• Title/Summary/Keyword: CA 242

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Electrochemical Properties of $LiFePO_4-LiCoO_2$ Cathode Materials in Lithium Secondary Batteries (리튬이차전지 정극활물질용 $LiFePO_4-LiCoO_2$의 전기화학적 특성)

  • Kong, Ming-Zhe;Kim, Hyun-Soo;Kim, Ke-Tack
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.241-242
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    • 2006
  • In this work, the $LiFePO_4-LiCoO_2$ mixed cathode electrodes were prepared and their electrochemical performances were measured in different current density. The cell of $LiFePO_4-LiCoO_2$ observed two voltage plateau regions at 3.4 and 3.9V. The cell of $LiFePO_4-LiCoO_2$ (90:10 wt%) mixed cathode delivered a discharge capacity of ca. 139.8 mAh/g at a 0.2C rate. The capacity of the cell decreased with the current rate and a useful capacity of ca 85.7mAh/g was obtained at a 2C rate.

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A Study on the Effects of first and second additives Magnetic Characteristics of Anisotropic $SrO-5.7Fe_2O_3$. (1,2차 첨가제가 이방성 $SrO-5.7Fe_2O_3$의 자기적 특성에 미치는 효과)

  • Song, Joon-Tae;Shin, Yeong-Duck;Jeong, In-Young;Jin, Hong-Bum
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.239-242
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    • 1990
  • The effect of $CaCo_3$, $SrCo_3$, $SiO_2$ and $H_3BO_3$ in the range of 0.1-1.0 wt% on strontium ferrites consisting of the magnetoplumbite phase $SrO-5.7Fe_2O_3$ were investigated. The hysteresis loop, density, demagnetization curve and the intrinsic coercive force were measured on anisotropic ferrite. The particle diameter and 0.5(wt%) of second additive $CaCo_3$ is particularly important for the properties of anisotropic ferrite. When the particle diameter is decreased from 1.98(${\mu}m$) to 1.07(${\mu}m$), the remance is increased from 2900 to 4010(G) and the coercive force from 2150 to 2850(Oe) at a sintering temperature 1230 ($^{\circ}C$). Remance Br(G), coercleve force(Oe) and maximum energy product of sample A-16 are87(%), 56(%), 67(%) of S-W model theoretical value.

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Zinc Deficiency Decreased Alkaline Phosphatase Expression and Bone Matrix Ca Deposits in Osteoblast-like MC3T3-E1 Cells

  • Cho Young-Eon;Lomeda Ria-Ann R.;Kim Yang-Ha;Ryu Sang-Hoon;Choi Je-Yong;Kim Hyo-Jin;Beattie John H.;Kwun In-Sook
    • Nutritional Sciences
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    • v.8 no.4
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    • pp.242-249
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    • 2005
  • It is well established that zinc plays an important role in bone metabolism and mineralization. The role of zinc in bone formation is well documented in animal models, but not much reported in cell models. In the present study, we evaluated zinc deficiency effects on osteoblastic cell proliferation, alkaline phosphatase activity and expression, and extracellular matrix bone nodule formation and bone-related gene expression in osteoblastic MC3T3-E1 cells. To deplete cellular zinc, chelexed-FBS and interpermeable zinc chelator TPEN were used. MC3T3-E1 cells were cultured in zinc concentration-dependent (0-15 ${\mu}M\;ZnCl_2$) and time-dependent (0-20 days) manners. MC3T3-E1 cell proliferation by MTT assay was increased as medium zinc level increased (p<0.05). Cellular Ca level and alkaline phosphatase activity were increased as medium zinc level increased (p<0.05). Alkaline phosphatase expression, a marker of commitment to the osteoblast lineage, measured by alkaline phosphatase staining was increased as medium zinc level increased. Extracellular calcium deposits measured by von Kossa staining for nodule formation also appeared higher in Zn+(15 ${\mu}M\;ZnCl_2$) than in Zn-(0 ${\mu}M\;ZnCl_2$). Bone formation marker genes, alkaline phosphatase and osteocalcin, were also expressed higher in Zn+ than in Zn-. The current work supports the beneficial effect of zinc on bone mineralization and bone-related gene expression. The results also promote further study as to the molecular mechanism of zinc deficiency for bone formation and thus facilitate to design preventive strategies for zinc-deficient bone diseases.

