• Journal of the Korea Organic Resources Recycling Association
• /
• v.24 no.4
• /
• pp.69-76
• /
• 2016

To produce the primary data for best management of soil nutrient in organically practiced soils, 75 leading organic farms whose paddy fields were certified as organic were selected. Soil samples were collected from the paddy fields before plowing, and then analyzed for the determination of physico-chemical properties. Soil pH, organic matter and available phosphate were analyzed and averaged 6.2, $25.6mg\;kg^{-1}$ and $88.4mg\;kg^{-1}$, respectively. Contrary to the national-scale-surveyed paddy soils including organic and conventional farming, pH was higher, available phosphate was lower in the organically practiced soils, but organic matter was similar. With the increasing cultivation period in organic, soil pH and porosity were also increased, EC, available phosphate, bulk density and soil hardness were lower than those from the national survey. Organic matter, however, was not significantly changed. The bulk density was negatively correlated with the organic matter content for both surface topsoil ($R^2=-0.5424$) and subsoil ($R^2=-0.6429$) (p<0.05). Soil quality is improved in most of soil chemical and physical composition factors excluding organic matter and available phosphate. However, it is necessary to establish the counter measure plan for organic matter management and to develop phosphate-containing materials which can be used as organic agricultural material in the future.

• Progress in Superconductivity
• /
• v.12 no.2
• /
• pp.88-92
• /
• 2011

[ $MgB_2$ ]superconducting sheets have been fabricated using powder roll compaction method. Sheet-type $MgB_2$ bulk samples were successfully fabricated using the pre-reacted $MgB_2$ powders. In this work, $MgB_2$ powders were compacted by two rotating rolls and squeezed out as a form of $MgB_2$ sheets of ~1 mm thickness. The rolling speed of 0.3-0.7 rpm and the gap distance of 0.3-0.8 mm between the two rollers were carefully controlled to get a full compaction of the powders into bulk $MgB_2$ sheets. The densities of $MgB_2$ sheets were 1.98-2.05 g/$cm^3$, which is 75.44-77.99 % of the theoretical value of 2.63 g/$cm^3$. And the density comparison was made compared to those of typical $MgB_2$ bulks from uni-axial pressing and $MgB_2$ wires from Powder-In-Tube processing.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.10 no.2
• /
• pp.129-138
• /
• 2005

Sediment texture, physical (porosity, water content, bulk density, grain density, and shear strength), and geoacoustic properties (compressional wave velocity and attenuation) were measured on eighteen core samples collected from the shelf off eastern Geoje Island, the South Sea of Korea. Based on these properties, the study area is divided into three different sub-areas: (1) Area I affected directly by the Nakdong River discharge; (2) Area II covered by the southern branch of the Nakdong River discharge; and (3) Area III dominated by relict sediment. Mean grain size, velocity, and bulk density decrease from Area $I(7.4\Phi,\;1528m/s,\;1.6g/cm^3,\;respectively)$ to Area $II(8.1\Phi,\;1485m/s,\;and\;1.5g/cm^3)$, and then increase rather rapidly in Area $III(1.4\Phi,\;1664m/s,\;and\;2.2g/cm^3)$. Porosity, on the other hand, exhibits an opposite trend, increasing from Area $I(64.5\%)$ to Area$II(73.9\%)$ and then decreasing significantly in Area $III(32.9\%)$ From the results measured and calculated, we suggest a specified geoacoustic model in the study area.

• Korean Journal of Soil Science and Fertilizer
• /
• v.39 no.2
• /
• pp.116-122
• /
• 2006

This study was carried out to compare physical properties of the horticultural substrates measured by the European standard methods (CEN methods) and the Rural Development Administration of Korea methods (RDA methods). Sixty horticultural substrates including 40 marketed substrates and 10 organic and inorganic raw materials such as peat moss, coir dust, rice hull, perlite and zeolite were sampled. The samples were then analyzed for 6 physical properties by both CEN methods and RDA methods. The results of both methods were analyzed by linear regression. Bulk density ($R^2=0.8304$), particle density ($R^2=0.8136$) and porosity ($R^2=0.6374$) values measured by the two methods were highly significant. Whereas those for easily available water (EAW, $R^2=0.3327$), water volume ($R^2=0.2692$) and air volume ($R^2=0.0739$) were not significant. Further research is needed to facilitate the conversion between the two methods.

