• 제목/요약/키워드: C.G.S method

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Head Space Analysis에 의한 n-Dodecane-1-Decanol, n-Dodecane-1- Dodecanol과 1-Decanol-1-Dodecanol계의 등온 기액 평형 (Isothermal vapor-liquid equilibria of n-Dodecane-1-Decanol, n-Dodecane-1 -Dodecanol and 1-Decanol-1-Dodecanol systems by Head Space Analysis)

  • 박소진;강용;이태종;최명재;이규완
    • 에너지공학
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    • 제2권2호
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    • pp.225-230
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    • 1993
  • n-dodecane-1-decanol, n-dodecane-1-dodecanol 및 1-decanol-1-dodecanol계 의 14$0^{\circ}C$ 등온 기액평형 데이타를 static method로써 Head Space Gas Chromatography (H.S.G.C)를 이용하여 측정하였다. 액상의 비이상성을 고려하여 계산된 활동도계수는 Margules, Van Laar, Wilson, NRTL g$^{E}$ 모델을 이용하여 상관관계를 구하였으며, Redlich-Kister의 열역학적 일치성 시험을 통해 데이타의 신빙성을 확인하였다. 측정한 이성분계중 n-dodecane-1-decanol계는 최소 공비점을 가짐을 알 수 있었다.

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잎담배 Hydrocarbon에 관한 연구 (Studies on the Hydrocarbon from Tobacco Leaves)

  • 장기철;김용옥;이운철
    • 한국연초학회지
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    • 제12권2호
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    • pp.77-83
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    • 1990
  • This study was conducted to develop the method of hydrocarbon analysis and investigate hydrocarbon contents in flue-cured and burley tobacco leaves harvested in Korea and U.S.A. Tobacco leaf was extract with hexane in soxhlet apparatus. Hydrocarbon was fractionated from hexane extract by silica gel column chromatography, and then separated and indentified by GC, GC/MS using SE-54 fused silica capillary column. The developed method was feasible to analyze neophytadiene, normal and branched hydrocarbons from Clo to Cn. The result of recovery test was decade 99%, eicosane 100%, triacontane 102%. The major hydrocarbon of tobacco leaves were neophytadiene, nC3l, iC31, nC33, aC33, aC32, aC30 and nC29. The amount of total hydrocarbon in burley and flue-cured tobacco leaves harvested in U.S.A. and Korea were 4591, 2931, 2929 and 3015$\mu\textrm{g}$/g, respectively.

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철강용 알칼리세정제의 제조에 관한 연구 (A Study on the Preparation of Alkaline Cleaning Agents for Steel)

  • 근장현;함현식;박홍수
    • 한국응용과학기술학회지
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    • 제10권2호
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    • pp.35-40
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    • 1993
  • Alkaline cleaning agent(ACA) was prepared by blending of POE(4)octadecylmine(S-204), $Na_2CO_3$, sodium orthosilicate(Na-OSi). Tetronix T-701(T-701), and MJU-100A. The physical properties of ACA tested with steel specimen showed the following results. The cleaning powers of ACA-6(S-204 80g/$Na_2CO_3$, 160g/Na-OSi, 80g/T-701, 60g/MJU-100A, 20g mixture) for press-rust preventing oil was 98% and 99% degreasing at 2wt%, $70^{\circ}C$ and $90^{\circ}C$, respectively : for quenching oil, the cleaning power of ACA-6 was 95% degreasing at 2wt% and $70^{\circ}C$. From these results, it was ascertained that ACA-6 exhibited a good cleaning power. Foam heights measured immediately after foaming by Ross & Miles method and Ross & Clark method at 3wt%. $60^{\circ}C$ were 17mm and 40mm, respectively. As the result, ACA-6 was proved a good low foaming cleaning agent.

