• 제목/요약/키워드: C-type electrode

검색결과 331건 처리시간 0.028초

저온 고체산화물 연료전지용 공기극 미세구조 제어 및 성능개선 (Cathode Microstructure Control and Performance Improvement for Low Temperature Solid Oxide Fuel Cells)

  • 강중구;김진수;윤성필
    • 한국세라믹학회지
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    • 제44권12호
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    • pp.727-732
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    • 2007
  • In order to fabricate a highly performing cathode for low-temperature type solid oxide fuel cells working at below $700^{\circ}C$, electrode microstructure control and electrode polarization measurement were performed with an electronic conductor, $La_{0.8}Sr_{0.2}MnO_3$ (LSM) and a mixed conductor, $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$(LSCF). For both cathode materials, when $Sm_{0.2}Ce_{0.8}O_2$ (SDC) buffer layer was formed between the cathode and yttria-stabilized zirconia (YSZ) electrolyte, interfacial reaction products were effectively prevented at the high temperature of cathode sintering and the electrode polarization was also reduced. Moreover, cathode polarization was greatly reduced by applying the SDC sol-gel coating on the cathode pore surface, which can increase triple phase boundary from the electrolyte interface to the electrode surface. For the LSCF cathode with the SDC buffer layer and modified by the SDC sol-gel coating on the cathode pore surface, the cathode resistance was as low as 0.11 ${\Omega}{\cdot}cm^2$ measured at $700^{\circ}C$ in air atmosphere.

동축형 전극길이 변화시의 연면무성방전에 의한 오존발생특성(I) (Ozone Generation Characteristics by Surface-Silent Discharge According to the Length of Coaxial Electrode)

  • 조국희;김영배;서길수;이형호;이상근;이광식
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권12호
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    • pp.791-797
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    • 1999
  • Recently the ozone generation system is well used for cleaning the contaminated water by using the strong oxidization effects of ozone. In this paper the concentration, yield and generation quantity of the ozone by the Surface-Silent Discharge According to the Length of Coaxial Electrode is described. The electrodes composed of 3 electrodes-2 gaps are coaxial type and the ozone generation tube were designed and fabricated from the point of view of the energy efficiency, stability and easy control. To investigate the ozone generation dependency on electrode length, a few discharge tubes with different lengths were fabricated. The experimental equipments were provided with cooling system and dehumidifier for the many testing conditions. The main results show that the concentration, yield and generation quantity of ozone are improved by decreasing gas temperatures and increasing electrode lengths.

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Ni/MH 2차전지용 Fe-Ti계 전극 제조공정에 대한 연구 (A Study on the Manufacturing Process of Fe-Ti Type Electrode for Ni/MH Secondary Battery)

  • 정상식;김기원;안효준;정순돌
    • 한국수소및신에너지학회논문집
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    • 제9권2호
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    • pp.65-75
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    • 1998
  • 실용적인 Fe-Ti계 수소저장합금전극을 제조하기위한 적절한 공정을 확립하기위하여 다섯가지의 서로다른 제조공정을 선택하여 조사하여 보았다. 전극제조를 위해 먼저 FeTi 합금을 플라즈마 아크 용해로에서 용해제조한 후 분쇄하여 분말을 만들고 이를 성형하였다. 성형전에 합금분말을 Ni무전해도금하여 본 결과 Fe-Ti 합금의 방전특성이 개선되었으며 열처리효과에 대하여도 검토하여 보았다. 성형전 합금분말을 열처리하는 경우 열처리 온도가 증가함에 따라 전극의 방전용량이 증가함을 확인하였으며 특히 성형후 $100^{\circ}C$의 온도에서 열처리하는 경우 가장 좋은 결과를 얻을 수 있었다. 이들 결과로 부터, Ni무전해도금과 열처리가 Fe-Ti 계 전극의 방전성능을 향상시키는데 결정적인 역할을 함을 알 수 있었다. 또한, 본 연구에서 제안된 공정에 따라서 Mn을 첨가하여 Fe-Ti-Mn 전극을 제조하고 그 성능을 조사하여 본 결과 대단히 바람직한 결과를 얻었다.

