• 한국환경보건학회지
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• 제44권3호
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• pp.244-249
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• 2018

Objectives: The purpose of this study was the investigation of bromide and bromate in drinking water of water supply plants, mineral springs and small water supply system located in northern area of Gyeonggi province. Methods: Analytical method was based on EPA 326.0 to use Postcolumn reaction (PCR). The instrument was 887 professional UV/VIS detector IC manufactured in Metrohm. Results: Bromate was detected at $0.5{\sim}2.4{\mu}g/L$ in tap water from 5 water supply plants. These plants were used as disinfection method for sodium hypochlorite and on-site chlorine that causes generate bromate as a by products even if not used ozone. Conclusions: The bromate was detected up to $2.5{\mu}g/Lin$ drinking water in northern Gyeonggi area that showed within $10{\mu}g/L$ for standard of tap water. However, the continuous monitoring of bromate is necessary in drinking water.

• 상하수도학회지
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• 제29권5호
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• pp.575-581
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• 2015

Although disinfection in drinking water treatment plants provides a safer water supply by inactivating pathogenic microorganisms, harmful disinfection by-products may be formed. In this study, the disinfectant, chlorine, was produced on-site from the electrolysis of salt (NaCl), and the by-products of the disinfection process, bromate and chlorate, were analyzed. The provisional guideline levels for bromate and chlorate in drinking water are $10{\mu}g/L$ and $700{\mu}g/L$, in Korea, respectively. Bromide salt was detected at concentrations ranging from 6.0 ~ 622 mg/kg. Bromate and chlorate were detected at concentrations ranging from non-detect (ND) ~ 45.3mg/L and 40.5 ~ 1,202 mg/L, respectively. When comparing the bromide concentration in the salt to the bromate concentration in the chlorine produced by salt electrolysis, the correlation of bromide to bromate concentration was 0.870 (active chlorine concentration from on-site production: 0.6-0.8%, n=40). The correlation of bromate concentration in the chlorine produced to that in the treated water was 0.866.

• 대한환경공학회지
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• 제28권2호
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• pp.178-182
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• 2006

오존으로 상수처리시 생성되는 소독부산물로써 독성이 강한 브롬산염을 철, 구리, 은 첨착활성탄을 이용하여 제거할 목적으로 회분식과 연속식으로 실험하였다. 활성탄 주입량별 브롬산염 제거 실험에서 각각의 활성탄을 0.1, 0.3, 0.5, 1.0 g씩 주입하여 240분 반응시킨 결과 브롬산염의 제거량은 주입량에 비례하였다. 그리고 산 처리한 활성탄을 사용할 때에는 브롬산염 제거 효율이 약 20%정도 증대되었다. 철, 구리, 은 첨착활성탄은 일반 활성탄보다 약 $30{\sim}50%$ 정도 제거 효율이 좋았으며 특히 철 첨착활성탄은 브롬산염을 약 92%제거하였다. 일반 활성탄을 이용하여 브롬산염을 제거하였을 경우 약 $0.02{\sim}0.45mg\;{BrO_3}^-/g$ AC이였지만 철, 구리, 은 첨착활성탄은 약 $0.9{\sim}1.5mg\;{BrO_3}^-/g$이었다. 연속식 칼럼 반응에서 브롬산염 유입량을 $15.6{\sim}46.8mL/min$으로 변화시켜 EBCT를 1, 2, 3 분으로 실험한 결과 96, 180, 252 시간에서 파과 현상을 보였다.

• 한국물환경학회지
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• 제22권6호
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• pp.1137-1143
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• 2006

In this study we investigated the removal characteristics of NOM and bromate formation characteristics in SOMT reactor. The system was recently developed as a novel ozone reactor and installed in SJ pilot plant. DOC values were decreased within 3% after treatment of 0.5~2.0 mg/L ozone dosage in SOMT reactor while the $UV_{254}$ value was 69% decreased at 2.0 mg/L ozone dosage. The composition of NOM was analysed by LC-OCD (Organic Cabon Detector) after ozone treatment in SOMT reactor to elucidate the variation of NOM character. Polysaccharide (more than 20,000 g/mol) fraction of NOM was decomposed while building blocks (350~500 g/mol) and neutral (less than 350 g/mol) fraction increased. Spiked bromide reacted with 0.5~2.0 mg/L ozone dosage in the SOMT reactor. The bromate formation was proportional to the ozone dosage ($R^2=0.978$) but not proportional to reaction time. The maximum concentration of formated bromate was not exceeded to 10% of spiked bromide concentration.

• 대한임상독성학회지
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• 제3권2호
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• pp.119-121
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• 2005

Sodium bromate or potassium bromate has been used as hair cold neutralizer. Sodium bromate intoxications occurred in children incidentally early days of marketing, but recently in adult suicidally. This chemical intoxication result in renal failure, ototoxicity, neurotoxicity, hemolytic anemia and so on. We experienced a 39-year-old woman of hairdresser with non-oliguric acute renal failure after ingestion hair neutralizer 500 ml. She received hemodialysis 3 times and discharged without complication on 8th admission days.

