• 제목/요약/키워드: C18 modification

검색결과 106건 처리시간 0.063초

수소첨가에 따른 옥수수유의 트리글리세리드 분자종 및 이화학적 특성의 변화 (Changes in the Physicochemical Characteristics and Triglyceride Molecular Species of Corn oil during Hydrogenation)

  • 김현위;차익수;김진호;김현석;박기문;손세형
    • 한국식품과학회지
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    • 제25권6호
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    • pp.637-642
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    • 1993
  • 반응온도 $180^{\circ}C$, 수소압력 $2.0{\pm}0.3bar$, 니켈촉매량 0.048%(Ni/oil by wt.), 교반속도 300rpm 조건하에서 수소첨가하면서 시간별로 얻은 옥수수 수소첨가유의 트리글리세리드 분자종 조성의 변화 및 이화학적 항수의 변화를 연구하였다. 시간에 따른 요드값 감소율로 표현되는 수소첨가반응의 효율은 1차 반응으로 진행 되었으며, K>0.01 이었다. 요드값 감소율이 39.9%였던 수소첨가 30분 경과시 18 : 1 생성이 최고치(77.06%)였고, 그후로 18 : 1은 감소하고 18 : 0는 증가하였다. 트리글리세리드 조성의 변화에 있어서는 수소첨가가 진행됨에 따라 PLO, PLL, OLO는 30분만에 제거되었으며, OLL, LLL은 10분만에 급격히 감소하고 이후 서서히 제거되었다. 반면, POO, PLS 등의 CN52와 OOO, SLO 등의 CN54는 30분까지 크게 증가하고 이후 거의 일정하였다. 녹는점은 수소첨가 20분경과시 $27.8^{\circ}C$, 60분경과시 $44.1^{\circ}C$였고, 트란스산은 40분에 46.8%로 최고치를 나타내다가 이후 미약하게 감소하였다. 수소첨가시간의 경과에 따라 고체지함량은 증가하였다. 상기의 결과로 부터 본 실험의 수소첨가조건은 이중결합이 많은 불포화지방산부터 순차적으로 수소첨가되고, 트란스이성체 형성이 활발히 진행되는 선택적 조건임을 확인하였다. 이와같은 유지의 수식기술에 따라 생성된 수소첨가유는 여러 유지제품 생산에 적용되리라 사료한다.

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Dietary Modification for Reducing Electrical Conductivity of Piggery Wastewater

  • Yu, I.T.;Su, J.J.;Wu, J.F.;Lee, S.L.;Ju, C.C.;Yen, H.T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제18권9호
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    • pp.1343-1347
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    • 2005
  • A total of 108 pigs (including 36 starters, 36 growers, and 36 finishers) were randomly allocated to six treatments, which involved a 2 (Crude Protein (CP): 100 and 80% of control diet)${\times}$3 (Ca, P, Salt (CPS): 100, 80 and 60% of control diet) factorial design to evaluate the effectiveness of reducing CP and CPS in reducing wastewater EC in different stages. Another 72 starters were adopted to examine the effect of the six treatment diets (as mentioned above) on the growth performance of pigs. Activated carbon and Reverse Osmosis System (RO) were adopted to examine the reducing efficiency of wastewater EC, and ion analysis was also applied to compare with the wastewater EC in different stages of the metabolism trial. The results of wastewater EC of the six treatment diets in different stages of metabolism trial demonstrated that diminishing dietary CP or CPS decreased wastewater EC. The largest decrease of EC was approximately 30%, and was achieved with 20 and 40% reduced dietary CP and CPS, respectively. Pig growth performance deteriorated somewhat when dietary CP or CPS was diminished. Wastewater ion concentration was not always consistent with dietary CP or CPS content, except for $NO_2^{-}$, $NH_4^{+}$ and $K^{+}$, which were positively correlated with dietary CP or CPS in different stages. Activated carbon is not effective for reducing wastewater EC, while, RO system is effective (90% elimination rate) in reducing wastewater EC, but the EC of concentrated (excreted) water is around 10% higher than that of intact wastewater, representing an additional problem besides the high cost of RO system treatment.

세로토닌 5-HT1A수용체 방사성 추적자 18F-Mefway의 합성과 소동물 뇌 PET 연구 (Synthesis and Small Animal Brain PET Study of a Serotonin Receptor Radiotracer, 18F-Mefway)

  • 안성민;홍태기;유영훈;최재용;김성철
    • 한국콘텐츠학회논문지
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    • 제9권11호
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    • pp.262-270
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    • 2009
  • 세로토닌 수용체 5-$HT_{1A}$에 대한 방사성추적자로 알려진 $^{18}F$-mefway를 개선된 방법으로 합성하고, 소 동물 뇌 microPET 연구를 통해서 이 수용체에 선택적으로 결합하는 지를 확인하려고 한다. 기존 합성 방법을 수정하여 전구체를 합성하고, $[^{18}F]^-$$130^{\circ}C$에서 30분간 교반하여 $^{18}F$-mefway를 합성하여, Solid phase extraction(SPE)과 HPLC를 이용해 정제한 다음, 소동물 뇌의 microPET 다이나믹 영상을 얻었다. Oxalyl chloride와 LAH/diethyl ether을 사용해서 기존 합성수율 9%에서 34%로 $^{18}F$-mefway 전구체를 향상된 수율로 합성할 수 있는 개선된 방법을 확립하였다. 이렇게 합성된 $^{18}F$-mefway는 세로토닌 5-$HT_{1A}$수용체 영상용 방사성 의약품으로서 신경정신질환 연구에 이용될 수 있을 것으로 사료된다.

