• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.156-156
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• 2016

The effect of nitrogen doping on the mechanical and tribological performance of single-layer tetrahedral amorphous carbon (ta-C:N) coatings of up to $1{\mu}m$ in thickness was investigated using a custom-made filtered cathode vacuum arc (FCVA). The results obtained revealed that the hardness of the coatings decreased from $65{\pm}4.8GPa$ to $25{\pm}2.4GPa$ with increasing nitrogen gas ratio, which indicates that nitrogen doping occurs through substitution in the $sp^2$ phase. Subsequent AES analysis showed that the N/C ratio in the ta-C:N thick-film coatings ranged from 0.03 to 0.29 and increased with the nitrogen flow rate. Variation in the G-peak positions and I(D)/I(G) ratio exhibit a similar trend. It is concluded from these results that micron-thick ta-C:N films have the potential to be used in a wide range of functional coating applications in electronics. To achieve highly conductive and wear-resistant coatings in system components, the friction and wear performances of the coating were investigated. The tribological behavior of the coating was investigated by sliding an SUJ2 ball over the coating in a ball-on-disk tribo-meter. The experimental results revealed that doping using a high nitrogen gas flow rate improved the wear resistance of the coating, while a low flow rate of 0-10 sccm increased the coefficient of friction (CoF) and wear rate through the generation of hematite (${\alpha}-Fe_2O_3$) phases by tribo-chemical reaction. However, the CoF and wear rate dramatically decreased when the nitrogen flow rate was increased to 30-40 sccm, due to the nitrogen inducing phase transformation that produced a graphite-like structure in the coating. The widths of the wear track and wear scar were also observed to decrease with increasing nitrogen flow rate. Moreover, the G-peaks of the wear scar around the SUJ2 ball on the worn surface increased with increasing nitrogen doping.

• 한국표면공학회지
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• 제25권5호
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• pp.271-281
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• 1992

Amorphous hydrogenated silicon carbide(a-Si1-xCx : H) films have been prepared by the rf sputtering using a silicon target in a gas mixture of Argon and methane with varying methane gas flow rate(fCH) in the range of 1.5 to 3.5 sccm at constant Argon flow rate of 30sccm and rf power in the range of 3 to 6 W/$\textrm{cm}^2$. The effects of methane flow rate and rf power on the structure and optical properties of a-Si1-xCx : H films have been analysed by measuring both the IR absorption spectrum and the UV transmittance for the films. With increasing the methane flow rate, the optical band gap(Eg) of a-Si1-xCx : H films increases gradually from 1.6eV to the maximum value of 2.42eV at rf power of 4 W/$\textrm{cm}^2$, which is due to an increases in C/Si ratio in the films by an significant increase in the number of C-Hn bonds. As the rf power increases, the number of Si-C and Si-Hn bonds increases rapidly with simultaneous reduction in the number of C-Hn bonds, which is associated with an increase in both degree of methane decomposition and sputtering of silicon. The effects of rf power on the Eg of films are considerably influenced by the methane flow rate. At low methane flow rate, the Eg of films decreased from 2.3eV to 1.8eV with the rf power. On the other hand, at high methane flow rate, that of films increased slowly to 2.4eV.

• 한국작물학회지
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• 제30권2호
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• pp.154-157
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• 1985

본 시험은 6월 14 일에 4년생 인삼 식물체의 각 기관별, 10월 1 일에 6년생을 근상태별로 구분하여 호흡량을 측정하였던 바 그 결과는 다음과 같다. 1. 기관별 호흡량은 유과≒엽>화경>경≒근의 순이었다. 2. 15$^{\circ}C$~3$0^{\circ}C$ 사이에서의 기관별 호흡계수는 유과 2.39, 엽 1.75, 근 1.57, 경 1.17, 화경 1.16이었다. 3. 채굴 당시 대편삼(117$\pm$8.8g)과 소편삼(54$\pm$4.0g)간에 호흡량의 차이는 인정되지 않았다. 4. 근내 수분함량이 감소할수록 호흡량은 저하되었으며 그 정도는 소편삼에서 현저하였다. 5 . 건전삼에 비해 근적변삼에서 근호흡량이 현저히 많았다.

