• Computers and Concrete
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• v.33 no.6
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• pp.689-706
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• 2024

This study is aimed at identifying structural element stiffness influence on vertical earthquake response of mid-rise R/C frame buildings. To this aim, a mid-rise RC building structure is designed as per the new Turkish Seismic Code for Buildings-2018, and 3D FE model of the building is established. Based on the established FE model, a total number of six buildings are considered depending on certain percentage increase in beam, slab, and column. The time-history response analyses (THA) are performed separately for only horizontal (H) and horizontal +vertical (H+V) earthquake motions to make a comparison between the load cases. The analysis results are presented comparatively in terms of the monitoring parameters of the base overturning moment (M_o), the top-story lateral displacement (d_L) and the top-story vertical displacement (d_V). The obtained results reveal that the base overturning moment and the top-story vertical displacement are affected by vertical earthquake motion regardless of the increase in the dimension of beam, slab, and column. However, vertical earthquake motion is not effective on the top-story lateral displacement due to no change between H and H+V load. The dimensional increase in either slab or beam leads to a considerable increase in the base overturning moment and the top-story vertical displacement while causing decrease in the top-story lateral displacement. In addition, the dimensional increase in column has a positive effect on the decrease in the monitoring parameters of the base overturning moment (M_o), the top-story lateral displacement (d_L) and the top-story vertical displacement (d_V).

• Computers and Concrete
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• v.33 no.6
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• pp.707-724
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• 2024

This paper proposes a study of cement replacement with rice husk ash (RHA) and eggshell ash (ESA) for enhanced mechanical properties of geopolymer (GP) concrete with and without admixture. The main objective is to investigate the mechanical properties of GP with various replacement levels of Pozzolana Portland cement by RHA and ESA. The GP resistance to durability is examined and impact of ash materials on concrete's durability performance is determined. The environmental benefits of using agricultural waste materials in GP manufacturing minimize cement usage and CO2 emissions. The goal is to assess value of RHA-ESA of building material, paving stones for structures to lessen environmental impact. The novelty lies in use of ESA and RHA as partial replacements for cement and investigation of admixtures to enhance concrete properties, and reduce environmental impact. The research contributes by introducing a novel approach to reducing cement consumption by using ESA and RHA to address environmental concerns. It also explores the potential benefits of admixtures improving concrete performance and reducing environmental pollution. A study is carried with and without impacts of admixture to find compressive strength of GP cubes. The cement has been replaced by RHA and ESA in the range of (2.5%+7.5%, 5%+5%, 7.5%+2.5) by weight of cement for M20 mix. The compressive strength (CS) and split tensile strength (STS) at 7days, 14 days and 28 days is obtained as 21 N/mm2 at 7.5%RHA+2.5%ESA and 2.3 at 7.5%RHA+2.5%ESA, 24 N/mm2 at 7.5%RHA+2.5%ESA and 2.3 at 7.5%RHA+2.5%ESA, 28 N/mm2 at 7.5%RHA+2.5%ESA and 2.8 at 7.5%ESA respectively with normal curing condition.

• Computers and Concrete
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• v.34 no.1
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• pp.93-122
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• 2024

One well-known reason for using Fiber Reinforced Polymer (FRP) composites is to improve concrete strength and strain capacity via external confinement. Hence, various studies have been undertaken to offer a good illustration of the response of FRP-wrapped concrete for practical design intents. However, in such studies, the strength and strain of the confined concrete were predicted using regression analysis based on a limited number of test data. This study presents an approach based on artificial neural networks (ANNs) to develop models to predict the strength and strain at maximum stress enhancement of circular concrete cross-sections confined with different FRP types (Carbone, Glass, Aramid). To achieve this goal, a large test database comprising 493 axial compression experiments on FRP-confined concrete samples was compiled based on an extensive review of the published literature and used to validate the predicted artificial intelligence techniques. The ANN approach is currently thought to be the preferred learning technique because of its strong prediction effectiveness, interpretability, adaptability, and generalization. The accuracy of the developed ANN model for predicting the behavior of FRP-confined concrete is commensurate with the experimental database compiled from published literature. Statistical measures values, which indicate a better fit, were observed in all of the ANN models. Therefore, compared to existing models, it should be highlighted that the newly developed models based on FRP type are remarkably accurate.

