• Title/Summary/Keyword: Bromobenzenesulfonates

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Synthesis of Neopentyl Biphenylsulfonates Using the Suzuki-Miyaura Reaction

  • Cho, Chul-Hee;Kim, Chul-Bae;Sun, Myung-Chul;Park, Kwang-Yong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1632-1636
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    • 2003
  • Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.