• 자원환경지질
• /
• 제45권2호
• /
• pp.181-188
• /
• 2012

일라이트에서 적층방식을 달리하여 나타나는 폴리타입은 대부분 1M과 $2M_1$이며, 적층 Disordering에 따른 $1M_d$ 또한 흔히 관찰된다. 본 해설에서는 일라이트의 폴리타입을 구분하고 정량적으로 해석할 수 있는 광물학적 이론적 근거와 방법을 소개하고, 소규모 열수환경에 준하는 단층대 내 생성시기 및 조건을 달리하는 일라이트 폴리타입 혼합물에의 적용을 통한 단층 활동 및 재활동연대 결정에의 활용 가능성을 검토하였다. 단층연대해석의 정확도와 신빙도를 높이기 위해서는 단층암 대상시료 내 일라이트 폴리타입의 생성환경에 대한 정보, 동정 및 광물학적 특성에 대한 규명이 이루어져야 한다. 또한 WILDFIRE(C)시뮬레이션을 이용한 정량분석에서, $1M_d$ 폴리타입의 Disordering 정도 및 I/S 광물의 팽창도에 기인한 (hkl) 회절선들의 Broadening 효과 등 일라이트 폴리타입 정량분석법의 오차요인을 최소화시키는 하기 방법을 고려해야 할 것이다.

• 한국진공학회지
• /
• 제21권5호
• /
• pp.225-232
• /
• 2012

수명 측정법과 동시 계수 도플러 넓어짐 양전자 소멸 분광법으로 p형과 n형 실리콘 시료에 3.98 MeV 에너지를 가진 $0.0{\sim}20.0{\times}10^{13}\;protons/cm^2$ 양성자 빔 조사에 의한 결함을 측정하여 실리콘 결함 특성에 대하여 조사하였다. 양전자와 전자의 쌍소멸로 발생하는 감마선 스펙트럼의 전자 밀도 에너지를 수리적 해석 방법인 S-변수와 열린 부피 결함에 대한 측정법으로서 양전자 수명 ${\tau}_1$과 ${\tau}_2$, 이에 따른 밀도 $I_1$과 $I_2$를 사용하여, 시료의 구조 변화를 측정하였다. 본 연구에서 측정된 S-변수와 양전자 수명은 시료에 조사된 양성자 조사량의 변화에 따라 결함이 증가하였으며, 양전자 수명 측정과 같은 경향을 보여준다. SRIM의 결과로써, 양성자 조사 에너지에 따른 Bragg 피크 때문에 양성자는 시료의 특정 깊이에 주로 결함을 형성하여 시료 전체에는 결함으로 잘 나타나지 않기 때문이다. 빔의 조사량에 따른 결함의 영향이 더 큰 것으로 나타났다.

• BMB Reports
• /
• 제34권5호
• /
• pp.446-451
• /
• 2001

The interaction of cytochrome c with binary phospholipid mixtures was investigated by solid-state $^2H$- and $^{31}P$-NMR. To examine the effect of the interaction on the glycerol backbones, the glycerol moieties of phosphatidylcholine (PC), and cardioliph (CL) were specifically deuterated. On the binding of cytochrome c to the binary mixed bilayers, no changes in the quadrupole splittings of each of the components were observed for the PC/PG, PE/CL and PE/PG liposomes. In contrast, the splittings of CL decreased on binging of protein to the PC/CL liposomes, although those of PC did not change at all. This showed that cytochrome c specifically interacts with CL in PC/CL bilayers, and penetrates into the lipid bilayer to some extent so as to perturb the dynamic structure of the glycerol backbone. This is distinctly different from the mode of interaction of cytochrome c with other binary mixed bilayers. In the $^{31}P$-NMR spectra, line broadening and a decrease of the chemical shift anisotropy were observed on the binding of cytochrome c for all binary mixed bilayers that were examined. These changes were more significant for the PC/CL bilayers. Furthermore, the line broadening is more significant for PC than for CL in PC/CL bilayers. Therefore, it can be concluded that with the polar head groups, not only CL but also PC are involved in the interaction with cytochrome c.

