• Title/Summary/Keyword: Bulk Amorphous Metal

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Phase Transformation and Work-hardening Behavior of Ti-based Bulk Metallic Glass Composite

  • Hong, Sung Hwan;Kim, Jeong Tae;Park, Hae Jin;Kim, Young Seok;Park, Jin Man;Suh, Jin Yoo;Na, Young Sang;Lim, Ka Ram;Kim, Ki Buem
    • Applied Microscopy
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    • v.45 no.2
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    • pp.37-43
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    • 2015
  • In present work, work-hardening behavior of TiCu-based bulk metallic glass composite with B2 particles has been studied by systemic structural and mechanical investigations. After yield, pronounced work-hardening of the alloy was clearly exhibited, which was mainly related to the martensitic transformation as well as the deformation twinning in B2 particles during deformation. At the early plastic deformation stage (work-hardening stage), the stress-induced martensitic transformation from B2 phase to B19' phase and deformation-induced twinning of B19' phase was preferentially occurred in the around interface areas between B2 phase and amorphous matrix by stress concentration. The higher hardness value was observed in vicinity of interface within the B2 particles which are probably connected with martensitic transformation and deformation twinning. This reveals that the work-hardening phenomenon of this bulk metallic glass composite is a result of the hardening of B2 particles embedded in amorphous matrix.

Spark Plasma Sintering of the Ductile Cu-Gas-atomized Ni Bulk Metallic Glass Composite Powders (연질 Cu 분말-가스분무 Ni계 벌크 비정질 복합분말의 방전플라즈마 소결에 관한 연구)

  • Kim, Jin-Chun;Kim, Yong-Jin;Kim, Byoung-Kee;Kim, Ji-Soon
    • Journal of Powder Materials
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    • v.13 no.5 s.58
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    • pp.351-359
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    • 2006
  • Ni based($Ni_{57}Zr_{20}Ti_{18}Si_2Sn_3$) bulk metallic glass(BMG) powders were produced by a gas atomization process, and ductile Cu powders were mixed using a spray drying process. The Ni-based amorphous powder and Cu mixed Ni composite powders were compacted by a spark plasma sintering (SPS) processes into cylindrical shape. The relative density varied with the used SPS mold materials such as graphite, hardened steel and WC-Co hard metal. The relative density increased from 87% to 98% when the sintering temperature increased up to $460^{\circ}C$ in the WC-Co hard metal mold.

Magnetism of Amorphous Bulk $(Sm_{1-x}Pr_x)Fe_2$ Alloys in a Low Magnetic Field (저자장에서 비정질 후막$(Sm_{1-x}Pr_x)Fe_2$의 자성)

  • Kim, Jai-Young
    • Korean Journal of Materials Research
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    • v.5 no.8
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    • pp.913-920
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    • 1995
  • RFe$_2$(R=rare earth) Laves Phase intermetallic compounds are one of the promising materials for magnetostrictive applications, due to large magnetostriction coefficients in the order of 10$^{-3}$ . However, because RFe$_2$intermetallic compounds have large magnetostriction constants as well as large magnetocrystalline anisotropy constants, a large external magnetic field is necessary to reach saturation magnetostriction. Hence researches on giant magnetostriction have been concentrated on producing materials exhibiting a high value of magnetostriction in a low magentic field. The main research trend of the giant magnetostriction to obtain the large value in the low magnetic filed, fortunately as the signs of magnetocrystalline anisotropy constans in RFe$_2$intermetallic compounds alternate with the rare earth metals, has been to substitute the rare earth metal for others and hence to reduce the magnetocrystalline anisotropy energy. In addition, amorphous RFe$_2$alloys have been researched. In this research, both of the methods which are substitution of the rare earth metal and amorphization in RFe$_2$ intermetallic compounds are simultaneously conducted to obtain the large magnetostriction coefficient in the low external magnetic field. Among them, SmFe$_2$and PrFe$_2$are selected, and amorphized in substrate-free bulk state. Magnetism in amorphous bulk (Sm$_{1-x}$ Pr$_{x}$) Fe$_2$alloys is investigated in the low magnetic field.ld.

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Failure Behavior of Laser Cladding Layer used by Fe-based Bulk Metallic Glass (Fe계 벌크 비정질 합금을 이용한 레이저 용접층의 파손 거동)

  • Lim, Byung-Chul;Kim, Dae-Hwan;Park, Sang-Heup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.9
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    • pp.5743-5747
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    • 2015
  • In this study, Fe-based bulk amorphous alloy powder manufactured using gas atomization fabrication was used for laser welding. the fracture behavior of welding layer were analyzed. Tensile test results show that the destruction occurred immediately after the elastic deformation, After plastic deformation of the substrate, the destruction occurred. The actual maximum tensile strength of the welding layer and the substrate are 959.9MPa and 220.4MPa. welding layer were each $485.5{\pm}21$ and $197.4{\pm}14$ to the substrate and the actual microhardness, The welding layer has very high hardness. The welding layer showed a very weak fine acicular structure. The base material was shown in the micro structure appear a coarse grain. SEM observations of the fracture after the tensile test. Fracture morphology of the base metal and the welding layer showed ductile fracture and brittle fracture, respectively.

