• Title/Summary/Keyword: CATION

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Impurity Diffusion Enhancement of Interdiffusion in GalnAsP Heterostructures Lattice Matched to GaAs and InP (GaAs와 InP에 격자정합된 GaINAsP 이중조직에서 불순물 확산에 의한 상호확산 촉진)

  • Park, Hyo-Hun;Lee, Gyeong-Ho;Nam, Eun-Su;Lee, Yong-Tak
    • ETRI Journal
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    • v.11 no.4
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    • pp.84-97
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    • 1989
  • The influence of Zn, Si and Te diffusion on the interdiffusion in $GaAs-Ga_1_-xIN_xAs_1__yP_y$and InP$Ga_1__xIn_xAs_1__yP_y$ heterostructures was studied. The heterostructures were grown by liquid phase epitaxy, and the impurity diffusion into the heterostructures was carried out using metal compound or element sources. The extent of interdiffusion for both group III and V atoms was observed by depth profiling of matrix elements with secondary ion mass spectrometry and Auger electron spectroscopy. Selective enhancement of cation interdiffusion was observed by the concurrent Zn diffusion in both the GaAs based-and InP based-crystals. In contrast to the Zn diffusion, the Si diffusion in the GaAs based-crystal and the Te diffusion in the InP based-crystal enhanced both cation and anion interdiffusion to the same extent. A kick-out mechanism is proposed to explain the selective enhancement of the cation interdiffusion due to Zn, and a single vacancy mechanism is proposed for the interdiffusion due to Si and Te.

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Retention Behavior of Lanthanides on Dinonylnaphthalene Sulfonic Acid Equilibrated Cation Exchanger (Dinonylnaphthalene Sulfonic Acid 를 양이온 교환체로 이용한 동적계에서 희토류 원소의 머무름 거동)

  • Kihsoo Joe;Sun Ho Han;Moo Yul Suh;Tae Yoon Eom;Youn Doo Kim
    • Journal of the Korean Chemical Society
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    • v.35 no.5
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    • pp.520-526
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    • 1991
  • Retention behavior of lanthanides was studied on the dynamic system using dinonylnaphthalene sulfonic acid cation exchanger and tartaric acid as a complexing agent. The relations between logk' and log$[NH^{4+}]$/log[tartarate], and between logk' and logR showed good linearity in isocratic and gradient elution, respectively. In gradient elution of tartaric acid the slopes were increased as the initial concentrations were decreased. Column efficiencies and resolution of lanthanides on dinonylnaphthalene sulfonic acid equilibrated cation exchanger were found to be better in ${\alpha}$-hydroxyisobutyric acid eluent than in tartaric acid.

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The Inhibitory Effect of Opioid on the Hyperpolarization-Activated Cation Currents in Rat Substantia Gelatinosa Neurons

  • Seol, Geun-Hee;Kim, Jun;Cho, Sun-Hee;Kim, Won-Ki;Kim, Jong-Whan;Kim, Sang-Jeong
    • The Korean Journal of Physiology and Pharmacology
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    • v.5 no.5
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    • pp.373-380
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    • 2001
  • The action of opioid on the hyperpolarization-activated cation current $(I_h)$ in substantia gelatinosa neurons were investigated by using whole-cell voltage-clamp recording in rat spinal brain slices. Hyperpolarizing voltage steps revealed slowly activating currents in a subgroup of neurons. The half-maximal activation and the reversal potential of the current were compatible to neuronal $I_h.$ DAMGO $(1\;{\mu}M),$ a selective- opioid agonist, reduced the amplitude of $I_h$ reversibly. This reduction was dose-dependent and was blocked by CTOP $(2\;{\mu}M),$ a selective ${\mu}-opioid$ antagonist. DAMGO shifted the voltage dependence of activation to more hyperpolarized potential. Cesium (1 mM) or ZD 7288 $(100\;{\mu}M)$ blocked $I_h$ and the currents inhibited by cesium, ZD 7288 and DAMGO shared a similar time and voltage dependence. These results suggest that activation of ${\mu}-opioid$ receptor by DAMGO can inhibit $I_h$ in a subgroup of rat substantia gelatinosa neurons.