• Biomedical Engineering Letters
• /
• 제8권4호
• /
• pp.383-392
• /
• 2018

For prompt gamma ray imaging for biomedical applications and environmental radiation monitoring, we propose herein a multiple-scattering Compton camera (MSCC). MSCC consists of three or more semiconductor layers with good energy resolution, and has potential for simultaneous detection and differentiation of multiple radio-isotopes based on the measured energies, as well as three-dimensional (3D) imaging of the radio-isotope distribution. In this study, we developed an analytic simulator and a 3D image generator for a MSCC, including the physical models of the radiation source emission and detection processes that can be utilized for geometry and performance prediction prior to the construction of a real system. The analytic simulator for a MSCC records coincidence detections of successive interactions in multiple detector layers. In the successive interaction processes, the emission direction of the incident gamma ray, the scattering angle, and the changed traveling path after the Compton scattering interaction in each detector, were determined by a conical surface uniform random number generator (RNG), and by a Klein-Nishina RNG. The 3D image generator has two functions: the recovery of the initial source energy spectrum and the 3D spatial distribution of the source. We evaluated the analytic simulator and image generator with two different energetic point radiation sources (Cs-137 and Co-60) and with an MSCC comprising three detector layers. The recovered initial energies of the incident radiations were well differentiated from the generated MSCC events. Correspondingly, we could obtain a multi-tracer image that combined the two differentiated images. The developed analytic simulator in this study emulated the randomness of the detection process of a multiple-scattering Compton camera, including the inherent degradation factors of the detectors, such as the limited spatial and energy resolutions. The Doppler-broadening effect owing to the momentum distribution of electrons in Compton scattering was not considered in the detection process because most interested isotopes for biomedical and environmental applications have high energies that are less sensitive to Doppler broadening. The analytic simulator and image generator for MSCC can be utilized to determine the optimal geometrical parameters, such as the distances between detectors and detector size, thus affecting the imaging performance of the Compton camera prior to the development of a real system.

• Nuclear Engineering and Technology
• /
• 제56권4호
• /
• pp.1165-1203
• /
• 2024

In the paper we validate theoretical models of the pulse against experimental data from the Jozef Stefan Institute TRIGA Mark II research reactor. Data from all pulse experiments since 1991 have been collected, analysed and are publicly available. This paper summarizes the validation study, which is focused on the comparison between experimental values, theoretical predictions (Fuchs-Hansen and Nordheim-Fuchs models) and calculation using computational program Improved Pulse Model. The results show that the theoretical models predicts higher maximum power but lower total released energy, full width at half maximum and the time when the maximum power is reached is shorter, compared to Improved Pulse Model. We evaluate the uncertainties in pulse physical parameters (maximum power, total released energy and full width at half maximum) due to uncertainties in reactor physical parameters (inserted reactivity, delayed neutron fraction, prompt neutron lifetime and effective temperature reactivity coefficient of fuel). It is found that taking into account overestimated correlation of reactor physical parameters does not significantly affect the estimated uncertainties of pulse physical parameters. The relative uncertainties of pulse physical parameters decrease with increasing inserted reactivity. If all reactor physical parameters feature an uncorrelated uncertainty of 10 % the estimated total uncertainty in peak pulse power at 3 $ inserted reactivity is 59 %, where significant contributions come from uncertainties in prompt neutron lifetime and effective temperature reactivity coefficient of fuel. In addition we analyse contribution of two physical mechanisms (Doppler broadening of resonances and neutron spectrum shift) that contribute to the temperature reactivity coefficient of fuel. The Doppler effect contributes around 30 %-15 % while the rest is due to the thermal spectrum hardening for a temperature range between 300 K and 800 K.

• 한국세라믹학회지
• /
• 제32권2호
• /
• pp.163-170
• /
• 1995

Sample size effect on ferromagnetic resonance (FMR) in polycrystalline MgFe2O4 has been investigated. The signal intensity (SI), resonance field (Hres) and line width (ΔH) were found to increase proportionally to r3 with the increase of sample radius. The r3-depencence of SI means the complete penetration of rf-field into the sample, and the broadening of ΔH due to the sample size appears to be closely related to the amount of scattering sources like pores. Meanwhile, the values of Hres (0) and ΔH (0) obtained by extrapolating the data of Hres (r) and ΔH (r) measured at several sizes to r=0, were in good agreement with those calculated using the Schlomann's equations for internal field and ΔH, respectively. This result indicates that the discrepancy between the measured FMR parameters and those calculated by Schlomann's equation could be ascribed to the effect of sample size. Thus it is suggested that the size effect on FMR should be removed for the analysis of the FMR parameters. Meanwhile, our result for the size dependance of ΔH was found to be contradictory to those reported by Dionne, where ΔH 1/r at a given surface roughness. This discrepancy appears to arise from the difference in the definition of reading the line width.

