• 제목/요약/키워드: CD spectrum

검색결과 193건 처리시간 0.027초

$CdIn_2Te_4$ 결정의 띠간격 에너지의 온도 의존성과 가전자대 갈라짐에 대한 연구 (Band gap energy and photocurrent splitting for CdIn2Te4 crystal by photocurrent spectroscopy)

  • 홍광준;김도선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.121-122
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    • 2006
  • Single crystal of $CdIn_2Te_4$ were grown by the Bridgman method without using seed crystals. From photocurrent measurements, its was found that three peaks, A, B, and C, correspond to the instrinsic transition from the valence band states of ${\Gamma}_7$(A), ${\Gamma}_6$(B), and ${\Gamma}_7$(C) to the conducton band states of ${\Gamma}_6$, respectively. Crystal field splitting and spin orbit splitting were found to be at 0.2360 eV and 0.1119 eV, respectively, from found to be photocurrent spectroscopy.

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Electro-optical Characterization of OLED Device

  • Lee Soon-Seok;Kim Ki-Seok;Lim Sung-Kyoo
    • International Journal of Contents
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    • 제2권3호
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    • pp.6-10
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    • 2006
  • Small molecule OLED devices were fabricated and the electro-optical characteristics were analyzed. The luminance and color coordinate of the fabricated OLED device were $24,390cd/m^2$ and (x=0.15, y=0.22), respectively. Current efficiency of 6.8 cd/A and power efficiency of 2.4 lm/W were also obtained under DC operating condition. Transient light intensity was also measured by using Si photodiode.

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Cadmium Sulphide Nanorods: Synthesis, Characterization and their Photocatalytic Activity

  • Giribabu, Krishnamoorthy;Suresh, Ranganathan;Manigandan, Ramadoss;Vijayaraj, Arunachalam;Prabu, Raju;Narayanan, Vengidusamy
    • Bulletin of the Korean Chemical Society
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    • 제33권9호
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    • pp.2910-2916
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    • 2012
  • Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.

Qauntum Dot Sensitized Solar Cell Using Ag2S/CdS Co-sensitizer

  • 황인성;용기중
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.461.1-461.1
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    • 2014
  • 본 연구진에서는 기존에 Ag2S 양자점을 흡광층으로 활용하여 양자점 감응형 태양전지(QDSC)를 제작, 그 성능과 특징을 분석하여 발표한 바 있다. 기존 연구에서 제작된 Ag2S QDSC는 11 mA/cm2의 비교적 높은 광전류와 260 mV의 비교적 낮은 전압으로 인해 1.2%의 광전환효율 성능을 나타내는 것으로 보고되었다. 추후 연구로 진행된 본 결과에서는, 기존에 Single absorber로 사용된 Ag2S의 한계를 보완하기 위해 CdS를 도입하여 co-sensitization을 활용하였다. CdS는 약 2.3 eV의 밴드갭 에너지를 갖는 물질로, 1.1 eV의 밴드갭을 갖는 Ag2S에 비해 흡광 영역은 좁지만 그만큼 전자-정공 재결합을 억제할 수 있는 장점을 가지고 있다. 또한, 전도층으로 사용한 n-type 물질인 ZnO 나노선과의 밴드구조가 매우 적합하게 조화되어, ZnO/CdS/Ag2S 순서로 이종구조를 접합시켰을 때 세 물질의 Conduction band level과 Valence band level이 순차적으로 연결되는 cascade-shaped 밴드구조를 이루게 된다. 빛을 받아 Ag2S와 CdS에서 생성된 전자는 이 cascade 모양의 conduction band를 따라 순차적으로 ZnO로 잘 전달되게 되어, 효율 향상에 큰 도움을 주었다. 이런 장점들로 인해, CdS-Ag2S co-sensitized QDSC는 Ag2S QDSC에 비해 2배나 향상된 효율인 2.4%를 기록하였으며, 이는 IPCE spectrum 측정 등으로 근거가 뒷받침되었다.