• Computers and Concrete
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• v.34 no.1
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• pp.1-14
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• 2024

The design of disturbed regions in reinforced concrete structures usually applies the well known Strut and Tie Method (STM). As an alternative, the Stringer-Panel Method (SPM), an intermediate model between STM and the Finite Element Method (FEM), consists in dividing a structure into two distinct elements: the stringers (which carry axial forces) and panels (which carry shear forces). SPM has already showed good applicability in manual calculations and computer implementations, and its most known application was SPanCAD, an AutoCAD plugin for linear and nonlinear analysis by SPM. Unfortunately, SPanCAD was discontinued by the developers, and it's not compatible with the most recent versions of AutoCAD. So, this paper aims to present a computer program that was developed as an upgrade to the latter: the Stringer Panel Modelling Tool (SPMTool), which is intended to be an auxiliary design tool and it presents improvements, in comparison to SPanCAD. It is possible to execute linear and nonlinear analysis by three distinct formulations: Modified Compression Field Theory (MCFT), Disturbed Stress Field Model (DSFM) and Softened Membrane Model (SMM). The nonlinear results were compared to experimental data of reinforced concrete elements that were not designed by SPM; these elements were also analyzed in SPanCAD. On overall, SPMTool made more realistic predictions to the behavior of the analyzed structures than SPanCAD. Except for DSFM predictions for corbels (1.24), in overall average, the ultimate load predictions were conservative (0.85 to 0.98), which is a good aspect for a design tool. On the other hand, the cracking load predictions presented overestimations (1.06 to 1.47) and higher variations (25.59% to 34.25%) and the post-cracking behavior could not be accurately predicted; for this use case, a more robust finite element software is recommended.

• Computers and Concrete
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• v.34 no.1
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• pp.33-48
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• 2024

This paper presents the detailed experimental and analytical investigation on the evolution of static (E_s) and dynamic modulus of elasticity (E_d) of concrete having 0%, 35%, and 50% FA used as partial cement replacement. Destructive and non-destructive tests were conducted on cylindrical specimens to evaluate the compressive strength and MoE of concrete in compression at the age of 28, 56, 90, and 150 days for all mixes. Experimental results show that the concrete having 35% FA achieved compressive strength and MoE similar to plain concrete at the age of 90 days, while 50% FA concrete attained satisfactory compressive strength and MoE at the age of 150 days. The comprehensive statistical analysis has been carried out in two ways on the basis of the experimental results. Firstly, the 28-day crushing strength of plain concrete in compression was used to design the models for the prediction of E_s and E_d of fly ash concrete at any age and percentage replacement of FA. Secondly, using the values of UPV and RHN, models have been developed to predict the age or time-dependent E_s and E_d of fly ash concrete. These models will be helpful in assessing the E_s and E_d of fly ash concrete without knowing the 28-day crushing strength of plain concrete in compression in the laboratory. Hence, the suggested models in the present study will be beneficial in conducting the health assessment of fly ash based concrete structures.

• Korean Journal of Environmental Agriculture
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• v.33 no.4
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• pp.388-394
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• 2014

BACKGROUND: Aclonifen is used as a systemic and selective herbicide to control a wide spectrum broad-leaf weeds by inhibition carotenoid biosynthesis, and then its MRLs(Maximum Residue Limits) will be determined in onion and garlic. In this study, a new official method was developed for aclonifen determination in agricultural products to routinely inspect the violation of MRL as well as to evaluate the terminal residue level. METHODS AND RESULTS: Aclonifen was extracted from crop samples with acetone and the extract was partitioned with dichloromethane and then purified by silica solid phase extraction(SPE) cartridge. The purified samples were detected GC using an ECD detector. Limits of detection(LOD) was 0.001 mg/kg and quantification(LOQ) was 0.005 mg/kg, respectively. For validation purposes, recovery studies were carried out at three different concentration levels (LOQ, $10{\times}LOQ$, $50{\times}LOQ$, n=5). The recoveries were ranged from 74.3 to 95.0% with relative standard deviations(RSDs) of less than 8%. All values were consistent with the criteria ranges requested in the Codex guidelines(CAC/GL 40). CONCLUSION: The proposed analytical method was accurate, effective and sensitive for aclonifen determination and it will be used to as an official method in Korea.

