• Title/Summary/Keyword: C:N

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Crystal growth of polyctystalline 3C-SiC thin films on AlN buffer layer (AlN 완충층을 이용한 다결정 3C-SiC 박막의 결정성장)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.333-334
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    • 2007
  • This paper describes the characteristics of poly (polycrystalline) 3C-SiC grown on SiOz and AlN substrates, respectively. The crystalline quality of poly 3C-SiC was improved from resulting in decrease of FWHM (full width half maximum) of XRD by increasing the growth temperature. The minimum growth temperature of poly 3C-SiC was $1100^{\circ}C$. The surface chemical composition and the electron mobility of poly 3C-SiC grown on each substrate were investigated by XPS and Hall Effect, respectively. The chemical compositions of surface of poly 3C-SiC films grown on $SiO_2$ and AlN were not different. However, their electron mobilities were $7.65\;cm^2/V.s$ and $14.8\;cm^2/V.s$, respectively. Therefore, since the electron mobility of poly 3C-SiC films grown on AlN buffer layer was two times higher than that of 3C-SiC/$SiO_2$, a AlN film is a suitable material, as buffer layer, for the growth of poly 3C-SiC thin films with excellent properties for M/NEMS applications.

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A Study on the Hydrolysis of p-Nitrophenyl Carboxylates by Micellar Surfactants Catalysts Involving Histidyl Residue (히스티딜기등을 포함하는 미셀성 계면활성제를 촉매로 사용한 파라니트로페닐 에스테르의 가수분해반응에 관한 연구)

  • Won Fae Koo;Choon Pyo Hong
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.3-10
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    • 1989
  • In order to obtain a clue in understanding enzymatic hydrolysis in which the His-Cys moieties of papain protease is involved, we prepared cationic peptide-sufactants bearing histidyl, cysteinyl, and both histydyl and cysteinyl residues. Their catalytic efficiency toward the hydrolysis of PNPL were investigated in comicellar phases formed with $N^{+}C_{2}CysC_{12}$, $N^{+}C_{2}HisC_{12}$, $N^{+}C_{2}HisCysC_{12}$ increased markedly in the same order compared with that of $N^{+}C_{2}AlaC_{12}$. The markedly increased catalytic effects are attributed to the imidazole groups of $N^{+}C_{2}HisC_{12}$ and the thiol groups of $N^{+}C_{2}CysC_{12}$, and the large catalytic efficiency of $N^{+}C_{2}HisCysC_{12}$, is considered due to the interaction of the imidazole and the thiol groups. In order to investigate catalytic activities, rate constants for the functional groups, km* and dissociation constants, pKa have been determined. The results showed that $k^{\ast}_m$ and pKa of the imidazole groups were $7.91{\times}10^{-4}S^{-1}$ and 6.49, and those of the thiol groups were $6.00{\times}10^{-4}S^{-1}$ and 10.50. The catalytic effects of comicellar systems on the hydrolysis of p-nitrophenyl esters has increased according to the increasing size of the alkyl carbon number. Therefore, the catalytic effects have been increasing by the interaction of micellar hydrophobic parts and substrates as well as action of the functional groups.

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Influence of COD/Nitrate-N Ratio on Denitrification and Methanogenesis in Anaerobic Sludge (COD/Nitrate-N비가 혐기성 슬러지에서 탈질과 메탄화에 미치는 영향)

  • Park, Sang-Min;Jun, Hang-Bae;Choi, Chang-Ok;Lee, Joon-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.739-745
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    • 2005
  • Simultaneous denitrification and methanogenesis at various influent COD/Nitrate-N(below C/N) ratio was investigated with two different anaerobic sludges of which one was inoculated with glucose only and the other was inoculated with glucose and nitrate. Three different C/N ratios of 30, 20, and 10 were applied with each anaerobic sludge in serum bottles agitated in a rotary shaker to monitor the time related changes of amount of gas production and gas composition. Glucose was used as a single carbon source, which was adjusted to 1,000 mg/L as COD and potassium nitrate was used as a nitrogen source to adjust the each C/N ratio. COD removal by methanogenesis was dominant at higher C/N ratios, while COD removal by denitrification was dominant at lower C/N ratios. With the sludges cultured at C/N ratios below 10, SMA and SDNR rising different carbon substrates were investigated. The most efficient carbon substrate was acetate and the highest SMA and SDNR were 0.76 g COD/g VSS day with pure anaerobic sludge and 1.38 g ${NO_3}^--N/g$ VSS day with sludge cultured at C/N ratio of 5, respectively.