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The design parameter evaluation of ion exchange process for ultra pure water production (초순수 생산을 위한 이온교환공정 설계특성 평가)

  • Park, Se-Chool;Kwon, Boung-Su;Lee, Kyung-Hyuk;Jung, Kwan-Sue
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.1
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    • pp.65-75
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    • 2015
  • In this study, cation and anion exchange process for performance evaluation was conducted. A pilot plant for the ultrpure water production was installed with the capacity of $25m^3/d$. The various production rate and regeneration of ion exchange rate were tested to investigate the design parameters. The test resulst was applied to calculate the operating costs. Changing the flow rate of the ion exchange capacity of the reproduction reviewed the cation exchange process as opposed to the design value is 120 to 164% efficiency, whereas both anion exchange process is 82 to 124% efficiency, respectively. This results can be applied for more large scale plant if the scale up parameters are consdiered. The ion exchange capacity of the application in accordance with the design value characteristic upon application equipment is expected to be needed. In this study, the performance of cation and anion exchange resin process was evaluated with pilot plant($25m^3/d$). The ion exchange capacity along with space velocity and regeneration volume was evaluated. In results, the operation results was compared with design parameters.

Application of Zeolite with Different Cation Exchange Capacity for the Stabilization of Heavy Metals in Upland Soil (양이온교환용량이 다른 제올라이트 처리에 따른 밭토양 내 중금속 안정화 평가)

  • Gu, Bon-Wun;Kim, Mun-Ju;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.59 no.5
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    • pp.41-49
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    • 2017
  • This study was aimed to investigate the influence of cation exchange capacity (CEC) and application amounts of zeolite on the stabilization of heavy metals (As, Ni, Pb, and Zn) in upland soils. The upland soils were sampled from field near mines located in Gyeonggi Province. The CEC of zeolite was treated at three different levels, ie, low, medium, and high, while zeolite was amended with soils at the ratio of 0.1 % and 0.5 % as to soil weight. A sequential extraction was performed for the soil sampled at 1, 2 4, and 8 week after zeolite was added to the soil. The concentrations of Pb and Zn appeared to be high in the sampled soils. The mobility of heavy metals obtained from sequential experiments was as follows: Pb > Zn > Ni >As. Addition of zeolite to contaminated soils effectively reduced exchangeable and carbonate fractions but increased organic and residual fraction, indicating that zeolite is effective for immobilizing heavy metals in soils. The influence of incubation time on the metal stabilization was rather pronounced as compared to the application amount and CEC of zeolite.

Solute Transport Model with Cation Exchange under Redox Environment and its Application for Designing the Slow Infiltration Set-up

  • GUERRA, GINGGING;JINNO, KENJI;HIROSHIRO, YOSHINARI;NAKAMURA, KOJI
    • Proceedings of the Korea Water Resources Association Conference
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    • 2004.05b
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    • pp.90-101
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    • 2004
  • The present trend of disposing treated sewage water by allowing it to infiltrate the soil brings a new dimension to environmental problems. It is therefore necessary to identify the chemicals likely to be present in treated sewage water. A soil column experiment was conducted to determine the behavior of chemical species in soil columns applied with secondary treated sewage water. To predict the behavior of chemical species, a multicomponent solute transport model that includes the biochemical redox process and cation exchange process was developed. The model computes changes in concentration over time caused by the processes of advection, dispersion, biochemical reactions and cation exchange reactions. The solute transport model was able to predict the behavior of the different chemical species. The model reproduced the sequential reduction reaction. To design the safe depth of plow layer where $NO_3^-$ is totally reduced, a numerical study of $NO_3^-$ leach was done and it was found out that the pore velocity and concentration of $CH_2O$ at the inject water was found to affect $NO_3^-$ reduction in the mobile pore water phase. It is revealed that the multicomponent solute transport model is useful to design the land treatment system for $NO_3^-$ removal from wastewater.

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Thermal and Mineralogical Characterization of Ca-Montmorillonite from Gampo Area (감포지역(甘浦地域) Ca-몬모릴로나이트의 열적(熱的) 및 광물학적(鑛物學的) 특성(特性))

  • Moon, Hi-Soo;Choi, Sun Kyung;Kim, Moon Young
    • Economic and Environmental Geology
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    • v.21 no.2
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    • pp.175-184
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    • 1988
  • Ten under 2 micron size fractions of the montmorillonite from Yongdongri area, Gyeongsangbug-Do were studied using X-ray powder diffraction, cation exchange measurement, differential thermal analysis, thermogravimetric analysis, differential thermal scanning calorimetry and chemical analysis. Montmorillonites occurring at same deposit show limited variation in chemical composition whereas in thermal properties they do not. Their dehydroxylation endothermic peaks are "abnormal" type with a small range of variation of peak temperature reflecting tetrahedral substitution of Al for Si. Data from DSC show that divalent-cation saturated montmorillonite has relatively a higher endothermic heat capacity than monovalent-cation saturated montmorillonite, indicating that cations with higher electronegativity hold more water molecules.

