• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.283.2-283.2
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• 2014

열필라멘트 화학증착공정(Hot Wire Chemical Vapor Deposition)에서 기상 에서 생성되는 하전된 실리콘 나노입자와 저온결정성 실리콘박막 증착의 연관성을 압력의 변화에 따른 상호비교를 통해 조사하였다. 필라멘트 온도는 $1800^{\circ}C$로 고정시키고 0.3~2 torr의 범위에서 공정 압력을 변화시키면서 증착하였다. 압력이 증가함에 따라 증착된 실리콘 박막의 결정화도는 증가하였으며, 증착속도는 감소하였다. 반응기 압력에 따른 기상에서 생성되는 나노입자의 크기분포의 변화를 조사하기 위하여 탄소막이 코팅된 투과전자현미경(Transmission Electron Microscopy) 그리드 위에 실리콘 나노입자를 포획하고 관찰하였다. 포획된 실리콘 나노입자의 크기분포와 개수농도는 압력이 증가함에 따라 감소하였다. 투과전자현미경을 이용하여 분석한 결과, 나노입자는 결정성 구조를 보였다. 압력이 증가함에 따라 나노입자의 크기가 감소하고 개수농도가 감소하는 것은 증착속도의 감소와 관련됨을 알 수 있다. 한편, 공정압력 증가에 따른 나노입자의 크기분포 및 개수농도 감소와 증착속도의 감소는 일반적으로 알려진 기상에서 석출하는 고상의 평형석출량(equilibrium amount of precipitation)이 압력의 증가함에 따라 증가한다는 사실과 일치하지 않는다. 이러한 압력경향성은 Si-H 시스템이 0.3~2 torr의 압력 영역에서 retrograde solubility를 갖는 것을 의미한다. 나노입자의 하전여부, 크기분포 및 개수농도를 측정하기 위하여 입자빔질량분석장비(Particle Beam Mass Spectroscopy)를 이용하였다. 그 결과, 실리콘 나노입자는 양 또는 음의 극성을 가진 하전된 상태임을 확인하였고, 투과전자현미경(TEM) grid에 포획한 실리콘 나노입자의 크기와 경향성이 일치하였다. 이는 나노입자가 저온의 기판에서 핵생성되어 성장하여 생성된 것이 아니라 열필라멘트 주위의 고온영역에서 생성된 것을 의미한다.

• Korean Journal of Materials Research
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• v.21 no.8
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• pp.461-467
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• 2011

Cu(In, Ga)$Se_2$ (CIGS) precursor films were electrodeposited on Mo/glass substrates in acidic solutions containing $Cu^{2+}$, $In^{3+}$, $Ga^{3+}$, and $Se^{4+}$ ions at -0.6 V (SCE) and pH. 1.8. In order to induce recrystallization, the electrodeposited $Cu_{1.00}In_{0.81}Ga_{0.09}Se_{2.08}$ (25.0 at.% Cu + 20.2 at.% In + 2.2 at.% Ga + 52.0 at.% Se) precursor films were annealed under a high Se gas atmosphere for 15, 30, 45, and 60 min, respectively, at $500^{\circ}C$. The Se amount in the film increased from 52 at.% to 62 at.%, whereas the In amount in the film decreased from 20.8 at.% to 9.1 at.% as the annealing time increased from 0 (asdeposited state) to 60 min. These results were attributed to the Se introduced from the furnace atmosphere and reacted with the In present in the precursor films, resulting in the formation of the volatile $In_2Se$. CIGS precursor grains with a cauliflower shape grew as larger grains with the $CuSe_2$ and/or $Cu_{2-x}Se$ faceted phases as the annealing times increased. These faceted phases resulted in rough surface morphologies of the CIGS films. Furthermore, the CIGS layers were not dense because the empty spaces between the grains were not removed via annealing. Uniform thicknesses of the $MoSe_2$ layers occurred at the 45 and 60 min annealing time. This implies that there was a stable reaction between the Mo back electrode and the Se diffused through the CIGS film. The results obtained in the present research were sufficiently different from comparable studies where the recrystallization annealing was performed under an atmosphere of Ar gas only or a low Se gas pressure.

• Korean Membrane Journal
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• v.8 no.1
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• pp.21-30
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• 2006

A faujasite NaY zeolite membrane was prepared on a tubular ${\alpha}-Al_2O_3$ support by the secondary growth process, and effects of permeation test conditions on the $CO_2/N_2$ separation were investigated. A NaY zeolite membrane with good $CO_2/N_2$ separation was successfully synthesized by using the hydrothermal solution ($Al_2O_3:SiO_2:Na_2O:H_2O$ = 1:6:14:840 in a molar base): at a permeation temperature of $30^{\circ}C$, its $CO_2$ permeance and $CO_2/N_2$ separation factor were $2.5{\times}10^{-7}mol/m^2secPa$ and 34, respectively. The $CO_2$ and $N_2$ permeations were highly dependent on permeation test conditions (feed composition, feeding rate, feed pressure, He sweeping rate and permeation temperature). The results indicated that (i) $CO_2$ and $N_2$ permeations through NaY zeolite membrane are governed by surface and micropore diffusions, respectively, (ii) the preparation of NaY zeolite membrane with a large permeating area is one of the most difficult hurdles for its real applications, and (iii) the retardation of $N_2$ permeation is an effective key to improve $CO_2/N_2$ separation factor in NaY zeolite membrane.

