• Title/Summary/Keyword: CA모형

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Effect of Micelles on the Reaction of RuBPCase in Maize Leaf (옥수수 잎의 RuBPCase 반응에 미치는 미셀들의 영향)

  • 김의락;김현묵
    • KSBB Journal
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    • v.9 no.3
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    • pp.325-331
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    • 1994
  • PGA is formed in a route of CO2 fixation of RuBP catalyzed by RuBPCase, followed by reduction of the PGA by NADH to GAP This reduction is enhanced in an anionic micellar solution(SDS), in which NADH is distributed in the aqueous and the micellar pseudophases in a given ratio. This micellar bounded NADH reacts to PGA, and in higher micellar concentration than $1.25{\times}10^{-2}M$, most of NADH is oxidized to NAD+ by PGA. On the other hand, in the solutions of the positive ionic(CTABr), zwitter ionic(Chaps) and nonionic (Brij and Triton X-100) micelles, the reactions are also enhanced and the concentrations of NADH reach minima with micellar concentrations. Such minima are typical of micellar catalyzed bimolecular reactions, and the fall in concentrations of the reductant followed by a gradual increase is charataristic of reactions of hydrophobic substrates: that is, the reductions of PGA by NADH are sharply enhanced in a range of the lower micellar concentrations, and NADH amounts in ca. $1.25-2.50{\times}10^{-3}M$ micellar solutions are reached to minima, followed by gradual increases of the reductant concentration.

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Model Development for Estimating Total Soil Contents of Pb and Cd Using Chemical Properties and Extractable Contents in Paddy Soil (논 토양의 이화학적 특성 및 침출성 함량을 이용한 납과 카드뮴의 전함량 예측 모형식 개발)

  • Go, Woo-Ri;Lee, Ji-Ho;Lee, Eun-Yong;Lim, Seong-Mook;Yoo, Ji-Hyock;Kim, Ji-Young;Kim, Kye-Hoon;Im, Geon-Jae;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1080-1084
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    • 2011
  • Predictive model for estimating total contents of cadmium (Cd) and lead (Pb) was developed by stepwise multiple-regression analysis using chemical properties and extractable contents of metal in paddy soil adjacent to abandoned mines in 2009 and 2010. Soil properties, e.g. pH, electrical conductivity (EC), organic matter (OM), available phosphorus ($P_2O_5$), and exchangeable cations (i.e. Ca, Na, K, Mg) were measured. Total contents of Cd and Pb as well as extractable contents of metals were analyzed by ICP-OES. Results showed that the total and extractable contents were estimated to be 3.55 and $0.27mg\;kg^{-1}$ in Cd and 83.38 and $24.32mg\;kg^{-1}$ in Pb on the average. From stepwise analysis, it was found that the contents of extractable Cd, Zn, Cu, as well as exchangeable Na were significantly influenced on estimation of the total contents of Cd in soil. Moreover, it also showed that the contents of extractable Pb, Zn, and Cu significantly affected estimation of the total contents of Pb in soil. More significant relationship between estimated and measured value in total contents of Pb was observed than those of Cd ($R^2$=0.87, p<0.0001). This demonstrates that extractable contents of metal are influenced more on estimation of total contents of Cd and Pb in soil than soil properties.

Relationship Between Soil Water-Stable Aggregates and Physico-chemical Soil Properties (토양 내수성 입단과 토양특성과의 관계)

  • Hyun, Byung-Keun;Jung, Sug-Jae;Song, Kwan-Cheol;Sonn, Yeon-Kyo;Jung, Won-Kyo
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.57-63
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    • 2007
  • Soil aggregation has been considered as an important factor not only for increasing soil productivity and soil quality but also improving nutrient use availability and water use efficiency. However, the relationship between soil aggregation and soil properties hasn't well reported for Korean soils. Objective of this research was to identify the relationship among soil water-stable aggregate (WSA), soil properties and soil dispersion ratio. Soil samples were analyzed for water-stable aggregate, Middleton's dispersion ratio, and soil physical and chemical properties. Water-stable aggregate was significantly correlated to soil textural properties, soil organic matter, and exchangeable cations. Middleton's dispersion ratio was significantly correlated with water-stable aggregate ($r=-0.76^{***}$). Regression equation for water-stable aggregate was estimated by Middleton's dispersion ratio (Y=-0.79X + 96.49; $r^2=0.58^{**}$). In this research, we conclude that water-stable aggregate was significantly correlated with some soil properties and was able to be estimated by rapid and easily measurable Middleton's dispersion ratio.

