• 한국대기환경학회지
• /
• 제15권3호
• /
• pp.327-333
• /
• 1999

Determination of chloride ion in concentrated NaOH solution by capillary electrophoresis has been studied. The analysis was performed by indirect UV absorption detection using chromate buffer at 254nm. The matrix effect of the sample has been observed so that the sensitivity in strong NaOH solutaion has decreased up to 10% of that in distilled water. The pH effect of the sample on the sensitivity of CE peaks has been investigated. The method for increasing the sensitivity have been investigated and the optimum pH and concentration of the buffer were 7.5 and 10mM, respectively. A cationic surfactant cetyltrimethylammonium bromide(CTAB), was added to a buffer solution in order to reverse the electroosmotic flow(EOF) in the capillary. This results in a short analysis time and better peak shapes. Using this optimum condition, the determination of chloride ion in real environmental sample has been performed, which is captured in strong NaOH absorbent prepared for absorbing gas from chimney. The standard addition method has been applied for the quantitative analysis, and it was obtained the good reproducibility.

• 대한화학회지
• /
• 제57권5호
• /
• pp.533-539
• /
• 2013

변전위법과 전기화학 임피던스 측정법을 이용하여 borate 완충용액에서 니켈 회전원판전극의 전기화학적 부식과 부동화를 연구하였다. Tafel 기울기, 임피던스, 회전원판전극의 회전속도, 그리고 부식전위와 부식전류의 pH 의존성으로부터 니켈의 부식과 부동화 반응 메커니즘과 환원반응에서의 수소 발생 반응구조를 제안하였다. EIS data로부터 등가회로를 제안하였으며 산화반응의 영역별로 전기화학적 변수들을 측정하였다. 부동화 반응에 의하여 생성된 $Ni(OH)_2$ 산화피막은 전기장의 영향을 받는 탈수반응에 의해 NiO로 전환되는 것으로 보인다.

• Journal of Pharmaceutical Investigation
• /
• 제22권3호
• /
• pp.211-217
• /
• 1992

Stabilization of liposomes against degradation by bile salts has been investigated in order to develop a liposomal model system for oral drug delivery. Two polysaccharides, amylopectin (AP) and chitin (CT), were employed to coat both empty liposomes and bromthymol blue (BTB)-encapsulated liposomes by adsorption-coating techniques. Turbidity changes and BTB-release characteristics in pH 5.6 buffer solutions with or without bile salts, sodium cholate and sodium glycocholate, were observed to compare the differences between uncoated liposomes and polysaccharide-coated liposomes. Initial turbidities of both uncoated and polysaccharide-coated liposomes in buffer solution were kept constant within 3% range during 4 hours of experiments. But they were decreased in a different manner in bile salts-containing buffer solutions, showing 10% or less decrease for polysaccharide-coated liposomes and 25% or more decrease for uncoated liposomes. BTB release from uncoated liposomes has been greatly increased upto 90% after 4 hours in bile salts-containing buffer solution, which is a clue for breakdown of liposomal vesicles. However, polysaccharide-coated liposomes showed the controlled-release pattern which is proportional to square-root of time, followed by around 50% release for the same time period. Consequently, it is possible to conclude that these polysaccharide-coated liposomes might be an available system for oral delivery of a drug which is unstable in gut environment.

• 대한화학회지
• /
• 제16권3호
• /
• pp.149-156
• /
• 1972

메타놀, N,N-디메칠포름아미드 및 아세토니트릴 속에서 유리전극의 pH 응답성을 여러가지 pH의 완충용액으로 시험한 바 전극을 물속에 보관하는 것보다 측정하고저 하는 용매속에 보관하는 것이 더 빨리 전위가 안정되었다. 같은 용매에서 용액의 염기성에 비례하여 응답속도가 느리고 강염기성 용액에서는 안정한 전위를 얻기 어려웠다. 산성용액에서의 pH 응답성은 보다 빠르나 같은 용액의 pH 측정에서도 전극의 사용한 이력에 따라 응답성과 측정치에 차이가 생겼다.

• 대한화학회지
• /
• 제6권1호
• /
• pp.29-31
• /
• 1962

電壓條件 永動時間 및 支持電解質溶液의 pH가 Al ion의 paper electrophoresis에 미치는 影響을 closed horizontal type의 泳動裝置를 써서 Michaelis buffer soln.으로 飽和시킨 paper strip에서 實驗的으로 檢討하였다. 그 結果 Al ion에 가장 適合한 pH, 電壓 및 泳動時間을 決定하였으며 pH=2.38에서 Al ion의 mobility는 $(1.004{\pm}0.0020){\times}10^{-4}\;cm^2\;sec^{-1}\;volt^{-1},\;Al(NO_3)_3\;soln.$의 isoelectric point는 pH=3.23 임을 알았다.

• 정보과학회 논문지
• /
• 제43권3호
• /
• pp.327-335
• /
• 2016

본 논문에서는 실감교류 멀티미디어 서비스에 적합한 버퍼 관리 방안을 제안한다. 수신 버퍼 크기가 왕복 시간 추정에 따라 달라질 수 있도록 전형적인 지연 최적화 환경을 고려한다. 이러한 환경에서, 버퍼 크기 단축 시 버퍼 내에 I/P/B 프레임을 드롭하는 경우 발생할 수 있는 정보 손실을 최소화하기 위한 최적화 기법을 제안한다. 근사 해를 찾기 위해 동적 프로그래밍을 이용하는 Knapsack Problem으로 문제를 모델링한다. 제안된 기법은 기존의 버퍼 관리 기법과 비교된다. 시뮬레이션 연구를 통해, 제안하는 접근 방식은 비디오 품질에 중요한 PSNR을 증가시킬 수 있음을 확인하였다.