• 유통과학연구
• /
• 제18권7호
• /
• pp.49-62
• /
• 2020

Purpose: The purpose of this study is to examine under what conditions suggestion programs conducted by organizations actually increase individual perception of their work effectiveness. Specifically, this study looks into the effects of cooperation perception and relational demography of employee on work effectiveness of suggestion programs. It does this by focusing on the interaction effect of organizational commitment. Research design, data and methodology: Data was collected from 1,872 participants who took part in the suggestion program of HCCP 6th DATA. This data was subjected to multiple regression analysis. Results: a) higher employee cooperation perception enhances work effectiveness of suggestion program, but relational difference of knowledge diversity between team members has no effect on work efficiency; b) Positive effect of cooperation perception, and difference in education level on work effectiveness become greater as commitment increases. However, organizational commitment decreases the positive effect of difference in organizational tenure on work effectiveness by suggestion program. Conclusion: The results point to the importance of broadening the current conceptual models of employee work effectiveness of suggestion program to include relational demography, as well as the utility of conducting additional cross-level research on suggestion programs.

• Bulletin of the Korean Chemical Society
• /
• 제25권10호
• /
• pp.1559-1563
• /
• 2004

The topoisomerase II poisoning effect of certain protoberberine alkaloids is associated with anti-cancer activity. Structure-activity relationships of protoberberine analogues substituted on the ring protons reveal that substitution at the C19 position is an important determinant of biological activity. In this study, the effects of substituent modification at the C19 position on the interaction of protoberberines with DNA are determined using UV and NMR spectroscopy. The line broadening effect on aliphatic resonances, chemical shift changes of the imino protons of HP14 upon berberine and berberrubine binding to HP14, and the rate of the exchange process between protoberberine analogs bound indicate that berberrubine binds HP14 more specifically than berberine. In addition, the free HP14 is altered by the substituent at the 19-position. UV spectra of berberrubine have shown a hypochromic effect together with a slight red shift, which are usually regarded as characteristics of DNA intercalation. These results are consistent with our previous report that the berberrubine is partially intercalated with HP14 with molar ratio 1 : 1, whereas a non-specific interaction is predominant between the berberine and HP14.

• Preventive Nutrition and Food Science
• /
• 제3권4호
• /
• pp.320-323
• /
• 1998

Lysozyme was covalentyl conjugated with galactomannan through a amino-carbonyl reaction between the lysine $\varepsilon$-amino groups of lysozyme and the reducing ends of galactomannan at a relative humidity of 79% and 6$0^{\circ}C$. The resulting lysozyme-galactomannan conjugate (LGC) was investigated for its antibacterial activity against Escherichia coli. Lysozyme alone did not exhibit antibacterial activity against E. coli. in contrast , significant bactericidal effect was observed for LGC, depending on the reaction temperature. The degree of conjugation between lysozyme and galactomannan was dependent on the incubation time, which affected the antibacterial efficiency against E. coli. This study demonstrated that the amino-carbonyl reaction between lysozyme and galactomannan could be a potential tool to modify lysozyme toward broadening its antibacterial spectrum to Gram-negative bacteria.

• 한국정보통신학회:학술대회논문집
• /
• 한국해양정보통신학회 2007년도 춘계종합학술대회
• /
• pp.584-587
• /
• 2007

PCS를 비롯하여 WLAN, DMB, W-CDMA, UWB 등의 무선통신 서비스가 증가함에 따라 안테나 동작 대역폭의 광대역화가 더욱 요구된다. 1/4 파장 선형 모노폴 안테나는 구조가 간단하고 전방향성을 갖는 복사특성으로 인하여 가장 널리 사용되는 안테나 중의 하나이다. 모노폴 안테나의 광대역화를 위해서 일반적으로 원통의 직경을 증가시키는 방법을 사용하지만, 평면 모노폴에 적용된 스텝 기법을 적용하여 광대역 특성을 얻을 수 있다. 그러나 스텝 모노폴 자체는 광대역 특성을 나타내지 않으며, 접지면에서도 일정 형태의 스텝 돌출부위가 필요하게 된다. 본 논문에서는 그라운드면의 볼록 계단 구조가 모노폴 안테나의 대역 특성에 미치는 영향을 분석하여 최적의 안테나 급전구조를 도출하고자 한다. 결과의 검증을 위해서 소프트웨어 시물레이션 및 측정결과를 제시한다.