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Thermal and Mechanical Properties of ZrB2-SiC Ceramics Fabricated by Hot Pressing with Change in Ratio of Submicron to Nano Size of SiC (서브마이크론/나노 크기의 SiC 비율변화에 따른 ZrB2-SiC 세라믹스의 열적, 기계적 특성)

  • Kim, Seongwon;Chae, Jung-Min;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.410-415
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    • 2013
  • $ZrB_2$-SiC ceramics are fabricated via hot pressing with different ratios of submicron or nano-sized SiC in a $ZrB_2$-20 vol%SiC system, in order to examine the effect of the SiC size ratio on the microstructures and physical properties, such as thermal conductivity, hardness, and flexural strength, of $ZrB_2$-SiC ceramics. Five different $ZrB_2$-SiC ceramics ($ZrB_2$-20 vol%[(1-x)SiC + xnanoSiC] where x = 0.0, 0.2, 0.5, 0.8, 1.0) are prepared in this study. The mean SiC particle sizes in the sintered bodies are highly dependent on the ratio of nano-sized SiC. The thermal conductivities of the $ZrB_2$-SiC ceramics increase with the ratio of nano-sized SiC, which is consistent with the percolation behavior. In addition, the $ZrB_2$-SiC ceramics with smaller mean SiC particle sizes exhibit enhanced mechanical properties, such as hardness and flexural strength, which can be explained using the Hall-Petch relation.

Relationship between the Serum De Ritis Ratio and Diabetes Tests in Korean Adults Who Underwent Health Screening at a General Hospital in Gyeonggi-do (경기도 일개 종합병원에서 건강검진을 받은 한국 성인의 혈청 De Ritis 비율과 당뇨 검사와의 관계)

  • Hyun Ho SUNG;Ho-Keun CHOI
    • Korean Journal of Clinical Laboratory Science
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    • v.55 no.1
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    • pp.9-15
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    • 2023
  • The purpose of this study was to analyze the relationship between diabetes and liver function test results. Unlike type 2 diabetes mellitus (T2DM), hepatogenous diabetes is caused by abnormal liver function. In this study, the relationship between liver enzymes, aspartate aminotransferase (AST), alanine transaminase (ALT), and the AST/ALT ratio (De Ritis ratio), indicating liver function, and diabetes-related tests was analyzed. The results of the study showed a positive correlation between AST and glucose (r=0.14, P<0.01), ALT and glucose (r=0.21, P<0.01), AST and glycated hemoglobin (HbA1c) (r=0.15, P<0.01), and ALT and HbA1c (r=0.20, P<0.01). The De Ritis ratio showed a negative correlation with glucose (r=-0.20, P<0.01) and HbA1c (r=-0.14, P<0.01). The results of regression analysis with AST, ALT, and the De Ritis ratio as independent variables and glucose (R2=0.05) and HbA1c (R2=0.04) as dependent variables revealed that the independent variables had a statistically significant effect on the dependent variables. AST showed a lower correlation between blood glucose and glycated hemoglobin than ALT, and an increase in ALT caused a decrease in the De Ritis ratio. Therefore, the De Ritis ratio can be said to be meaningful in relation to diabetes-related tests.

A Study on the Chemically Vapor Deposited TiC, TiN, and TiC(C, N) on $Si_3N_4$-TiC Ceramic Tools. ($Si_3N_4-TiC$ Ceramic 공구에 화학증착된 TiC, TiN 및 Ti(C, N)에 관한 연구)

