• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1993년도 하계학술대회 논문집 B
• /
• pp.1265-1267
• /
• 1993

The switching and the retention characteristics with the injection conditions(pulse height and pulse width) were investigated in the nonvolatile MNOS memories with thin oxide layer of $23{\AA}$ thick. The shift of flatband voltage was measured using the fast ramp C-V method and experimental results were analized using the previously developed models. It was shown that the experimental results were described quit well by the trap-assisted and modified Fowler-Nordheim tunneling models for the voltage pulse of $15V{\sim}19V,\;24V{\sim}25V$, respectively. However, the direct tunneling model was agreement with experimental values in all range of pulse height. As increasing the initial shift of the flatband voltage, the decay rate was increased. But for the same initial shift of the flatband voltage, the decay rate was smaller for low and long pulse than for high and short one.

• Journal of Magnetics
• /
• 제10권3호
• /
• pp.128-132
• /
• 2005

We report optical ab-plane properties of the layered sodium cobaltate, $Na_xCoO_2$ for x = 0.35 and 0.75. Two samples show metallic behaviors according to dc resistivity transport. Overall temperature dependent optical conductivities of both samples are very similar to those of the high temperature superconducting underdoped cuprates. We found that the optical scattering rate of x = 0.75 sample, which is in a Curie-Weiss metallic phase, varies linearly (non-Fermi liquid) with frequency and temperature while that of x = 0.35 sample, which is in a paramagnetic metallic phase, varies quadratically (Fermi liquid) with frequency and temperature. Both x = 0.35 and 0.75 samples have an onset of scattering around $600\;cm^{-1}$ which can be attributed to the interaction of charge carriers with a bosonic collective mode in a system.

• Corrosion Science and Technology
• /
• 제20권1호
• /
• pp.15-21
• /
• 2021

Through a simple filtration process, followed by carbonization within a reductive environment, coffee waste grounds can be transformed into a non-porous hard carbon for use in multiple contexts. This resulting coffee-waste carbon has been evaluated as an eco-friendly and cost-effective replacement for conventional graphite. When compared with different types of carbon, our study found that the coffee-waste carbon fell into the category of hard carbon, as verified from the galvanostatic charge/discharge profiles. The coffee-waste carbon showed a superior rate capability when compared to that of graphite, while compromising smaller capacity at low C rates. During electrochemical reactions, it was also found that the coffee-waste carbon is well exposed to electrolytes, and its disordered characteristic is advantageous for ionic transport which leads to the low tortuosity of Li ions. Finally, the high irreversible capacity (low initial Coulombic efficiency) of the coffee-waste carbon, which if also often observed in amorphous carbon, can be adequately resolved through a solution-based prelithiation process, thereby proving that the coffee-waste carbon material is quite suitable for commercial use as an anode material for quickly-chargeable electrodes.

• Bulletin of the Korean Chemical Society
• /
• 제15권2호
• /
• pp.161-167
• /
• 1994

Rate constants have been measured spectrophotometrically for the nucleophilic substitution reactions of aryl substituted benzenesulfonates (3) with alkali metal ethoxides ($EtO^-M^+$) and butane-2,3-dione monoximates ($Ox^-M^+$) in ethanol at $25^{\circ}C$. The reactivity of the alkali metal ethoxides decreases in the order $EtO^-K^+> EtO^- > EtO^-Li^+$, indicating that $K^+$ ion behaves as a catalyst and $Li^+$ ion acts as an inhibitor for all the substrates studied. For the corresponding reactions of 3 with Ox^-M^+$, $Li^+$ ion also exhibits inhibitory effect for all the substrates, while, $K^+$ ion shows catalytic or inhibitory effects depending on the nature of substituents on the acyl and phenyl moieties. A study of substituent effect on rate has revealed that both EtO^- $and Ox^-$ systems have the same reaction mechanism. The different behavior shown by $K^+$ ion for the reaction of 3 with $EtO^-$ and $Ox^-$ would be attributed to a difference in charge polarization of S=O bond in the transition state between the two systems and/or a change in conformation of Ox^-K^+$.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제49권6호
• /
• pp.328-334
• /
• 2000

A lithium ion secondary battery using carbon as a negative electrode has been developed. Further improvements to increase the cell capacity are expected by modifying the structure of the carbonaceous material. There are hopes for the development of large capacity lithium ion secondary batteries with long cycle, high energy density, high power density, and high energy efficiency. In the present paper, needle cokes from petroleum were examined as an anode of lithium ion secondary battery. Petroleum cokes, MCL(Molten Caustic Leaching) treated in Korea Institute Energy Research, were carbonized at various temperatures of 0, 500, 700, $19700^{\circ}C$ at heating rate of $2^{\circ}C$/min for lh. The electrolyte was used lM liPF6 EC/DEC (1:1). The voltage range of charge & discharge was 0.0V(0.05V) ~ 2.0V. The treated petroleum coke at $700^{\circ}C$ had an initial capacity over 560mAh.g which beyond the theoretical maximum capacity, 372mAh/g for LiC6. This phenomena suggests that carbon materials with disordered structure had higher cell capacity than that the graphitic carbon materials.