Effect of Etching Treatment of SAPO-34 Catalyst on Dimethyl Ether to Olefins Reaction (DTO 반응에 미치는 SAPO-34 촉매의 식각 처리 효과)

  • Song, Kang;Yoon, Young-Chan;Park, Chu-Sik;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.20-27
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    • 2021
  • Effects of the etching treatment of SAPO-34 catalyst were investigated to improve the catalytic lifetime in DTO reaction. The aqueous NH3 solution was a more appropriate treatment agent which could control the degree of etching progress, compared to that of using a strong acid (HCl) or alkali (NaOH) solution. Therefore, the effect on characteristics and lifetime of SAPO-34 catalyst was observed using the treatment concentration and time of aqueous NH3 solution as variables. As the treatment concentration or time of aqueous NH3 solution increased, the growth of erosion was proceeded from the center of SAPO-34 crystal plane, and the acid site concentration and strength gradually decreased. Meanwhile, it was found that external surface area and mesopore volume of SAPO-34 catalyst increased at appropriate treatment conditions. When the treatment concentration and time were 0.05 M and 3 h, respectively, the lifetime of the treated SAPO-34 catalyst was the longest, and was significantly enhanced by ca. 36% (based on DME conversion of > 90%) compared to that of using the untreated catalyst. The model for the etching progress of SAPO-34 catalyst in a mild treatment process using aqueous NH3 solution was also proposed.

Evaluation of the dimensional change of 3D-printed complete denture after post-curing (후경화에 따른 3차원 프린팅 의치의 체적변화)

  • Suyeon, Lee;Younghun, Kwak;Eunchul, Park;Heejung, Kim
    • Journal of Dental Rehabilitation and Applied Science
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    • v.38 no.4
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    • pp.233-241
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    • 2022
  • Purpose: The purpose of this study was to assess the dimensional change of 3D-printed dentures after post-curing. Materials and Methods: The upper and lower dentures were designed in Exocad DentalCAD software and exported as STL files. The upper and lower dentures were printed from 10 STL files using a DLP-type dental 3D printer. The printed upper and lower dentures were cleaned, and a scan file was created using a model scanner before and after post-curing. The dimensional change was evaluated by superimposing the scanned denture files before and after post-curing and measuring the distance between measurement points on the denture. SPSS was used for statistics, and the level of significance was 5%. Results: The maxillary denture reduced in size during post-curing, with the most notable color change occurring in the posterior palatal region. The reduction in anteroposterior maxillary denture length (A-D, A-E, A-F), as well as the distance between the first molars on both sides (B-C), was statistically significant. After post-curing, the mandibular denture showed more noticeable color change in the posteriorly buccal and lingual region. The decrease of length on the posterior (A-M, A-D, A-E, A-L, A-H, A-I, H-I) and lingual (J-K, L-M) sides of the denture were statistically significant. Conclusion: There was significant dimensional change in both the length and width of the 3D-printed maxillary and mandibular dentures after post-curing in this experiment. Consequently, it is seemed necessary to develop post-curing techniques and materials that reduce such denture deformation.

Chemical Factors of Soil Associated with the Prediction Model for Fertilizer Need of N and K in Flooded Rice based on the Multinutrient Factor Balance Concept (다요인조절개념하(多要因調節槪念下)에서의 수도(水稻) N. K 시비적량여측(施肥適量予測) 모형식(模型式)에 관여(關與)하는 토양화학적(土壤化學的) 요인(要因))

  • Park, Chon-Suh
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.3
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    • pp.210-222
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    • 1983
  • The chemical factors of topsoil, which are associated with the prediction models of urea nitrogen (N kg/ha) need under the concept of multinutrient factor balance in soil to maintain optimum nutrient balance in rice plant grown in flooded condition, were the x/z and the Kas/Kai values. In the prediction model or equation $NRe=(58.5+0.647x/z){\cdot}F$, the F was difined as the productivity factor, which was considered to be dependent on the variety, climate and soil, and found to be better estimated as the function of Kas/Kai rather than x/z from the equation Fb=0.65+1.086kas/kai, where the x, z, Kas and Kai, respectively, were available $SiO_2$ ppm, % organic matter, K activity ratio or exchangeable $K^+/(\sqrt{Ca+Mg}+Na^+)$ in topsoil and the ideal K activity ratio determined by the equation Kai=0.03+0.00083x/z for standard variety Jinheung. The relative K activity ratio or Kas/kai in topsoil, which have to be equal to 1.0 in the prediction of K fertilizer need for standard Japonica Variety Jinheung, found to be 1.63 for the varieties of Indica ${\times}$ Japonica or Milyang No. 23 grown in Korean condition and 0.322 for the Indica varieties of IR 8, 20, 36 and 42 gown in the Philippines condition. The ideal K activity rations for different Varieties such as Indies ${\times}$ Japonica grown in Korea or $Kai_1$ and Indica grown in the Philippines or $Kai_2$ were computed to be estimated from the following equations respectively ; $\\Kai_1=0.0489+0.001353X/Z\\Kai_2=0.01+0.000267X/Z$.