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Variation in IR and Raman Spectra of CD3CN upon Solvation of InCl3 in CD3CN: Distinctive Blue Shifts, Coordination Number, Donor-Acceptor Interaction, and Solvated Species

  • Cho, Jun-Sung;Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • 제30권4호
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    • pp.803-809
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    • 2009
  • Notable blue shifts of the ν2 $C{\equiv}N$ stretching, $_{v4}$ C-C stretching and $_{v8}$ CCN deformation bands of $CD_3CN$ are observed upon solvation of $InCl_3$, resulting from the donor-acceptor interaction. The Raman spectrum in the $_{v2}$ region shows further details; at least two new bands emerge on the blue side of the $_{v2}$ band of free $CD_3CN$, whose relative intensities vary with concentration, suggesting that there exist at least two different cationic species in the solution. The strong hydrogen bonds formed between the methyl group and ${InCl_4}^-$ result in a large band appearing on the red side of the ν1 $CD_3$ symmetric stretching band. The solvation number of $InCl_3$, determined from the Raman intensities of the $C{\equiv}N$ stretching bands for free and coordinated $CD_3CN$, increases from $\sim$1.5 to $\sim$1.8 with decreasing concentration.

CaS:Eu,S 전계발광소자의 특성 (Characteristics of CaS:Eu,S electroluminescent devices)

  • 조제철;유용택
    • E2M - 전기 전자와 첨단 소재
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    • 제8권6호
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    • pp.752-758
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    • 1995
  • Red emitting CaS:Eu,S electroluminescent(EL) device prepared at 550.deg. C by an electron-beam evaporation technique, demonstrated luminance of 175cd/m$\^$2/ and efficiency of 0.311m/W with 3kHz drive. Luminance was increased with the increase of applied voltage and frequency. From the results of the PL spectrum and the EL spectrum, the CaS:Eu, S device showed emission peak near 640nm resulted from the transition of EU$\^$2+/ 4f$\^$6/5d.rarw.4f$\^$7/. The capacitance of the phosphor layer from the Sawyer-Tower circuit was 10.5nF/cm$\^$2/.

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기판온도 및 열처리온도에 대한 CdS 박막의 전기적 및 광학적 특성 (Dependence of the Electrical and Optical Properties of CdS Thin Films on Substrate and Annealing Temperatures)

  • 박기철;심호섭;김정규
    • 센서학회지
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    • 제6권2호
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    • pp.163-171
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    • 1997
  • CSVT(close spaced vapor transport)증착시스템으로 태양전지의 창재에 적합한 CdS박막을 기판온도에 따라 증착하였으며, 실온에서 증착된 CdS박막을 온도를 변화시켜 가면서 열처리하였다. 증착 및 열처리후의 CdS박막의 구조적, 전기적 및 광학적 특성을 조사하였다. 증착조건에 무관하게 CdS박막들은 육방정계구조로 (002)면으로 기판에 수직으로 성장함을 확인하였다. 기판온도가 $25^{\circ}C$에서 $300^{\circ}C$까지 증가함에 따라 비저항은 $60{\Omega}cm$로 부터 $2{\times}10^{4}{\Omega}cm$로 단순증가하였으며 기판온도 $25^{\circ}C$에서 가시광영역에서의 광투과도가 80%정도로 가장 높았다. 열처리온도가 증가함에 따라 막내의 결정결함의 증가에 따라 비저항은 현저하게 증가하였으며 광투과도는 현저하게 감소하였다.