• 공업화학
• /
• 제35권2호
• /
• pp.140-147
• /
• 2024

바이오매스 활용을 높이기 위하여, 열처리 공정을 통해 강아지풀 기반 리튬 이온 이차 전지용 탄소음극재(SV-C)를 제조한 뒤 전기화학적 성능을 고찰하였다. 강아지풀의 열처리 온도가 750 ℃로 낮을 때 낮은 결정성과 높은 비표면적(126 m²/g)과 함께, 표면에 많이 존재하는 산소의 (-) 전하가 리튬을 끌어당김으로 인하여 비정전용량(1003.3 mAh/g, at 0.1 C)이 높지만, 용량 유지율은 61.0% (at 500 cycles and 1 C)로 낮아지는 것으로 여겨진다. 또한, 열처리온도가 1150 ℃로 증가하면 탄소층이 축합되어 배열이 우수해짐에 따라 구조 결함이 감소하여 기공이 크게 줄어 비표면적(32 m²/g)이 감소한 것으로 확인되었다. 또한, 음극재 표면결함이 감소하여 결정성이 높아지게 되면, 용량 유지율은 89.7% (at 500 cycles and 1 C)로 높지만, 결함 정도가 작아 활성점이 줄어들어 비정전용량이 471.7 mAh/g로 매우 낮은 것으로 여겨진다. 본 연구 범위에서, 열처리 온도에 따라 제조된 강아지풀 기반 탄소음극재의 경우, 비표면적에 비해 표면 산소 함량과 결정성 등이 음극재의 전기화학적 특성에 더 높은 신뢰도를 갖는 것으로 나타났다.

• 전기화학회지
• /
• 제2권1호
• /
• pp.46-49
• /
• 1999

Electron-beam 증발장치를 이용하여 리튬 박막 2차 전지 양극용 lithium cobalt oxide 박막을 제조하였다. Stainless steel -기판 위에 입혀진 $LiCoO_2$ 박막은 열처리 과정을 거쳐 잘 발달된 hexagonal 구조의 (003)면을 나타냈으며, 3.9 V 부근에서 전위 평탄 영역이 나타났다. $LiCoO_2$, 박막은 증착속도가 증가함에 따라 Li/co 조성비가 양론비에 근접하였으며, $15{\AA}/s$의 증착속도로 제작한 경우 높은 방전용량을 나타내었다. 열처리 온도가 증가함에 따라 용량이 증가하여 $700^{\circ}C$에서 최대 값을 나타내었으나, 그 이상의 온도에서는 기판과의 반응 때문에 방전용량이 현저히 감소하였다. 박막 내부의 리튬과 코발트의 불균일한 조성은 초기 방전용량의 감소를 가져왔다.

• 전력전자학회논문지
• /
• 제20권2호
• /
• pp.175-181
• /
• 2015

In this study, a lithium polymer battery (LiPB) is simply expressed by a primary RC equivalent model. The PI state observer is designed in Matlab/Simulink. The non-linear relationship with the OCV-SOC is represented to be linearized with 0.1 pu intervals by using battery parameters obtained by constant-current pulse discharge. A state equation is configured based on battery parameters. The state equation, which applied Peukert's law, can estimate SOC more accurately. SOC estimation capability was analyzed by utilizing reduced Federal Test Procedure (FTP-72) current profile and using a bi-directional DC-DC converter at temperature ($25^{\circ}C$). The PI state observer, which is designed in this study, indicated a SOC estimation error rate of ${\pm}2%$ in any of the initial SOC states. The PI state observer confirms a strong SOC estimation performance despite disturbances, such as modeling errors and noise.

• International Journal of Automotive Technology
• /
• 제7권6호
• /
• pp.675-680
• /
• 2006

In the direct injected gasoline engine, atomized spray is desired to achieve efficient mixture formation needed to good engine performance because the injection process leaves little time for the evaporation of fuels. Therefore, substantial understanding of global spray structure and quantitative characteristics of spray are decisive technology to optimize combustion system of a GDI engine. The combustion and emission characteristics of gasoline-fueled stratified-charge compression ignition(SCCI) engine according to intake temperature and compression ratio was examined. The fuel was injected directly to the cylinder under the high temperature condition resulting from heating the intake port. With this injection strategy, the SCCI combustion region was expanded dramatically without any increase in NOx emissions, which were seen in the case of compression stroke injection. Injection timing during the intake temperature was found to be an important parameter that affects the SCCI region width. The mixture stratification and the fuel reformation can be utilized to reduce the required intake temperature for suitable SCCI combustion under each set of engine speed and compression ratio conditions.

• 대한가정학회지
• /
• 제47권10호
• /
• pp.123-136
• /
• 2009

The purpose of this study was to examine whether childbirth encouragement policy is actually helping those childbirth, and also discuss the possible directions of this policy to unfold in the future, should take. For this, We have surveyed 412 married and 437 unmarried men and women in order to investigate the individual values that influence childbirth, From these respondents and we interviewed and surveyed recipients of grants (244people), administrative officers in charge (41people), and experts (34people) to investigate their social view on the Korean government's impact. The results of this study are as follows: Firstly, most of the people (unmarried 70.3%, married 69.1%) surveyed said that important life objectives for them. Secondly, most of the people(male 44.4%, female 73.8%) surveyed said that once married shied away from having babies, (a) due to the finance and childcare burden is heavy of running a family while both parents are fulltime employed (b) because it is difficult to get pregnant due to health problems, and (c) foremost because having several children exacerbates their financial burden. Thirdly, grant recipients(75.4%), administrative officers in charge(65.9%), and experts(53.0%) all said that childbirth encouragement policy currently being implemented has little impact on their childbirth. Finally, it was established that the incentives to encourage childbirth is best suited for individuals that favor having many children.