• Biotechnology and Bioprocess Engineering:BBE
• /
• 제6권1호
• /
• pp.37-41
• /
• 2001

HPLC separation of ionic samples tends to be more complicated and difficult to understand than that of non-ionic compounds. On the other hand, band spacing is much more easily manipulated for ionic than for neutral samples. Ion-suppression RP-HPLC method was used with organic modifier and aqueous buffer solution. In this work, five mononucleotides of cytidine-5-monophosphate (5-CMP) disodium salt, uridine-5-monophosphate disodium salt (5-UMP), guanosine-5-monophosphate disodium salt (5-GMP), inosine-5-monophosphate disodium salt (5-IMP), and adenosine-5-monophosphate disodium salt (5-AMP) were examined. Acetic acid and sodium phosphate were used as buffers, and methanol as an organic modifier. A new relationship between the retention factor and the buffer concentration at a fixed modifier content (5% of methanol) could be expressed by following: K = (k(sub)-1 + k(sub)0 (k(sub)B/k(sub)S)/(1 + (k(sub)B/k(sub)S) C(sub)B(sup)a), where C(sub)B was the concentration of buffer. Using this relationship, the calculated values closely matched the experimental data. The derived relationship showed that as the buffer concentration increased, the retention factor approached a certain value, and this was buffer dependent.

• Restorative Dentistry and Endodontics
• /
• 제18권2호
• /
• pp.277-290
• /
• 1993

Dental caries is considered to be caused by demineralization by organic acid produced by microorganism. But the formation of subsurface lesion in initial caries make it diffcult to explain by simple demineralization. This study is carried out on the basis of thermodynamic concept proposed by Margolis and Moreno. The purpose of this study is to evaluate the effects of acid concentration and pH of lactate buffer system on the artificial caries lesion progress. 160 teeth without any crack, defect or opaque enamel were used and coated with nail varnish except the window ($2{\times}3$ mm). Under the constant degree of saturation(D.S.). The teeth were divided into 8 groups according to acid concentration(10mM, 25mM, 50mM, 100mM) and pH(4.3, 5.0, 6.0). Each group was immersed in buffer solution for 3, 6, 9, 18 days under controlled temperature($25^{\circ}C$). After cutting through the window and grinding, the specimens, 100-150 um in thickness, were imbibed in water or air and examined using polarilizing microscope. The depth of the surface and subsurface surface lesion were measured. 1. In the constant pH and D. S. value, the subsurface lesion progresses more rapidly as the concentration of lactic acid increases. (0.01, 0.025, 0.05, 0.1) 2. In the constant acid concentration and DS value, the subsurface lesion progresses more slowly as the pH increases. (4.3, 5.0, 5.5, 6.0) 3. The width of surface lesion seems to be constant independant of pH and acid concentration.

• 약학회지
• /
• 제30권5호
• /
• pp.228-231
• /
• 1986

The effect of temperature and pH on the degrdation of minoxidil in the aqueous solution was investigated and the stability of pharmaceutical preparation for solution was also studied. The degradation of minoxidil in the aqueous solution was first order type reaction and the rate constant at $20^{\circ}C$ in pH 7.0 phosphate buffer solution was 9.464${\times]10^{-3} day^{-1}$ and calculated activation energy was 11.7 kcal/mol. The degradation of minoxidil was acid-base catalytic reaction and the most stable range of pH was about 5.0. The liquid pharmaceutical preparation was very stable in 3 months.

• 대한전자공학회논문지TC
• /
• 제40권10호
• /
• pp.95-102
• /
• 2003

광 전송 네트워크의 스위칭 기술에서 자원 충돌 문제를 해결하기 위한 방법으로 버퍼링은 중요한 문제중 하나이다. 본 논문은 가변길이 광 패킷 스위칭에 있어서 Fiber Delay Line(FDL)을 사용한 광 버퍼의 dimensioning과 패킷의 손실률에 대하여 연구하였다. 우선 단단(single-stage) FDL 버퍼에서의 granularity와 버퍼 손실에 대한 관계를 고찰하고 간단한 구조의 다단(multi-stage) FDL 버퍼 구조를 제안하였다. 다단 FDL 버퍼는 구현 기술이나 경제성의 측면에서 현 시점에서는 실용성이 높지 않지만 본 논문에서는 미래에 실용화가 가능할 것이라는 가정 하에 다단 FDL 버퍼 구조들을 제안한다. 제안한 FDL 버퍼 구조에서 각 스테이지에 사용되는 지연 및 패스 라인의 소요량을 시뮬레이션을 통해 고찰하고 그 사용율에 근거하여 multi-stage FDL 버퍼를 dimensioning하였다. 또한 보다 실질적인 구조의 다단(multi-stage) FDL 버퍼를 제안하고 그 적합성을 버퍼 크기와 패킷 손실율의 관계를 통하여 연구하였다.