• Journal of Food Hygiene and Safety
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• v.29 no.3
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• pp.234-240
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• 2014

Fluxapyroxad is classified as carboxamide fungicide that inhibits succinate dehydrogenase in complex II of mitochondrial respiratory chain, which results in inhibition of mycelial growth within the fungus target species. This study was carried out to assure the safety of fluxapyroxad residues in agricultural products by developing an official analytical method. A new, reliable analytical method was developed and validated using High Performance liquid Chromatograph-UV/visible detector (HPLC-UVD) for the determination of fluxapyroxad residues. The fluxapyroxad residues in samples were extracted with acetonitrile, partitioned with dichloromethane, and then purified with silica solid phase extraction (SPE) cartridge. Correlation coefficient($R^2$) of fluxapyroxad standard solution was 0.9999. The method was validated using apple, pear, peanut, pepper, hulled rice, potato, and soybean spiked with fluxapyroxad at 0.05 and 0.5 mg/kg. Average recoveries were 80.6~114.0% with relative standard deviation less than 10%, and limit of detection (LOD) and limit of quantification (LOQ) were 0.01 and 0.05 mg/kg, respectively. All validation parameters were followed with Codex guideline (CAC/GL 40). LC-MS (Liquid Chromatograph-Mass Spectrometer) was also applied to confirm the analytical method. Base on these results, this method was found to be appropriate fluxapyroxad residue determination and can be used as the official method of analysis.

• Analytical Science and Technology
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• v.29 no.2
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• pp.94-103
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• 2016

An analytical method was developed to determine the amount of spinetoram (spinetoram J and spinetoram L) in livestock samples. The spinetoram was extracted with acetonitrile and purified through a primary secondary amine (PSA) sorbent. The spinetoram residues were then quantified and confirmed using a liquid chromatography–tandem mass spectrometer (LC-MS/MS) in the positive ion mode using multiple reactions monitoring (MRM). Matrix-matched calibration curves were linear over the calibration ranges (0.005-0.5 mg/kg) into a blank extract with r² > 0.994. The limits of detection and quantification were 0.002 and 0.01 mg/kg, respectively. The recovery results of spinetram ranged between 81.9-106.4% at different concentration levels (LOQ, 10LOQ, 50LOQ, n=5) with relative standard deviations (RSDs) less than 10%. All values were consistent with the criteria ranges requested in the Codex guidelines (CAC/GL40, 2003). An interlaboratory study was conducted to validate the method. The proposed analytical method proved to be accurate, effective, and sensitive for spinetoram determination. The method will be used as an official analytical method in Korea.

• The Korean Journal of Pesticide Science
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• v.20 no.2
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• pp.93-103
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• 2016

A simultaneous analytical method was developed for the determination of isoxaflutole and metabolite (diketonitrile) in agricultural commodities. Samples were extracted with 0.1% acetic acid in water/acetonitrile (2/8, v/v) and partitioned with dichloromethane to remove the interference obtained from sample extracts, adjusting pH to 2 by 1 N hydrochloric acid. The analytes were quantified and confirmed via liquid chromatograph-tandem mass spectrometer (LC-MS/MS) in positive-ion mode using multiple reaction monitoring (MRM). Matrix matched calibration curves were linear over the calibration ranges ($0.02-2.0{\mu}g/mL$) for all the analytes into blank extract with $r^2$ > 0.997. For validation purposes, recovery studies were carried out at three different concentration levels (LOQ, 10LOQ, and 50LOQ) performing five replicates at each level. The recoveries were ranged between 72.9 to 107.3%, with relative standard deviations (RSDs) less than 10% for all analytes. All values were consistent with the criteria ranges requested in the Codex guideline (CAC/GL40, 2003). Furthermore, inter-laboratory study was conducted to validate the method. The proposed analytical method was accurate, effective, and sensitive for isoxaflutole and diketonitrile determination in agricultural commodities.

• Journal of Food Hygiene and Safety
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• v.31 no.3
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• pp.186-193
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• 2016

An analytical method was developed for the determination of oxathiapiprolin in agricultural commodities. Oxathiapiprolin is a new oomycide (fungicide of piperidinyl thiazole isoxazoline class) which controls downy mildew in cucurbits caused by Pseudoperonospora cubensis (oomycete plant pathogen). Agricultural commodities were extracted with acetonitrile and partitioned with dichloromethane to remove the interference, adjusting pH between 9 and 10 by 1 N sodium hydroxide. After purification by silica SPE cartridge to clean up the interference of organic compounds, they were finally quantified by HPLC-UVD (high performance liquid chromatograph ultraviolet detector) using a wavelength at 260 nm and confirmed by LC-MS (liquid chromatograph mass spectrometer) in electro-spray ionization positive ion mode. The standard calibration curve was linear with coefficients of determination ($r^2$) 1.00 over the calibration ranges (0.025-2.5 mg/L). Recoveries were ranged between 86.7 to 112.7%, with relative standard deviations less than 10% at three concentration levels (LOQ, 10LOQ, and 50LOQ) performing five replicates. The overall results were determined and estimated according to the CODEX guidelines (CAC/GL40). The proposed method for determination of oxathiapiprolin residues in agricultural commodities can be used as an official method.