• 한국산학기술학회논문지
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• 제19권8호
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• pp.32-36
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• 2018

500kgf 용량의 Instron 시험기를 이용하여 폴리프로필렌 판재의 인장시험 평가를 행하였다. 두께가 0.8 mm인 폴리프로필렌 판재의 변형속도민감도를 평가하기 위하여 변형속도는 $5{\times}10^{-4}/sec{\sim}5{\times}10^{-2}/sec$으로 100배 변화를 주어 상온 및 고온인장시험 하였다. 이를 통하여 변형속도 및 온도 변화에 따른 강도변화를 비교하였다. 실험결과 초기 변형속도가 증가할수록 강도가 증가하였으며 이는 폴리프로필렌은 변형속도민감도가 강한 양의 값을 지닌 재료임을 알 수 있었다. 또한 폴리프로필렌 판재의 고온 인장특성을 평가하기 위하여 온도는 80, 120, $160^{\circ}C$로 변화시켜 시험하였다. 고온인장시험 결과 온도가 증가할수록 강도는 감소하였으며 특히 $160^{\circ}C$에서는 강도가 인장강도가 0으로 강하하였다. 변형속도 증가에 따른 온도 증가의 영향을 살펴보면 상온, $80^{\circ}C$ 및 $120^{\circ}C$까지는 항복강도 및 인장강도의 증가 폭이 비슷한 수준을 나타내었으나 $160^{\circ}C$에서는 응력이 0에 가까워짐에 따라 강도 증가가 거의 없는 것으로 나타났다. 고온 인장시험에서 변형속도 증가에 따라 항복강도 값이 증가하는 양 보다는 인장강도 값이 증가하는 폭이 컸다.

• 산업진흥연구
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• 제3권2호
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• pp.1-8
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• 2018

본 연구에서는 탄화수소 개질을 위한 예비 개질기에서 에탄의 반응 메커니즘과 이에 적합한 반응속도식에 대한 연구를 수행하였다. 반응 mechanism 분석을 통해 ethane의 개질 반응 중 (CO2+H2,C2H6+H2,C2H6+H2O)3개의 반응이 진행되는 것을 확인할 수 있었으며, 각각의 반응 속도 (CO2+H2($r=3.42{\times}10-5molgcat.-1\;s-1$), C2H6+H2($r=3.18{\times}10-5mol\;gcat.-1s-1$), C2H6+H2O($r=1.84{\times}10-5mol\;gcat.-1s-1$)) 를 구하였다. 이를 통해 C2H6+H2O반응이 rate determining step (RDS)임을 확인하고, Langmuir-Hinshelwood model (L-H model)을 통해 이 반응의 반응식을 r=kS*(KAKBPC2H6PH2O)/(1+KAPC2H6+KBPH2O)2 (KA=2.052,KB=6.384,$kS=0.189{\times}10-2$)로 나타낼 수 있었다. 이렇게 얻어진 반응식은 반응 메커니즘을 고려하지 않고 유도된 power rate law와 비교하였으며, power rate law는 좁은 농도 변화 영역 (ethane 약 2.5-4%, water 약 60-75%)에서는 비교적 유사한 fitting이 이루어졌지만, 넓은 농도 변화영역에서는 반응 mechanism을 토대로 얻은 L-H model 반응식이 실험값과 더 유사한 값을 보이는 것을 확인하였다.

• 대한한방내과학회지
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• 제21권2호
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• pp.329-336
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• 2000

During 9 months the clinical study on the 45 cases constipation patients caused by C.V.A, who were treated with Bo-Riu Enema, was done in the Department of Oriental Internal Medicine II, Oriental Medicine Hospital, Taejon University. The result of this study is compared with glycerin-enema treated group. The results were as follows ; 1. The incidence rate of constipation caused by C.V.A is higher in old aged group. 2. The incidence rate of constipation caused by C.V.A is higher in Tae-Um-In(太陰人). 3. The improvement rate of constipation caused by C.V.A is higher in Bo-Riu Enema treated group than in glycerin-enema. 4. The admission period is shorter in Bo-Riu Enema treated group than in glycerin-enema. 5. In case of paralytic ileus, the improvement rate of constipation caused by C.V.A is higher in Bo-Riu Enema treated group than in glycerin-enema.