• Korean Journal of Agricultural Science
• /
• v.27 no.2
• /
• pp.95-100
• /
• 2000

This study was carried out to estimate the effect of forest fire on physical and chemical properties of soil. The forest fire was in April 1997 in pinus densiflora dominant forest at Chungju of Chungbuk. After forest fire, dead trees were not cut. Soil samples were collected at 0-5, 5-10, and 10-20cm soil depths in November 1998 from the burned and unburned sites. The analyzed factors were soil organic matter, total N, available P, exchangeable K, Ca, and Mg, and CEC, pH, bulk density, and moisture content. There was no forest floor in burned site, but unburned site has the forest floor of 4cm thick. There were no differences in soil organic matter, total N, available P, exchangeable K, Ca, and Mg, and CEC, pH, bulk density, moisture content in all soil depth, between burned and unburned sites, except in available P in 5-10cm soil depth. Forest fire had not changed the physical and chemical soil properties in this study. However, burning of vegetation and forest floor organic matter may have adverse influence on long-term site productivity.

• Journal of Korean Dental Science
• /
• v.11 no.2
• /
• pp.71-81
• /
• 2018

Purpose: The purpose of this study was to investigate the corrosion behaviors of dental implant alloy after microsized surface modification in electrolytes containing Mn ion. Materials and Methods: $Mn-TiO_2$ coatings were prepared on the Ti-6Al-4V alloy for dental implants using a plasma electrolytic oxidation (PEO) method carried out in electrolytes containing different concentrations of Mn, namely, 0%, 5%, and 20%. Potentiodynamic method was employed to examine the corrosion behaviors, and the alternatingcurrent (AC) impedance behaviors were examined in 0.9% NaCl solution at $36.5^{\circ}C{\pm}1.0^{\circ}C$ using a potentiostat and an electrochemical impedance spectroscope. The potentiodynamic test was performed with a scanning rate of $1.667mV\;s^{-1}$ from -1,500 to 2,000 mV. A frequency range of $10^{-1}$ to $10^5Hz$ was used for the electrochemical impedance spectroscopy (EIS) measurements. The amplitude of the AC signal was 10 mV, and 5 points per decade were used. The morphology and structure of the samples were examined using field-emission scanning electron microscopy and thin-film X-ray diffraction. The elemental analysis was performed using energy-dispersive X-ray spectroscopy. Result: The PEO-treated surface exhibited an irregular pore shape, and the pore size and number of the pores increased with an increase in the Mn concentration. For the PEO-treated surface, a higher corrosion current density ($I_{corr}$) and a lower corrosion potential ($E_{corr}$) was obtained as compared to that of the bulk surface. However, the current density in the passive regions ($I_{pass}$) was found to be more stable for the PEO-treated surface than that of the bulk surface. As the Mn concentration increased, the capacitance values of the outer porous layer and the barrier layer decreased, and the polarization resistance of the barrier layers increased. In the case of the Mn/Ca-P coatings, the corroded surface was found to be covered with corrosion products. Conclusion: It is confirmed that corrosion resistance and polarization resistance of PEO-treated alloy increased as Mn content increased, and PEO-treated surface showed lower current density in the passive region.

• Journal of Food Hygiene and Safety
• /
• v.38 no.6
• /
• pp.420-429
• /
• 2023

GC-MS/MS using liquid-liquid extraction (LLE) and C18 cartridges was used to identify and quantify levels of chlorpyrifos, chlorpyrifos-methyl, cypermethrin, deltamethrin and permethrin in bulk raw milk. A calibration curve spanning 10 ng/mL to 200 ng/mL was obtained with a satisfactory correlation coefficient of 0.99. The limits of detection (LOD) and limits of quantitation (LOQ) for chlorpyrifos, chlorpyrifos-methyl, cypermethrin, deltamethrin, and permethrin in the matrix ranged from 0.06 to 1.81 ng/mL and 0.19 to 6.04 ng/mL, respectively. The recoveries of 5 pesticides from spiked samples at 37.5-125 ng/mL ranged from 86.1 to 102.1%. The measurement of uncertainty of the GC-MS/MS method for these five pesticides was developed based on the analytical process and quantification. An analysis method that is easier and faster than the method specified in the Korean food standards codes for analyzing these five pesticides in raw material milk was developed. Moreover, the analytical method for chlorpyrifos, chlorpyrifos-methyl, cypermethrin, deltamethrin, and permethrin in bulk raw milk by GC-MS/MS was established.

