 6 s, respectively.