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Pd/다결정 3C-SiC 쇼트키 다이오드형 수소센서의 제작 (Fabrication of Pd/poly 3C-SiC Schottky diode hydrogen sensors)

  • 정동용;정귀상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.236-236
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    • 2009
  • This paper describes the fabrication and characteristics of Schottky micro hydrogen sensors for high temperatures by using polycrystalline(poly) 3C - SiC thin film grown on Si substrates with thermal oxide layer using APCVD. Pd/poiy 3C-SiC Schottky diodes were made and evaluated by I-V and C-V measurements. Electric current density and barrier height voltage were $2\times10^{-3}\;A/cm^2$ and 0.58 eV, respectively. These devices could operate stably at about $400^{\circ}C$. According to $H_2$ concentrations, their barrier height($\Phi_{Bn}$) were changed 0.587 eV, 0.579 eV, 0.572 eV and 0.569 eV, respectively. the current was increased. Characteristics of implemented sensors have been investigated in terms of sensitivity, linearity of response, response rate and response time. Therefore, from these results, Pd/poly 3C-SiC Schottky devices have very high potential for high temperature chemical sensor applications.

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시화호 인근 연안 퇴적물의 유기물 분해 특성, 저층 영양염 용출 및 조절요인 (Rates and Controls of Organic Matter Mineralization and Benthic Nutrient Release in the Coastal Sediment Near Lake Shihwa)

  • 신재혁;안성욱;최재훈;이효진;우승범;현정호;김성한
    • 한국해양학회지:바다
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    • 제26권2호
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    • pp.110-123
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    • 2021
  • 시화호 인근 연안 퇴적물에서 유기물 분해 특성, 퇴적물로부터의 영양염 용출 및 주요 조절요인을 파악하기 위해 공극수와 퇴적물 내 지화학 성분, 혐기성 유기물 분해율, 황산염 환원율 및 저층 영양염 용출률을 측정하였다. 연구정점은 소래포구 인근 정점(E0), 송도갯벌 정점(E1), 오이도 선착장 부근 정점(E3), 시화 조력발전소 수문 앞 정점(E5)으로 선정하였다. 유기탄소와 공극수 내 암모니아, 인산염 농도는 정점 E0에서 가장 높게 나타났으며, 외측 해역(정점 E1, E3, E5)으로 갈수록 점진적으로 감소하였다. 혐기성 유기물 분해율과 황산염 환원율은 정점 E0에서 각각 260.6 mmol C m-2 d-1와 91.4 mmol S m-2 d-1로 외측 정점들보다 각각 4-9배, 6-54배 높게 나타났다. 혐기성 유기물 분해에서 황산염 환원이 차지하는 비율은 정점 E3, E5에서 11-23%로 미미한 것으로 나타났으나, 정점 E0, E1에서는 47-70%로 황산염 환원에 의해 혐기성 유기물 분해가 주도되는 것으로 나타났다. 또한, 혐기성 유기물 분해율과 황산염 환원율은 용존 유기탄소와 상관성이 매우 높은 것으로 나타났다(r2 = 0.795, 0.777). 한편, 정점 E0, E1, E3에서 퇴적물로부터 용출된 무기질소와 무기인은 각각 일차생산자가 요구하는 무기질소와 무기인의 120-510%와 26-178%를 공급하는 것으로 나타났다. 이상의 결과들은, 시화호 인근 연안 퇴적물 내 유기물 분해는 이용 가능한 용존 유기탄소의 공급에 의해 조절되고 있으며, 과도한 유기물 분해는 저층 영양염 용출을 촉진시켜 부영양화를 야기할 수 있음을 의미한다.

The Corrosion Study of Al Current Collector in Phosphonium Ionic Liquid as Solvent for Lithium Ion Battery

