• Steel and Composite Structures
• /
• 제27권4호
• /
• pp.509-523
• /
• 2018

This paper presents experimental results on the residual bond-slip behavior of high strength concrete-filled square steel tube (HSCFST) after elevated temperatures. Three parameters were considered in this test: (a) temperature (i.e., $20^{\circ}C$, $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$); (b) concrete strength (i.e., C60, C70, C80); (c) anchorage length (i.e., 250 mm, 400 mm). A total of 17 HSCFST specimens were designed for push-out test after elevated temperatures. The load-slip curves at the loading end and free end were obtained, in addition, the distribution of steel tube strain and the bond stress along the anchorage length were analyzed. Test results show that the shape of load-slip curves at loading ends and free ends are similar. With the temperature constantly increasing, the bond strength of HSCFST increases first and then decreases; furthermore, the bond strength of HSCFCT proportionally increases with the anchoring length growing. Additionally, the higher the temperature is, the smaller and lower the bond damage develops. The energy dissipation capacity enhances with the concrete strength rasing, while, decreases with the temperature growing. What is more, the strain and stress of steel tubes are exponentially distributed, and decrease from the free end to loading end. According to experimental findings, constitutive formula of the bond slip of HSCFST experienced elevated temperatures is proposed, which fills well with test data.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
• /
• pp.170-171
• /
• 2006

The chemical shift of SiOC film was observed according to the flow rate ratio. SiOC film has the broad main band of $880{\sim}1190cm^{-1}$ and the sharp Si-$CH_3$ bond at $1252cm^{-1}$, and the infrared spectra in the Si-O-C bond moved to low frequency according to the increasing of an oxygen flow rate. The chemical shift affected the carbon content in the SiOC film, and the decreasing of carbon atoms elongated the C-H bonding length, relatively. The main bond without the sharp Si-$CH_3$ bond at $1252cm^{-1}$ consisted of Si-C, C-O and Si-O bonds, and became the bonding structure of the Si-O-C bond.

• Advances in concrete construction
• /
• 제10권2호
• /
• pp.113-125
• /
• 2020

This paper presents experimental results on bond-slip behavior of steel reinforced high-strength concrete (SRHC) after exposure to elevated temperatures. Three parameters were considered in this test: (a) high temperatures (i.e., 20℃, 200℃, 400℃, 600℃, 800℃); (b) concrete strength (i.e., C60, C70, C80); (c) anchorage length (i.e., 250 mm, 400 mm). A total of 17 SRHC specimens subjected to high temperatures were designed for push out test. The load-slip curves at the loading end and free end were obtained, the influence of various variation parameters on the ultimate bond strength and residual bond strength was analyzed, in addition, the influence of elevated temperatures on the invalidation mechanism was researched in details. Test results show that the shapes of load-slip curves at loading ends and free ends are similar. The ultimate bond strength and residual bond strength of SRHC decrease first and then recover partly with the temperature increasing. The bond strength is proportional to the concrete strength, and the bond strength is proportional to the anchoring length when the temperature is low, while the opposite situation occurs when the temperature is high. What's more, the bond damage of specimens with lower temperature develops earlier and faster than the specimens with higher temperature. From these experimental findings, the bond-slip constitutive formula of SRHC subjected to elevated temperatures is proposed, which fills well with test data.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2010년도 제39회 하계학술대회 초록집
• /
• pp.56-56
• /
• 2010

Using first-principles density-functional theory calculations, we find dramatically different electronic states in the C chains generated on the H-terminated C(111) surface, depending on their length and parity. The infinitely long chain has $\pi$ electrons completely delocalized over the chain, yielding an equal C-C bond length. As the chain length becomes finite, such delocalized $\pi$ electrons are transformed into localized ones. As a result, even-numbered chains exhibit a strong charge-lattice coupling, leading to a bond-alternated structure, while odd-numbered chains show a ferrimagnetic spin ordering with a solitonlike structure. These geometric and electronic features of infinitely and finitely long chains are analogous to those of the closed (benzene) and open (polyacetylene) chains of hydrocarbons, respectively.

• 자연과학논문집
• /
• 제15권1호
• /
• pp.47-56
• /
• 2005

The substituent dependence of geometric distortion through the two independent electronic substituent effects is analyzed for mono-substituted benzene derivatives of $C_{2v}$. Based on resonance structures, quantitative relationships expressing the resonance and field/inductive contribution terms in bond distortions are derived. The calculated field-effect parts of $C_{ipso}$_$C_{ortho}$ ring bonds increase and decrease compared to benzene for electropositive and electronegative substituents respectively. The nonbonded axial distance, $C_{ipso}$....$C_{para'}$ decreases for electronegative substituents and increases for electropositive substituents. As the electronegativity increases, the distance $C_{ortho}$....$C_{ortho'}$ increases. With the $\pi$-donors, $C_{meta}$....$C_{meta'}$ nonbonded distances are shorter compared to the ones of benzene, and for $\pi$-acceptors, the are longer. Our model based on valence bond approach predicts that the average bond length determined the area of ring, and the sum of the angles <$C_{ortho}$_$C_{ispo}$_$C_{ortho}$ and <$C_{meta}$_$C_{para}$_$C_{meta}$ determines the axial distance.