Geochemical Characteristics on Geological Groups of Stream Sediment in the Boseong-Hwasun Area, Korea (보성-화순지역 하상퇴적물에 대한 지질집단별 지구화학적 특성)

  • Park, Young-Seog;Kim, Jong-Kyun
    • Journal of the Korean earth science society
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    • v.32 no.7
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    • pp.707-718
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    • 2011
  • We study the natural background and geochemical characteristics on geological groups of stream sediment in the Boseong-Hwasun area. We collected 186ea stream sediment samples along the primary channels and dried them naturally in laboratory. The contents of major, trace and rare earth elements were determined by XRF, ICP-AES and NAA analysis methods. In order to know the natural background and geochemical characteristics of geological groups, we classified the studied area into granitic gneiss (GGn) area and porphyroblastic gneiss (PGn) area. The contents range of major elements for GGn area is $SiO_2$ 45.5-73.09 wt.%, $Al_2O_3$ 12-20.76 wt.%, $Fe_2O_3$(T) 3.72-8.85 wt.%, $K_2O$ 2.38-4.2 wt.%, MgO 0.75-2.77 wt.%, $Na_2O$ 0.78-1.88 wt.%, CaO 0.27-2.1 wt.%, $TiO_2$ 0.56-1.72 wt.%, $P_2O_5$ 0.06-0.73 wt.% and MnO 0.03-0.95 wt.%, and for PGn area it is $SiO_2$ 43.74-70.71 wt.%, $Al_2O_3$ 11.54-25.05 wt.%, $Fe_2O_3$(T) 3.44-13.46 wt.%, $K_2O$ 2.08-3.86 wt.%, MgO 0.65-2.99 wt.%, $Na_2O$ 0.63-1.7 wt.%, CaO 0.35-2.07 wt.%, $TiO_2$ 0.68-4.17 wt.%, $P_2O_5$ 0.1-0.31 wt.% and MnO 0.07-0.33 wt.%. The contents range of hazard elements for GGn area is Cr 41.7-242 ppm, Co 7.6-25.1 ppm, Ni 12-61 ppm, Cu 10-47 ppm, Zn 48.5-412 ppm, Pb 17-215 ppm, and for PGn area, it is Cr 29.6-454 ppm, Co 5.9-53.7 ppm, Ni 8.7-287 ppm, Cu 6.4-134 ppm, Zn 43.6-370 ppm, Pb 15-37 ppm area. There is a good correlation between Cr and MgO and Co among $Al_2O_3$, $Fe_2O_3$(T), MgO and Ni among $Fe_2O_3$(T), CaO, MgO whereas Cu, Zn and Pb have a low correlation for major elements in GGn area. Generally Cr, Co, Ni, and Cu have a good correlation with major elements, but a low correlation with Zn and Pb in PGn area.

The deactivation behavior of SCR catalyst by alkali and alkali earth metal (알칼리 및 알칼리 토금속에 의한 SCR 촉매 비활성 거동)

