• 한국자동차공학회논문집
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• 제11권6호
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• pp.86-92
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• 2003

To analyze the characteristics of ozone formation, measurements of the concentrations of individual exhaust hydrocarbon species have been made under various engine operating parameters in a 2-liter 4-cylinder engine for natural gas and LPG. Tests were performed at constant engine speed, 1800 rpm for two compression ratios of 8.6 and 10.6, with various operating parameters, such as excess air ratio of 1.0~1.6, bmep of 250~800 na and spark timing of BTDC 10~$55^{\circ}$. It was found that the natural gas gave the less ozone formation than LPG in various operating conditions. This was accomplished by reducing the emissions of propylene($C_3H_6$), which has relatively high maximum incremental reactivity factor, and propane($C_3H_8$) that originally has large portion of LPG. In addition, the natural gas show lower values in the specific reactivity and brake specific reactivity. Higher compression ratio of the test engine showed higher non methane HC emissions. However, specific reactivity value decreased since fuel species of HC emissions increase. brake specific reactivity showed almost same values under high bmep, over 500kPa for both fuels. This means that the increase of non methane HC emissions and the decrease of specific reactivity with higher bmep affect each other simultaneously. With advanced spark timing, brake specific reactivity values of LPG were increased while those of natural gas showed almost constant values.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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• pp.183-188
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• 1999

For two engine design parameters; compression ratio and intake swirl ratio, measurement of concentrations of hydrocarbon species has been made as a function of various air-fuel ratio in order to investigate the ozone formation of HC emissions from LPG fuel. Higher compression ratio gave lower SR values due to larger aIkan species and higher BSR values because of larger NMHC generation. Swirl ratio did not affect HC emissions and ozone formation. For ${\lambda}=1.1{\sim}1.2$, higher SR values resulted from the species of aIken which has higher MIRs were highly produced. Leaner mixture showed lower SR values due to the increase of the aIkan which has a lower MIR.

• 한국자동차공학회논문집
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• 제10권3호
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• pp.93-100
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• 2002

For natural gas and LPG fuel, measurements on the concentrations of individual exhaust hydrocarbon species have been made as a function of air-fuel ratio in a 2-liter four-cylinder engine using a gas chromatography. NMHC in addition to the species of HC, other emissions such as CO$_2$, CO and NOx were examined for natural gas and LPG at 1800rpm far two compression ratios (8.6 and 10.6). Fuel conversion efficiencies were also investigated together with emissions to study the effect of engine parameters on the combustion performances in gas engines especially under the lean bum conditions. It was found that CO$_2$ emission decreased with smaller C value of fuel, leaner mixture strength and the higher compression ratio. HC emissions from LPG engine consisted primarily of propane (larger 60%), ethylene and propylene, while main emissions from natural gas were mothane (larger than 60%), ethane, ethylene and propane on the average. The natural gas was proved to give the less ozone formation than LPG fuel. This was accomplished by reducing the emissions of propylene, which has relatively high MIR factor, and propane that originally has large portion of LPG. In addition, natural gas shows a benefit in other emissions (i.e. NMHC,NOx, CO$_2$and CO), SR and BSR values except fuel conversion efficiency.