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The Effect of Glide Path on Canal Centering Ability in Reciprocating File System (Reciprocating 파일 시스템에서 Glide Path가 근관만곡도 유지에 미치는 영향)

  • Zang, Ki-Choul;Kim, Jin-Woo;Cho, Kyung-Mo;Park, Se-Hee
    • Journal of Dental Rehabilitation and Applied Science
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    • v.28 no.3
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    • pp.245-252
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    • 2012
  • The purpose of this study was to evaluate the influence of glide path on canal centering ratio after instrumentation with different single file systems; WaveOne and Reciproc. Reciproc R25 (VDW), WaveOne Primary (Dentsply Maillefer) and PathFile #13, 16, 19 (Dentsply Maillefer) were used in this study. In no glide path groups, Reciproc files and WaveOne files used for canal preparation without glide path. In glide path groups, the PathFile were used before canal preparation. Methylene blue dye was introduced into the canal to obtain a clear pre-instrumentation image. Pre-instrumentation images and post-instrumentation images were scanned using Epson Perfection V700 Photo scanner (Epson, Nagano, Japan). Transparencies of post-instrumentation images were changed and superimposed on pre-instrumentation images using Adobe Photoshop CS 3 (Adobe Systems Incorporated, San Jose, CA, USA). The centering ratio was calculated for each instrumented canal using the following formula: CR=|X1-X2|/Y. It was statistically analyzed using two-way ANOVA at 95% confidential level. The centering ratio in glide path groups were significant less than it in no glide path groups at 3, 4, 5 and 6 mm level. Except 1 and 6 mm level, WaveOne groups had significant less centering ration than Reciproc groups. At 6 mm level, there was no significant difference between WaveOne and Reciproc. In the limitation of this study, creation of a previous glide path before reciprocating motion instrumentation in curved canal appears to be appropriate and WaveOne system can be used for preparation of curved canal without severe aberrations.

Effects of Temperature on the Development and Reproduction of Phaedon brassicae Baly (Coleoptera: Chrysomelidae) (좁은가슴잎벌레의 발육과 생식에 미치는 온도의 영향)

  • Jeong Joon Ahn;Kwang Ho Kim;Hong Hyun Park;Gwan Seok Lee;Jeong Hwan Kim;In-Hong Jeong
    • Korean journal of applied entomology
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    • v.62 no.4
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    • pp.315-323
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    • 2023
  • The brassica leaf beetle, Phaedon brassicae Baly (Coleoptera: Chrysomelidae), is one of the important pests infesting cruciferous vegetables. In order to understand the biological characteristics of the insect, we investigated the effects of temperature on development of each life stage, adult longevity and fecundity of P. brassicae at four constant temperatures of 15, 20, 25 and 27.5℃ for immature life stage and five constant different temperatures of 10, 15, 20, 25 and 27.5℃ for adult stage. Eggs and larvae successfully developed next life stage at temperature tested. The development period of egg, larva, and pupa decreased as temperature increased. Lower developmental threshold (LDT) and thermal constant (K) were calculated using linear regression as 8.7℃ and 344.73DD, respectively. Lower and higher threshold temperature (TL and TH) from egg to adult emergence were estimated by Briere function as 5.3℃ and 40.4℃, respectively. Adults produced eggs at the temperature range between 10℃ and 27.5℃, and showed an estimated maximum number, ca. 627.5 eggs at 21.7℃. Adult oviposition models including aging rate, age-specific survival rate, age-specific cumulative oviposition, and temperature-dependent fecundity were constructed. Temperature-dependent development models and adult oviposition models would be useful components to understand the population dynamics of P. brassicae and to establish the strategy of integrated pest management in cruciferous crops.

Dose verification for Gated Volumetric Modulated Arc Therapy according to Respiratory period (호흡연동 용적변조 회전방사선치료에서 호흡주기에 따른 선량전달 정확성 검증)