• Membrane Journal
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• v.18 no.1
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• pp.35-43
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• 2008

In this study, we tried to solve membrane fouling with membranes made by fine nano-particle in MBR process. And we confirmed good fouling resistance in pilot test. In this test, we confirmed our membrane with titania out-standing quality by testing in the pilot long-term test by comparing to other company product. Our membrane keep up steadily $20{\sim}25 L/m^2{\cdot}hr$ high flux in $7,000{\sim}13,000mg/L$ MLSS high sludge concentration. In addition to this quality, we studied membrane flux character related membrane arrangement, membrane-air line arrangement, air-line hole size, cleaning solution concentration, treatment method, etc. Using the optimization of this additional parameter, we tried to search method of maximizing membrane quality.

• KSBB Journal
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• v.18 no.5
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• pp.371-376
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• 2003

Antioxidative and cholesterol-reducing activity of Bacillus polyfermenticus SCD were measured to characterize its probiotic properties. DPPH (1,1-diphenyl-2-picyryl hydrazyl) radical scavenging activity of the culture supernatant of B. polyfermenticus SCD was estimated to be 48%. The culture supernatant on the peroxidation of linoleic acid were investigated and the value was shown to be about 45%. The inhibition of TBA (2-thiobarbituric acid) formation of the culture supernatant was revealed 60% when stimulator was presented. The SOD-like activity of the culture supernatant was about 15%, which is similar to BHT (butylated hydroxytoluene) and ${\alpha}$-tocopherol. After cultured in TSB broth added soluble cholesterol either 0.1% or 0.3% of oxgall in 37$^{\circ}C$ for 24 h aerobically, cholesterol-reducing activities were revealed about 67% or 64%, respectively. To test whether the products are cholesterol-related or not, residual activity was determined. The cholesterol activity was rarely changed. In addition, when the cell extracts recovered after cultivation, was tested in absence of cholesterol, cholesterol activity was not detected. However, cholesterol activity was detected in the presence of cholesterol. Thus, it was assumed that B. polyfermenticus SCD could reduce cholesterol by conjugating with it, rather than by digesting the cholesterol using cholesterol-hydrolyzing enzymes.

• KSBB Journal
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• v.7 no.3
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• pp.229-234
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• 1992

Alcohol fermentations were carried out to confirm the capacity of ethanol production from glucose, starch and soluble starch(dextrin) by Schwanniomyces castellii NRRL Y-2477. Schw. castellii NRRL Y-2477 was able to produce the 63.9g/l ethanol using 94% subtrate from 150g/l-glucose medium. The direct alcohol fermentation of starch having the maximum solubility of 20g/1 at $30^{\circ}C$ yielded 9.1g/l ethanol upon complete depletion of starch, whereas 34.5g/1 ethanol was produced by utilizing 82% of 100g/1 soluble starch medium. The fermentation of 150g/1 soluble starch produced 52.1g/l ethanol using about 79% of substrate. Thus, it was found that the limiting step of direct alcohol fermentation of starch by Schwanniomyces castellii NRRL Y-2477 was a hydrolysis of starch.

• Biotechnology and Bioprocess Engineering:BBE
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• v.6 no.1
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• pp.25-30
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• 2001

Viral safety is a prerequisite for manufacturing clinical albumin and immunoglobulins from human plasma pools. This study was designed to evaluate the efficacy of cold ethanol fractionation and pasteurization (60$\^{C}$ heat treatment for 10h) for the removal/inactivation of human immunodeficiency virus type 1 (HIV-1) during the manufacturing of albumin and immunoglobulins. Samples from the relevant stages of the production process were spiked with HIV-1, and the amount of virus in each fraction was quantified by the 50% tissue culture infectious dose(TCID(sub)50). Both fraction IV fractionation and pasteurization steps during albumin processing were robust and effective in inactivating HIV-1, titers of which were reduced from an initial 8.5 log(sub)10 TCID(sub)50 to undetectable levels. The log reduction factors achieved were $\geq$ 4.5 and $\geq$ 6.5, respectively. In addition, fraction III fractionation and pasteurization during immunoglobulins processing were robust and effective in eliminating HIV-1. HIV-1 titers were reduced from an initial 7.3 log(sub)10 TCID(sub)50 to undetectable levels. The log reduction factors achieved in this case were $\geq$ 4.9 and $\geq$ 5.3, respectively. These results indicate that the process investigated for the production of albumin and immunoglobulins have sufficient HIV-1 reducing capacity to achieve a high margin of safety.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.140-140
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• 2017