  • Cha, Eun-Hee;Mun, Jun-Young;Cho, E.-Rang;Yim, Tae-Eun;Kim, Young-Gyu;Oh, Seung-M.;Lim, Soo-A;Lim, Jea-Wook
    • 전기화학회지
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    • 제14권3호
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    • pp.152-156
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    • 2011
  • A room temperature ionic liquid (RTIL) based on trihexyl (tetradecyl)phosphonium bis(trifluoromethanesulfonyl) imide ([$(C_6H_{13})_3P(C_{14}H_{29)}$] [TFSI];P66614TFSI) was synthesized and analyzed to determine their characteristics and properties. The bis(trifluoromethanesulfonyl)imide (TFSI) anion is widely studied as an ionic liquid (IL) forming anion which imparts many useful properties, notably electrochemical stability. Especially its electrochemical and physical characteristics for solvent of lithium ion battery were investigated in detail. $P_{66614}$ TFSI exhibits fairly low conductivity (0.89 mS $cm^{-1}$) and higher viscosity (298 K: 277 cP; 343 K: 39 cP) than other ionic liquids, but it exhibits a high thermal stability (over $400^{\circ}C$). Especially corrosion behavior on Al current collector was tested at room temperature and further it was confirmed that thermal resistivity for Al corrosion was highly increased in 1.0M LiTFSI/$P_{66614}$-TFSI electrolyte comparing with other RTILs by linear sweep thermometry.

eRF1aMC and $Mg^{2+}$ Dependent Structure Switch of GTP Binding to eRF3 in Euplotes octocarinatus

  • Song, Li;Jia, Yu-Xin;Zhu, Wen-Si;Chai, Bao-Feng;Liang, Ai-Hua
    • Journal of Microbiology and Biotechnology
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    • 제22권2호
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    • pp.176-183
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    • 2012
  • Eukaryotic translation termination is governed by eRF1 and eRF3. eRF1 recognizes the stop codons and then hydrolyzes peptidyl-tRNA. eRF3, which facilitates the termination process, belongs to the GTPase superfamily. In this study, the effect of the MC domain of eRF1a (eRF1aMC) on the GTPase activity of eRF3 was analyzed using fluorescence spectra and high-performance liquid chromatography. The results indicated eRF1aMC promotes the GTPase activity of eRF3, which is similar to the role of eRF1a. Furthermore, the increased affinity of eRF3 for GTP induced by eRF1aMC was dependent on the concentration of $Mg^{2+}$. Changes in the secondary structure of eRF3C after binding GTP/GDP were detected by CD spectroscopy. The results revealed changes of conformation during formation of the eRF3C GTP complex that were detected in the presence of eRF1a or eRF1aMC. The conformations of the eRF3C eRF1a GTP and eRF3C eRF1aMC GTP complexes were further altered upon the addition of $Mg^{2+}$. By contrast, there was no change in the conformation of GTP bound to free eRF3C or the eRF3C eRF1aN complex. These results suggest that alterations in the conformation of GTP bound to eRF3 is dependent on eRF1a and $Mg^{2+}$, whereas the MC domain of eRF1a is responsible for the change in the conformation of GTP bound to eRF3 in Euplotes octocarinatus.

고등학생의 프로토콜 분석을 통한 과학 탐구능력과 개념 중심의 탐구능력 대범주별 과학 문제 해결 특성 (Inquiry Problem Solving Characteristics among Categories with Science Process Skills and Concepts by High School Student's Protocol Analysis)

  • 이항로
    • 한국과학교육학회지
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    • 제19권3호
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    • pp.355-366
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    • 1999
  • 자료의 해석과 분석 능력의 범주에 속하는 과학 탐구 문제의 학습에는 관련 탐구능력 보다 과학 개념을, 탐구의 설계 및 수행 능력의 범주에 속하는 과학 탐구 문제의 학습에는 관련 탐구능력과 과학 개념을 강조하는 학습법의 적용이 유효할 것으로 기대된다. 과학 탐구 문제를 해결해 가는 사고 과정을 심층적으로 분석해 보면 현재와 같이 성공자에게는 1점, 실패자에게는 0점을 부여하는 이분법적(dichotomous)인 평가 방법으로는 문제를 해결해 가는 과정이 동일한데도 불구하고 성공자와 실패자를 완전하게 별별하고 있지 못해 과학 교육 활동의 전반적인 정치(replacement) 활동에 문제가 내재할 가능성이 있음을 유추할 수 있다. 따라서 본 연구를 통해 밝혀진 바와 같이 과학 탐구 문제 해결 사고 과정 분석에 의한 제 1유형에는 1점, 제 2유형에는 0.8점, 제 3유형에는 0.6점, 제 4유형에는 0.4점, 제 5유형에는 0.2점, 제 6형에는 0점을 부여하는 대안적 다단계 평가 방법에 대한 이론적 실천적 연구가 필요할 것으로 사료된다.