The study on the cystallization and electrical properties of Ge-Se-Bi system chalcogenide glasses (Ge-Se-Bi chalcogenide glass의 비정질 및 결정화에 따른 전기전도도의 변화)

  • 이명원;강원호;박창만;이기암
    • Electrical & Electronic Materials
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    • v.6 no.2
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    • pp.175-183
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    • 1993
  • Amorphous Semicondyctor로서 Chalcogenide계의 Ge-Se-Bi계 비정질화와 결정화 실험을 통하여 전기전도도를 평가코자 하였다. 시료의 조성범위는 G $e_{15-25}$S $e_{65-85}$B $i_{2.5-15B}$의 범위에서 5N의 Ge, Se, Bi metal분말을 사용하였다. 시료는 석영관에 진공 장입후 용융시켜 비정질화 하였다. 이때 열처리 조건은 1000.deg.C에서 10시간 동안 가열하였으며 급냉 조건은 3834.deg.C/sec로 처리하였다. 비정질 sample의 결정화는 결정핵을 형성 시킨 후 온도 변화 및 시간의 변화를 주면서 결정을 성장시켰으며 이때 B $i_{2}$S $e_{3}$와 GeS $e_{2}$ 결정상을 관찰 할 수 있었다. 박막화는 위의 실험에 사용된 Bulk sample을 사용하여 박막을 제작하였으며 유리화 영역은 Ge 15 at%, Se 70 at% 이상, Bi가 10 at% 이하일 때 비정질화가 용이하였다. Bulk의 경우 Ge를 20 at%로 고정시 Bi의 at% 함량이 증가함에 따라 전기전도도가 증가했으며 Bi가 7.5 at%이상일때 급격한 전도도의 증가를 가져왔다. 박막의 경우엔 Bulk sample보다 Bi의 함량이 증가시 더욱 큰 전도도의 증가를 가져왔다. G $e_{20}$S $e_{77.5}$B $i_{2.5}$ 저성의 결정화 경우 330.deg.C에서 4hr 유지시킨 경우가 가장 양호하였다.다.하였다.다.

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A Study on the Micro Forming of Al-based Superplastic Alloy and Zr-BMG for the Cavity Position (Al5083 초소성 합금과 Zr-BMG의 Cavity 위치에 따른 마이크로 성형연구)

  • Son, S.C.;Park, K.Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.258-262
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    • 2008
  • Micro forming is a suited technology to manufacture very small metallic parts(several $mm{\sim}{\mu}m$). In this study, the micro forming property was studied, using Al5083 superplastic alloy with micro grain, suitable for the micro forming process and Zr-BMG amorphous with pseudo-superplastic phenomena in the supercooled liquid state. Micro forming experiments under stastic load status showed that distortion by slip and spin of the grain system and slip inside the grain was observed in the Al5083 superplastic alloy. In case of Zr-BMG, because there is no grain, the distribution of the forming property was similar to the load distribution between punch and metal.

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Research in Crystalization and Conductivity of Electricity of Ge-Se-Bi System Chalcogenide Glass (Ge-Se-Bi계 칼코게나이드 유리의 비정질 및 결정화에 따른 전기 전도도의 변화)

  • Lee, Myeong-Won;Gang, Won-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.77-81
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    • 1992
  • The purpose of this research was th evaluate conductivity of electricity of Ge-Se-Bi system Chalcogenide glass as a amorphous semiconductor by observing its dissolution and crystallization. In this experiment. Ge-Se-Bi metal powder in the rage of $Ge_{12-25}$, $Se_{65-85}$, $Bi_{2.5-15}$ was used as the sample ore. The ore was. put into a vaccous quartz tube and then melted. The condition of heat treatment was to dispose it to $1000^{\circ}C$ heat for 10 hours and then rapidly quenched it at $3834^{\circ}C$/see. The crystallization of the fused sample ripened as the change of temperature and time, after the crystal core was formell. At that time it was possible to observe the state that $Bi_2Se_3$ and $GeSe_2$ were crystallized. In the experiment of making memberance, the memberance was produced by using the previously experimented bulk sample. And decrystalization was well progressed when Ge was over 15 at %, Se was over 70 at %, and Bi was under 10 at%. As for bulk. when Ge was fixed to 20 at %, the conducting of electricity was increased as Bi gained at %. In the case of memberance, the conductivity was much more increased than that of bulk sample as the increase of at the increase of at % of Bi. In the experiment on $Ge_{20}$, $Se_{77.5}$ and $Bi_{2.5}$, the crystallization sswas most vigorous when they were kept at $330^{\circ}C$ for 4 hours.

