• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.493-500
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• 2003

The effect of reductive treatment with elemental iron on the extent of mineralization by Fenton oxidation was studied for the explosive 2,4,6-trinitrotoluene (TNT) and hexahydro-l,3,5-trinitro-l,3,5-triazine (RDX) using a completely-stirred tank reactor (CSTR). The results support the hypothesis that TNT and RDX are reduced with elemental iron to products that are oxidized more rapidly and completely by Fenton's reagent. Iron pretreatment enhanced the extent of TOC removal by approximately $20\%\;and\;60\%$ for TNT and RDX, respectively. Complete TOC removal was achieved for TNT and RDX solutions with iron pretreatment under optimal conditions. On the other hand, without iron pretreatment, complete mineralization of TNT and RDX solutions were not achieved even with much higher $H_2O_2$ and $Fe^{2+}$ concentrations. The bench-scale iron treatment-Fenton oxidation integrated system showed more than $95\%$ TOC removal for TNT and RDX solutions under optimal conditions. The proposed zero-valent iron-Fenton process was evaluated with pink water from the Iowa Army ammunition plant. Results from batch and column experiments show that TNT, RDX, and octahydro-l,3,5,7-tetranitro-l,3,5,7-tetrazocine (HMX) were completely removed from the pink water and that triaminotoluene (TAT) and ${NH_4}^+$ were recovered as products in reduction with zero-valent iron. By using an integrated system, $83.3\pm4.2\%$ of TOC was removed in a CSTR with 10 mM of $Fe^{2+}$ and 50 mM of $H_2O_2$. These results suggest that the reduction products of TNT and RDX are more rapidly and completely mineralized by Fenton oxidation and that a sequential iron treatment-Fenton oxidation process may be a viable technology for pink water treatment.

• Journal of the Microelectronics and Packaging Society
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• v.25 no.4
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• pp.149-154
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• 2018

This paper describes the fabrication and heat transfer property of 50 watts rated LED array module where multiple chips are mounted on chip-on-board type ceramic-metal hybrid substrate with high heat dissipation property for high power street and anti-explosive lighting system. The high heat transfer ceramic-metal hybrid substrate was fabricated by conformal coating of thick film glass-ceramic and silver pastes to form insulation and conductor layers, using thick film screen printing method on top of the high thermal conductivity aluminum alloy heat-spreading panel, then co-fired at $515^{\circ}C$. A comparative LED array module with the same configuration using epoxy resin based FR-4 PCB with thermalvia type was also fabricated, then the thermal properties were measured with multichannel temperature sensors and thermal resistance measuring system. As a result, the thermal resistance of the ceramic-metal hybrid substrate in the $4{\times}9$ type LEDs array module exhibited about one third to the value as that of FR-4 substrate, implying that at least triple performance of heat transfer property as that of FR-4 substrate was realized.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.1
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• pp.1-10
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• 2005

The purpose of this study was to evaluate the potential of a gamma irradiation to decompose 2,4,6-trinitrotoluene(TNT) in an aqueous solution. The decomposition reaction of TNT by gamma irradiation was a pseudo first-order kinetic over the applied initial concentrations($25{\sim}100mg/L$). The dose constant was strongly dependent on the initial TNT concentration. The removal of TNT was more efficient at pH below 3 and at pH above 11 than at neutral pH(pH 5-9). The required irradiation dose to remove over 99% of TNT was 40, 80 and 10 kGy, individually at pH 2, 7 and 13. The dose constant was increased by 1.6 fold and over 15.6 fold at pH 2 and 13, respectively, when compared with that at pH 7 When irradiation dose of 200 kGy was applied, the removal efficiencies of TOC were 91, 46 and 53% at pH 2, 7 and 13, respectively. Ammonia and nitrate were detected as the main nitrogen byproducts of TNT and glyoxalic acid and oxalic acid were detected as organic byproducts. The results showed that a gamma irradiation was an attractive method for the decomposition of TNT in an aqueous solution. However, regarding the application of high energy radiation for the TNT decomposition and mineralization, an application of an acidic pH below 3 to the solution before irradiation should be considered.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.65-65
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• 2012

