• Journal of the Korean Ceramic Society
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• v.35 no.9
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• pp.939-944
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• 1998

The formation microstructure and properties of novel ceramic composite materials by active filler con-trolled polymer pyrolysis were investigated. Polymethlsiloxane filled with W is of particular interested be-cause of the formation of ceramic bonded hard materials (WC-$W_{2}C$-$S_{1}OC$) for wear resistant applications. Highly metal-filled polymer suspensions were prepared and their conversion to ceramic composites by an-nealing in $N_{2}C$ atmosphere at 1000-$1600^{\circ}C$ were studied. Dimensional change porosity and phase distribution (filler network) were analyzed and correlated to the resulting material properties. Microcrystalline com-posites with the filler reaction products embedded to the resulting material properties. Microcrystalline com-posites with the filler reaction products embedded in a silicon oxycarbide glass matrix were produced. De-pending on the pyrolysis conditions ceramic composites with a density up to 95 TD% a hardness of 7-8.8GPa Yong's modulus of 220-230 GPa a fracture toughness of 6-6.8$MPam^{1/2}$ and a flexual strength of 380-470 MPa were obtained.

• Composites Research
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• v.30 no.3
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• pp.188-192
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• 2017

The mechanical properties of composites are significantly affected by external environment. It is essential to understand the degradation of material performance and judge the material's lifetime in advance. In the current research, changes in mechanical properties of glass fiber and unsaturated polyester composite materials (GFRP, Glass fiber reinforced plastic) were investigated under different bending stress and submerged in hot water at a temperature of $80^{\circ}C$. Loading time of 100 H (hours), 200 H, 400 H, 600 H, 800 H for testing under stresses equal to 0% (stress-free state), 30%, 50% and 70% of the ultimate strength was applied on the GFRP specimens. From the values of bending stress, obtained from three-point bending test, fracture energy, failure time, and life curve were analysed. Moreover, a normalized strength degradation model for this condition was also developed. It was observed that within 100 H, the decline rate of the bending strength was proportional to the pressure.

• Progress in Superconductivity and Cryogenics
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• v.25 no.3
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• pp.43-48
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• 2023

Polymer composites, especially glass fiber reinforced polymer (GFRP) are finding ever-increasing applications in areas such as superconductivity, space technology, cryogenic rocket engines, and cryogenic storage vessels. Various components made of polymer composites are much lighter than their metallic counterparts but have equivalent strength for ultra-low temperature applications. In this paper, we have investigated the tensile properties of an indigenously prepared unidirectional cylindrical hollow composite tube for its use as a neck of the cryogenic vessel. XRD and SEM of the tube are completed before cryogenic conditioning to ascertain the fiber and resin distribution in the matrix. The result shows that for composites, after 15, 30, 45, and 60 minutes of cryogenic conditioning at 77K in a liquid nitrogen bath, the strength and modulus increase significantly with the increase of strain rate and reach the optimum value for 45 minutes of conditioning. The results are encouraging as they will be helpful in assessing the suitability of GFRP in the structural design of epoxy-based components for cryogenic applications.

• Composites Research
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• v.12 no.6
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• pp.8-14
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• 1999

This research is focused on the investigation of impact strength and the microscopic observation of material behavior of glass fiber reinforced polypropylene in solid phase forming. The fiber weight per-centage of the composite materials was 20%, 30% and 40%. The solid-phase formed specimens were pre-strained to 10%,20%. and 30% strain levels. The forming temperatures of specimens were $100^{\circ}C$, $125^{\circ}C$ and $150^{\circ}C$. Izod impact test was performed with unnotched specimens. With increasing the glass fiber content ; the impact strength was increased.

• The Korean Journal of Ceramics
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• v.1 no.3
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• pp.155-159
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• 1995

Borosilicate, $B_2O_3$ and BN derived from liquid precursors have been tested as shielding materials for the long period of oxidation resistance of C/BN composites at $650^{\circ}C$. Borosilicate coating displayed excellent oxidation resistance and low moisture absorbance, while $B_2O_3$ and BN were less effective in elevating the oxidation resistance. The enhancement of the oxidation resistance was explained as self-healing effect by viscous flow of the borosilicate glass over Tg, resulting in the reduction of the exposed carbon fibers in a BN matrix.