• The Korean Journal of Petroleum Geology
• /
• v.5 no.1_2 s.6
• /
• pp.48-58
• /
• 1997

Core samples from the B, E, F, H wells in the Tertiary Pohang Basin were analysed for total organic carbon (TOC) content and subject to Rock-Eval pyrolysis in order to assess petroleum geochemical characteristics of organic matter. Following geochemical screening, we selected samples from each well for the study of bitumen and kerogens such as optical observation, infra-red spectroscopy and biomarker analyses. Sediments of the Tertiary Yonil Group contain total organic carbon ranging from $0.55{\%} to 3.74{\%}$ with S1+S2 values higher than 2mgHC/g Rock in B, E and F wells, which indicates fair hydrocarbon generation potential. Most organic matter in the B, E, F wells is compared to type II based on the Rock-Eval pyrolysis, infra-red spectroscopy and optical observation. However, organic matter in the H well is compared to type III because the well is located at the margin of the basin where the preservation of terrestrial material is dominant. Geochemical analyses show that organic matter in the Yonil Group is thermally immature although thermal maturity slightly increases with depth. Maturity levels of the extracted kerogens are similar to those of bulk samples ($Tmax<435^{\circ}C$. Petroleum geochemical charateristics of the sediments in the Tertairy Yonil Group is fair in terms of the organic richness and hydrocarbon genetic potential, but organic matter is thermally immature due to the shallow burial depth. Optical observation of the kerogens and biomarker analysis show that organic matter in the Yonil Group is both marine and terrestrial origin, although it was deposited in marine environment. Pristane/phytane ratio suggests rather anoxic depositional environment. Transitional characteristics of organic matter indicate that the marine Yonil Group was deposited near the terrestrial environments. Input of terrestrial organic matter is more prevalent in the samples recovered from the lowermost horizon in the wells due to the terrestrial environment at the time of basin formation.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.5
• /
• pp.1241-1246
• /
• 2010

Ternary Cu/ZnO/$Al_2O_3$ catalysts were prepared by a co-precipitation method. The precursor structures were monitored during the aging. The first precipitate structure was amorphous georgeite, which transformed into the unknown crystalline structure. The transition crystalline structure was assigned to the crystalline georgeite, which was suggested with elemental analysis, IR and XRD. The final structure of precursors was malachite. The Cu surface area of the resulting Cu/ZnO/$Al_2O_3$ was maximized to be 30.6 $m^2$/g at the aging time of 36 h. The further aging rapidly decreased Cu surface areas of Cu/ZnO/$Al_2O_3$. ZnO characteristic peaks in oxide samples almost disappeared after 24 h aging, indicating that ZnO was dispersed in around bulk CuO. TOF of the prepared catalysts of the Cu surface area ranges from 13.0 to 30.6 $m^2/g_{cat}$ was to be 2.67 ${\pm}$ 0.27 mmol/$m^2$.h in methanol synthesis at the condition of $250^{\circ}C$, 50 atm and 12,000 mL/$g_{cat}$. h irrespective of the XRD and TPR patterns of CuO and ZnO structure in CuO/ZnO/$Al_2O_3$. The pH of the precipitate solution during the aging time can be maintained at 7 by $CO_2$ bubbling into the precipitate solution. Then, the decrease of Cu surface area by a long aging time can be prevented and minimize the aging time to get the highest Cu surface area.

• Korean Journal of Materials Research
• /
• v.22 no.6
• /
• pp.280-284
• /
• 2012

Bismuth antimony telluride (BiSbTe) thermoelectric materials were successfully prepared by a spark plasma sintering process. Crystalline BiSbTe ingots were crushed into small pieces and then attrition milled into fine powders of about 300 nm ~ 2${\mu}m$ size under argon gas. Spark plasma sintering was applied on the BiSbTe powders at 240, 320, and $380^{\circ}C$, respectively, under a pressure of 40 MPa in vacuum. The heating rate was $50^{\circ}C$/min and the holding time at the sintering temperature was 10 min. At all sintering temperatures, high density bulk BiSbTe was successfully obtained. The XRD patterns verify that all samples were well matched with the $Bi_{0.5}Sb_{1.5}Te_{3}$. Seebeck coefficient (S), electric conductivity (${\sigma}$) and thermal conductivity (k) were evaluated in a temperature range of $25{\sim}300^{\circ}C$. The thermoelectric properties of BiSbTe were evaluated by the thermoelectric figure of merit, ZT (ZT = $S^2{\sigma}T$/k). The grain size and electric conductivity of sintered BiSbTe increased as the sintering temperature increased but the thermal conductivity was similar at all sintering temperatures. Grain growth reduced the carrier concentration, because grain growth reduced the grain boundaries, which serve as acceptors. Meanwhile, the carrier mobility was greatly increased and the electric conductivity was also improved. Consequentially, the grains grew with increasing sintering temperature and the figure of merit was improved.