• Title/Summary/Keyword: Boron compound

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A Study for the Sintering of Boron Carbide ($B_4C$의 소결에 관한 연구)

  • 오정훈;오근호;이종근;김도경;이준근;김종희
    • Journal of the Korean Ceramic Society
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    • v.22 no.1
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    • pp.60-66
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    • 1985
  • Hard shaped bodies are made by sintering a cold-pressed compact of a boron carbide compound which contains a densification aid. Titanium diboride and carbon were used as a densification aid in a range of 1% to 10% by weight. The effects of sintering temperature and additives on linear shrinkage porosity hardness bend strength and microstructure were examined. The initial partical size dependence on the sintered density was also discussed.

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Effectiveness of Regranulized Fused Phosphate Containing Boron and Compound Fused Phosphate on the Growth and Yield of Soybean (대두(大豆)에 대(對)한 함붕소립상용인(含硼素粒狀熔燐) 및 복합비료(複合肥料)의 비효에 관(關)하여)

  • Ha, Ho-Sung;Lee, Yun-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.1
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    • pp.43-50
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    • 1978
  • In order to compare the effectiveness of different phosphorus forms (pulverized as regranulized) and formulars (compound fertilizers) of fused phosphate and to compare the effectiveness of boron from different forms (straight borax, granulized with fused phosphate and included in compound fertilizer), a field experiment was conducted on a relatively fertile upland soil using soybean as a test crop. Results are summarized as following. 1. Yield of soybean was significantly higher in the plots fertilized with P when compared to check plot (no p). However, no significant differences were observed among the different forms or formulars of fused phosphate, indicating that the regranulization or formulation of compound fertilizer did not influence the effectiveness of phosphorus. 2. The application of boron, regardless of its formular, brought about higher B content in plant tissue and higher grain yield. There was a tendency that boron contained in ragranulized fused phosphate was more effective than straight borax. The results also indicated that when boron is to be included in NPK compound fertilizer, its content should be at the least 1.5% as $B_2O_3$. 3. The effectiveness of boron appeared as increased number of pod, higher B, and Ca contents in plant and the amounts of uptake of these elements by soybean. 4. The analysis of soil after the experiment indicated that different forms or formulars of fused phosphate were similarly effective in increasing the available P, Ca, and Mg contents in the soil. 5. Slight increase in available B contents in the experimental plot soils applied with boron fertilizer was observed after the trial.

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The Movement of Boron Compound by Infusion Method and Combination of Injection and Bandage-Wrapping

  • DAMAYANTI, Ratih;SRIBUDIANI, Evi;SOMADONA, Sonia;Djarwanto, Djarwanto;TARMADI, Didi;AMIN, Yusup;YUSUF, Sulaeman;SATITI, Esti Rini;ARSYAD, Wa Ode Muliastuty;SULAEMAN, Rudianda;Syafrinal, Syafrinal;PRAMASARI, Dwi Ajias
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.4
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    • pp.513-526
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    • 2020
  • The existing preservation methods are difficult to be applied to a large dimension log which is needed for making traditional wooden ship 'Jalur' in Riau Province. Novel techniques to provide the use of readily available species to replace traditional species alternative were investigated. These included infusion and a combination of injection and bandage-wrapping methods for preserving living trees of Balam (Macaranga conifera (Rchb.f. & Zoll.) Müll.Arg.) and Bintangor (Calophyllum soulattri Burm.f.). Water-based boron compounds were applied as wood preservatives. In total, 18 discs from the bottom, middle, and top of four trees and two controls were used. Trees undergoing treatment were also used to see how wood anatomical structure might affect the boron penetration. The overall aim was to identify the best method for use in Jalur manufacturing. The results showed that in infused Balam tree where the hose position for the preservative intake was deep (10-15 cm from the bark), no boron compound was observed in the outer sapwood. Combination of injection and bandage-wrapping method gave higher percentage of boron penetration at bottom and middle of Balam tree. However, infused Bintangor showed 100% boron penetration. The larger vessel diameter, the absence of tyloses, and the simple perforation plates in Bintangor wood were likely to have contributed to the higher penetration of boron. The combination of bandage-wrapping and infusion, or alternatively by infusing the living trees close to the bark, and at as low as position in the stem gives better protection when treatments are applied to living trees.

