• Journal of the Korean Vacuum Society
• /
• v.19 no.2
• /
• pp.81-90
• /
• 2010

We introduce a novel and versatile approach for preparing self-assembled nanoporous multilayered films with antireflective properties. Protonated polystyrene-block-poly (4-vinylpyrine) (PS-b-P4VP) and anionic polystyrene-block-poly (acrylic acid) (PS-b-PAA) block copolymer micelles (BCM) were used as building blocks for the layer-by-layer assembly of BCM multilayer films. BCM film growth is governed by electrostatic and hydrogen-bonding interactions between the oppositely BCMs. Both film porosity and film thickness are dependent upon the charge density of the micelles, with the porosity of the film controlled by the solution pH and the molecular weight (Mw) of the constituents. PS7K-b-P4VP28K/PS2K-b-PAA8K films prepared at pH 4 (for PS7K-b-P4VP28K) and pH 6 (for PS2K-b-PAA8K) are highly nanoporous and antireflective. In contrast, PS7K-b-P4VP28K/PS2K-b-PAA8K films assembled at pH 4/4 show a relatively dense surface morphology due to the decreased charge density of PS2K-b-PAA8K. Films formed from BCMs with increased PS block and decreased hydrophilic block (P4VP or PAA) size (e.g., PS36K-b-P4VP12K/PS16K-b-PAA4K at pH 4/4) were also nanoporous. Furthermore, we demonstrate that the nanostructured electrochemical sensors based on patterning methods show the electrochemical activities. Anionic poly(styrene sulfonate) (PSS) layers were selectively and uniformly deposited onto the catalase (CAT)-coated surface using the micro-contact printing method. The pH-induced charge reversal of catalase can provide the selective deposition of consecutive PE multilayers onto patterned PSS layers by causing the electrostatic repulsion between next PE layer and catalase. Based on this patterning method, the hybrid patterned multilayers composed of platinum nanoparticles (PtNP) and catalase were prepared and then their electrochemical properties were investigated from sensing $H_2O_2$ and NO gas. This study was based on the papers reported by our group. (J. Am. Chem. Soc. 128, 9935 (2006); Adv. Mater. 19, 4364 (2007); Electro. Mater. Lett. 3, 163 (2007)).

• Restorative Dentistry and Endodontics
• /
• v.29 no.2
• /
• pp.177-184
• /
• 2004

Objectives : This study investigated the hypothesis that increasing light-curing time would leave the oxygen-inhibited layer (OIL) of the adhesive thinner, and in turn, result in lower shear bond strength (SBS) than those obtained by the routine curing procedures. Methods：120 human extracted posterior teeth were randomly divided into three groups for bonding with three adhesives：All Bond 2/sup (R)/, One Step/sup (R)/, and Adper Prompt/sup (R)/. They were subsequently divided into four subgourps with different light-curing time (10, 20, 30 and 60s). The assigned adhesives were applied on superficial occlusal dentin according to the manufacturer's instructions and cured with one of the four curing times. Composite resin cylinder, 2.35㎜ in diameter, were built on the cured adhesive and light-cured for 40s. SBS were measured after 24h from the bonding using a universal testing machine (crosshead speed 1.0 ㎜/min). The relative thickness of the OIL and the degree of conversion (DC) were determined from the adhesive on a slide glass using FT-NIR in an absorbance mode. Data were analysed with One-way ANOVA and Duncan's multiple test (p〈0.05), Results：With increasing cure time, although there were no significant difference in th SBS of One-step and Adper Prompt (p〉0.05), those of All Bond 2 decreased significantly (p〈0.05). The relative thicknesses of the OIL on each adhesive were not affected by the cure time (p〉0.05). Although the DC of All-Bond 2 were statistically not different with increasing cure time (p〉0.05), those of One-Step and Adper Prompt showed an increasing trends with increasing cure time (p〈0.05). Conclusions：Increasing light-curing time did not affect on the relative thickness of the OIL of the adhesives, and in turn, on the SBS to dentin.

• Steel and Composite Structures
• /
• v.34 no.2
• /
• pp.189-213
• /
• 2020

Stainless-clad (SC) bimetallic steels that are manufactured by metallurgically bonding stainless steels as cladding metal and conventional mild steels as substrate metal, are kind of advanced steel plate products. Such advanced composite steels are gaining increasingly widespread usage in a range of engineering structures and have great potential to be used extensively for large civil and building infrastructures. Unfortunately, research work on the SC bimetallic steels from material level to structural design level for the applications in structural engineering field is very limited. Therefore, the aim of this paper is to investigate the material behaviour of the SC bimetallic steels under the cyclic loading which structural steels usually could encounter in seismic scenario. A number of SC bimetallic steel coupon specimens are tested under monotonic and cyclic loadings. The experimental monotonic and cyclic stress-strain curves of the SC bimetallic steels are obtained and analysed. The effects of the clad ratio that is defined as the ratio of the thickness of cladding layer to the total thickness of SC bimetallic steel plate on the monotonic and cyclic behaviour of the SC bimetallic steels are studied. Based on the experimental observations, a cyclic constitutive model with combined hardening criterion is recommended for numerical simulation of the cyclic behaviour of the SC bimetallic steels. The parameters of the constitutive model for the SC bimetallic steels with various clad ratios are calibrated. The research outcome presented in this paper may provide essential reference for further seismic analysis of structures fabricated from the SC bimetallic steels.