A study on the chemically vapor deposited TiC, TiN, and Ti(C, N) on $Si_3N_4$-TiC ceramic tools ($Si_3N_4$-TiC ceamic 공구에 화학증착된 TiC, TiN 및 Ti(C, N)에 관한 연구)

  • 김동원;김시범;이준근;천성순
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1988.06a
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    • pp.39-42
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    • 1988
  • 요업체 절삭공구(ceramic tool)는 공구강이나 초경제품에 비해 고속 절삭 작업이 가능하며 생산성을 높일 수 있기 때문에 최근 주목을 받고 있다. 본 실험에서 모재(substrate)로 사용된 $Si_3N_4$-TiC ceramic은 요업체 공구중에서 파괴인성이 우수하며, 주철이나 초합금을 절삭할 때 우수한 성능을 나타낸다. 그러나 요업체 절삭공구중에서 경도가 낮은 편에 속하며, Fe,Mn,O와 $Si_3N_4$가 화학적 반응을 일으켜서, steel을 절삭할 때 상면 마모(crater wear)가 심하게 발생하기 때문에 우수한 성능을 나타내지 못하고 있는 실정이다. 따라서 이러한 단점을 보완하기 위해 공구의 표면에 보호피막(protective coating)을 입히는 것은 필수적이다. 본 연구에서는 반응변수들이 TiC 및 TiN 증착층의 증착속도, 미세구조, 화학적 조성 및 증착층과 substrate 사이의 interface를 조사하여 각 증착층의 최적증착조건을 규명하고자 한다.

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The Test of Combining Ability and Heterosis on the Silkworm(Bombyx mori) Breeding (누에 견.사질에 관한 잡종강세 및 조합능력검정)

  • 문병원;한경수
    • Journal of Sericultural and Entomological Science
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    • v.36 no.1
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    • pp.8-25
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    • 1994
  • The study was conducted to obtain the genetic information on heterosis and combining ability of the quantitative characters for F1 hybrid breeding in silkworms. Six parental varieties and each set of 30 diallel crosses in F1's were used as materials, and bred on the randomized complete block design with three replications. Fourteen characters were observed with the twenty samples in each tray. The data were analyzed for (1) heterosis and combining ability in F1 hybrid. The heterosis in the weight and the length of cocoon showed positively high at 24.51%, and 23.4%, respectively and the weight of the whole cocoon as well as the weight of the whole cocoon layer showed a siginificant heterosis ranging from 15.56% to 15.71% and from 17.14% to 19.01%, but the fifth and the total instar period showed negative heterosis. It was found that the combination between, C70XRomogua and N9 X Romogua showed highly a negative heterosis on the fifth instar period and for the cocoon weight. The female of N9+Sansuian and the male of Romogua X Sansurian have a high heterosis effect, on the cocoon shell weight, and Sansurian X Romogua(reciprocal) on the length and the weight of cocoon filament with no regard to sexuality. The significant maternal and cytoplasmic effect on heterosis of the cocoon weight and the cocoon shell weight were observed with the combinations, N9 X C5, N63 X C70 and on the length of the cocoon filament with the combinations, Sansurian X N63, Sansurian X C5, Sansurian X C70 and N9 X C70, N63 X C70 on the weight of cocoon filament. As mean squared of GCA, SCA and RCA were significant with these combining ability for all characters resulted from additive and non-additive altogether and there is a significant difference between reciprocals. Sansurian showed a negative GCA effect on the fifth and total larval duration, but the higher positive GCA effects took places with varieties N9 and C5 on the length, width, weight of cocoon, cocoon shell weight, percentage of cocoon shell weight, length and weight of cocoon filament, percentage of raw-silk with no regard to both generations and silkworm sexuality. The values of SCA between the cross combinations varied generation-wise and sex-wise. It was shown that SCA value for the fifth instar period was highly negative for Sansurian X C70, Romogua X C70, Sansurian X C5, Romogua X C5, but it was positive effect on the cocoon weight, cocoon shell weight with N9 X C5, and C70 X Sansurian, on the length of cocoon filament with N9 X C5, Romogua X Sansurian on the weight of cocoon filament between Romogua and N63 and on the percentage of raw-silk between the combination of Sansurian X Romoga.

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Change Of the Properties and the $Cr_3C_2$ Phase by Sintering Atmospere on $Ti(C, N)-Cr_3C_2$ Ceramics ($Ti(C, N)-Cr_3C_2$, 소결체의 오결분위기에 따른 물성과 $Cr_3C_2$ 상변화)

  • 김무경;이재의
    • Korean Journal of Crystallography
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    • v.3 no.1
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    • pp.44-52
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    • 1992
  • The effect of sintering atmosphere on the final properties and phase change of Ti (C, N) Cr3c2 ceramics was investigated. In the case of sintering in vacuum and N2 atmosphere, densely packed sintered body was obtained. In Ar atmosphere, however, densification was much decreased compared to sintering in vacuum and Na. XRD analysis showed that in vacuum atmosphere Cr3c2 phase was changed to Cr7c3 Phase whereas in N2 and Ar atmosphere phase change was not occurred. That is, for vacuum sintering, the formation of defects in Ti(C, N) structure occurred through de-nitridation process, and it promotes the diffusion of C in Cr3c2 and raises the densification effects. But in the case of N2 atmosphere, densification phenomenon was considered to be due to sintering mechanism that enabled formation of free carbon and removal of oxygen by free carbon and existence of carbon in the grain boundary.

