• 한국식품과학회지
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• 제36권3호
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• pp.385-392
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• 2004

시판 오이지 9종에 대하여 pH, 산도, 염도, 색도의 이화학적인 특성과 파쇄성, 경도, 씹힘성을 포함한 조직감 특성, 총균수, 젖산균수, 효모수의 미생물학적 특성, 및 관능적 특성을 분석하였다. 시판오이지 6종의 염도는 3.42-4.47%이었고 재래 오이지는 3.92-7.23%로 시판오이지에 비하여 높았다. 오이지의 pH 범위는 3.43-3.85, 5.10이었으며, 산도는 0.39-0.75%의 범위를 나타내었다. 명도는 시판오이지(37.86-41.48)가 재래오이지 (44.86-50.79)에 비하여 명도가 낮은 경향을 나타내었으며, 시판 오이지의 b값은 13.29-15.94이었고 재래오이지는 16.08-17.90으로 재래오이지의 황색도 값이 시판오이지에 비하여 높은 경향을 나타내었다. 시판 오이지의 a값은-1.47-3.71의 범위이었다. 시판오이지중에서 산도가 높은 오이지는 b값이 높았고 산도가 낮은 오이지는 b값이 낮은 경향을 나타내었다. 시판오이지 6종의 총균수($1{\times}10^{4}-2{\times}10^{7}cfu/mL$)는 재래오이지 3종($1{\times}10^{7}-1.3{\times}10^{9}cfu/mL$)에 비하여 적었다. 젖산균수는 시판오이지 6종$(1{\times}10^{4}-6{\times}10^{6}cfu/mL)$는 재래오이지 3종($4{\times}10^{6}-4.7{\times}10^{8}cfu/mL$)에 비하여 적었다. 효모수는 시판오이지 6종($1{\times}10^{4}-6{\times}10^{6}cfu/mL$ 재래오이지 3종($1.3{\times}10^{6}-3{\times}10^{8}cfu/mL$)에 비하여 적었다. 기계적 조직감 특성 중 파쇄성은 시판오이지 6종은 2,103-2,836g이었고, 재래오이지3종은 2,255-3,010g이었다. 경도는 시판오이지 6종은 475-688g이었고, 재래오이지 3종은 409-890g으로 차이가 있었다. 전반적인 수용도를 평가한 결과, 가장 높은 점수를 받은 제품은 C1과 C2로 7.4-8.0점을 나타내었다. 관능적 특성치와 이화학적 특성치를 주성분 분석한 결과 제1주성분은 79.94%, 제2주성분은 19.94% 설명 가능하였다. 시판오이지의 특성치는 제1주성분이 79.94% 설명 가능하였으며, 제2주성분은 19.94% 설명 가능하였다 C1, C2, C3 및 C7은 전반적인 수용도, 전반적인 맛, 감칠맛, 외관, 경도, b value가 제2주성분에 대하여 음의 방향으로 부하되어 있었다. 또한, 기계적 특성치 중에서 경도와 씹힘성은 염도와 양의 상관을, 관능적 특성치중에서 전반적인 수용도는 감칠맛과 전반적인 맛에 대한 수용도와 양의 상관을 나타내었다(p<0.05).

• Archives of Pharmacal Research
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• 제20권6호
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• pp.620-628
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• 1997

6-Aryl-5-cyano-4-pyrimidinon-2-thione derivatives 1a-c reacted with ethyl iodide to give the corresponded 2-S-ethylpyrimidin-4-one-derivatives 2a-c. Compounds 2a-c was, in turn, reacted with hydrazine hydrate to give the sulfur free reaction products, 3a-c. These reaction products were taken as the starting materials for the synthesis of several newly synthesized heterocyclic derivatives. Reactions with several halogenated ketones, esters, chloroacetic acid and chloroacetamide give pyrimidotriazines 8,12 and 15 while their reactions with formic acid, acetic acid and carbon disulfide gave the corresponded triazolopyrimidines 17 and 21. The reaction with both acetyl acetone and ethylacetoacetate gave the corresponded 2-$(3^{I},5^{I}-dimethyl-1^{I}-pyrazoly$pyrimidine derivatives 20a-c and 24a-c respectively while the reaction with cinnamonitriles 25a-h afforded the corresponded aryl hydrazopyrimidines 27a-f. The structure of these reaction products were eatablished based on both elemental anlayses and spectral data studies.