• Korean Journal of Materials Research
• /
• v.29 no.4
• /
• pp.258-263
• /
• 2019

Since the directly bonded interface between TiAl alloy and SCM440 includes lots of cracks and generated intermetallic compounds(IMCs) such as TiC, FeTi, and $Fe_2Ti$, the interfacial strength can be significantly reduced. Therefore, in this study, Cu is selected as an insert metal to improve the lower tensile strength of the joint between TiAl alloy and SCM440 during friction welding. As a result, newly formed IMCs, such as $Cu_2TiAl$, CuTiAl, and $TiCu_2$, are found at the interface between TiAl alloy and Cu layer and the thickness of IMCs layers is found to vary with friction time. In addition, to determine the relationship between the thickness of the IMCs and the strength of the welded interfaces, a tensile test was performed using sub-size specimens obtained from the center to the peripheral region of the friction-welded interface. The results are discussed in terms of changes in the IMCs and the underlying deformation mechanism. Finally, it is found that the friction welding process needs to be idealized because IMCs generated between TiAl alloy and Cu act to not only increase the bonding strength but also form an easy path of fracture propagation.

• International Journal of Concrete Structures and Materials
• /
• v.8 no.1
• /
• pp.83-97
• /
• 2014

This paper presents the results of an investigation aimed at developing reinforced concrete beams consisting of precast permanent U-shaped reinforced mortar forms filled with different types of core materials to be used as a viable alternative to the conventional reinforced concrete beam. To accomplish this objective, an experimental program was conducted and theoretical model was adopted. The experimental program comprised casting and testing of thirty beams of total dimensions $300{\times}150{\times}2,000mm$ consisting of permanent precast U-shaped reinforced mortar forms of thickness 25 mm filled with the core material. Three additional typical reinforced concrete beams of the same total dimensions were also cast to serve as control specimens. Two types of single-layer and double-layers steel meshes were used to reinforce the permanent U-shaped forms; namely welded wire mesh and X8 expanded steel mesh. Three types of core materials were investigated: conventional concrete, autoclaved aerated lightweight concrete brick, and recycled concrete. Two types of shear connections between the precast permanent reinforced mortar form and the core material were investigated namely; adhesive bonding layer between the two surfaces, and mechanical shear connectors. The test specimens were tested as simple beams under three-point loadings on a span of 1,800 mm. The behavior of the beams incorporating the permanent forms was compared to that of the control beams. The experimental results showed that better crack resistance, high serviceability and ultimate loads, and good energy absorption could be achieved by using the proposed beams which verifies the validity of using the proposed system. The theoretical results compared well with the experimental ones.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.28 no.1
• /
• pp.28-33
• /
• 2015

The needle electrode is inserted into the cross-linked polyethylene(XLPE) which is the ultra high voltage cable for electric power. By changing the tilt of the needle electrode, we investigated how the void and the thickness of the insulating layer influence the partial discharge(PD) characteristics and the insulating breakdown. In order to investigate the PD characteristics, The XLPE cable was used to the specimens and the tungsten electrode was used with the needle electrode. And the inner semi-conductive layer material of XLPE cable was used with the negative electrode by bonding with the use of conduction tape. The size of the specimens was manufactured to be $16{\times}40{\times}30[mm^3]$. We confirmed the effect on changing the PD characteristics according to the changing voltage and the tilt of the electrode after applying the voltage on the electrode from 1[kV] to 40[kV] at room temperature. In the PD characteristics, it was confirmed that the PD current of air void specimens with tilt was unstable more than that of no void specimens with tilt. It was also confirmed that the breakdown voltage was decreased because the effect of air void is more active than the change of the needle electrode tilt in the specimen with air void inside the insulation.