• Bulletin of the Korean Chemical Society
• /
• 제26권11호
• /
• pp.1711-1716
• /
• 2005

Fragmentations and ion-molecule reactions of ionized cyclohexane propionic acid and cyclohexane butyric acid were studied using FTMS and theoretical calculations. The difference in bond dissociation depending on the aliphatic chain length was investigated and mechanisms for the possible rearrangements depending on the aliphatic carbon length were suggested. The most abundant fragment ion of the ionized cyclohexane propionic acid was c-$C_6H_{11}CH_2\;^+$ formed from the molecular ion by the direct C-C bond cleavage, while that of the ionized cyclohexane butyric acid was c-$C_6H_9C(OH)=OH^+$ formed by rearrangement of the molecular ion from the acid to diol form and loss of propyl radical. Stabilities of the radical and distonic ions of $C_nH_{2n}O^{+\bullet}$ formed from the molecular ion were compared. Protonated molecules were dissociated into smaller ions by losing one or two water molecules. The $[nM + H]^+$, $[nM + H - H_2O]^+$, and $[nM + H - 2H_2O]^+$ with n = 2 and 3 were generated by solvation with the neutral molecules in the ICR cell at long ion trapping time.

• 콘크리트학회지
• /
• 제11권2호
• /
• pp.77-84
• /
• 1999

최근들어 그 필요성이 증대되고 있는 경량 콘크리트의 경우, 부착강도의 저하를 고려하여 ACI 규준에서는 부착길이 보정계수를 도입하여 안전율을 높이고 있으나, 경량 콘크리트가 고강도화됨에 따라 어느 정도 부착강도의 증징이 있을 것으로 판단된다. 따라서 ACI 규준에서 정하고 있는 경량 콘크리트에 대한 부착길이 보정계수 ${\lambda}$=1.3을 고강도 경량 콘크리트에 적용할 경우 그 적정성 여부에 대한 검토가 필요하다. 본 연구에서는 고강도 경량 콘크리트의 부착특성을 알아보기 위하여 콘크리트 압축강도, 피복두께, 철근직경, 부착길이 등을 변수로 하여 Pull-out 실험을 실시하였다. 실험결과 부착응력은 콘크리트 압축강도 제곱근과 피복두께가 증가함에 따라 증가하였고, 철근직경과 부칙길이가 증가함에 따라 감소하였으며, 파괴양상은 피복두께에 따라 쪼개짐 파괴와 뽑힘 파괴를 나타내었다. 고강도 경량 콘크리트의 부착응력을 보통중량 콘크리트보다는 큰 값을 나타낸다. 따라서 ACI 규준에서 정하고 있는 경량 콘크리트 부착길이 보정계수를 고강도 경량 콘크리트에 적용할 경우 경량 콘크리트의 고강도화에 따른 부착응력 상승효과를 고려하여 하향조정하여야 할 것으로 판단된다. 또한 피복두께 2.5$d_b$ 이상일 경우 적용하는 피복두께 보정계수 0.8은 고강도 경량 콘크리트에도 그대로 적용할 수 있음을 알 수 있다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
• /
• pp.873-878
• /
• 2000

Tension stiffening effects of reinforced concrete member with large diameter bar, mainly used at reactor building of nuclear power plant, are studied by uniaxial structural tests. Bond length and stress of steel bar, size of steel bar, and compressive strength of concrete are evaluated to tension stiffening by uniaxial tests. Problems and solution during the uniaxial test are suggested. The prevent splitting cracks, concrete cover-to-bar diameter ratio $c/d_{b}$ is kept 2.6~2.8. Because the bond length is increased as the size of steel bar, the specimen length of the D35 steel bar is required at least 2.0 m. The specimen length must be decided with bond length as well as concrete cover-to-bar diameter ratio to prevent splitting crack.

• Bulletin of the Korean Chemical Society
• /
• 제32권1호
• /
• pp.277-280
• /
• 2011

We studied the relative stability and atomic structure of five $C_{20}^{2+}$ isomers obtained by two-electron ionization of a $C_{20}$ cage (the smallest fullerene). All the isomers are bond-stretch isomers, i.e., they differ in bond length. In particular, in one of the isomers with Ih symmetry, all the bond lengths are equal. Full geometry optimizations of the dipositive ion $C_{20}^{2+}$ were performed using the hybrid density functional (B3LYP/6-31G(d)) methods. All isomers were found to be true minima by frequency analysis at the level of B3LYP/6-31G(d) under the reinforced tight convergence criterion and a pruned (99,590) grid. The zero-point correction energy for the cage bond-stretch isomers was in the increasing order $D_{2h}<C_{2h}<C_2<T_h<I_h$ of $C_{20}^{2+}$. The energy difference among the isomers of cage dipositive ions was less than that among neutral cage isomers. Our results suggest that these isomers show bond-stretch isomerism and that they have an identical spin state and an identical potential energy curve. Although the predominant electronic configurations of the isomers are similar, the frontier orbital characteristics are different, implying that we could anticipate an entirely different set of characteristic chemical reactions for each type of HOMO and LUMO.

• Bulletin of the Korean Chemical Society
• /
• 제12권2호
• /
• pp.182-188
• /
• 1991

The reactions of aniline with benzyl and phenacyl compounds are studied by the AM1 method. Two types of modeling were adopted: Cation-neutral, in which a proton is attached to the leaving group F and anion-neutral model, in which aniline was replaced by phenoxide with Cl as the leaving group. The cation-neutral model represented the reactvery well, reproducing the various solution-phase experimental results. In the benzyl system, the ${\pi}$-electrons of the two rings (X-ring in the nucleophile and Y-ring in the substrate) interact conjugatively in the transition state (TS) resulting in a bond contraction of the $C_{\alpha}-C_{Y1}$ bond (benzylic effect), whereas in the phenacyl system the ${\pi}$ electrons of the X-ring delocalizes more efficiently into the carbonyl group than into the Y-ring (resonance shunt effect) with a bond contraction of the $C_{\alpha}-C_{\beta}$ bond. The bond contraction in the benzylic effect was substantially greater than that in the resonance shunt effect. The TS was rather loose for benzyl while it was tighter for phenacyl system. Various bond length changes with substituents in the TS were, however, found to be irregular.