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Enhancement of Magneto-Optical Kerr Effect in Annealed Granular Films of Co-Au and $Co-AlO_x$

  • Abe, Masanori;Takeda, Eishi;Kitamoto, Yoshitaka;Shirasaki, Fumio;Todoroki, Norikazu;Gorodetzky, Gad;Ohnuma, Shigehiro;Masumoto, Tasuku;Inoue, Mitsuteru
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.100-102
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    • 2000
  • Co fine particles were dispersed in Au metal and $AlO_x$ amorphous matrices by vacuum evaporation and rf-sputtering, respectively, thus forming granular composite films having chemical compositions of $Co_{0.59}-Au_{0.41}$ and $Co_{0.52}/(AlO_x$)_{0.48}$. The films were annealed at 200~$500^{\circ}C$ to increase the size of the Co particles, from 30$\AA$ to 180$\AA$ in the Au matrix and 40$\AA$ to 180$\AA$ in the $AlO_x$ matrix, as revealed by X-ray diffraction analysis. The Co metal in as-deposited films have saturation magnetization equivalent to that of bulk Co, which is unchanged by the annealing, showing that the Co metal is not oxidized by the annealing. Magneto-optical Kerr rotation measured at $\lambda$=400-900nm for the $Co_{0.59}-Au_{0.41}$ film as deposited is larger than that calculated for the composition. The rotation increases as the film is annealed at $200^{\circ}C$ and $300^{\circ}C$, approaching to that of bulk Co. The Kerr rotation for the $Co_{0.52}-(AlO_x)_{0.48}$ film as deposited is smaller than that calculated for the composition based on Bruggeman effective medium theory. However, the rotation increases much, exceeding the rotation of the bulk Co as annealed at $300^{\circ}C$ and $400^{\circ}C$. As a possible origin of the marked magneto-optical enhancement a weak localization of light in granular structure is suggested.

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Polymers and Inorganics: A Happy Marriage?

  • Wegner Gerhard;Demir Mustafa M.;Faatz Michael;Gorna Katazyrna;Munoz-Espi Rafael;Guillemet Baptiste;Grohn Franziska
    • Macromolecular Research
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    • v.15 no.2
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    • pp.95-99
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    • 2007
  • The most recent developments in two areas: (a) synthesis of inorganic particles with control over size and shape by polymer additives, and (b) synthesis of inorganic-polymer hybrid materials by bulk polymerization of blends of monomers with nanosized crystals are reviewed. The precipitations of inorganics, such as zinc oxide or calcium carbonate, in presence and under the control of bishydrophilic block or comb copolymers, are relevant to the field of Biomineralization. The application of surface modified latex particles, used as controlling agents, and the formation of hybrid crystals in which the latex is embedded in otherwise perfect crystals, are discussed. The formation of nano sized spheres of amorphous calcium carbonate, stabilized by surfactant-like polymers, is also discussed. Another method for the preparation of nanosized inorganic functional particles is the controlled pyrolysis of metal salt complexes of poly(acrylic acid), as demonstrated by the syntheses of lithium cobalt oxide and zinc/magnesium oxide. Bulk polymerization of methyl methacrylate blends, with for example, nanosized zinc oxide, revealed that the mechanisms of tree radical polymerization respond to the presence of these particles. The termination by radical-radical interaction and the gel effect are suppressed in favor of degenerative transfer, resulting in a polymer with enhanced thermal stability. The optical properties of the resulting polymer-particle blends are addressed based on the basic discussion of the miscibility of polymers and nanosized particles.

Analysis and Mechanical Behavior of Coating Layer in Metallic Glass Matrix Composite (비정질 기지 복합재 코팅층의 미세조직 분석 및 기계적 거동)

  • Jang, Beom Taek;Yi, Seong Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.6
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    • pp.629-636
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    • 2014
  • For surface modification, bulk metallic glass coatings were fabricated using metallic glass powder and a mixture of a self-fluxing alloy or/and hard metal alloys with a heat-resisting property using a high velocity oxy-fuel coating thermal spraying process. Microstructural analyses and mechanical tests were carried out using X-ray diffraction, a scanning electron microscope, an atomic force microscope, a three-dimensional optical profiler, and nanoindenation. As a result, the monolithic metallic glass coating was found to consist of solid particle and lamellae regions that included many pores. Second phase-reinforced composite coatings with a self-fluxing alloy or/and hard metal alloy additives were employed with in-situ $Cr_2Ni_3$ precipitate or/and ex-situ WC particles in an amorphous matrix. The mechanical behaviors of the solid particles and lamella regions showed large hardness and elastic modulus differences. The mechanical properties of the particle regions in the metallic glass composite coatings were superior to those of the lamellae regions in the monolithic metallic glass coatings, but indicated similar trends in matrix region of all the coating layers.