• 제목/요약/키워드: Brillouin spectroscopy

검색결과 11건 처리시간 0.022초

Micro-Brillouin Spectroscopy Applied to the Glass Transition of Anti-inflammatory Egonol

  • Kim, Tae-Hyun;Ko, Jae-Hyeon;Kwon, Eun-Mi;Jun, Jong-Gab
    • Journal of the Optical Society of Korea
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    • 제14권4호
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    • pp.403-408
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    • 2010
  • The acoustic properties of anti-inflammatory egonol were investigated by using micro-Brillouin scattering spectroscopy, by use of a 6-pass tandem Fabry-Perot interferometer and an optical microscope specially modified for spectroscopic purposes. The measured Brillouin spectrum was composed of a central peak centered at zero and a Brillouin doublet arising from the longitudinal acoustic waves, i.e. propagating density fluctuations. For the first time, the glass transition of egonol was identified to be about $5^{\circ}C$ at which the Brillouin peak position and the half width showed abrupt changes. The substantial damping of acoustic phonons of egonol near the glass transition temperature indicated that the contribution of internal relaxation processes such as small-amplitude librations of side chains to the damping of acoustic phonons may be substantial depending on the internal structure of molecules.

Pressure Dependence of Acoustic Properties of Liquid Ethanol by using High-pressure Brillouin Spectroscopy

  • Ko, Jae-Hyeon;Jeong, Min-Seok;Lee, Byoung Wan;Kim, Jae Hyun;Ko, Young Ho;Kim, Kwang Joo;Kim, Tae Hyun;Kojima, Seiji;Ahart, Muhtar
    • 한국광학회지
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    • 제24권5호
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    • pp.279-286
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    • 2013
  • Brillouin spectroscopy has been widely used for the investigation of acoustic properties of condensed matters in the hypersonic region. A high-pressure Brillouin spectrometer was set up by combining a diamond anvil cell and a tandem multi-pass Fabry-Perot interferometer. It was successfully applied to liquid ethanol, and the pressure dependence of the sound velocity, the refractive index and other acoustic properties were derived based on the measurements. The detailed optical setup and experimental procedure are described.

Determination of Birefringence by Brillouin Spectroscopy

  • Chey, Tong-Chull;Lee, Suk-Mock
    • Journal of the Optical Society of Korea
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    • 제2권2호
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    • pp.45-49
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    • 1998
  • We have combined Brillouin scattering experiments and fucdamental optics theory to determine the birefringence of single crystals. Double refraction in anisotropic materials give rise to doublet peaks in Brillouin spectra. With the incident plane orthogonal to the optic axis, the birefrigence of the materials can be determined from one spectrum. We present the Brillouin spectra to confirm this fact for a single crystal $PbMoO_4$.

Measurement of Birefringence with Brillouin Spectroscopy

  • Lee, Suk-Mock;Hwangbo, Chang-Kwon
    • Journal of the Optical Society of Korea
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    • 제5권3호
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    • pp.67-69
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    • 2001
  • An alternative way to determine the birefringence for uniaxial crystals with Brillouin scattering experiments equipped with a Fabry-Perot interferometer is presented. The value of the minimum cavity spacing of the interferometer to observe the birefringence was found, and it is shown that the experimental error of the birefringence could be reduced by increasing the cavity spacing. For a single crystal of $\alpha$-LiIO$_3$, the birefringence was found to be 0.14814$\pm$0.0007 at 514.5 nm.

납이 포함되지 않은 압전 특성의 (Na1/2Bi1/2TiO3)(1-x)-(BaTiO3)x 상전이 거동 연구 (Phase Transition Behaviors of Lead-Free Piezoelectric (Na1/2Bi1/2TiO3)(1-x)-(BaTiO3)x)

  • 이병완;;김정규
    • 세라미스트
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    • 제23권1호
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    • pp.101-109
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    • 2020
  • In this study, the phase transition behaviors of lead-free (Na1/2Bi1/2TiO3)(1-x)-(BaTiO3)x (NBT-BT) are investigated by using Brillouin spectroscopy. The elastic properties, sound velocity and absorption coefficient of NBT-BT are characterized as a function of temperature along different crystallographic axes. The temperature dependences of the elastic constants of NBT-BT near the morphotropic phase boundary are determined for the first time. The unpoled NBT-BT single crystals exhibits the typical relaxor behaviors, presenting broad acoustic and dielectric anomalies. The application of electric field induced discontinuous changes in the elastic properties at ~110℃, which indicates field-induced phase transition occurred. The electric field also changes the dielectric constant from more relaxor-like to ferroelectric-like dielectric behavior.