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복수의 어업에 의해 어획되는 수산자원의 관리를 위한 연구 (A Study on the Rational Utilization of Resource Catched by Multiple Fisheries)

  • 김병호
    • 수산경영론집
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    • 제14권1호
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    • pp.44-56
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    • 1983
  • This study is attempted to serve the fundamental theory for ‘The reorganization of Korean coastal and adjacent water fishery.’ On the Korean coastal and adjacent water fishery where one species stock is catched by multiple fisheries, traditional analysis is not suitable, as analyzing through adjusting the heterogeneous fishing effort among the fisheries to an unit having same fishing strength. Therefore, this study presents the ‘Multi-Variable Model’, adopting fishing effort from each fishery as independent variable, respectively, in order to analyze the quantitative fluctuation of fishery resource not with fishing strength but with amount of fishing effort, measured by the unit of each fishery. For the sake of simplication, this study assumes that one species is catched by two fishery, premise two assumption. 1) Every fishery has not the selectivity in fishing 2) The promotion of fishing efficiency is accomplished in the same speed. Resource equilibrium equation of each fishery is; $$CPUE_1=\frac{Y_1}{E_1}=a_1+ b_1\cdot E_1+c_1\cdot E_1$$ $$CPUE_1=\frac{Y_1}{E_1}=a_1+ b_1\cdot E_1+c_1\cdot E_1$$ Sustainable yield equation is; $$SY_1=a_1\cdot E_1+\cdot b_1E{_1}{^2}+c_1\cdot E_1\cdot E_1$$ $$SY_1=a_1\cdot E_1+b_1\cdot E_1\cdot E_1+c_1\cdot E{_1}{^2}$$ This study is rudimentary, hereafter, refinemental analysis will be supplemented.

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Superconducting properties and microstructure of electron beam irradiated MgB2 superconductors

  • Kim, C.J.;Lee, Y.J.;Cho, I.H.;Jun, B.H.
    • 한국초전도ㆍ저온공학회논문지
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    • 제24권1호
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    • pp.18-22
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    • 2022
  • The effect of electron beam (EB) irradiation on superconducting properties and microstructures of MgB2 bulk superconductors were investigated. At E-beam doses of 1×1016 e/cm2 and 1×1017 e/cm2, the effect of irradiation on a superconducting transition temperature (Tc) of MgB2 was weak. As a dose increases to 5×1017 e/cm2, Tc decreases by 0.5 K. The critical current density (Jc) measured at 4.2 K and 20 K, and 0 T - 5 T increases slightly as exposure time increases. X-ray diffraction for the irradiation surface of MgB2 shows that the diffraction intensity of (hkl) peaks decreases proportionally as the exposure time increases. This indicates that the crystallinity of MgB2 was degraded by irradiation. TEM investigation for the irradiated sample showed distorted lattice structure, which is consistent with the XRD results. The Jc increase and Tc reduction of MgB2 by irradiation are believed to be caused by the lattice distortion.

Photoluminescence Characteristics of the Light-Emitting Chromophores Obtained from Organic-Inorganic Hybrid Silica Spheres

  • Park, Eun-Hye;Jeong, Chang-Gi;Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • 제4권3호
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    • pp.93-97
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    • 2016
  • Light-emitting chromophores have been separated from silica spheres modified the surface with 3-(trimethoxysilyl)propylmethacrylate (TMSPM). The photoluminescence characteristics of the chromophores were investigated with various excitation wavelengths. The TMSPM was attached to the surface of silica spheres at $75^{\circ}C$. Large number of round shaped particles of the TMSPM was on the surface of silica spheres after 3 h reaction. The TMPSM was completely covered on the surface of the spheres after 6 h reaction. The surface modified silica spheres were soaked into acetone and stored for 20 days at ambient condition. The solution color slowly changed from light yellow to deep yellow with the increase of the storing time. The FTIR absorption peaks at 3348, 2869, 2927, 1715, 1453/1377, 1296, and $1120cm^{-1}$ represent C-OH, $R-CH_3$, $R_2-CH_2$, -C=O, C-H, C=C-H, and Si-O-Si absorption, respectively. The FTIR absorption peak at $1715cm^{-1}$ representing the ester -C=O stretching vibration for silica spheres stored for 20 days was increased compared with the spheres without aging. The UV-visible absorption peaks were at 4.51 eV (275 nm) and 3.91 eV (317 nm). There were two luminescence peaks at 2.51 eV (495 nm) and 2.25 eV (550 nm). The emission at 2.51 eV was dominant peak when the excitation energy was higher than 2.58 eV, and emission at 2.25 eV became dominant peak when the excitation energy was lower than 2.58 eV.

