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Nano-Silica effect on the physicomechanical properties of geopolymer composites

  • Khater, H.M.
    • Advances in nano research
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    • v.4 no.3
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    • pp.181-195
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    • 2016
  • Addition of nano-$SiO_2$ (NS) to geopolymer composites has been studied through measurement of compressive strengths, FTIR and XRD analysis. Alumino-silicate materials are coarse aggregate included waste concrete and demolished walls with its cementing binder, cement kiln dust (CKD) used and can possess a pronouncing activation for the geopolymer reaction resulting from the high alkali contents within. Materials prepared at water/binder ratios in a range of 0.30: 0.40 under curing of $40^{\circ}C$ and 100% Relative Humidity (R.H.), while the used activator is sodium hydroxide in the ratio of 2 wt. %. First, CKD is added in the ratio from 10 up to 50 wt., %, and the demolished walls was varied depending on the used CKD content, while using constant ratio of waste concrete (40 wt., %). Second step, depending on the optimum CKD ratio resulted from the first one (40 wt. %), so the control geopolymer mix composed of cement kiln dust, demolished walls and waste concrete in the ratio (40:20:40, wt %). Nano-silica partially replaced waste concrete by 1 up to 8%. Results indicated that, compressive strengths of geopolymer mixes incorporating nano-silica were obviously higher than those control one, especially at early ages and specially with 3%NS.

Performance Evaluation of Nano-Lubricants at Refrigeration Oil (나노입자를 적용한 냉장고 압축기용 오일의 윤활특성 평가)

  • Lee, Kwang-Ho;Hwang, Yu-Jin;Kwon, Lae-Un;Lee, Jae-Keun;Kim, Seok-Ro;Kim, Sun-Wook
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.184-188
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    • 2008
  • It has been recognized that friction coefficient decreased with decreasing viscosity of oil in lubrication. In general, the more viscosity decreases, the more wear rate increases due to decrease load carrying capacity. It has been proposed that nano particles in oil decrease friction coefficient and wear rate. The purpose of this study is to apply oil of lower viscosity that mix with nano particles at the compressor used in a refrigerator to decrease friction coefficient keeping Load carrying capacity. Mineral oil of 8 cSt were used and mixed with nano particle. Friction coefficient was evaluated by a disk-on-disk tester. As a result, friction coefficient of nano oil decreased by 90% in comparison with raw oil. These results lead us to the conclusion that nano oil is new plan to raise efficiency of the compressor.

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Growth and Characterization of $CuInS_2$ Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE) 방법에 의해 성장된 $CuInS_2$)

  • 최승평;홍광준
    • Korean Journal of Crystallography
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    • v.11 no.3
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    • pp.137-146
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    • 2000
  • The stoichiometric mix of evaporating materials for he CuInS₂ single crystal thin films was prepared. To obtain the single crystal thin films, CuINS₂ mixed crystal was deposited on etched semi-insulator GaAs(100) substrate by the hot wall epitaxy(HWE) system. The source and substrate temperature were 640℃ and 430℃, respectively and the thickness of the single crystal thin films was 2 ㎛. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility deduced from Hall data are 9.64x10/sup 22//㎥ and 2.95x10/sup -2/ ㎡/V·s, respectively at 293 K. he optical energy gap was found to be 1.53 eV at room temperature. From the photocurrent spectrum obtained by illuminating perpendicular light on the c-axis of the thin film, we have found that the values of spin orbit coupling splitting ΔSo and the crystal field splitting ΔCr were 0.0211 eV and 0.0045 eV at 10K, respectively. From PL peaks measured at 10K, were can assign the 807.7 nm (1.5350 eV) peak to E/sub x/ peak of the free exciton emission, the 810.3 nm(1.5301 eV) peak to I₂ peak of donar-bound exciton emission and the 815.6 nm(1.5201 eV) peak to I₁ peak of acceptor-bound excition emission. In addition, the peak observed at 862.0 nm(1.4383 eV) was analyzed to be PL peak due to donor-acceptor pair(DAP).