The Safety and Pharmacokinetics of Cyanidin-3-Glucoside after 2-Week Administration of Black Bean Seed Coat Extract in Healthy Subjects

  • Jeon, Sang-Il;Han, Seung-Hoon;Lee, Jong-Tae;Hong, Tae-Gon;Yim, Dong-Seok
    • The Korean Journal of Physiology and Pharmacology
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    • 제16권4호
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    • pp.249-253
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    • 2012
  • We analyzed the pharmacokinetics of C3G on data from twelve subjects, after 2-week multiple dosing of black bean (Phaseolus vulgaris, Cheongjakong-3-ho) seed coat extract, using the mixed effect analysis method (NONMEM, Ver. 6.2), as well as the conventional non-compartmental method. We also examined the safety and tolerability. The PK analysis used plasma concentrations of the C3G on day 1 and 14. There was no observed accumulation of C3G after 2-week multiple dosing of black bean seed coat extract. The typical point estimates of PK were CL (clearance)=3,420 l/h, V (volume)=7,280 L, Ka (absorption constant)=9.94 $h^{-1}$, ALAG (lag time)=0.217 h. The black bean seed coat extract was well tolerated and there were no serious adverse events. In this study, we confirmed that a significant amount of C3G was absorbed in human after given the black bean seed coat extract.

Determination of Normal Saturated- and Polycyclic Aromatic Hydrocarbons in the River Water of Bangladesh by Liquid-Liquid Extraction and Gas Chromatography

  • Mottaleb, M.A.;Sarma, D.K.;Sultana, S.;Husain, M.M.;Alam, S.M.M.;Salehuddin, S.M.
    • Bulletin of the Korean Chemical Society
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    • 제24권1호
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    • pp.99-105
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    • 2003
  • A liquid-liquid extraction followed by evaporative concentration method was used to determine the concentration of normal, or straight chain, saturated hydrocarbons (NSH) $(C_{10}\;to\;C_{24})$ and polycyclic aromatic hydrocarbons (PAH) here defined as: fluorene, anthracene, pyrene, chrysene and perylene, in the Buriganga River water of Bangladesh. Samples were collected from 5 and 25 cm depth of water at the southern, middle and northern parts of the river at Postogolla, Sadarghat and Sowarighat stations. Hydrocarbons were extracted from 450 mL of water into 75 mL n-hexane and then concentrated into 1 or 2 mL solution by evaporation. These solutions were analyzed by gas chromatography. The highest and lowest concentrations were determined as $257\;{\mu}gL^{-1}\;for\;C_{13}\;and \;0.24\;{\mu}g\;L^{-1}\;for\;C_{22}$ at 5 ㎝ depth of water, at the northern part of the Sowarighat and southern part of the Postogolla, respectively. This method could allow the analysis of water for $C_{22}$ as low as $0.24\;{\mu}g\;L^{-1}$.

후춧가루에 인위접종된 Escherichia coli O157:H7, Salmonella Typhimurium에 대한 UV-C와 mild heat의 살균 효과 (Combination Effect of UV-C and Mild Heat Treatment Against Artificially Inoculated Escherichia coli O157:H7, Salmonella Typhimurium on Black Pepper Powder)

  • 곽승해;김진희;오세욱
    • 한국식품위생안전성학회지
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    • 제33권6호
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    • pp.495-499
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    • 2018
  • 후춧가루에 존재하는 식중독 균을 저감화시키기 위한 방법으로 UV-C와 mild heat를 병합 처리 가능성을 타진하였다. Escherichia coli O157:H7 (ATCC 35150)와 Salmonella Typhimurium (ATCC 19585)를 후춧가루에 각각 $10^6$, $10^7CFU/g$ 수준으로 인위접종하여 $2.32W/cm^2$의 UV-C와 $60^{\circ}C$의 mild heat을 10분에서 70분 동안 처리하였다. 그 후 미생물 분석 및 후춧가루의 품질변화를 측정하였다. UV-C를 단독으로 70분 동안 처리했을 때 E. coli O157:H7과 S. Typhimurium는 각각 1.89, 2.24 log CFU/g 수준으로 감소하였지만, UV-C와 mild heat을 70분 동안 병합처리 했을 때는 각각 2.46, 5.70 log CFU/g으로 감소하였다. E. coli O157:H7 보다는 S. Typhimurium의 저감효과가 더 컸다. 색도는 모든 처리구에서 유의적인 차이가 없는 것으로 나타났다. 따라서 UV-C와 mild heat 병합처리는 후춧가루에 존재하는 식중독 균을 사멸시키는 데 효과적이기 때문에 산업적인 살균처리 기술로 활용될 수 있을 것으로 판단되었다.