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고전압 회전 스파크 공격간의 이온 이동특성 (Ion Migration Characteristics of a High Voltage Rotary Spark Airgap)

  • 문재덕;김태훈;황덕현
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권9호
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    • pp.427-432
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    • 2005
  • Ion migration characteristics of a rotary spark airgap of high voltage Pulse generator had been investigated. It was considered that the ion migration speed and the ions of the gases(atmosphere gases, $O_2,\;N_2,,\;and\;H_{2}O,\;etc$.) and the charged very fine particles(about $10\~100nm$ size) migrated through the upper stator ball and bottom stator ball of the rotary spark airgap would determined the rise and fall times of the output high voltage pulse. In this paper, a basic study on the ion migration characteristics of the rotary spark airgap between the spark stator ball and the ion-sensing electrode of the proposed high voltage pulse generator have been investigated experimentally. As a result, the three kinds of ion speeds were detected by the ion-sensing electrode installed at the position of the bottom stator ball of the ball type sparkgap high voltage pulse generator. The migration velocities, diameters, masses, charges, numbers of the ions and particles were obtained by experiments and calculations, which, however, would determine the rise and fall times of the output high voltage pulse.

구형파 펄스를 인가한 정전분무 장치의 대전량 특성 (Charging Characteristics of Electrostatic Sprayer Applied Square Pulse)

  • 박승록;문재덕
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권12호
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    • pp.573-578
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    • 2003
  • In this study, new type of induction charging system for electrostatic spraying was manufactured and proposed to improve the electrical safety and charging efficiency. And parameters of proposed system to generate the maximum deposition current with electrical safety were selected and investigated. The selected parameters were frequency of square pulse and thickness of insulation material, outer diameter of device and thickness and positions of electrode. Charging quantity of water drop was measured by deposition current detected from sensing plate indirectly. The maximum deposition current for each parameter were 3.5[uA] at the frequency of 15[kHz] and thickness of 0.25[mm] insulating layer. And maximum deposition currents were 2.8[uA] and 3.0[uA] at 25[mm] outer diameter of charging device and 0.25[mm] thickness of electrode each. Effects of electrode position from spraying nozzle on deposition current was a little.

알칼리형 연료전지의 수소극용 Co-Mo 및 Ni-Mo 금속간화합물 전극의 전기화학적 안정성 (Electrochemical Stability of Co-Mo and Ni-Mo Intermetallic Compound Electrodes for Hydrogen Electrode of Alkaline Fuel Cell)

  • 이창래;강성군
    • 전기화학회지
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    • 제2권3호
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    • pp.150-155
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    • 1999
  • [ $H_2-O_2$ ] 알칼리형 연료전지용 수소극으로서 아크융해법으로 제조된 Brewer-Engel type의 Co-Mo$(35\;wt\%)$ 및 Ni-Mo$(35\;wt\%)$ 금속간화합물 전극의 전기화학적 안정성이 조사되었다. $N_2$가스로 용존산소를 제거한 $80^{\circ}C$ 6N KOH 전해질 내에서 금속간화합물 전극의 전기화학적 안정성에 미치는 전해질의 농도 및 온도의 영향이 조사되었다. 또한, AFC의 정상 작동조건하에서는 Co-Mo및 Ni-Mo전극의 전기화학적 안정성에 대한 분극전압(과전압)의 영향이 논의되었다. Co-Mo전극은 Ni-Mo전극에 비하여 낮은 전기화학적 안정성을 보였다. 수소가스 평형전위로부터 낮은 양분극 과전압 하에서 Co-Mo전극에서는 Co와 Mo의 용해가 동시에 일어났다. 그러나, Co는 Mo에 비하여 급격히 용해되었다 높은 양분극 과전압에서는 전극표면에 $Co(OH)_2$ 부동태 피막이 형성되었다. Ni-Mo전극의 경우에는 Mo의 용해반응이 치밀한 $Ni(OH)_2$, 부동태 피막형성에 의하여 억제되어 우수한 전기화학적 안정성을 보였다.

3전극형 반사형 디스플레이에서 패키징 방법에 의한 광특성 개선에 관한 연구 (A Study on Improvement of Optical Characteristics by Packaging Methods in Three Electrode-Type Reflective Display)

  • 박상현;김영조
    • 한국전기전자재료학회논문지
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    • 제30권3호
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    • pp.170-174
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    • 2017
  • In 3 electrode reflective displays using a plastic substrate, unstable packaging induces particle clumping and optical degradation due to external air inflow and electronic ink evaporation. In this work, we fabricate 3 electrode electronic paper using glass wafer, ITO/plastic film, and ITO/glass/gas barrier film as an upper substrate after injecting electronic ink onto the lower substrate. Then, we studied its properties. After operating under stress conditions for 336 hours at $85^{\circ}C$ and 75% humidity, the reflectivity of driven e-paper panels with white color was 25.5% for the panels using glass wafer, 22.5% for plastic film including a gas barrier layer, and 16% for plastic film only. From these optical properties, we conclude that gas barrier film improves upper film isolation as a desirable packaging method.