Smoke Generation by Burning Test of Cypress Plates Treated with Boron Compounds (붕소 화합물로 처리된 편백목재의 연소시험에 의한 연기발생)

  • Chung, Yeong-Jin;Jin, Eui
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.670-676
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    • 2018
  • Experiments on combustion gases generation of untreated cypress specimens or treated with boric acid, ammonium pentaborate, and boric acid/ammonium pentaborate additive were carried out. Test specimens were painted three times with 15 wt% boron compound aqueous solutions. After drying, the generation of combustion gas was analyzed using a cone calorimeter (ISO 5660-1). As a result, comparing to untreated specimen, the smoke performance index (SPI) of the specimens treated with the boron compound increased by 1.37 to 2.68 times and the smoke growth index (SGI) decreased by 29.4 to 52.9%. The smoke intensity (SI) of the specimens treated with boron compounds is expected to be 1.16 to 3.92 times lower than that of untreated specimens, resulting in lower smoke and fire hazards. Also, the maximum carbon monoxide ($CO_{peak}$) concentration of specimens treated with boron compounds was 12.7 to 30.9% lower than that of untreated specimens. However, it was measured to produce fatal toxicities from 1.52 to 1.92 times higher than that of permissible exposure limits (PEL) by Occupational Safety and Health Administration (OSHA). The boron compounds played a role in reducing carbon monoxide, but it did not meet the expectation of reduction effect because of the high concentration of carbon monoxide in cypress itself.

Effect of Boron Content and Temperature on Interactions and Electron Transport in BGaN Bulk Ternary Nitride Semiconductors

  • Bouchefra, Yasmina;Sari, Nasr-Eddine Chabane
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.1
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    • pp.7-12
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    • 2017
  • This work takes place in the context of the development of a transport phenomena simulation based on group III nitrides. Gallium and boron nitrides (GaN and BN) are both materials with interesting physical properties; they have a direct band gap and are relatively large compared to other semiconductors. The main objective of this paper is to study the effect of boron content on the electron transport of the ternary compound $B_xGa_{(1-x)}N$ and the effect of the temperature of this alloy at x=50% boron percentage, specifically the piezoelectric, acoustic, and polar optical scatterings as a function of the energy, and the electron energy and drift velocity versus the applied electric field for different boron compositions ($B_xGa_{(1-x)}N$), at various temperatures for $B_{0.5}Ga_{0.5}N$. Monte carlo simulation, was employed and the three valleys of the conduction band (${\Gamma}$, L, X) were considered to be non-parabolic. We focus on the interactions that do not significantly affect the behavior of the electron. Nevertheless, they are introduced to obtain a quantitative description of the electronic dynamics. We find that the form of the velocity-field characteristic changes substantially when the temperature is increased, and a remarkable effect is observed from the boron content in $B_xGa_{(1-x)}N$ alloy and the applied field on the dynamics of holders within the lattice as a result of interaction mechanisms.

Effect of cooling rate on the hot ductility of boron bearing steel during continuous casting (Study for prevention of corner crack on continuous casting slab) (보론 첨가강에서 연주 냉각속도가 고온연성에 미치는 영향 연구 (주편 코너 크랙 발생 방지 방안 확보 연구))

  • Cho, Kyungchul;Koo, Yangmo;Park, Joongkil
    • Korean Journal of Metals and Materials
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    • v.46 no.6
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    • pp.329-337
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    • 2008
  • During the continuous casting of boron-bearing steel, the corner cracks on the slab are formed by deformation with low strain rate and rapid cooling at the unbending temperature within the range of 800- $1000^{\circ}C$. Especially, the rapid cooling in the corner of slab during the continuous casting leads to as corner cracking. Therefore, in this study, the hot tensile tests applied to the different cooling rates were taken into account in order to study the effect of cooling rate on the hot ductility of boron-bearing steel. The results revealed that increasing cooling rate deteriorate the hot ductility of boron- bearing steel. Rapid decreasing of the hot ductility is caused by formation of a film-like ferrite and precipitate at the austenite grain boundaries. The morphology of the precipitates in the boron-bearing steel was monitored by PTA (Particle Tracking Autoradiography) and TEM, we observed MnS and BN compound and their morphology was quite different depending on the cooling rates. When the cooling rate is increased, rodshape MnS and BN precipitates can be formed along the austenite grain boundaries. It can cause that weakening the boundary region and decreasing the hot ductility of boron-bearing steel.