한국 울릉도의 너도밤나무(Fagus multinervis Nakai)림 및 섬잣나무(Pinus parviflora S. et Z.)림의 식물사회학적 연구 (Phytosociological Studies on the Beech(Fagus multinervis Nakai) Forest and the Pine (Pinus parviflora S. et Z.) Forest of Ulreung Island, Korea)

  • 김성덕
    • Journal of Plant Biology
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    • 제29권1호
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    • pp.53-65
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    • 1986
  • The montane forests of Ulreung Island, Korea, were investigated by the ZM school method. By comparing the montane forests of this island with those of Korean Peninsula and of Japan, a new order, F a g e t a l i a m u l t i n e r v i s, a new alliance, F a l g i o n m u l t i n e r v i s, a new association, H e p a t i c o-F a g e t u m m u l t i n e r v i s and Rhododendron brachycarpum-Pinus parviflora community were recognized. The H e p a t i c o - F a g e t u m m u l t i n e r v i s was further subdivided into four subassociations; Subass. of Sasa kurilensis, Subass. of Rumohra standishii, Subass. of Rhododendron brachycarpum and Subass. of typicum. Each community was described in terms of floristic, structural and environmental features.

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Effect of coarse aggregates and sand contents on workability and static stability of self-compacting concrete

  • Mohamed, Sahraoui;Taye, Bouziani
    • Advances in concrete construction
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    • 제7권2호
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    • pp.97-105
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    • 2019
  • In this paper, the workability and static stability were evaluated using a proposed test method. Workability and static stability represent a key property of self-compacting concrete (SCC) in fresh state. A number of standardized test methods were developed to assess these properties. However, no accelerated test method reliably predicts both workability and static stability of SCC. In the present work, a modified K-slump test method was developed to evaluate workability and static stability of SCC. In order to take implicit mixture variations of SCC constituents that can affect fresh SCC properties, a central composite design was adopted to highlight the effect of gravel to sand ratio (G/S), gravel 3/8 to gravel 8/15 ratio (G1/G2), water to cement ratio (W/C), marble powder to cement ratio (MP/C) and superplasticizer content (SP) on workability measured with slump and flow time (T50) tests and static stability measured with sieve stability test (Pi), segregation test index (SSI), Penetration test (Pd) and the proposed K-slump test (Km). The obtained results show that G/S ratio close to 1 and G1/G2 ratio close to 60% can be considered as optimal values to achieve a good workability while ensuring a sufficient static stability of SCC. Acceptable relationships were obtained between Slump flow, Pi, Pd and Km. Results show that the proposed K-slump test allow to assess both workability and static stability of fresh SCC mixtures.

PVC를 원료로 탄소코팅한 Mo6S8의 합성 및 전기화학적 특성 (Synthesis and Electrochemical Properties of Carbon Coated Mo6S8 using PVC)

  • 현시철;조병원;나병기
    • Korean Chemical Engineering Research
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    • 제61권3호
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    • pp.348-355
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    • 2023
  • 마그네슘 이차전지는 기존에 사용되고 있는 리튬이온전지를 대체할 수 있는 가능성으로 인해 많은 주목을 받고 있다. 마그네슘 이차전지용 양극활물질인 Mo6S8을 MSS (Molten Salt Synthesis)법으로 합성하였고, Mo6S8의 전기화학적 특성을 향상시키기 위하여 탄소소재인 PVC (Poly Vinyl Chloride)를 첨가하여 탄화시켰다. 물질의 결정 구조와 크기, 표면 상태는 XRD (X-ray Diffraction), SEM (Scanning Electron Microscope)으로 분석하였다. 전기화학적 특성은 배터리충방전기를 이용하여 충·방전 프로파일과 출력 특성 등을 측정하였다. PVC를 2.81 wt% 첨가한 물질의 경우, 0.125 C-rate에서 85.8 mAh/g, 0.5 C-rate에서 69.2 mAh/g, 1 C-rate에서 60.5 mAh/g의 용량을 나타내어 우수한 출력특성을 보여주었다.