• 대한환경공학회지
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• 제31권9호
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• pp.747-752
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• 2009

본 연구에서는 다양한 재질의 입상활성탄들을 이용하여 연속흡착실험에서 $BrO_3\;^-$의 파과특성을 조사하였다. 활성탄 재질별 파과시점은 석탄계 재질의 활성탄들이 가장 늦게 파과에 도달하였으며, 다음으로 야자계와 목탄계 재질의 활성탄으 로 나타났다. 활성탄 g당 $BrO_3\;^-$에 대한 최대 흡착량(X/M)은 석탄계 재질의 활성탄들이 각각 1334.5 ${\mu}g$/g 및 798.2 ${\mu}g$/g으로 가장 컸으며, 야자계 668.6 ${\mu}g$/g, 목탄계 156.8 ${\mu}g$/g으로 나타났고, 석탄계 활성탄들이 야자계와 목탄계에 비하여 최대 흡착량이 약 2.0배~8.5배 정도 큰 것으로 조사되었다. $BrO_3\;^-$에 대한 CUR은 석탄계 재질의 활성탄들이 각각 0.19 g/day과 0.25 g/day, 야자계와 목탄계가 각각 0.33 g/day과 0.71 g/day로 나타났다. 활성탄의 흡착용량을 나타내는 k값의 경우 석탄계 재질의 활성탄들이 각각 121.3과 76.7로 나타나 야자계와 목탄계의 43.3과 14.6에 비하여 석탄계 활성탄들이 월등히 높은 k값을 나타내어 다른 재질의 활성탄에 비하여 $BrO_3\;^-$ 흡착용량이 큰 것으로 조사되었다.

• 분석과학
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• 제24권5호
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• pp.401-405
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• 2011

본 연구는 수용액 중의 발암물질로 규제되고 있는 브롬산 이온($BrO_3^-$)을 제거하는 방법에 관한 것이다. 브롬산 이온은 먹는 물의 정수 과정 중 브롬 이온의 존재 하에 오존 처리과정에서 생성되는 물질이다. 본 방법은 별다른 물리적 화학적 변화의 과정이 필요하지 않고, 활성알루미나를 이용하여 효과적으로 제거할 수 있어 먹는 물 등의 정수에도 유용하게 적용될 수 있다. 브롬산 이온 500 ${\mu}g$/L 농도의 용액을 표면 개질된 산성 활성알루미나를 사용하여 1~2 분 내에 95% 이상 제거하는 효과를 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.267-270
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• 2004

The bromate-1,4-cyclohexanedione-ferroin oscillating reactions are uncovered to support two types of wave activities, in which spontaneous formation of circular waves has been achieved after the disappearance of initial waves. The induction period of the revival wave is typically above 10 hours and its dependence on the initial concentrations of reactants is qualitatively different from that of initial waves. In addition to their differences in propagating speed and wavelength, the initial waves and the revival patterns have different colors, suggesting that different reaction mechanisms are involved in the formation of these spatiotemporal behaviors. Our experiments further show that the addition of hydroquinone to the reacting system can significantly shorten the induction time of the revival wave, which implicates that hydroquinone is not only a product in the bromate-1,4-cyclohexanedione-ferroin oscillating reaction but also plays a critical role in the following reactions.

• 대한화학회지
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• 제15권4호
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• pp.183-189
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• 1971

Stoichiometry of hydrazine-bromate reaction has been studied in acid media of varying compositions, elucidating the effects of bromide and chloride ions in sulfuric acid, perchloric acid, hydrochloric acid, and hydrobromic acid at varying concentrations of hydrogen ion and cupric ion. The study shows that the number of red-ox equivalent consumed by one mole of hydrazine becomes practically 4.00 if the concentrations of bromide and hydrogen ions are kept higher than 0.1M and 6M, respectively. The presence of copper tends to reduce the bromate consumption by hydrazine in an irregular manner, but such an effect becomes unimportant if the concentrations of bromide and hydrogen ions are kept sufficiently high.

• 분석과학
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• 제12권2호
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• pp.99-104
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• 1999

자외선검출법과 이온크로마토그래피를 이용하여 소금물 중에 함유하는 몇 가지 음이온의 분리정량에 대하여 검토하였다. 분리관은 음이온교환수지(Dionex, AS7)를 사용하였고 용리액으로서는 sodium chloride/sodium phosphate 완충용액을 사용하였다. 단계적용리법을 적용하므로서 최적분리가 가능하였으며 8가지 음이온(iodate, bromate, nitrite, bromide, nitrate, chromate, iodide와 thiocyanate)이 40분내에 분리되었다. 여러 가지 농도의 NaCl용액(0.0 M-1.0 M)속에 존재하는 음이온들의 거동을 살펴보았다. NaCl의 농도가 진할수록 bromate, nitrite, bromide와 nitrate의 피크의 모양이 점점 넓어졌으나 chromate, iodide와 thiocyanate는 1.0 M NaCl 용액의 농도까지 피크모양이 거의 변하지 않았다. 또한 여러 가지 농도의 NaCl용액에서 음이온들의 검량곡선은 좋은 직선성을 보여주었으며, $50{\mu}L$ 시료용액에서 검출한계는 $10-720{\mu}g/L$ 이었다. 바닷물중의 bromide, nitrate와 iodide의 측정에 이방법을 적용하였다.