Preparation of Intermetallic Compound of Ternary Al-B-C System by Mechanical Alloying

  • Takahashi, Teruo;Yamashita, Michiru;Yamada, Kazutoshi;Kohzuki, Hidenori
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1033-1034
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    • 2006
  • Metallic compound of ternary Al-B-C system was prepared by mechanical alloying (MA) using Al, boron and graphite powders as starting materials. MA was carried out using Spex 8000 mixer/mill for 50 hours in an argon atmosphere without process control reagent such as methyl alcohol. The MA powders obtained were heat-treated in vacuum at the temperature of 873 and 1273 K for 5 hour. Pure ternary Al-B-C compound was obtained in the chemical content of Al:B:C=55:27:18. The ternary compound obtained in this study has a new phase whose crystal structure is not identified yet.

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New Synthetic Method of Perfluoro-Silanes for the Stable Electrolyte of Lithium Ion Battery Application

  • Koh, Kyungkuk;Sohn, Honglae
    • Journal of Integrative Natural Science
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    • v.10 no.3
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    • pp.171-174
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    • 2017
  • Non-hydrolyzable fluorinated organosilicon compounds as an eletrolyte for the application of lithium-ion batteries (LIB) are synthesized. New synthetic method for the perfluorinated organosilicon compound containing spacer such as ethyl and propyl group with cyano moiety instead of ethylene glycol to prevent hydrolysis and to promote conductivity are developed in one pot reaction with moderately high yield. Air-sensitive boron trifluoride etherate is no longer required in this reaction. The products are characterized by spectroscopic analysis.

A Study on Laser Welding Characteristics of 1500MPa Grade Ultra High Strength Steel for Automotive Application (자동차용 1500MPa급 초고강도강의 레이저 용접 특성에 관한 연구)

  • Choi, Jin-Kang;Kim, Jong-Gon;Shin, Seung-Min;Kim, Cheol-Hee;Rhee, Se-Hun
    • Laser Solutions
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    • v.13 no.3
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    • pp.19-26
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    • 2010
  • In this study, fundamental experiment was conducted with various strength of UHSS (Ultra High Strength Steel) by $CO_2$ laser. And then, butt and lap joint laser welding with boron alloyed steel and Al-Si coated boron alloy steel have been done by changing laser beam feature, existence of gap and existence of coating layer to know welding characteristics of those materials. As a result, in case of fundamental experiment with various strength steel, hardening was found in the weld metal of all tested materials and softening was found at the heat affected zone of SGAFC 1180. In case of laser butt welding of UHSS, mechanical properties was improved by using small laser beam diameter and Al-Si coating layer caused fracture of weld metal. In case of laser lap welding of UHSS, Al-Si coating layer resulted in formation of intermetallic compound at the fusion boundary where fracture occurred. Al-Si coating layer caused lowering mechanical properties of weld metal.

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Examination of the Characteristics of Mortar Mixed with Boron Compounds Presenting Various Levels of Alkalinity (다양한 알칼리도를 가진 붕소화합물이 혼입된 모르타르의 특성 검토)

  • Lee, Binna;Lee, Jong-Suk;Min, Jiyoung;Lee, Jang Hwa
    • Journal of the Korea Concrete Institute
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    • v.29 no.1
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    • pp.85-92
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    • 2017
  • This study examines the characteristics of mortar mixed with various boron compounds. The adapted boron compounds, classified into acid, slightly alkaline and strongly alkaline with respect to the value of the pH are acid-based boron (AA), low-alkaline-based boron (AB), and high-alkaline-based boron (HB). The pH test, setting test and compressive strength test are performed to evaluate the physical and chemical properties of mortar, and SEM imaging is conducted to analyze the microstructure of mortar. The measured pH shows that the specimens mixed with boron compounds have lower pH than the basic mortar without boron and that loss of pH occurs according to time. The setting test reveals that the initial and final setting times of the specimens mixed with boron compounds occur later than the basic mortar, which disagrees slightly with the previous literature stating that the setting time can be shortened according to the alkalinity. From the compressive strength test and SEM imaging results, it is recommended to determine the optimal content of boron considering type and composition of the boron compounds.