  • Jeon, Soo Dong;Bae, Sun Myung;Yoon, In Ha;Kang, Tae Young;Baek, Geum Mun
    • The Journal of Korean Society for Radiation Therapy
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    • v.26 no.1
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    • pp.137-147
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    • 2014
  • Purpose : The purpose of this study is to verify the accuracy of dose delivery according to the patient's breathing cycle in Gated Volumetric Modulated Arc Therapy Materials and Methods : TrueBeam STxTM(Varian Medical System, Palo Alto, CA) was used in this experiment. The Computed tomography(CT) images that were acquired with RANDO Phantom(Alderson Research Laboratories Inc. Stamford. CT, USA), using Computerized treatment planning system(Eclipse 10.0, Varian, USA), were used to create VMAT plans using 10MV FFF with 1500 cGy/fx (case 1, 2, 3) and 220 cGy/fx(case 4, 5, 6) of doserate of 1200 MU/min. The regular respiratory period of 1.5, 2.5, 3.5 and 4.5 sec and the patients respiratory period of 2.2 and 3.5 sec were reproduced with the $QUASAR^{TM}$ Respiratory Motion Phantom(Modus Medical Devices Inc), and it was set up to deliver radiation at the phase mode between the ranges of 30 to 70%. The results were measured at respective respiratory conditions by a 2-Dimensional ion chamber array detector(I'mRT Matrixx, IBA Dosimetry, Germany) and a MultiCube Phantom(IBA Dosimetry, Germany), and the Gamma pass rate(3 mm, 3%) were compared by the IMRT analysis program(OmniPro I'mRT system software Version 1.7b, IBA Dosimetry, Germany) Results : The gamma pass rates of Case 1, 2, 3, 4, 5 and 6 were the results of 100.0, 97.6, 98.1, 96.3, 93.0, 94.8% at a regular respiratory period of 1.5 sec and 98.8, 99.5, 97.5, 99.5, 98.3, 99.6% at 2.5 sec, 99.6, 96.6, 97.5, 99.2, 97.8, 99.1% at 3.5 sec and 99.4, 96.3, 97.2, 99.0, 98.0, 99.3% at 4.5 sec, respectively. When a patient's respiration was reproduced, 97.7, 95.4, 96.2, 98.9, 96.2, 98.4% at average respiratory period of 2.2 sec, and 97.3, 97.5, 96.8, 100.0, 99.3, 99.8% at 3.5 sec, respectively. Conclusion : The experiment showed clinically reliable results of a Gamma pass rate of 95% or more when 2.5 sec or more of a regular breathing period and the patient's breathing were reproduced. While it showed the results of 93.0% and 94.8% at a regular breathing period of 1.5 sec of Case 5 and 6, it could be confirmed that the accurate dose delivery could be possible on the most respiratory conditions because based on the results of 100 patients's respiratory period analysis as no one sustained a respiration of 1.5 sec. But, pretreatment dose verification should be precede because we can't exclude the possibility of error occurrence due to extremely short respiratory period, also a training at the simulation and careful monitoring are necessary for a patient to maintain stable breathing. Consequently, more reliable and accurate treatments can be administered.

UBVI CCD Photometry of NGC 7790 (NGC 7790의 UBVI CCD 측광)

  • Choi, Dong Yeol;Kim, Hee Soo;Lim, Beomdu;Sung, Hwankyung
    • Journal of the Korean earth science society
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    • v.36 no.7
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    • pp.661-673
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    • 2015
  • UBVI CCD photometry of the intermediate age open cluster NGC 7790 has been obtained using AZT-22 1.5 m telescope (f/7.74) at the Maidanak Astronomical Observatory in Uzbekistan. NGC 7790 contains three ${\delta}$ Cep variable stars including CEa Cas, CEb Cas, and CF Cas. PSF photometry was carried out using IRAF/DAOPHOT for all observations. The total number of stars observed both in V and I filter was 1008 and the limiting magnitude was $V{\approx}22$. To determine atmospheric extinction coefficients and photometric zero points, many blue and red standard stars as well as the standard stars in the celestial equator under various airmass were observed. Photometric data were transformed into the standard Johnson-Cousins' UBVI standard system. From the analysis of UBVI color-magnitude diagram and color-color diagram, the color excess in V and I filter [$E(B-V)=0.58{\pm}0.02$], the selective extinction ratio in V and I filter [$R_V{\equiv}A_V/E(B-V)=3.02{\pm}0.09$] and distance modulus ($V_0-M_V=12.65{\pm}0.10$) of the cluster were determined. The age of the cluster was estimated to be log $age=8.05{\pm}0.05$ [yr] based on the position of these three Cepheid variables in the color-magnitude diagram, the isochrone of the Geneva group ($Ekstr{\ddot{o}}m$ et al., 2012-Z=0.019), and the isochrone of the Padova group (Bressan et al., 2012-Z=0.014) were used to compare each other. Of them, the Geneva models that considered stellar rotation well described the position of ${\delta}$ Cepheid variables in the blue loop. Although they were well consistent with standard period-luminosity relation of ${\delta}$ Cepheid variables, three Cepheid variables in NGC 7790 were, on average, brighter by about 0.5 mag than the absolute magnitude estimated from the mean period-luminosity relation at a given period.