• Polymer(Korea)
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• v.24 no.3
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• pp.350-357
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• 2000

Curing behaviors of glass/epoxy prepreg for printed circuit boards (PCB) were studied by using dielectrometer and differential scanning calorimeter. This prepreg was showed the lowest ionic viscosity at about 115$^{\circ}C$, and then the ionic viscosity was gradully increased up to 15$0^{\circ}C$. This indicated that the curing reaction of this prepreg started at 115$^{\circ}C$ and the molecular weight was increased by the accelerated thermal cross-linking reaction. The loss factor and tan $\delta$ values were also measured and discussed. The dielectric behaviors of this prepreg system were also measured according to the cure cycle for PCB. This material was found to be thermally stable up to about 30$0^{\circ}C$ and then was showed an abrupt decomposition beyond this temperature.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.2
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• pp.199-204
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• 2013

Owing to the global energy crisis, studies have strongly focused on realizing energy savings through vehicle weight reduction using light metal alloys or polymer composites. Polymer composites afford many advantages including enabling the fabrication of complex shapes by injection molding, and glass and carbon fibers offer improved mechanical properties. However, the high temperature in an engine room and the high humidity during the rainy season can degrade the mechanical properties of the polymer. In this study, the mechanical properties of injection-molded glass-fiber-reinforced polymer were assessed at a temperature of $85^{\circ}C$ and the maximum moisture absorption conditions. The result showed a 23% reduction in the maximum tensile strength under high temperature, 30% reduction under maximum moisture absorption, and 70% reduction under both heat and moisture conditions. For material selection during the design process, the effects of high temperature and high humidity should be considered.

• Composites Research
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• v.32 no.1
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• pp.78-84
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• 2019

This study focused on the prediction of the long-term performance of carbon fiber/epoxy composites using Dynamic Mechanical Analysis (DMA) and Time-Temperature Superposition (TTS). Single-frequency test, multi-frequency test, and creep TTS test were performed. A sinusoidal load of $20{\mu}m$ amplitude was applied while increasing the temperature from $-30^{\circ}C$ to $240^{\circ}C$ at $2^{\circ}C/min$ for the single-frequency test and the multi-frequency test. The frequencies applied to the multi-frequency test were 0.316, 1, 3.16, 10 and 31.6 Hz. In the creep TTS test, a stress of 15 MPa was applied for 10 minutes at every $10^{\circ}C$ from $-30^{\circ}C$ to $230^{\circ}C$. The glass transition temperature was determined by single-frequency test. The activation energy and the storage modulus curve for each temperature were obtained from glass transition temperature for each frequency by the multi-frequency test. The master curve for the reference temperature was obtained by applying the shift factor using the Arrhenius equation. Also, TTS test was used to obtain the creep compliance curves for each temperature and the master curve for the reference temperature by applying the shift factors using the manual shift technique. The master curve obtained through this process can be applied to predict the long-term performance of carbon fiber/epoxy composites for a given environmental condition.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.2
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• pp.169-175
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• 2000

The object of this study was to investigate the feasibility of solid-phase forming of the composites and to characterize the material behavior in the biaxial stretch forming. The materials tested contained 20%, 30%, and 40% glass fibers by weight in a polypropylene matrix. Biaxial stretch forming tests were performed at three forming speeds of 10mm/sec, 1mm/sec, and 0.1mm/sec and at four forming temperatures of $75^{\circ}C, 100^{\circ}C, 125^{\circ}C, and 150^{\circ}C$ to investigate effects of forming speed and forming temperature. The microscopic observation of a formed part was conducted at various strain levels to characterize the material behavior. The strain distribution on a formed part was measured and displayed on the farmed geometry with a contour display The material behavior of the composite in the biaxial stretch forming was strongly influenced by the forming conditions.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.3
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• pp.253-258
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• 2016

The effect of temperature on the fracture energy, crack propagation, and crack tip opening displacement (CTOD) was determined for particulate reinforced composites using the wedge splitting test. The materials that were used consisted of a polymer binder, an oxidizing agent, and aluminum particles. The test rate of the wedge splitting specimen was 50 mm/min, the temperature conditions were $50^{\circ}C$, room temperature, $-40^{\circ}C$, and $-60^{\circ}C$. The fracture energy, calculated from splitting load-crack mouth opening displacement(CMOD) curves, increased with decreasing temperature from $50^{\circ}C$ to $-40^{\circ}C$. In addition, the strength of the particulate reinforced composites increased sharply at $-60^{\circ}C$, and the composites evidenced brittle fracture due to the glass transition temperature. The strain fields near the crack tip were analyzed using digital image correlation.