  • 김동원;김시범;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.36-43
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    • 1988
  • Titanium carbide(TiC) and titanium nitride(TiN) flims were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$ and $TiCl_4-H_2-N_2$ gas mixtures, respectively. The nonmetal to metal ratio of deposit increases with increasing $m_{C/Ti}$(mole ratio of CH$_4$ to TiCl$_4$ in the input) for TiC coatings and $m_{N/Ti}$(mole ratio of N$_2$ to TiCl$_4$ in the input) for TiN coatings. The nearly stoiahiometric films could be obtained under the deposition condition of $m_{C/Ti}$ between 1.15 and 1.61 for TiC, and that of $m_{N/Ti}$ between 25 and 28 for TiN. Also maximum microhardness of the coatings can be obtained in these ranges. The interfacial region of TiC coatings on $Si_3N_4$-TiC ceramics is wider than that of TiN coatings according to Auger depth profile analysis, which indicates good interfacial bonding for TiC. Experimental results show that TiC coatings have an randomly equiaxed structure and Columnar structure with(220) preferred orientation can be obtained for TiN coatings. And, multilayer coatings have a dense and equiaxed structure.

The Prediction of Blending Ratio of Cut Tobacco, Expanded Stem, and Expanded Cut Tobacco in Cigarettes using Near Infrared Spectroscopy (근적외분광법을 이용한 권련 중 일반각초, 팽화주맥 및 팽화각초 배합비 분석)

  • 김용옥;정한주;김기환
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.1
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    • pp.76-83
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    • 2000
  • This study was carried out to predict blending ratio of cut tobacco(CT), expanded stem(ES), and expanded cut tobacco(ECT) in cigarettes. CT, ES, and ECT samples from A brand were, ground and blended with reference to A blending ratio, and scanned by near infrared spectroscopy(NIRSystem Co., Model 6500). Calibration equations were developed and then determined blending ratio by NIRS. The standard error of calibration(SEC) and performance(SEP) of C factory samples between NIRS and known blending ratio were 0.97%, 1.93% for CT, 0.50%, 1.12 % for ES and 0.68%, 1.10% for ECT, respectively. The SEP of CT, ES and ECT of Band D factory samples determined by C factory calibration equation were more inaccurate than those of C factory samples determined by C factory calibration equations. These results were caused by the difference of CT, ES and ECT spectra followed by each factory. The SEP of CT, ES and ECT of Band D factories determined by calibration equations derived from each factory samples were more accurate than those of determined by calibration equation derived from C factory samples. Each factory SEP of CT, ES and ECT determined by calibration equation derived from all calibration samples(B+C+D factory) was similar to that determined by calibration equation derived from each factory samples. To improve the analytical inaccuracy caused by spectra difference, we need to apply a specific calibration equation for each factory sample. Data in development of specific calibrations between sample and NIRS spectra might supply a method for rapid determination of blending ratio of CT, ES, and ECT.

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Study on axial compressive behavior of quadruple C-channel built-up cold-formed steel columns

  • Nie, Shaofeng;Zhou, Tianhua;Liao, Fangfang;Yang, Donghua
    • Structural Engineering and Mechanics
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    • v.70 no.4
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    • pp.499-511
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    • 2019
  • In this study, the axial compressive behavior of novel quadruple C-channel built-up cold-formed steel columns with different slenderness ratio was investigated, using the experimental and numerical analysis. The axial compressive capacity and failure modes of the columns were obtained and analyzed. The finite element models considering the geometry, material and contact nonlinearity were developed to simulate and analyze the structural behavior of the columns further. There was a great correlation between the numerical analyses and test results, which indicated that the finite element model was reasonable and accurate. Then influence of, slenderness ratio, flange width-to-thickness ratio and screw spacing on the mechanical behavior of the columns were studied, respectively. The tests and numerical results show that due to small slenderness ratio, the failure modes of the specimens are generally local buckling and distortional buckling. The axial compressive strength and stiffness of the quadruple C-channel built-up cold-formed steel columns decrease with the increase of maximum slenderness ratio. When the screw spacing is ranging from 150mm to 450mm, the axial compressive strength and stiffness of the quadruple C-channel built-up cold-formed steel columns change little. The axial compressive capacity of quadruple C-channel built-up cold-formed steel columns increases with the decrease of flange width-thickness ratio. A modified effective length factor is proposed to quantify the axial compressive capacity of the quadruple C-channel built-up cold-formed steel columns with U-shaped track in the ends.