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Effect of Fatty Acid Profiles on Sensory Properties of Beef Evaluated by Korean and Australian Consumer Groups

  • Cho, Soo-Hyun;Kim, Jae-Hee;Kim, Jin-Hyoung;Park, Beom-Young;Hwang, In-Ho;Lee, Jong-Moon;Seong, Pil-Nam;Kim, Dong-Hun
    • Food Science and Biotechnology
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    • v.17 no.3
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    • pp.495-500
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    • 2008
  • This study assessed the role of fatty acids on beef preference of 2 consumer groups from South Korea and Australia. Three muscles (longissimus dorsi, triceps brachii, and semimembranosus) were obtained from 36 carcasses (18 Hanwoo steers and 18 Angus steers) and the cooked beef samples were evaluated by 1,080 consumers (720 Korean consumer panels and 360 Australian consumer panels). The cluster analysis showed that the Korean consumers had more significant relationship with fatty acid composition of beef than that of the Australian consumers when evaluated Australian Angus beef Only C20:5(n-3), and C22:5(n-3) affected preference clustering for Australian consumers; while saturated (C16:0 and C 18:0) as well as unsaturated fatty acids [C16:1(n-7), C18:2(n-6), C18:3(n-3), C20:3(n-6), C20:4(n-6), C20:5(n-3), C22:4(n-6), C22:5(n-3)] affected preference clustering for Korean consumers (p<0.05). In the discriminant analysis of Korean consumer's preference clustering, C20:5(n-3) was a significant fatty acid for Australian Angus beef while the C20:4(n-6) and C 18:0 for Korean Hanwoo beef to evaluate the palatability (p<0.05). Therefore, fatty acid compositions impact Korean consumer's preference of beef.

Syntheses of SiC and $SiC-Si_3N_4$ Powder from Jecheon Quartz (제천규석으로부터 SiC 및 $SiC-Si_3N_4$계 분말 합성)

  • 이홍림;배철훈;문준화
    • Journal of the Korean Ceramic Society
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    • v.23 no.1
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    • pp.67-73
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    • 1986
  • SiC and $SiC-Si_3N_4$ powder were synthesized via the carbiding and carbiding-nitriding reaction of Jecheon quartz respectively using graphite as a reducing agent. $\beta$-SiC+($\alpha$+$\beta$)-$Si_3N_4$ composite was obtained by the carbiding-nitriding reaction of Jecheon quartz-graphite mixture at 1, 35$0^{\circ}C$ in $H_2$ atmosphere. $\beta$-SiC+($\alpha$+$\beta$)-$Si_3N_4$ composite was obtained by the carbidint-nitriding reaction of Jecheon quartz-graphite mixture at 1, 35$0^{\circ}C$ in $N_2-H_2$ atmosphere. The ratio of $\beta$-SiC+($\alpha$+$\beta$)-$Si_3N_4$ content in a produced composite could be controlled by adjusting the reaction time and gaseous mixture.

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GENERATING NEW FRAMES IN $L^2(\mathbb{R})$ BY CONVOLUTIONS

  • Kwon, Kil-Hyun;Lee, Dae-Gwan;Yoon, Gang-Joon
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.15 no.4
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    • pp.319-328
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    • 2011
  • Let $\mathbf{c}=\{c_n\}_{n{\in}\mathbb{Z}}\in{\ell}^1(\mathbb{Z})$ and $\{f_n\}_{n{\in}\mathbb{Z}}$ be a frame (Riesz basis, respectively) of $L^2(\mathbb{R})$. We obtain necessary and sufficient conditions of $\mathbf{c}$ under which $\{\mathbf{c}{\ast}_{\lambda}f_n\}_{n{\in}\mathbb{Z}}$ becomes a frame (Riesz basis, respectively) of $L^2(\mathbb{R})$, where ${\lambda}$ > 0 and $(\mathbf{c}{\ast}_{\lambda}f)(t)\;:=\;{\sum}_{n{\in}\mathbb{Z}}c_nf(t-n{\lambda})$. When $\{\mathbf{c}{\ast}_{\lambda}f_n\}_{n{\in}\mathbb{Z}}$ becomes a frame of $L^2(\mathbb{R})$, we present its frame operator and the canonical dual frame in a simple form. Some interesting examples are included.

Nitrogenation of Coal Ash in the Presence of Carbon and Product Distributions of AlN, SiC and Si₃N₄ (석탄회의 탄소가 첨가된 질화반응과 AlN, SiC 그리고 Si₃N₄의 생성분포)

  • 양현수;홍원표;노재성;서동수;손응권
    • Journal of the Korean Ceramic Society
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    • v.27 no.8
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    • pp.956-956
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    • 1990
  • A nitrogenation of coal ash in the presence of carbon was carried out to examine the effects of reaction temperature, reaction time and carbon composition on the formation of AlN, SiC and Si3N4. Decreasing the particle size increased the formation of AlN and its maximum composition in the product was obtaiend under 1450∼1500℃, 2 hours of reaction time and about 30% of carbon addition(on the basis of sample weight). Compositions of SiC and Si3N4 were distributed to the opposite so that SiC showed a higher composition compared with Si3N4 at a lower temperature, a shorter reaction time and a greater carbon addition.