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Synthesis of CdS with Graphene by CBD(Chemical Bath Deposition) Method and Its Photocatalytic Activity

  • Pawar, R.C.;Lee, Jin-Yong;Kim, Eun-Jeong;Kim, Hyungsub;Lee, Caroline Sunyong
    • 한국재료학회지
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    • 제22권10호
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    • pp.504-507
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    • 2012
  • Synthesis of RGO (reduced graphene oxide)-CdS composite material was performed through CBD (chemical bath deposition) method in which graphene oxide served as the support and Cadmium Sulfate Hydrate as the starting material. Graphene-based semiconductor photocatalysts have attracted extensive attention due to their usefulness for environmental and energy applications. The band gap (2.4 eV) of CdS corresponds well with the spectrum of sunlight because the crystalline phase, size, morphology, specic surface area and defects, etc., of CdS can affect its photocatalytic activity. The specific surface structure (morphology) of the photocatalyst can be effective for the suppression of recombination between photogenerated electrons and holes. Graphene (GN) has unique properties such as a high value of Young's modulus, large theoretical specific surface area, excellent thermal conductivity, high mobility of charge carriers, and good optical transmittance. These excellent properties make GN an ideal building block in nanocomposites. It can act as an excellent electron-acceptor/transport material. Therefore, the morphology, structural characterization and crystal structure were observed using various analytical tools, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. From this analysis, it is shown that CdS particles were well dispersed uniformly in the RGO sheet. Furthermore, the photocatalytic property of the resulting RGO-CdS composite is also discussed in relation to environmental applications such as the photocatalytic degradation of pollutants. It was found that the prepared RGO-CdS nanocomposites exhibited enhanced photocatalytic activity as compared with that of CdS nanoparticles. Therefore, better efficiency of photodegradation was found for water purification applications using RGO-CdS composite.

전자빔 증착법에 의한 CdSe/GaAs epilayer의 성장과 그 전기-광학적 특성 (Growth and electro-optical characteristics of CdSe/GaAs epilayers prepared by electron beam epitaxy)

  • 양동익;신영진;이춘호;최용대;유평렬
    • 한국결정성장학회지
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    • 제7권1호
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    • pp.70-75
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    • 1997
  • Electron beam 증착법을 보완하여 GaAs(100)기판위에 cubic(zinc blende) CdSe 에피충을 성장시켜 그의 특성을 조사하였다 .. CdSe 에피충의 격자 상수는 6.077 A였으며, 배향 성은 ECP 패번에 의하여 확인되고 결정성은 DCXR curve로 관찰하였다. 상온에서 측정된 H Hall data로는 에피충의 운반자 농도와 이통도는 각각 1018cm-3, 102cm2N' see 정도임을 알았 고 30 K에서 측정한 PC spectra peak는 cubic CdSe의 free exciton에 기인된 것으로 1.746 e eV에서 예리하게 나타냐고 있음을 보여주고 있다.

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테라헤르츠 시간 영역 분광의 광정류시 발생하는 테라헤르츠 스펙트럼 모델링 (Modeling of THz Frequency Spectrum via Optical Rectification in THz Time Domain Spectroscopy)

  • 이강희;이민우;안재욱
    • 비파괴검사학회지
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    • 제28권2호
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    • pp.119-124
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    • 2008
  • 최근 비파괴 검사를 위한 테라헤르츠 전자기파 기술에 대한 관심이 높아지고 있으며 특히 비파괴검사에서 많은 응용이 기대된다. 테라헤르츠 시간 영역 분광법은 이러한 테라헤르츠 기술에 핵심이 되는 기술로 많은 실험이 이루어지고 있다. 본 논문에서는 테라헤르츠 시간 영역 분광에서 비선형 전광물질을 이용하는 광정류 방식을 통해 발생된 테라헤르츠 전자기파 스펙트럼이 비선형 맥스웰 방정식의 해와 실험에 의해 결정되는 흡수, 회절, 표면간섭 효과 등을 고려한 본문의 모델을 통하여 예측가능하며 실제 티타늄:사파이어 레이저 펄스를 $400{\mu}m$ CdTe에 조사하여 발생된 테라헤르츠파 주파수 스펙트럼의 측정 결과와 비교하여 매우 유사하다는 사실을 보여준다. 이를 통하여 본문에서 소개된 모델은 다른 전광물질을 통해 발생된 테라헤르츠 스펙트럼에도 확장되어 적용 될 수 있다.