• Journal of Microbiology
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• 제38권3호
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• pp.150-155
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• 2000

A bioluminescent assay method for detecting the activity of phospholipase C(PLC; phosphatidyl choline cholinephosphohydrolase, EC 3.1.4.3) was developed using bioluminescent marine bacteria. Phospholipase C from Bacillus cereus and sn-1,2- dimyristoyl glycerol was further hydrolyzed with lipase from Candida ecylidracea. The hydrolyzed myristic acid was quantified using a dark mutant of Vibrio harveyi (designated as M-17). The in vivo light intensity of which was stimulated specifically up to one thousand fold in the presence of myristic acid. The rates of the hdrolysis of the DMPC substrate by the phospholipase measured by the luminescence method were linear with time and the were estalished to detect as little as 0.1 mUnit of phospholipase C and 5 nM of myristic acid production.

• 한국식품위생안전성학회지
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• 제11권2호
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• pp.107-114
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• 1996

The distribution of Listeria spp. in various foods and its fatty acid composition were examined. A total 60 samples of dairy products(15), seafoods(20), meat products(18), factory waster(2), and salades(5) were tested. Listeria spp. was found 10 samples, showing about 16.7% detection ratio; dairy products 0(0%),,seafoods 1(5%), meat product 7(38.9%), and factory wastes 2(100%). Whereas L. welshimeri was isolated from meat products 1(5.6%) and factory wastes 1(50%). The cellular fatty acid composition determined by gas chromatography was found not to differ among L. innocua isolated from food has similar fatty acid profiles when grown at 3$0^{\circ}C$,24 hrs on the tryptic soy plate with C15 and C17 anteiso branched acids accounting for about 80% of total.

• 대한원격탐사학회지
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• 제30권5호
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• pp.571-586
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• 2014

Moderate Resolution Imaging Spectroradiometer(MODIS)로부터 산출된 기온과 이슬점 온도프로파일 자료는 5 km의 공간해상도로 연속적으로 지상을 감시하고 있으며, 2012년부터 기존의 산출 알고리즘(Collection 5, C005)을 개선한 Collection 6(C006) MODIS07_L2 대기프로파일 자료를 생산하고 있다. 이 연구에서는 두 가지 버전의 알고리즘으로 산출된 Aqua MODIS07_L2(MYD07_L2) 대기 프로파일 자료로부터 획득한 기온과 이슬점 온도에 대한 신뢰도를 평가하는 것으로, 전국 77 개소 정규기상관측지점을 대상으로 하였다. 또한 기온과 이슬점 온도를 이용하여 대기수증기압을 추정하여 미기상인자 산출에 대한 MYD07_L2의 적용 가능성을 살펴보았다. C006 기온은 지상 관측 자료와 비교에서 C005 기온의 오차(ME = -1.89 K, RMSE = 4.06 K)보다 개선된 결과를 보였다(ME = -0.76 K, RMSE = 3.34 K). 한편, 이슬점 온도의 경우에는 C006이 C005의 오차(ME = -0.39 K, RMSE = 5.65 K)보다 크게 나타났다. MYD07_L2 산출 고도와 지상 관측지점 간에 발생할 수 있는 고도 차이를 보정하기 위해 대기기온감률 방법을 적용한 결과, 기온의 경우 C005와 C006에서 모두 개선 효과를 확인할 수 있었지만, 이슬점 온도의 경우에는 C006에서 오차가 소폭 증가하였다(1.4%). 두 가지 버전의 MYD07_L2 자료를 이용하여 대기수증기압을 추정한 결과, C006 자료를 이용하였을 때 다소 개선된 결과를 보였다. 이 연구를 통해 한국에 대한 C006 MYD07_L2 산출물 중 기온의 신뢰도가 전반적으로 개선되었음을 확인할 수 있었다.