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Reactions of Various Ceramic Materials with Cobalt Sulfate Solution (황산코발트 용액에 의한 다양한 세라믹소지의 반응)

  • Won, Il-An;Kim, Kyung-Nam
    • Korean Journal of Materials Research
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    • v.24 no.2
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    • pp.93-97
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    • 2014
  • In this study, a cobalt sulfate ceramic coating was sintered on various clays at $1250^{\circ}C$. The specimen characteristics were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM), TG-DTA, UV-vis spectrophotometer, and HRDPM. The ceramic coating had a constant thickness of thousands ${\mu}m$, and the surface was confirmed to be densely fused. Other new compounds were produced by the cobalt sulfate sintering process and reactions. These compounds were a $CoAl_2O_4$ phase, $Co_2SiO_4$ phase, anorthite($CaAl_2Si_2O_8$) phase, and $FeAl_2O_4$ phase, respectively. UV properties of the coated specimen were investigated, celadon clay specimen in 530-550 nm band is showing a dark gray color. The white clay and white mix clay specimen in 460-500 nm band is showing a blue color. The cobalt-aluminate($CoAl_2O_4$) spinel and the cobalt-silicate olivine($Co_2SiO_4$) were the strongest of the ceramic pigments, producing a very pure, navy blue color.

The Mechanical Properties of Porous Concrete using Recycled Asphalt Aggregate (아스팔트순환골재를 이용한 투수성 콘크리트의 역학적 특성)

  • Lee, Dong-Wook;Yun, Jung-Mann;Kim, Nam-Sik;Kang, Young-Min
    • Journal of the Korean Geosynthetics Society
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    • v.10 no.1
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    • pp.37-42
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    • 2011
  • In this study, it is analyzed that mechanical properties and required strength of porous concrete according to the mixing ratio of cement, fine aggregate, and water/cement ratio in order to evaluate mechanical properties of porous concrete using recycled asphalt aggregate. Recycled asphalt aggregates of 13 mm were used without modification of aggregate grading to extend porous concrete application. The water/concrete ratio was poor mix and the range of compressive strength was 18.2 to 19.5 MPa. The average value of permeability showed 8.0E-02 cm/sec.

Plant Regeneration from Leaf Segment Culture of Chrysanthemum zawadskii ssp. coreanum (한라구절초 잎절편 배양에 의한 식물체 재분화)

  • 박영철;김성용;한태완
    • Korean Journal of Plant Resources
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    • v.17 no.1
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    • pp.43-47
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    • 2004
  • The effect of plant growth regulators and gelling agents for plant regeneration from leaf segment of Chrysanthemum zawadskii ssp. coreanum was investigated. NAA was more effective than BA for plant regeneration. MS medium supplemented with NAA 1 mg/L was the most effective in plant regeneration. The effect of agar and gelite as gelling agent was compared. Agar(0.8%) was more effective than gelite(0.2%) in plant regeneration. Regenerated shoots was successfully increased by shoot grafting in MS medium supplemented with NAA 0.1 mg/L in vitro, and hardened by shoot grafting in artificial soil mix(Peatmoss : Perlite = 1 : 1).

Computer-aided approach of parameters influencing concrete service life and field validation

  • Papadakis, V.G.;Efstathiou, M.P.;Apostolopoulos, C.A.
    • Computers and Concrete
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    • v.4 no.1
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    • pp.1-18
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    • 2007
  • Over the past decades, an enormous amount of effort has been expended in laboratory and field studies on concrete durability estimation. The results of this research are still either widely scattered in the journal literature or mentioned briefly in the standard textbooks. Moreover, the theoretical approaches of deterioration mechanisms with a predictive character are limited to some complicated mathematical models not widespread in practice. A significant step forward could be the development of appropriate software for computer-based estimation of concrete service life, including reliable mathematical models and adequate experimental data. In the present work, the basis for the development of a computer estimation of the concrete service life is presented. After the definition of concrete mix design and structure characteristics, as well as the consideration regarding the environmental conditions where the structure will be found, the concrete service life can be reliably predicted using fundamental mathematical models that simulate the deterioration mechanisms. The prediction is focused on the basic deterioration phenomena of reinforced concrete, such as carbonation and chloride penetration, that initiate the reinforcing bars corrosion. Aspects on concrete strength and the production cost are also considered. Field observations and data collection from existing structures are compared with predictions of service life using the above model. A first attempt to develop a database of service lives of different types of reinforced concrete structure exposed to varying environments is finally included.