Dynamic Vibration Absorber Having Coil Springs and Oil Damper for a Damped Vibration System (감쇠진동계에 부착된 코일스프링과 오일댐퍼로 구성된 동흡진기)

  • Ahn, C.W.;Park, S.C.;Lee, H.B.
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.12
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    • pp.129-135
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    • 1996
  • This paper presents the effectiveness of the dynamic vibration absorber consisting of a single mass, coil springs and oil damper on the resonance freauency ratio and amplitude ratio for damped linear systems, that is, primary vibration system with damping. The effects of the dynamic vibration absorber are investigated numerically and experimentally for values of mass ratio, natural frequency ratio, and damping ratio. The experimental results show good agreement with calculated ones. As a result, the characteristics shown by the present work are useful in optimal tuning the dynamic vibration absorber in practice.

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Preparation of Zirconium Carbide Powders from $ZrCl_4$-Mg-C System ($ZrCl_4$-Mg-C 계 반응에 의한 탄화지르코늄(ZrC) 분체의 합성)

  • 김원영;김성현;장윤식;박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.28 no.4
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    • pp.315-323
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    • 1991
  • The preparation of zirconium carbide powders by the halogenide process of ZrCl4-C-Mg system (1:1:2, molar ratio) was studied between 300。 and 120$0^{\circ}C$ under Ar gas flow (200 mι/min). The formation mechanism and kinetics of zirconium carbide and characteristics of the synthesized powder were examined by TG-DTA, XRD, SEM and PSA. 1) The formation mechanism of zirconium carbide were as follows, above 30$0^{\circ}C$ ZrCl4(S)+Mg(s)longrightarrowZrCl2(s)+MgCl2(s) above 40$0^{\circ}C$ ZrCl2(S)+Mg(s)longrightarrowZr(s)+MgCl2(s) above 50$0^{\circ}C$ Zr(s)+C(s)longrightarrowZrC(s) 2) The apparent activation energy of the reduction-carbonization at temperature of 800$^{\circ}$to 100$0^{\circ}C$ was 11.9 kcal/mol. 3) The lattice parameter and the crystallite size of ZrC which was produced from the mixture powder of ZrCl4, C and Mg (1:1:2, molar ratio) at 100$0^{\circ}C$ for 1 h were 4.700A and 180A, respectively. 4) The powders obtained from the mixture powder of ZrCl4, C and Mg(1:1:2, molar ratio) at 100$0^{\circ}C$ for 1 h were agglomerate with the average size of about 13${\mu}{\textrm}{m}$ in SEM micrograph.

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Characterization of SiC-SiC Whisker Matrix Retaining Electrolyte in Phosphoric Acid Fuel Cell (인산형 연료전지용 SiC-SiC Whisker 전해질 매트릭스의 특성)

  • 윤기현;이현임;이근행;김창수
    • Journal of the Korean Ceramic Society
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    • v.29 no.8
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    • pp.587-592
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    • 1992
  • Sheets of SiC-SiC whisker maxed matrix were prepared from the mixed slurry of SiC whisker and SiC matrix by the rolling method. With the increase of SiC whisker, the pore size, the porosity and the phosphoric acid absorbency of the matrix were increased, while the bubble pressure was decreased. The activation energy for the transfer of H+ ion was decreased with the increase of mixing ratio of SiC whisker to the SiC matrix from the measurement of hydrogen ion conductivity. The activation energy was evaluated as 0.25 eV when the mixing ratio of SiC whisker to the SiC matrix was 1 : 2 and the activation energy was 0.16 eV for the 2 : 1 matrix. It means that SiC whisker matrix contributes to attain a better microstructure for the diffusion of hydrogen ion. From the measurement of single cell performance of matrix with various mixing ratio, it is concluded that if SiC-SiC whisker maxed matrix has a sufficient bubble pressure to prevent the crossover of H2 gas, the current density of a fuel cell is increased with the increase of acid absorbency of the matrix. Current density was improved from 140 mA/$\textrm{cm}^2$ for 0.25 mm thickness of matrix to 170 mA/$\textrm{cm}^2$ for the 0.20 mm one at 700 mV.