NEUTRON THREE-AXIS SPECTROMETRY AT THE ADVENT OF 21ST CENTURY

  • Kulda Jiri
    • Nuclear Engineering and Technology
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    • 제38권5호
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    • pp.433-436
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    • 2006
  • The implementation of multiplexing techniques combined with advances in neutron optics make the neutron three-axis spectrometers (TAS) an efficient tool to map inelastic response from single crystals over momentum transfer ranges comparable to the size of a single Brillouin zone. Thanks to recent progress in polarization techniques such experiments can be combined relatively easily with neutron polarization analysis, which does not only provide unambiguous separation of response corresponding to structural and magnetic degrees of freedom, but permits a quantitative analysis of the magnetic response anisotropy, often of crucial importance to test theoretical predictions. In the forthcoming decade we therefore expect a further development of the complementary use, rather than competition, of the reactor-based TAS's with time-of-flight (TOF) instruments for single crystal spectroscopy at the existing (ISIS) as well as at the newly built (SNS, J-PARK) pulsed sources.

각분해 광전자 분광법을 이용한 Pd(111)의 전자구조 연구 (Electronic Structure of Pd(111) using Angle-Resolved Phothemission Spectroscopy)

  • 황도원;강정수;홍재화;정재인;문종호;김건호;이정주;이영백;홍순철;민병일
    • 한국진공학회지
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    • 제5권1호
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    • pp.14-24
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    • 1996
  • We have investigated atomic and electronic structures of a clean Pd(111) surface using low energy electron diffraction (LEED) and angle-resolved photoemission spectroscopy (ARPES). A typical clean LEED pattern with a 3-fold symmetry has been observed, corresponding to that for an fcc (111) surface. ARPES measurements have been performed along the $\Gamma-M,\Gamma-K,\Gamma-M$TEX> symmetry lines, from which the experimental band structure of Pd(111) has been determined. The experimental band structure and work function of Pd(111) surface are found to agree well with the calculated band structure of bulk Pd and the calculated work function of Pd(111), respectively. However, the peak positions in the experimental band structure are located closer to the Fermi level than in the theoretical band structure by 0.1~0.8 eV, depending on the $\kappa$-points in the Brillouin zone. In additin, the experimental band widths are narrower than the theoretical band widths by about 0.5eV. The effects of the localized surface Pd 4d states and the Coulomb interaction between Pd 4d bulk electrons have been discussed as possible origins of such discrepancies between experiment and theory.

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ARPES study of Ultrathin Fe Grown on Cu (001) surface

  • Poornima, L.;Oh, Y.R.;Park, Y.S.;Kim, W.;Kim, C.G.;Hong, J.;Hwang, Chan-Yong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.350-350
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    • 2011
  • The spin structure of Fe over layers on Cu (001), especially in region II is one of the unsolved problem for many years. We study the out - of - plane (OP) Fermi surfaces (FSs) of 7 monolayer Fe/Cu (001) films using angle resolved photo emission spectroscopy (ARPES). Ultrathin Fe was grown on Cu (001) substrate at room temperature and the experimental measurements were carried out at room temperature and low temperature. Fermi surfaces measured about $\frac{1}{4}$ of the Brillouin Zone (BZ) using photon energies ranging from 170 eV to 280 eV. Our results confirmed that ferromagnetic signal at 7 ML Fe on Cu (001) is nearly zero. These results are consistent with our recent x-ray magnetic circular dichroism (XMCD) and surface magneto - optic Kerr effect (SMOKE) experiments. Based on our observations we have made a simple model of this system, which explains all the experimental results.

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Perovskite $Gd_{1-x}Sr_xFeO_{3-y}$ (X = 0.0, 0.5)의 Mossbauer연구 (Mossbauer Studies of Perovskite $Gd_{1-x}Sr_xFeO_{3-y}$ (X = 0.0, 0.5))

  • 엄영랑;김철성;서정철;오영제
    • 한국자기학회지
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    • 제8권2호
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    • pp.67-73
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    • 1998
  • perovskite Gd1-xSrxFeO3-y(x=0.0, 0.5) 시료의 결정학적 및 자기적 성질을 X-ray 회절과 Mossbauer 분광법 및 VSM를 이용하여 연구하였다. 결정 구조는 모두 orthorhormcis 구조를 가지며 Gd0.5Sr0.5FeO3-y의 격자상수는 a0=5.53$\AA$, bo=5.608$\AA$, C0=7.724$\AA$이었다. Gd1-xSrxFeO3-y(x=0.0, 0.05,)의 Mossbauer 실험을 4.2K부터 690K 온도 영역에서 수행하였고 Neel 온도는 GdFeO3 는 690K로 Gd0.5Sr0.5FeO3-y는 515K로 결정 하였다. GdFeO3 시료의 이온 상태는 Fe3+임을 알 수 있었고 Brillouin 함수값S=5/2를 만족하며 팔면체 자리를 나타내고 있다. Mossbauer spectrum과 Mohrdua 분석에 의해 Gd0.5Sr0.5FeO3-y 시료는 Fe3+와 Fe4+이온이 공존하여 존재합을 알았다.

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