  • Han, Seungyun;Shin, Min-Chul;Lee, Heesoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.6
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    • pp.238-242
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    • 2016
  • The effect of the alkali, alkali earth metal elements on selective catalytic reduction(SCR) catalyst deactivation behavior were investigated in terms of microstructure, surface area, pore volume and De-NOx test. Poisoned SCR catalyst were manufactured by injection of $K_2CO_3$, $Na_2CO_3$, $Ca(CH_3COO)_2{\cdot}H_2O$, $C_4H_6MgO_4{\cdot}4H_2O$, $H_3PO_4$ solutions in the new SCR catalyst at $350^{\circ}C$ for 6 hours. New and poisoned catalysts surface were similar. But specific surface area, pore volume decrease from Na, Mg, K, Ca, P compared to new SCR catalyst. Especially, Na poisoned catalyst surface area and pore size extremely decreased by $10.20m^2/g$, $0.061cm^2/g$. De-NOx test results of new and poisoned catalysts at $150{\sim}450^{\circ}C$ indicated that alkali metal (K, Na) poisoned SCR catalysts have the lowest De-NOx efficiency, alkali earth metal poisoned SCR catalysts (Ca, Mg) De-NOx efficiency are higher than alkali metal poisoned SCR catalysts. P poisoned SCR catalyst De-NOx efficiency is similar new SCR catalyst. It were considered that physical deactivation of SCR catalyst was affected by SCR catalyst surface area and pore volume change.

Survey on IEEE 802.11 DCF Game Theoretic Approaches (IEEE 802.11 DCF에서의 게임 이론적 접근방법 소개)

  • Choi, Byeong-Cheol;Kim, Jung-Nyeo;Ryu, Jae-Cheol
    • Proceedings of the KIEE Conference
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    • 2007.04a
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    • pp.240-242
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    • 2007
  • The game theoretic analysis in wireless networks can be classified into the jamming game of the physical layer, the multiple access game of the medium access layer, the forwarder's dilemma and joint packet forwarding game of the network layer, and etc. In this paper, the game theoretic analysis about the multiple access game that selfish nodes exist in the IEEE 802.11 DCF(Distributed Coordination Function) wireless networks is addressed. In this' wireless networks, the modeling of the CSMA/CA protocol based DCF, the utility or payoff function calculation of the game, the system optimization (using optimization theory or convex optimization), and selection of Pareto-optimality and Nash Equilibrium in game strategies are the important elements for analyzing how nodes are operated in the steady state of system. Finally, the main issues about the game theory in the wireless network are introduced.

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Six Newly Recorded Fungal Taxa from Freshwater Niche in Korea

  • Lim, Hyo Jin;Nguyen, Thuong T.T;Lee, Hyang Burm
    • Mycobiology
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    • v.49 no.2
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    • pp.105-121
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    • 2021
  • Six interesting fungal strains were isolated during a survey of fungal diversity associated with freshwater; these strains were designated as CNUFC YJW2-22, CNUFC MSW11-6-2, CNUFC HRS5-3, CNUFC MSW242-6, CNUFC DMW2-2, and CNUFC CPWS-1. Based on a polyphasic approach including phylogenetic analyses of internal transcribed space (ITS), large subunit (LSU), beta-tubulin (BenA), and calmodulin (CaM) gene sequences, morphological analyses, the six strains were found to be identical to Acremonium guillematii, Cadophora novi-eboraci, Lectera nordwiniana, Mycoarthris corallina, Talaromyces siamensis, and Tetracladium globosum, respectively. To our knowledge, these are the first records of the rare Lectera, Mycoarthris, and Tetracladium genera in Korea, and the first reports of A. guillematii, C. novi-eboraci, L. nordwiniana, M. corallina, T. siamensis, and Te. globosum in a freshwater environment.

Analysis of Chemical Composition in leaf and foot of Acrorus calamus L. (창포(Acorus calamus L. var. angustatus Bess.) 잎과 뿌리 중의 성분 분석)

  • Kim, Hye-Ja;Kim, Se-Won;Shin, Chang-Sik
    • Korean Journal of Food Science and Technology
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    • v.32 no.1
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    • pp.37-41
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    • 2000
  • This study has been carried out to investigate the chemical composition of Acorus calamus L., a wild plant (Chang Po) which has long been used as a medicine or a hair rinse in Korea and China. Potassium was found to be the most predominant mineral in leaf and root, followed by calcium, magnesium, and phosphorus, in a decreasing order. Contents of potassium in leaf and root account for 54a.65 mg% and 242.87 mg%, respectively. Contents of these minerals in leaf were higher value than that in root. Glucose and fructose were found to be the major free sugars in leaf and root. Malic acid was the most abundant organic acid of leaf and root, and followed by citric acid. Fourteen different kinds of fatty acids were identified from the leaf and root. Content of unsaturated fatty acids. such as linolenic, and linoleic acid ware higher than that of saturated fatty acids. Content of total amino acids was 3 times higher in leaf than that in root. Leucine was the major amino acid in leaf and glutamic acid in root.