4륜 장착 자동차의 토크 전달은 2륜 구동, 4륜 구동 모드를 간단히 전환하는 방식(part time 4WD)과 항시 사륜 구동 모드에서 전후륜의 토크 전달비를 제어하는 방식(AWD, all wheel drive)이 있다. 경제의 발달에 따라서 취미 인구의 확대로 국내에만 180만 명의 R/C car 사용자가 있다. 이 중 2WD-4WD의 전환을 differential lock mechanism으로 구현한 수입산 모델의 가격이 1,000,000원을 호가하지만 가변 제어 방식이 아닌, 정차 후 2-4륜 구동 전환 방식을 적용하고 있으며 상대적으로 내구성이 떨어진다. DC motor의 출력이 늘어나고 배터리의 성능이 좋아진 현재 소형 RC car의 최고 속도는 80 km/h 정도로 빨라졌다. 그러나 마찰 계수가 낮은 노면(실내의 대부분 평활 처리된 복도)에서는 2륜 구동 모드의 활용도가 매우 낮다. 미끄러운 노면에서 후륜 구동 모드로는 oversteer가 발생하여 차량이 스핀하기 쉽고 전륜 구동 모드로는 understeer가 발생하여 제대로 된 코너링이 어렵다. 상시 4륜 구동 모드는 에너지 소모가 크고 전후륜이 tight coupling되어 있는 문제 때문에 일반적인 노면에서 부드러운 코너링이 잘 이루어지지 않는 문제가 있다. 본 연구에서 제안하는 방식은 그림 1와 같이 center shaft의 중간에 영구 자석으로 만들어진 토크 전달용 판이 있고 그 사이에 자계를 차폐할 수 있는 강자성체 셔터를 서보 기구에 연결하여 서보 회전각에 따라서 구동 쪽의 토크가 피구동축으로 전달되는 양을 연속 가변제어할 수 있다. 토크 전달용 판의 차폐 면적에 따른 토크 전달양을 전/후륜 바퀴의 Static torque를 통해 측정하였으며(그림 2), 공중 상태에서 즉 공기저항만을 고려한 상태에서의 RPM 회전수 차이 측정(그림3)을 통해 구동 쪽의 회전수가 피구동축으로 전달되는 양을 측정하여 연속가변 토크 제어 전달 기구의 성능을 확인하였다. 이 기구는 현재 1차적으로는 remote controller의 ch 3(ON/OFF제어 방식)에 연결하여 특정한 양의 토크를 전륜 쪽으로 보낼 수 있도록 구현이 가능하며, ch 2(PID제어 방식)에 연결하여 연속 가변 조절이 가능하도록 구현이 가능하다. 부가적으로 Arduino board를 내장하여 전후륜의 휠센서에서 입력되는 신호를 감지하여 자동적으로 전후륜에 배분되는 토크를 제어할 수 있도록 설계 중에 있다.

• Journal of Pharmaceutical Investigation
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• v.38 no.1
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• pp.9-14
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• 2008

Cation exchange resin complex of amlodipine free base has been investigated to improve the stability and dissolution profile. The complex was prepared by reacting amlodipine solution with activated cation exchange resin, and amlodipine content in the complex was 31.6% calculated by HPLC determination. Its product was not physical mixture but the complex formed by ionic bond, which was identified by microscope system, differential scanning calorimetry and X-ray diffractometry. Each tablet containing amlodipine free base(I) and its complex(II) was prepared for the accelerated stability test ($40^{\circ}C$, 75%RH) and dissolution test in the pH 1.2 buffer solution and purified water media. Dissolution patterns of formulation II in both media were similar to those of $Norvasc^{(R)}$ tablet, but the pattern of formulation I in purified water was different. After 6 months storage under stability test, amlodipine content of formulation I, II and $Norvasc^{(R)}$ tablet were $99.3{\pm}1.2%,\;98.9{\pm}1.4%\;and\;83.9{\pm}3.4%$, respectively. While amlodipine free base was unstable at the condition, its complex was not only significantly stable, but also similar in the dissolution pattern. These results suggest the usefulness of complex as a stable carrier for amlodipine free base.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.50 no.2
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• pp.105-107
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• 2005

A field study was conducted to investigate and ascertain the effects of boron and molybdenum with recommended N P K S Zn fertilizers (RFD) for sustained sugarcane yield in the sandy acidic soil in Old Himalayan Piedmont Plain of Bangladesh. Results revealed that the treatment $T_7$ having recommended fertilizers of N 120, P 35, K 100, S 25 and Zn 2kg $ha^{-1}$ + B 2kg $ha^{-1}$ + Mo 2 kg $ha^{-1}$ produced significantly higher number of millable cane (126.96\times10^3\;ha^{-1})$ except in $T_9$ with RFD + B 2 kg $ha^{-1}$ + Mo 4kg $ha^{-1}$, and higher cane yield (92.83 Mg $ha^{-1}$) among all except in $T_3$ with RFD + B2 kg $ha^{-1}$, $T_5$ with RFD + Mo 2kg $ha^{-1}$ and $T_9$ where the effects were statistically identical. The increase in cane yield by $T_7$ was $164.6\%$ over control. The treatment $T_7$ having RFD + B 2kg $ha^{-1}$ + Mo 2kg $ha^{-1}$ further gave the highest additional net economic benefit of Taka 16, 500.00 for added Band Mo at 2kg $ha^{-1}$ among all the treatments in the study.