Prediction of Adiabatic Temperature in Concrete as Semiadiabatic Temperature (간이단열온도로서 콘크리트의 단열온도 추정을 위한 연구)

  • Moon, Han-Young;Moon, Dae-Joong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.5 no.4
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    • pp.121-129
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    • 2001
  • The semi-adiabatic temperature rise and the losses of temperature of cement paste, mortar and concrete were measured by an apparatus of semi-adiabatic temperature. Heat of hydration was measured by a conduction calorimeter and adiabatic temperature rise of concrete was measured by an adiabatic calorimeter. The derived equation which can assume the adiabatic temperature was proposed by measuring the semi-adiabatic temperature of concrete. The maximum adiabatic temperature rise of concrete obtained by the derived equation of adiabatic temperature, $T_{ad}(t)=T_{sad}(t)+T_{dis}(t)$, showed $55^{\circ}C$ approximately and it had good relation with the other one obtained by the heat of hydration of cement paste and with maximum value which was measured by the adiabatic calorimeter. The adiabatic temperature rise obtained by derived equation was a different information in comparison with the value obtained by adiabatic temperature rise equations by Hell and et. al. in early age, but it showed similar tendencies with the other one according to elapsed time. Adiabatic temperature rise of lich mix concrete with highly cement content was predicted. The adiabatic temperature rise of cement paste and mortar obtained by derived equation from us showed comparatively matching results to compared with that of obtained by adiabatic temperature equation from concrete standard specification.

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Optimization of Flowable Fill with High Volume Fly Ash Conten (다량의 플라이애시를 사용한 고유동 충전재의 최적배합설계)

  • 원종필
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.3
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    • pp.81-90
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    • 1999
  • The purpose of this study is to examine the uses of fly ash asa type of construction material. This paper presents the results of research performed to identify optimum mix proportions for production of lowable fill with high volume fly ash content . The fly ash used in this study met the requirements of KS L 5405 and ASTM C 618 for Class F material. The flowable fill with high volume fly ash content was investigated for strength and flowability characteristics. Tests were carried out on flowable fill designed to have 10 ~15kgf/$\textrm{cm}^2$ compressive strength at 28 days with fly ash contents of approximately 260kgf/㎥. Slump was held at 25$\pm$1cm for all mixtures produced to range from 5kgf/$\textrm{cm}^2$ to 14kgf/$\textrm{cm}^2$ compressive strengths at 28 days. To produce flowable fill with high volume fly ash , first the influential variables were identified in an experimental study based on factorial design. Among the proportioning variables investigated, cement ,fly ash, and sand contents were found to have statistically significant effect on strength and slump of flowable fill . Subsequently, response surface analysis techniques were used to devise an experimental program that helped determine the optimum combinations of the selected influential variables based on material properties and cost. The optimized flowable fill were then technically evaluated. It is shown that flowable fill has acceptable compressive strength , slump flow, hardening time, and permeability.

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High density plasma etching of CoFeB and IrMn magnetic films with Ti hard mask

  • Xiao, Y.B.;Kim, E.H.;Kong, S.M.;Chung, C.W.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.233-233
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    • 2010
  • Magnetic random access memory (MRAM), based on magnetic tunnel junction (MTJ) and CMOS, is a prominent candidate among prospective semiconductor memories because it can provide nonvolatility, fast access time, unlimited read/write endurance, low operating voltage and high storage density. The etching of MTJ stack with good properties is one of a key process for the realization of high density MRAM. In order to achieve high quality MTJ stack, the use of CoFeB and IrMn magnetic films as free layers was proposed. In this study, inductively coupled plasma reactive ion etching of CoFeB and IrMn thin films masked with Ti hard mask was investigated in a $Cl_2$/Ar gas mix. The etch rate of CoFeB and IrMn films were examined on varying $Cl_2$ gas concentration. As the $Cl_2$ gas increased, the etch rate monotonously decreased. The effective of etch parameters including coil rf power, dc-bais voltage, and gas pressure on the etch profile of CoFeB and IrMn thin film was explored, At high coil rf power, high dc-bais voltage, low gas pressure, the etching of CoFeB and IrMn displayed better etch profiles. Finally, the clean and vertical etch sidewall of CoFeB and IrMn free layers can be achieved by means of thin Ti hard mask in a $Cl_2$/Ar plasma at the optimized condition.

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