• 대한기계학회논문집A
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• 제23권7호
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• pp.1139-1146
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• 1999

Reliability analysis of structures based on fracture mechanics requires knowledge on statistical characteristics of the parameter C and m in the fatigue crack growth law, $da/dN=C({\Delta}K)^m$. The purpose of the present study is to investigate if it is possible to predict fatigue crack growth rate by only the fluctuation of the parameter C. In this study, Paris-Erdogan law is adopted, where the author treat the parameter C as random and m as constant. The fluctuation of crack growth rate is assumed only due to the parameter C. The growth resistance coefficient of material to fatigue crack growth (Z=1/C) was treated as a spatial stochastic process, which varies randomly on the crack path. The theoretical crack growth rates at various stress intensity factor range are discussed. Constant ${\Delta}K$ fatigue crack growth tests were performed on the structural steel, SM45C. The experimental data were analyzed to determine the autocorrelation function and Weibull distributions of the fatigue crack growth resistance. And also, the effect of the parameter m of Paris' law due to variation of fatigue crack growth resistance was discussed.

• 한국재료학회지
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• 제27권2호
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• pp.119-126
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• 2017

WC-CrC-Ni coatings were prepared by nine processes of the Taguchi program with three levels for the four spray parameters: spray distance, flow rates of hydrogen and oxygen, and powder feed rate. The optimal coating process (OCP) was oxygen flow rate of 38 FMR, hydrogen flow rate of 53 FMR, powder feed rate of 25 g/min, and spray distance of 7 inches. Hardness of 1150 Hv and porosity of 1.2 %, were obtained by OCP; these are better results compared with the highest 1033 Hv and the lowest 1.5 % porosity obtained by nine processes of the Taguchi program. Friction coefficient of the WC-CrC-Ni coating decreased from $0.36{\pm}0.07$ at $25^{\circ}C$ to $0.23{\pm}0.07$ at $450^{\circ}C$. These values were smaller than those of the EHC (electrolytic hard chrome) plating at both temperatures due to lubrication from the oxide debris. The wear trace and wear depth of the coating are smaller than those of the EHC at both temperatures. Pitting was not found in the WC-CrC-Ni coating sample, while it did appear in the EHC sample.

• Journal of Welding and Joining
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• 제18권5호
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• pp.105-111
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• 2000

The wear behavior of thermal sprayed AlSiMg-40TiC composite coatings were studied as a function of load and sliding velocity under unlubricated conditions. Experiments were performed using a block-on-ring(WC-6wt%/Co, Hv 1500) type. The tests were carried out a various load(30∼ 125.5N) and sliding velocity(0.5∼2.0m/s). Three wear rate regions were observed in the AlSiMg-40TiC composite coatings. The wear rate in region I at low load (less then 8N( were less than 1×{TEX}$10^{-5}${/TEX}㎣/m. Low wear rates in region I resulted from the load-bearing capacity of TiC particles. The transition from region I to II occurred when the applied load exceeded the fracture and pull-out strength of the particles. The TiC fractured particles trapped between the specimen and the counterface acted as third-body abrasive wear. The subsurface layer worn surface in region II was composed of the mechanically mixed layer (MML). The wear rate increase abruptly above a critical load (region III). The high wear rate in region III was induced by frictional temperature and involves massive surface damage.

• Journal of Ecology and Environment
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• 제33권3호
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• pp.187-193
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• 2010

Seed germination is a biological process that is affected by a variety of genetic and environmental factors. The cardinal temperature and thermal time are required for germination. The principal objective of this study was to identify and characterize variations in the base, optimum, and maximum germination temperatures of Haloxylon aphyllum L. from two seed sources, in order to establish models for use in predicting seeding dates. Mature H. aphyllum seeds were germinated at temperatures between 5 and $35^{\circ}C$. The germination behavior of H. aphyllum seeds to different temperature regimens in light was evaluated over a temperature range of $5-35^{\circ}C$ at intervals of $5^{\circ}C$. The rate of germination increased between base and optimum thermal conditions, and decreased between optimum and maximum thermal conditions; the germination rate varied in a linear fashion at both sub-optimal and supra-optimal temperatures. The linear regression fit the range of germination rates at $5^{\circ}C$ to $25^{\circ}C$ and $25^{\circ}C$ to $30^{\circ}C$, and thus the base temperature, optimum temperature, and maximum temperature for the germination of H. aphyllum were measured to be $0.6^{\circ}C$, $25.69^{\circ}C$, $37.90^{\circ}C$, and $1.76^{\circ}C$, $21.56^{\circ}C$, $37.90^{\circ}C$ for Qom and the Fars dune desert respectively.