• 한국연초학회지
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• 제6권2호
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• pp.131-139
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• 1984

The pyrolytic behavior of vanillin, a flavorant for manufactured cigarettes, was examined to find its contribution to the smoke composition. Vanillin was pyrolyzed at various temperatures (500-$900^{\circ}C$) in a stream of nitrogen. Pyrolytic products at $800^{\circ}C$ were identified with GC/MS. As increasing temperature, pyrolytic products did not appear with qualitative differences. Component analysis of the resulting products showed that 24 compounds were identified. and phenolic compounds were major products. The pyrolytic pathway of vanillin was also discussed.

• 한국식품영양학회지
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• 제26권3호
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• pp.352-357
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• 2013

This study estimates the classification criteria which distinguishes the types of omega-3 health functional foods, fish oils and fish oil usages through $^{13}C$-NMR spectra and fatty acids contents analysis. The major fatty acids of omega-3, eicosapentaenoic acid (EPA, $C_{20:5}$) and docosahexaenoic acid (DHA, $C_{22:6}$) are being analyzed. 10 ethyl ester (EE) forms and 10 triglyceride (TG) forms are the most common types of fish oils for 20 omega-3 products. Gas chromatography (GC) analysis generally shows the matching EPA and DHA contents of the products listed on the notation. But EE form contents of EPA and DHA are higher and are more varied than the TG form. Most of the samples of EPA/DHA ratio show different content ratios of indicated on the products when comparing with standards. The $^{13}C$-NMR analysis of EPA and DHA on sn-1,3 and sn-2 carbonyl peak position with fish oil triglycerides display whether the reconstituted triglycerides (rTG) are being confirmed or not. As a result of the 9 TG form, the 10 TG products showed similar values: EPA sn-1, 3; 13.46~15.66, sn-2; 3.00~4.52, DHA sn-1, 3; 2.43~4.40, sn-2; 3.84~6.36. But one product showed lower contents (EPA: sn-1, 3; 5.88, sn-2; 2.86, DHA sn-1, 3; 2.29, sn-2; 5.95) of EPA, thus it can be considered a different type of oil and only matched six products according to the label. This study is intended to provide basic materials which identify the status for the types and quality of omega-3 fish oil products according to fatty acids profiles and the $^{13}C$-NMR spectrum confirmed the location specificity of EPA and DHA.

• 생약학회지
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• 제10권2호
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• pp.55-59
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• 1979

Mass spectra of the dammarane triterpenes having open side chain and $C_{20}-C_{25}-epoxy$ side chain were measured. Principal fragment ions were assigned and plausible mechanisms for the formation of the fragment ions were proposed. In general, the triter-penoids of $C_{20}-C_{25}-epoxy$ side chain. produce $h_{1}-species$ fragment ions by the deletion of side chain at $C_{20}-C_{22}$ bond and open side chain triterpenoids produce $h_{2}$ species fragmentions whose mass numbers are higher by two mass unit than those of $h_{1}$ species. The mass number of h species fragment ions will serve as the diagnostic tool for the elucidation of side chain structure of tetracyclic triterpenoids.