Metal-Ion Catalysis in Alkaline Ethanolysis of 2-Pyridyl Thionobenzoate: Effects of Modification of Electrophilic Center from C=O to C=S

  • Um, Ik-Hwan;Song, Yoon-Ju;Kim, Min-Young;Lee, Jae-In
    • Bulletin of the Korean Chemical Society
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    • 제34권5호
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    • pp.1525-1529
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    • 2013
  • Pseudo-first-order rate constants ($k_{obsd}$) have been measured spectrophotometrically for the nucleophilic substitution reactions of 2-pyridyl thionobenzoate (5b) with alkali-metal ethoxides (EtOM, $M^+=Li^+$, $Na^+$, $K^+$, and 18-crown-6-ether complexed $K^+$) in anhydrous ethanol at $25.0{\pm}0.1^{\circ}C$. The plots of $k_{obsd}$ vs. $[EtOM]_o$ curve upward regardless of the nature of the $M^+$ ions, while those of $k_{obsd}/[EtO^-]_{eq}$ vs. $[EtO^-]_{eq}$ are linear with a positive intercept. Dissection of $k_{obsd}$ into $k_{EtO^-}$ and $k_{EtOM}$ (i.e., the second-order rate constants for the reactions with the dissociated $EtO^-$ and ion-paired EtOM, respectively) has revealed that the ion-paired EtOM is more reactive than the dissociated $EtO^-$, and $M^+$ ions catalyze the reactions in the order $K^+$ < $Na^+$ < $Li^+$ < 18C6-complexed $K^+$. The plot of log $k_{EtOM}$ vs. $1/r_{Stokes}$ results in an excellent linear correlation, indicating that the reactions are catalyzed by the solvated $M^+$ ions but not by the bare $M^+$ ions. The reactions of 5b with EtOM have been concluded to proceed through a six-membered cyclic TS, in which the solvated $M^+$ ions increase the electrophilicity of the reaction center and the nucleofugality of the leaving group.

Cystatin C as a novel predictor of preterm labor in severe preeclampsia

  • Wattanavaekin, Krittanont;Kitporntheranunt, Maethaphan;Kreepala, Chatchai
    • Kidney Research and Clinical Practice
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    • 제37권4호
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    • pp.338-346
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    • 2018
  • Background: The most common cause of acute kidney injury (AKI) in pregnancy is preeclampsia. Serum cystatin C (CysC) is a potential biomarker of early kidney damage as its levels are not disturbed by volume status changes in pregnancy, and serum CysC levels could serve as a replacement for conventionally used creatinine. In this study, we investigated the serum levels of CysC in severe preeclampsia cases and the associations between CysC levels and poor obstetric outcomes. Methods: Our cohort included severe preeclampsia patients with a normal serum creatinine level. Creatinine was measured to calculate estimated glomerular filtration rate (eGFR) based on the Cockcroft and Gault, Modification of Diet in Renal Disease Study (MDRD), and Chronic Kidney Disease Epidemiology Collaboration (CKD-EPI) equations, while CysC was measured to calculated eGFR based on a CysC-based equation. We then evaluated the correlations between serum CysC level, eGFR, and obstetric outcomes. Results: Twenty-six patients were evaluated of which 38.5% delivered preterm and 30.8% had low-birth weight babies. Unlike creatinine-based eGFR and CysC-based eGFR, serum CysC demonstrate significant negative correlation with gestational age. Receiver operating characteristic curve analysis indicated that serum CysC is a potential biomarker of preterm delivery with a cut-off serum level of 1.48 mg/L with 80% sensitivity and 75% specificity. Conclusion: GFR estimation using CysC is likely to be inaccurate in pregnancy. However, we found a significant correlation between preterm delivery and serum CysC level. Our results suggest that serum CysC level has the potential to predict preterm delivery in severe preeclampsia patients.