Copper zinc tin sulfide ($Cu_2ZnSnS_4$, CZTS) is a very promising material as a low cost absorber alternative to other chalcopyrite-type semiconductors based on Ga or In because of the abundant and economical elements. In addition, CZTS has a band-gap energy of 1.4~1.5eV and large absorption coefficient over ${\sim}10^4cm^{-1}$, which is similar to those of $Cu(In,Ga)Se_2$(CIGS) regarded as one of the most successful absorber materials for high efficient solar cell. Most previous works on the fabrication of CZTS thin films were based on the vacuum deposition such as thermal evaporation and RF magnetron sputtering. Although the vacuum deposition has been widely adopted, it is quite expensive and complicated. In this regard, the solution processes such as sol-gel method, nanocrystal dispersion and hybrid slurry method have been developed for easy and cost-effective fabrication of CZTS film. Among these methods, the hybrid slurry method is favorable to make high crystalline and dense absorber layer. However, this method has the demerit using the toxic and explosive hydrazine solvent, which has severe limitation for common use. With these considerations, it is highly desirable to develop a robust, easily scalable and relatively safe solution-based process for the fabrication of a high quality CZTS absorber layer. Here, we demonstrate the fabrication of a high quality CZTS absorber layer with a thickness of 1.5~2.0 ${\mu}m$ and micrometer-scaled grains using two different non-vacuum approaches. The first solution-processing approach includes air-stable non-toxic solvent-based inks in which the commercially available precursor nanoparticles are dispersed in ethanol. Our readily achievable air-stable precursor ink, without the involvement of complex particle synthesis, high toxic solvents, or organic additives, facilitates a convenient method to fabricate a high quality CZTS absorber layer with uniform surface composition and across the film depth when annealed at $530^{\circ}C$. The conversion efficiency and fill factor for the non-toxic ink based solar cells are 5.14% and 52.8%, respectively. The other method is based on the nanocrystal dispersions that are a key ingredient in the deposition of thermally annealed absorber layers. We report a facile synthetic method to produce phase-pure CZTS nanocrystals capped with less toxic and more easily removable ligands. The resulting CZTS nanoparticle dispersion enables us to fabricate uniform, crack-free absorber layer onto Mo-coated soda-lime glass at $500^{\circ}C$, which exhibits a robust and reproducible photovoltaic response. Our simple and less-toxic approach for the fabrication of CZTS layer, reported here, will be the first step in realizing the low-cost solution-processed CZTS solar cell with high efficiency.

• Bulletin of the Korean Chemical Society
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• v.29 no.6
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• pp.1157-1161
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• 2008

2,6-Dinitrophenol (2,6-DNP) complexes with lanthanide series including yttrium (except Pm, Tm, and Lu) have been synthesized and their crystal structures have been analyzed by X-ray diffraction methods. Singlecrystal X-ray structure determinations have been performed at 296 K on the Ce$\rightarrow$Yb species and shown them to be isomorphous, triclinic, P1, a = 8.6558(2)$\rightarrow$8.5605(3) $\AA$, b = 11.8813(3)$\rightarrow$11.6611(4) $\AA$, c = 13.9650(3) $\rightarrow$13.8341(5) $\AA$, $\alpha$ = 73.785(1)$\rightarrow$73.531(2)o, $\beta$ = 74.730(1)→74.903(2)${^{\circ}}$, $\gamma$ = 69.124(1)→ 69.670 $(2){^{\circ}}$, V = 1266.86(5)→1221.53(7) $$\AA^{3}$$, Z = 2. In Ln(III) complexes, three 2,6-DNP ligands coordinate directly to the metal ion in the bidentate fashion. The nine coordinated Ln(III) ion forms slightly distorted tri-capped trigonal prism. There are no water molecules in the crystal lattice. The dependences of metal to ligand bond lengths are discussed on the atomic number of lanthanide elements. The thermal properties of lanthanide complexes of 2,6- DNP have also studied by TG-DTG and DSC thermal analysis methods.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.30 no.10C
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• pp.965-975
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• 2005

In this paper, we propose and evaluate joint carrier and sampling frequency offset estimation schemes based on the channel estimation sequences in PLCP (Physical Layer Convergence Procedure) preamble for the proper and effcient synchronization of the MB-OFDM WB (Multi-Band Orthogonal Frequency Division Multiplexing Ultra Wide Band) systems which have recently drawn explosive attention for future W-PAN (Wireless Personal Area Network) applications. In the joint estimation schemes, we first estimate the sampling frequency offset, and then estimate the carrier frequency offset using the estimated sampling frequency offset. Moreover, to improve the reliability of the estimated offset values, each process uses a combination scheme based on weighting factors. Simulation results using IEEE 802.15 Task Group 3a UWB channel models reveal that the estimation scheme using the simple weighting factors based on easily-measurable received signal power of each sub-channel shows favorably comparable performance to the ideal scheme using the weighting factors based on the perfectly-estimated frequency response of the channel.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.5C
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• pp.185-192
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• 2012

The objective of this study is to present and verify a method for evaluating the fundamental period of a rockfill dam using artificially generated vibration from a blasting event. In this study, the artificial blasting vibration tests were carried out at the site adjacent to the existing Seongdeok Dam for the first time in Korea. The artificial vibrations were induced by 4 different types of blasting with the various depths of blasting boreholes and the various explosive charge weight. During the tests, the accelerations time histories were recorded at the crest of the dam. In this acceleration history, only free vibration decay part following the main vibration event was extracted and it was analyzed by frequency domain analysis using Fast Fourier Transform (FFT). From the results of FFT, the fundamental period of the target dam was evaluated. It is found that the effect of different blasting types on the fundamental period of the target dam is negligible and the fundamental period of the target dam can be consistently obtained by blasting vibration tests. Furthermore, it is found that the period of the target dam calculated by the method using blasting vibration test is similar to that obtained by the method of previous researchers using the real earthquake records. Therefore, in case that the earthquake record is not available, the fundamental period of a rockfill dam can be reasonably evaluated if blasting vibration test is allowed at the site adjacent to the dam.