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A Study on the Effect of Electrolyte Additives on Zn Electrode with Pb3O4 in Zn-AgO Secondary Battery System (Zn-AgO 이차 전지에서 Pb3O4가 첨가된 아연 전극에 미치는 전해질 첨가제의 영향에 관한 연구)

  • Park, Kyung-Wha;Moon, Kyung-Man
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.242-249
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    • 2003
  • Zn electrode was widely used as an anode material in alkaline battery systems in highly concentrated KOH electrolyte, however it was well known that its cycle life is significantly shortened by growth of dendrite due to the high dissolution of $Zn(OH)_2$ and rapid electrochemical reaction. In this study when by the additives such as $Ca(OH)_2$, Citrate, tartrate and Gluconate were added to $40\%$ KOH electrolyte at solution temperature of $25^{\circ}C$ and the amount of $5wt\%\;Pb_3O_4$ was mixed to Zn electrode and then the effect of $Pb_3O_4$ and additives on the electrochemical behavior of Zn electrode was investigated by Potentiodynamic Polarization Curves, Cyclic Voltammetry, Accelerated Life Cycle lest, and SEM image analyses. The addition of $Pb_3O_4$ reduced the corrosion rate of Zn electrode. The corrosion potential of Zn electrode with $Pb_3O_4$ was higher or lower than that of pure Zn electrode however was not influenced practically to the open circuit voltage. And the addition of 4 type additives had an important role in improving both cycle life in accelerated cycle life test and corrosion resistance. Furthermore the additive of Tartrate indicated comparatively a good effect to corrosion resistance as well as charging-discharging property Improvement among those four type additives.

Effects of Coal Fly Ash on Composting Process of Household Garbage (음식쓰레기 퇴비화 과정에서 석탄회 첨가 효과)

  • Seong, Soon-Hee;Kim, Woo-Seong;Seo, Jeoung-Yoon
    • Korean Journal of Environmental Agriculture
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    • v.15 no.3
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    • pp.282-288
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    • 1996
  • Because of the high water content of the household garbage, it is difficult to compost it. Therefore, this study was conducted to investigate the possibility of using coal fly ash as humidity conditioner for the household garbage composting. The summarized results are as follows : 1. The maximum temperatures were $35^{\circ}C$ in spring, $47^{\circ}C$ in summer, and $43^{\circ}C$ in winter during the composting periods. 2. The mass was reduced to 70.5% after 60 days. The average volume reduced down to 74.7% after 60 days. 3. The seasonal variation of pH values showed a similar tendency and reached 8.5 after 60 days. 4. The water content was reduced at an early stage of composting and not much changed thereafter. It had 49.7% in spring, 33.9% in summer, and 56.5% in winter after 60 days. Ash contents were not much changed during the composting periods. 5. The contents of inorganic compounds were in the range of $0.06{\sim}4.03%$ $P_2O_5$, $0.01{\sim}2.87%$ CaO, $0.18{\sim}1.43%$ MgO, and $0.39{\sim}2.03%$ $K_2O$. Heavy metal contents were in the range of $ND{\sim}14.08$ Hg ${\mu}g/kg$, $ND{\sim}0.80$ Cd mg/kg, $4.99{\sim}28.95$ Cu mg/kg, $ND{\sim}242.62$ Cr mg/kg, $ND{\sim}20.24$ Pb mg/kg, and $ND{\sim}59.87$ Zn mg/kg.

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