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Use of N-alkanes to Estimate Intake and Digestibility by Beef Steers

  • Premaratne, S.;Fontenot, J.P.;Shanklin, R.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.11
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    • pp.1564-1568
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    • 2005
  • The objective of the study was to evaluate the use of n-alkanes to estimate DM intake and digestibility by beef cattle. Six steers were blocked (3 blocks, 2 animals/block) according to the body weight (279${\pm}$19 kg) and randomly allotted within blocks to two diets (3 steers/diet). A second trial was conducted with the same animals (321${\pm}$18 kg) after 36 days (d), using a switch back design. The diets consisted of two types of chopped sun-cured hay, alfalfa (Medicago sativa L) hay, or fescue (Festuca arundinacea Schreb) and alfalfa mixture, which were fed in equal amounts to steers. Animals were dosed with $C_{32}$ and $C_{36}$ alkanes, employing an intra-ruminal controlled-release device at the beginning of each trial. Hay intake per animal was measured from d 6 to 12 and sub samples were taken for chemical analysis. Rectal samples of feces were taken from each animal once/daily from d 8 to 14, freeze dried, and ground prior to alkane analysis. Alkanes were extracted from ground hay and feces. Feed intake was calculated from the dose rate of $C_{32}$ alkane and, the herbage and fecal concentrations of adjacent odd ($C_{33}$ or $C_{31}$) and even ($C_{32}$) chain length alkanes. Crude Protein, NDF, ADF, ash concentrations and In vitro dry matter digestibility (IVDMD) were 17.7, 42.2, 28.4, 7.9 and 71.7 for alfalfa, and 12.4, 56.5, 30.4, 6.9 and 69.1% for fescue/alfalfa mixture, respectively. For both diets, intake estimated from $C_{33}$:$C_{32}$ ratio was not different from the measured intake, but intake estimated from $C_{31}$:$C_{32}$ ratio was lower (p<0.05), than the measured intake for both diets. The average estimated forage intake from $C_{33}$:$C_{32}$ ratio was 4.86 and 0.69% below than the measured intake for alfalfa and, fescue/alfalfa mixed diets, respectively. The respective estimates with $C_{31}$:$C_{32}$ ratio were 9.59 and 11.33% below than the measured intake. According to these results, alkane $C_{33}$:$C_{32}$ ratio is better than alkane $C_{31}$:$C_{32}$ ratio for the estimation of intake by beef steers.

Electrical Properties and Blend Effect of Blended Low-Density Polyethylene (브렌드 저밀도 폴리에틸렌의 전기적 특성 및 브렌드 효과)

  • Cho, Don-Chan;Moti, Tatsuo;Mizutani, Teruyoshi;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1617-1620
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    • 1999
  • In this work, the effect of blend on physical and electrical properties investigated. The two kinds of low-density polyethylene (LDPE) whose densities are evaluated at $0.9179[g/cm^3]$ and $0.9192[g/cm^3]$, respectively, were used and blended according to the different blend ratio. The LDPE with the blend ratio of 50[wt%] represented the lowest impulse breakdown strength, $F_{BImp}$ at $30[^{\circ}C]$, but the highest $F_{BImp}$ at $90[^{\circ}C]$. DC breakdown strength, $F_{BDC}$. decreased with the increase of blend ratio at $30[^{\circ}C$, but increased at $60[^{\circ}C]$. The current density decreased with a blend ratio up to 75 [wt%] at $90[^{\circ}C]$. By analyzing the diffraction patterns of XRD, we found that the LDPE with the blend ratio of 50 [wt%] represented the largest crystal size of (020) plane. We investigated the relationship between the effect of blend and electrical properties and these results are discussed.

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