• Weed & Turfgrass Science
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• v.4 no.1
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• pp.1-9
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• 2015

Many irrigated and drainage canals, reservoirs, lakes, and rivers are choked by the explosive growth of aquatic weeds, resulting in enormous direct loss in Korea. Distribution of aquatic weeds and exotic invasive plant species in irrigation and drainage waterways, and riparian wetlands was reviewed to provide basic information for management of aquatic weeds and invasive plant species in wetlands. Dominant emergent weeds in canals, reservoirs and lakes were Phragmites communis, Leersia japonica, Zizania latifolia, Conyza canadensis, C. annuus, Rumex crispus, Panicum dichotomiflorum, Bidens frondosa, and Oenothera odorata. Dominant emergent weeds in wetlands of rivers include Digitaria sanguinalis, P. communis, R. crispus, Artemisia princeps, Humulus japonicus, Echinochloa crusgalli, B. frondosa, and Persicaria thunbergii. In irrigation and drainage canals and lakes, dominant submersed weeds were Hydrilla verticillata, Najas minor, Potamogeton malaianus, P. crispus, Ceratophyllum demersum, Myriophyllum verticillatum, Salvinia natans, and Trapa natans. Dominant exotic weeds in wetlands include Trifolium repens, O. odorata, C. annuus, B. frondosa, Avena fatua, Ambrosia artemisiifolia, X. strumarium, and P. dichotomiflorum. Approaches to aquatic weed control were mechanical, chemical and biological control techniques. Periodic monitoring of aquatic weeds and exotic weeds, and their integrated management studies are needed in waterways and riparian wetlands in Korea.

• Korean Journal of Environment and Ecology
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• v.30 no.3
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• pp.344-352
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• 2016

The goal of this study was to identify the water temperature and sound environment of oviposition sites of the Huanren brown frog (Rana huanrensis), which breeds in valleys in early spring. The study was conducted in Chiak National Park, central Korea, between March 23 and April 24, 2015. Correlation analysis of the physical factors of oviposition sites revealed that the number of egg clutches was positively correlated (p < 0.05) with the water temperature and negatively correlated (p < 0.05) with the sound volume of the oviposition sites. However, no correlation was found between clutch number and the total area or depth of water. The water temperature of the oviposition sites was $2.2^{\circ}C$ higher on average than that of the mainstream (p < 0.001). To avoid the low early spring temperatures, R. huanrensis spawned in sites with accumulated water, in which the depths were less than 10cm and the temperature was relatively high. Further, eggs were spawned in clusters in small spaces to maximize the thermal insulation effect. In terms of noise levels, oviposition sites were found to be 6.9 dB quieter than the mainstream (p<0.001). In conclusion, R. huanrensis was found to spawn in warm, quiet, and small oviposition sites in valleys to avoid low early spring temperatures and loud water noise. This study is significant because it is the first to characterize the sound environment of amphibian oviposition sites.

• Korean Journal of Soil Science and Fertilizer
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• v.11 no.2
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• pp.61-66
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• 1979

This experiment was conducted to find out the simple and economical method to improve physical properties of the soil that was very poor for the establishment of orchard. Jeonnam clay loam soils distributed mainly on rolling and hill side slope, were treated with the explosion of two kinds of dynamite at the depth of 1 m. The change of physical properties was investigated vertically and horizontally after soil profile had settled to some extent. The results were summarized as : 1. The original soil was very high in bulk density and soil hardness. Total porosity and aeration porosities were lower than critical level providing root elongation. It was more apparent in the subsoil than in the surface soil. 2. It was recognized that soil mass destruction and cracking by dynamite explosion decreased soil bulk density and soil hardness and increased porosity, especially non-capillary pores. 3. Effective radius of the improved physical properties by explosion with two dynamites was 100cm at 60cm depth and 30cm at 80cm depth. But with the use of three dynamites it was 100cm at 80cm depth. 4. It was thought that soil mass destruction and cracking caused by explosion was uneven in the two dynamites, and three dynamites was more effective to improve physical properties evenly. 5. With the use of two dynamites, Ammonium explosive was superior to gelatin dynamite.