• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.81.3-81
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• 1998

• Journal of Powder Materials
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• v.26 no.1
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• pp.22-27
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• 2019

In this study, the effects of powder size and composition on the reflectance of Al-Si based alloys are presented. First, the reflectance of Al-Si bulk and powder are analyzed to confirm the effect of powder size. Results show that the bulk has a higher reflectance than that of powder because the bulk has lower surface defects. In addition, the larger the particle size, the higher is the reflectance because the interparticle space decreases. Second, the effect of composition on the reflectance by the changing composition of Al-Si-Mg is confirmed. Consequently, the reflectance of the alloy decreases with the addition of Si and Mg because dendrite Si and $Mg_2Si$ are formed, and these have lower reflectance than pure Al. Finally, the reflectance of the alloy is due to the scattering of free electrons, which is closely related to electrical conductivity. Measurements of the electrical conductivity based on the composition of the Al-Si-Mg alloy confirm the same tendency as the reflectance.

• Korean Journal of Metals and Materials
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• v.46 no.5
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• pp.296-303
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• 2008

Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.

• Composites Research
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• v.34 no.1
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• pp.51-56
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• 2021

This paper studied the possibility of manufacturing bulk graphite using coal tar, a precursor of coal tar pitch, as a binder and impregnant. Carbonization was conducted after mixing and molding with natural graphite as a filler and coal tar as a binder. Impregnation-recarbonization was performed five times after carbonization. Coal tar used as impregnant. Measuring density, porosity, compressive strength, and anisotropy ratio was conducted. The maximum density of bulk graphite specimen was 1.76 g/㎤ and the minimum porosity was 15.6% which could be controlled by process control. The highest compressive strength was 20.3 MPa. Then the maximum anisotropic ratio of bulk was shown 0.34 through XRD analysis. Therefore, it was confirmed that it was possible to manufacture artificial graphite in a bulk form by using coal tar as a binder and an impregnant.

• Journal of Sensor Science and Technology
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• v.32 no.3
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• pp.174-179
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• 2023

Bulk trailers, used for the transportation of powdered materials, such as cement and fly ash, are crucial in the construction industry. The speedy exhaustion of powdered materials stored in the tank of bulk trailers is relevant to improving transportation efficiency and reducing transportation costs. The exhaust time can be reduced by developing an automatic control system to replace the manual exhaust operation. The instantaneous or accumulated exhausts of powdered materials must be measured for automatic control of the bulk trailer exhaust system. Accordingly, we previously proposed a recurrent neural network (RNN) model that estimated the instantaneous exhaust based on low-cost pressure sensor signals without an expensive flowmeter for powders. Although our previous study utilized only an RNN model, models such as multilayer perceptron (MLP) and convolutional neural network (CNN) are also widely utilized for time-series estimation. This study compares the performance of three neural network models (MLP, CNN, and RNN) in estimating instantaneous and accumulated exhausts. In terms of the instantaneous exhaust estimation, the difference in the performance of neural network models was insignificant (that is, 8.64, 8.62, and 8.56% for the MLP, CNN, and RNN, respectively, in terms of the normalized root mean squared error). However, in the case of the accumulated exhaust, the performance was excellent in the order of CNN (1.67%), MLP (2.03%), and RNN (2.20%).

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1485-1490
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• 2014

We have designed and developed a new ladder type tetrafused ${\pi}$-conjugated building block such as dihydroindolo[3,2-b]indole (DINI) and investigated its role as an electron rich unit. The photovoltaic properties of a new semiconducting ${\pi}$-conjugated polymer, poly[[5,10-bisoctyl-5,10-dihydroindolo[3,2-b]indole-[5,6- bis(octyloxy)-4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole]], represented by PDINI-OBTC8 are described. The new polymer PDINI-OBTC8 was synthesized in donor-acceptor (D-A) fashion, where fused ${\pi}$-conjugated tetracyclic DINI, and 5,6-bis(octyloxy)-4,7-di(thiophen-2-yl) benzo[c][1,2,5]thiadiazole (OBTC8) were employed as electron rich (donor) and electron deficient (acceptor) moieties, respectively. The conventional bulk heterojunction (BHJ) device structure ITO/PEDOT:PSS/PDINI-OBTC8:PCB71M/LiF/Al was utilized to fabricate polymer solar cells (PSCs), which comprises the blend of PDINI-OBTC8 and [6,6]-phenyl-$C_{71}$-butyric acid methyl ester ($PC_{71}BM$) in BHJ network. A BHJ PSC that contain PDINI-OBTC8 delivered power conversion efficiency (PCE) value of 1.68% with 1 vol% of 1,8-diidooctane (DIO) under the illumination of A.M 1.5G 100 $mW/cm^2$.

• Proceedings of the Materials Research Society of Korea Conference
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• 1996.05a
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• pp.1-1
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• 1996

• Proceeding of EDISON Challenge
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• 2017.03a
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• pp.317-323
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• 2017

Due to the unique characteristic of auxetic material, negative poisson's ratio, it has a variety of distinctive properties compared to conventional materials. Numerous researches have been conducted on the auxetic material in order to find out how to make auxetics. In this study, we analyzed triangular and rectangular patterned rotating rigid units using finite element method. Our purpose is to investigate the mechanical properties of the rotating rigid units and to show their auxetic behaviors. We studied the Poisson's ratio and the bulk modulus of the rotating rigid units depending on their unit cell sizes. The Poisson's ratio and the bulk modulus decreased as the number of unit cells increased. Also, when the geometry of the unit cell was changed, the tendency of the Poisson's ratio and the bulk modulus was also different from the previous case. The results of the Poisson's ratio and the bulk modulus referred that they were critically affected by the number of unit cells and the shape of unit cell.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.433-434
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• 2013

• Journal of Powder Materials
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• v.14 no.6
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• pp.399-404
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• 2007

The Cu-based bulk metallic glass (BMG) composite was fabricated by spark plasma sintering (SPS) using of gas-atomized metallic glass powders and ductile brass powders. No defect such as pores and cavities was observed at the interface between the brass powder and the metallic glass matrix, suggesting that the SPS process caused a severe viscous flow of the metallic glass and brass phases in the supercooled liquid region, resulting in a full densification. The BMG composites shows some macroscopic plasticity after yielding, although the levels of strength decreased.