Effect of the surface modification using MWCNTs with different L/D by two different methods of deposition on the IFSS of single carbon fiber-epoxy resin composite

  • Herrera-Sosa, Minerva L.;Valadez-Gonzalez, Alex;Vazquez-Torres, Humberto;Mani-Gonzalez, Pierre G.;Herrera-Franco, Pedro J.
    • Carbon letters
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    • 제24권
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    • pp.18-27
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    • 2017
  • Multiwall carbon nanotubes (MWCNT) with two different (L/D) aspect ratios ($7{\pm}2{\mu}m/140{\pm}30nm$ and $0.5-2{\mu}m/8-15nm$) were surface treated using nitric acid ($HNO_3$) and polyethyleneimine (PEI) prior to their deposition on carbon fibers (CF). Before the hierarchical reinforcement with CF-MWCNT, the CFs were treated with 3-glycidoxypropyltrime-thoxysilane, a coupling agent (Z6040) and with poly(amidoamine) (PAMAM) a dendrimer containing an ethylenediamine core and amine surface groups. The MWCNT were deposited on the CF using two methods, by electrostatic attraction and by chemical reactions. The changes in the CF surface morphology after the MWCNT deposition were analyzed using SEM, which revealed a higher density and uniform coverage for the PAMAM-treated CF and the short MWCNTs. The interfacial adhesion of the composite materials was evaluated using the single fiber fragmentation technique. The results indicated an improvement in the interfacial shear strength with the addition of the short-MWCNTs treated with acid solutions and grafted onto the surface of the CF fiber using electrostatic attraction.

Interior seeding combined with top seeding for the fabrication of single grain REBCO bulk superconductors

  • Lee, Hee-Gyoun
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권2호
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    • pp.14-18
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    • 2017
  • This study presents three dimensional (3-D) seeding technique which is a modification of interior seeding. 3-D seeding is beneficial for shortening the processing period and enhancing the magnetic properties of REBCO bulk superconductors fabricated by melt growth. Oxygen channels were provided by using divided powder compacts instead of by using a rubber insert. Microstructure observations revealed that the grains grown from the seeds impinged each other and formed low angle grain boundaries of (001)/(001). It has been shown that the 3-D seeding technique reduces the volume fraction of a-c growth sector and thereby maximizes the area of a-b growth sector which attribute to the high magnetic characteristics of single grain REBCO bulk superconductors.

Axial BP Zoning for the Soluble Boron Free Operation in Medium-Sized PWR

  • Kim, Jong-Chae;Kim, Myung-Hyun
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 추계학술발표회논문집(1)
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    • pp.59-64
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    • 1996
  • Feasibility of soluble boron free operation for the medium-sized commercial reactors was investigated. Westinghouse advanced reactor, AP-600 was chosen as a design prototype. Design modification was applied for the assembly design with gadolinia burnable poison-high Gd enrichment and axial poison zoning. CASMO and NECTA-C code system checked axial offset and peaking factors as fuels burned up. A core with complex axial burnable poison zoning satisfied design goals - small excess reactivity for 18 month cycle. Therefore, critical bank positioning for three control rod banks was sought with ease. A.O. value and Fq value were kept within the safety limit.

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Complete genome sequence of Streptococcus hyointestinalis B19, a strain producing bacteriocin, isolated from chicken feces

  • Lee, Ju-Eun;Heo, Sunhak;Kim, Geun-Bae
    • Journal of Animal Science and Technology
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    • 제62권3호
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    • pp.420-422
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    • 2020
  • Streptococcus hyointestinalis B19 was isolated from chicken feces collected from local farm in Anseong, Korea. S. hyointestinalis B19 was shown to produce bacteriocin-like compounds exhibiting inhibitory activities against several pathogens including strains of Clostridium perfringens and Listeria monocytogenes. The whole genome of S. hyointestinalis B19 strain was sequenced using PacBio RS II platform. The genome comprised four contigs with a size of 2,217,061 bp. The DNA G + C content was found to be 42.95 mol%. Annotation results revealed 2,266 coding sequences (CDSs), 18 rRNAs, and 61 tRNA genes. Based on genome analysis, we found that the strain B19 possessed various genes associated with bacteriocin synthesis, modification, and transport.

커널 기반 가상머신을 이용한 시스템 무결성 모니터링 시스템 (System Integrity Monitoring System using Kernel-based Virtual Machine)

  • 남현우;박능수
    • 정보처리학회논문지C
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    • 제18C권3호
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    • pp.157-166
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    • 2011
  • 가상화 계층은 커널 보다 높은 권한 계층에서 수행되어 운영체제가 사용하고 있는 자원 정보를 모니터링 하는데 적합하다. 하지만 기존 가상화 기반 모니터링 시스템은 CPU나 메모리 사용률과 같은 기초적인 정보만을 제공하고 있다. 본 논문에서 메모리, 레지스터 GDT, IDT 그리고 시스템 콜과 같은 동적인 시스템 커널 객체를 모니터링하기 위하여 전가상화 방식의 모니터링 시스템을 제안한다. 모니터링 시스템을 검증하기 위해 커널의 수정 없이 바로 리눅스 커널에 적용된 전가상화 방식의 KVM을 기반으로 시스템을 구현하였다. 구현된 시스템은 KVM 내부 객체에 접근하기 위한 KvmAccess 모듈, 그리고 가상머신 모니터링 결과를 외부 모듈에서도 사용할 수 있도록 API를 제공하였다. 구현된 모니터링 시스템의 성능을 측정한 결과 1초 주기로 시스템을 모니터링을 하더라도 0.37% 정도의 CPU 점유율을 차지하여 그 성능 부하가 아주 작았다.