흑색 P. E. Film 피복에서 초당옥수수의 생육기간을 표시하는 GDD모델 개발 (A GDD Model for Super Sweet Corn Grown under Black P. E. Film Mulch)

  • 이석순;양승규;홍승범
    • 한국작물학회지
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    • 제53권1호
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    • pp.42-49
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    • 2008
  • 흑색 P E. film 피복과 노지재배에서 초당옥수수를 원하는 시기에 수확할 수 있는 파종기를 결정하는 방법을 찾기 위하여 "Cambella-90"을 4월 1일에서 6월 30일까지 10일 간격으로 파종한 후 파종기와 관계없이 파종에서 수확까지 생육기간을 일정하게 나타낼 수 있는 GDD 모델과 기준온도를 설정하였으며, 그 결과를 요약하면 다음과 같다. 1, 초당옥수수의 생육기간은 파종기에 따라 흑색 P. E. film 피복에서는 $64{\sim}93$일, 노지에서는 $66{\sim}97$일로 파종기간 CV는 각각 13.8 및 14.2%이었다. 그러나 생육기간을 GDD로 표시하면 최적 기준온도를 적용하였을 때 파종기간 GDD의 CV는 모델에 따라 흑색 P. E. film 피복에서는 $1.1{\sim}2.4%$, 노지에서는 $1.5{\sim}1.8%$이었다. 2. 초당옥수수의 생육기간을 나타내는 가장 적합한 GDD 모델은 파종에서 수확까지 일 최고기온과 최저기온을 합하여 2로 나눈 후 기준온도를 빼서 GDD를 계산하되 일 최고 기온이 $30^{\circ}C$가 넘을 때는 일 최고기온에서 $30^{\circ}C$를 넘는 만큼 $30^{\circ}C$에서 빼어 그 값을 최고기온으로 대치하고, 최저기온이 기준온도 이하일 때는 기준온도로 대치하여 계산하는 방법이었다. 이때 기준온도는 흑색 P. E. film 피복에서는 $9^{\circ}C$, 노지재배에서는 $10^{\circ}C$이었다. 3. 원하는 시기에 수확하기 위한 파종기를 결정하기 위해서는 그 지역의 누적 GDD표를 만들고, 수확 예정일의 누적 GDD에서 그 품종의 GDD를 빼서 그 GDD에 해당되는 일자를 선택하면 된다.

Temperature Effect on the Functional Expression of Human Cytochromes P450 2A6 and 2E1 in Escherichia coli

  • Yim Sung-Kun;Ahn Taeho;Jung Heung-Chae;Pan Jae-Gu;Yun Chul-Ho
    • Archives of Pharmacal Research
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    • 제28권4호
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    • pp.433-437
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    • 2005
  • Human cytochromes P450 (GYP) 2A6 and 2E1 are of great interest because of their important roles in the oxidation of numerous drugs and carcinogens. Bacterial expression systems, especially Escherichia coli cells, have been widely used for the production of various GYP enzymes in order to obtain high yield of proteins. The expression methods usually employ longer culture time (30-72 h) at lower temperature (usually under $30^{\circ}C$). Expression levels of GYPs 2A6 and 2E1 at $37^{\circ}C$ were compared to those at $28^{\circ}C$, which is a usual temperature used in most bacterial expression systems for human GYP expression. Within 18 h the expression levels of GYPs 2A6 and 2E1 reached up to 360 and 560 nmol per liter culture at $37^{\circ}C$, respectively, which are compatible with those of 36 h culture at $28^{\circ}C$. The activities of GYPs expressed at $37^{\circ}C$ were also comparable to those expressed at $28^{\circ}C$. The present over-expression system can be useful for rapid production of large amounts of active human GYPs 2A6 and 2E1 in E. coli.