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The Bio-Softning Finish of Tencel Fabric(II) - Change of Mechanical Properties - (텐셀직물(織物)의 바이오-유연가공(柔軟加工)에 의한 물성변화(物性變化) (II) - 역학적(力學的) 특성(特性)의 변화(變化) -)

  • Song, Wha-Soon;Kim, In-Young;Oh, Soo-Min
    • Journal of Fashion Business
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    • v.5 no.2
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    • pp.67-72
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    • 2001
  • Tencel fabric was treated with cellulase and softener. And then Mechanical properties were investigated. Basic characteristic values of clothing wearing were calculated. With the treatment of cellulase and softener treatment, WT, RT, LC, WC, RC of mechanical characteristics were increased, and G, 2HG, 2HG5, B, 2HB were decreased. B/W, $\sqrt[3]{B/W}$, $\sqrt{2HB/W}$, 2HB/B, W/T of Basic characteristic values of clothing wearing were decreased. WC/W, WC/T were increased, Therefore, drapability, crease resistance, pressing softness, air content were improved. In consideration of mechanical characteristics and basic characteristic values of clothing wearing depending on the softener, values of WT, WC/W, WC/T were bigger with the treatment of epoxy and snow softener than with the treatment of cation and blend softener. LC, WC, RC, B/W, $\sqrt[3]{B/W}$, $\sqrt{2HB/W}$, 2HB/B, W/T were bigger with the treatment of cation and blend softener than with the treatment of epoxy and snow softener. Thereofre, with the treatment of epoxy and snow softener, drapability, crease resistance, air content were improved. With the treatment of cation and blend softener, pressing softness were improved.

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Selective Disproportionation of Toluene over Various Cation-exchanged ZSM-5 Catalysts (양이온 교환된 ZSM-5 촉매상에서 톨루엔의 선택적인 반응)

  • Jong Shin Yoo;Byoung Joon Ahn;Hakze Chon
    • Journal of the Korean Chemical Society
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    • v.27 no.2
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    • pp.127-132
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    • 1983
  • The catalytic activity of ZSM-5 catalyst for the disproportionation of toluene is dependent on the type of cation exchanged, the degree of ion-exchange and the reaction temperature. The activity increases in the order of alkaline-, alkali earth-, hydrogen, and rare-earth-exchanged ZSM-5 and decreases with increasing degree of cation exchange. Among the ion-exchanged ZSM-5 catalyst, only Cs-ZSM-5 shows predominant selectivity for p-xylene. The selectivity increases with increasing degree of $Cs^+$-exchange and decreasing reaction temperature. This phenomenon is interpreted in terms of shape selectivity arising from the partial blocking of channel intersections by large cesium ions.

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Research on Preparation of Sheath-Core Bicomponent Composite Ion Exchange Fibers and Absorption Properties to Metal Ion

  • Ding, Zhi-Jia;Qi, Lu;Ye, Jian-Zhong
    • Macromolecular Research
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    • v.16 no.1
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    • pp.21-30
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    • 2008
  • Based on the sheath-core bicomponent composite fibers with modified polystyrene (PS) and the modified polypropylene (PP), composite fibers obtained were further cross-linked and sulphonated with chlorosulphonic acid to produce strong acidic cation ion exchange fibers. The structures of the fibers obtained were characterized using Fourier transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC) etc. The optimal technology of the fibers obtained is discussed. The static absorption capacity of the sheath-core bicomponent composite cation exchange fibers for $Zn^{2+}$, $Cu^{2+}$ was determined. The absorption kinetics and major factors affecting the absorption capacities of $Zn^{2+}$, $Cu^{2+}$ were studied, and its chemical stability and regenerating properties were probed. The results suggest that cation exchange fibers with better mechanical properties and higher exchange capability were obtained. Moreover, this type of ion exchange fiber has good absorption properties and working stability to various metal ions. Hence, they have higher practicability.