패턴된 전극을 가진 표면 전도형 단실형 고체산화물 연료전지의 제조 (Fabrication of Co-Planar Type Single Chamber SOFC with Patterned Electrodes)

  • 안성진;김용범;문주호;이종호;김주선
    • 한국세라믹학회지
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    • 제43권12호
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    • pp.798-804
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    • 2006
  • Co-planar type single chamber solid oxide fuel cell with patterned electrode on a surface of electrolyte has been fabricated by robo-dispensing method and microfluidic lithography. The cells were composed of NiO-GDC-Pd or NiO-SDC cermet anode, $(La_{0.7}Sr_{0.3})_{0.95}MnO_3$ cathode, and yttria stablized zirconia electrolyte. The cell performance at $900^{\circ}C$ was investigated as a function of electrode geometries, such as anode-to-cathode distance, numbers of electrode pairs. Relationship between OCV and I-V characteristics at the optimized operation condition was also studied by DC source meter under the mixed gas condition of methane, air, and nitrogen. An increase of anode-facing-cathode area leads to lower OCV due to intermixing between product gases of anode and cathode, which in turn decreases the oxygen partial pressure difference.

미생물연료전지의 전기생산에 미치는 운전온도 및 전극간 거리의 영향 (Effects of Operating Temperature and Electrode Gap Distance on Electricity Generation in Microbial Fuel Cells)

  • 최영대;이명은;송영채;우정희;유규선;이채영;정재우
    • 유기물자원화
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    • 제20권1호
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    • pp.41-49
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    • 2012
  • 이형반응기 미생물연료전지(MFC) 시스템의 전기생산에 미치는 운전온도 및 전극간 거리의 영향에 관한 실험실 규모 실험을 수행하였다. 외부저항이 $(100\;{\Omega})$인 조건에서 시스템의 평균온도가 $30^{\circ}C$에서 $34^{\circ}C$로 증가할 때 외부저항 양단의 전압은 약 1.4배 증가하였다. 운전온도의 증가는 MFC의 OCV(open circuit voltage)를 증가시키며, 전극간 거리가 감소하고 운전온도가 증가함에 의해 최대전력이 얻어지는 전류가 상승하는 것으로 나타났다. MFC 시스템의 운전온도 증가에 의해 모든 전극간 거리조건에서 최대전력밀도가 크게 증가하였다. 시스템의 평균온도가 $4^{\circ}C$로 증가할 때 5~10 cm의 전극간 거리에서 얻어지는 최대전력밀도는 1.9~2.4배 증가하였고 동일한 온도조건에서는 전극간 거리가 감소할수록 전력수율이 증가하였다. MFC의 전기생산에 미치는 운전온도와 전극간 거리의 영향은 시스템의 내부저항과 밀접하게 관련되어 있는 것으로 나타났다. 즉, MFC의 운전온도가 증가하고 전극간 거리가 감소함에 의해 시스템의 내부저항이 감소함으로써 전기생산이 증가하였다.

지중 금속구조물 부식감시를 위한 영구매설용 기준전극 개발 (Development of Permanent Reference Electrode for Corrosion Monitoring of Underground Metallic Structures)

  • 하윤철;배정효;하태현;이현구;이재덕;김대경
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 학술대회 논문집 정보 및 제어부문
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    • pp.532-534
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    • 2004
  • The advancement of electronics and telecommunication technologies has forced the risk management system for underground metallic structures to evolve into the remote monitoring and control system. Especially, facilities such as gas pipelines, oil pipelines and water distribution lines might make hazardous effect on human safety without continuous monitoring and control. As a result, pipeline engineers have applied cathodic protection system to prevent the degradation of their facilities by corrosion and carried out a periodic monitoring of the pipe-to-soil (P/S) potentials at numberous test boxes along their pipelines. The latter action on a road in downtowns, however, is so much dangerous that the inspectors should be ready to suffer the threatening of their lives and maintenance. In order to minimize these social costs and hazards, a stand-alone type corrosion monitoring equipment which can be installed in test box, store the P/S data for given Belied and send the data by wired/wireless telecommunications is under development. In order to obtain the exact P/S data, however, a reference electrode should be located as close to the pipeline as possible. Actually, the measured potential by a conventional portable reference electrode contain inevitably an IR drop portion caused by the current flow from the cathodic protection rectifier or the subway railroad. To minimize this error, it is recommended that the reference electrode should be buried within 10 cm from the pipeline. In this paper, we describe the design parameters for fabricating the permanent type reference electrode and the characteristics of the developed reference electrode.

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