• 한국연초학회지
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• 제25권2호
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• pp.103-110
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• 2003

This study was conducted to investigate the pyrolysis products of ι-menthol by Curie-Point pyrolysis. The pyrolysis of ι-menthol was performed at 16$0^{\circ}C$, 42$0^{\circ}C$, $650^{\circ}C$, and 92$0^{\circ}C$ by Curie-Point Pyrolyzer and their pyrolysis products were analyzed by GC/MSD. In addition, tobacco leaves added ι-menthol were pyrolyzed at the same condition in case of ι-menthol. The beginning temperature for pyrolysis formation was in the vicinity of 42$0^{\circ}C$ and the major components of the pyrolysis products identified were iso-menthol, 2-menthene, menthomenthene, and menthone. The amount of these components was increased by increasing temperature and the hydrocarbons such as hexadecene and pentadecene formed by ring cleavage were generated at 92$0^{\circ}C$. The yield of ι-menthol in pyrolysis of tobacco leaves was decreased as the temperature of pyrolysis was raised and the pyrolysis products of ι-menthol weren't identified in the pyrolysis of tobacco leaves. Also, to analyze the weight decrease, ι-menthol was analysed by thermal analyzer(TA), and then the weight decrease of ι-menthol was occurred in the vicinity of 18$0^{\circ}C$.

• 생약학회지
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• 제16권4호
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• pp.233-238
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• 1985

A number of sedative alkaloids were isolated from Sanjoin(酸棗仁), the seeds of Zizyphus vulgaris Lamark var. spinosus Bunge (Rhamnaceae) which is an important Chinese medicinal material used to treat insomnia and sometimes to treat sleepiness. Those compounds were designated as Sanjoinine-A, B, C, D, etc. depending on the order of increasing polarity. Sanjoinine-A, $C_{31}H_{42}N_4O_4$, $mp\;249^{\circ}$, $[{\alpha}]^{27}_D-316$, Sanjoinine-B, $C_{30}H_{40}N_4O_4$, $mp\;212{\sim}4^{\circ}$, Sanjoinene, $C_{29}H_{35}N_3O_4$, $mp\;281{\sim}2^{\circ}$, $[{\alpha}]^{22}_D-272$, Sanjoinine-D, $C_{32}H_{46}N_4O_5$, $mp\;256{\sim}8^{\circ}$, $[{\alpha}]^{22}_D-53.6$, Sanjoinine-F, $C_{31}H_{42}N_4O_5$, $mp\;228{\sim}9^{\circ}$, $[{\alpha}]^{22}_D-215$, and $Sanjoinine-G_1,\;C_{31}H_{44}N_4O_5,\;mp\;236{\sim}8^{\circ},\;[{\alpha}]^{22}_D-68.6$, were found as 14-membered cyclic peptide alkaloids, $Sanjoinine-G_2,\;C_{30}H_{42}N_4O_4,\;mp\;182^{\circ},\;[{\alpha}]^{22}_D-79.2$, as being open chain peptide alkaloid, and Sanjoinine-E, $C_{19}H_{21}NO_2$, $mp\;166^{\circ}$, $[{\alpha}]^{20}_D-146.2$, N-Methylasimilobine, $C_{18}H_{19}NO_2$, $mp\;193{\sim}5^{\circ}$, $[{\alpha}]^{20}_D-204$, Sanjoinine-Ia, $C_{18}H_{19}NO_2$, $mp\;155{\sim}7^{\circ}$, $[{\alpha}]^{20}_D-140$, Sanjoinine-Ib, $C_{19}H_{21}NO_4$, $mp\;184^{\circ}$, Sanjoinine-K, $C_{16}H_{19}NO_3$, $mp\;159{\sim}61^{\circ}$, $[{\alpha}]^{20}_D+35$, Caaverine, $C_{17}H_{17}NO_2$, $mp\;204^{\circ}$, $[{\alpha}]^{20}_D-80$, and Zizyphusine, $C_{20}H_{24}NO_4$, $mp\;214{\sim}6^{\circ}$, $[{\alpha}]^{20}_D+317$ as being aporphine alkaloids. The heat treatment of the cyclic peptide alkaloids produced their isomeric products which showed enhanced sedative activity. The chemical structure of the isomeric products will be discussed.