• Carbon letters
• /
• v.21
• /
• pp.68-73
• /
• 2017

We have demonstrated the production of thin films containing multilayer graphene-coated copper nanoparticles (MGCNs) by a commercial electrodeposition method. The MGCNs were produced by electrical wire explosion, an easily applied technique for creating hybrid metal nanoparticles. The nanoparticles had average diameters of 10-120 nm and quasi-spherical morphologies. We made a complex-electrodeposited copper thin film (CETF) with a thickness of $4.8{\mu}m$ by adding 300 ppm MGCNs to the electrolyte solution and performing electrodeposition. We measured the electric properties and performed corrosion testing of the CETF. Raman spectroscopy was used to measure the bonding characteristics and estimate the number of layers in the graphene films. The resistivity of the bare-electrodeposited copper thin film (BETF) was $2.092{\times}10^{-6}{\Omega}{\cdot}cm$, and the resistivity of the CETF after the addition of 300 ppm MGCNs was decreased by 2% to ${\sim}2.049{\times}10^{-6}{\Omega}{\cdot}cm$. The corrosion resistance of the BETF was $9.306{\Omega}$, while that of the CETF was increased to 20.04 Ω. Therefore, the CETF with MGCNs can be used in interconnection circuits for printed circuit boards or semiconductor devices on the basis of its low resistivity and high corrosion resistance.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.02a
• /
• pp.382-382
• /
• 2010

$TaO_2$ thin films as gate dielectrics have been proposed to overcome the problems of tunneling current and degradation mobility in achieving a thin equivalent oxide thickness. An extremely thin $SiO_2$ layer is used in order to separate the carrier in MOSFETchannel from the dielectric field fluctuation caused by phonons in the dielectric which decreases the carrier mobility. The electronic and optical properties influenced the device performance to a great extent. The atomic structure of amorphous and crystalline Tantalum oxide ($TaO_2$) gate dielectrics thin film on Si (100) were grown by utilizing atomic layer deposition method was examined using Ta-K edge x-ray absorption spectroscopy. By using X-ray photoelectron spectroscopy and reflection electron energy loss spectroscopy (REELS) the electronic and optical properties was obtained. In this study, the band gap (3.400.1 eV) and the optical properties of $TaO_2$ thin films were obtained from the experimental inelastic scattering cross section of reflection electron energy loss spectroscopy (REELS) spectra. EXAFS spectra show that the ordered bonding of Ta-Ta for c-$TaO_2$ which is not for c-$TaO_2$ thin film. The optical properties' e.g., index refractive (n), extinction coefficient (k) and dielectric function ($\varepsilon$) were obtained from REELS spectra by using QUEELS-$\varepsilon$(k, $\omega$)-REELS software shows good agreement with other results. The energy-dependent behaviors of reflection, absorption or transparency in $TaO_2$ thin films also have been determined from the optical properties.

• Korean Journal of Materials Research
• /
• v.19 no.7
• /
• pp.349-355
• /
• 2009

Metal thin film patterns on a LTCC substrate, which was connected through inner via and metal paste for electrical signals, were formed by a screen printing process that used electric paste, such as silver and copper, in a conventional method. This method brought about many problems, such as non uniform thickness in printing, large line spaces, and non-clearance. As a result of these problems, it was very difficult to perform fine and high resolution for high frequency signals. In this study, the electric signal patterns were formed with the sputtered metal thin films (Ti, Cu) on an LTCC substrate that was coated with protective oxide layers, such as $TiO_2$ and $SiO_2$. These electric signal patterns' morphology, surface bonding strength, and effect on electro plating were also investigated. After putting a sold ball on the sputtered metal thin films, their adhesion strength on the LTCC substrate was also evaluated. The protective oxide layers were found to play important roles in creating a strong design for electric components and integrating circuit modules in high frequency ranges.

• Journal of the Korean Wood Science and Technology
• /
• v.46 no.1
• /
• pp.67-72
• /
• 2018

This study was conducted to investigate a potential of Yellow poplar (Liriodendron tulipifera L.) as a raw material for the manufacturing of particleboard (PB) and oriented strandboard (OSB). PB panels were prepared at the parameters of $0.7g/cm^3$ density, 15 mm thickness, three-layer, $E_1$ grade urea-formaldehyde (UF) resin, emulsion wax, and hardener. OSB panels were manufactured with a density of $0.65g/cm^3$, thickness of 10 mm, and $E_1$ grade of UF resin. Particle size of the face layer of PB was 20~80 mesh with 7~9% moisture content (MC), while that of core-layer was 3~20 mesh with 3~5% MC, which was similar to the production condition of commercial PB. As a result, the manufactured PB panels with 15.8 mm thickness, $0.7g/cm^3$ density, and 5.8% MC satisfied the requirement of bending strength of 15 type PB of Korean Industrial Standard (KS F 3104). Both internal bonding (IB) strength and surface screw withdrawal resistance also satisfied the requirement of 18 type PB of the standard. But, the edge screw withdrawal resistance satisfied the requirement of 15 type PB of the standard. These differences in properties could be due to the slenderness ratio of raw particles. In case of OSB panels with 10.7 mm thickness, $0.68g/cm^3$ density, and 5.8% MC satisfied all the requirements of bending strength, screw withdrawal resistance, and IB strength of 18 type PB of the standard. These results suggest that Yellow poplar wood has a good potential as a raw material for the production of PB and OSB.