• Title/Summary/Keyword: Bond order

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Strength Development Properties of Latex Modified Concrete For New Concrete Bridge Deck Overlay (신설 콘크리트 교면 덧씌우기를 위한 라텍스 개질 콘크리트의 강도발현 특성)

  • Yun, Kyong-Ku;Kim, Ki-Heoun;Lee, Joo-Hyung;Hong, Chang-Woo;Kim, Dong-Ho
    • International Journal of Highway Engineering
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    • v.3 no.3 s.9
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    • pp.135-146
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    • 2001
  • This study focused on the investigation of compressive and flexural strengths development, and bond strength of latex modified concrete in order to validate the feasibility of application into concrete bridge deck overlay. Pull-out bond test was used for evaluating the bond strength of latex modified concrete to substrate. The main experimental variables were latex-cement ratio, surface preparation and moisture levels. The compressive strength of latex modified concrete decreased slightly and the flexural strength increased as the latex content increased from 5% to 20%. This might be due to the flexibility latex filled in voids and interconnections of hydrated cement and aggregates by a film of latex particles, respectively. In general, increasing the amount of latex will produce concrete with increased tensile and flexural strength and lower modulus of elasticity. Significant improvements in bond strength between new and existing concrete were achieved through the modification of the new concrete bridge deck overlay by latex polymers. The effect of surface preparation on bond of latex modified concrete to conventional concrete were significant at the conditions by sand paper and wire brush. A better bond could be achieved by rough surface rather than smooth. The saturated condition of surface is the most appropriate moisture level among the considered followed by dry condition and wet condition.

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Comparison of bond strengths of ceramic brackets bonded to zirconia surfaces using different zirconia primers and a universal adhesive

  • Lee, Ji-Yeon;Ahn, Jaechan;An, Sang In;Park, Jeong-won
    • Restorative Dentistry and Endodontics
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    • v.43 no.1
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    • pp.7.1-7.7
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    • 2018
  • Objectives: The aim of this study is to compare the shear bond strengths of ceramic brackets bonded to zirconia surfaces using different zirconia primers and universal adhesive. Materials and Methods: Fifty zirconia blocks ($15{\times}15{\times}10mm$, Zpex, Tosoh Corporation) were polished with 1,000 grit sand paper and air-abraded with $50{\mu}m$ $Al_2O_3$ for 10 seconds (40 psi). They were divided into 5 groups: control (CO), Metal/Zirconia primer (MZ, Ivoclar Vivadent), Z-PRIME Plus (ZP, Bisco), Zirconia Liner (ZL, Sun Medical), and Scotchbond Universal adhesive (SU, 3M ESPE). Transbond XT Primer (used for CO, MZ, ZP, and ZL) and Transbond XT Paste was used for bracket bonding (Gemini clear ceramic brackets, 3M Unitek). After 24 hours at $37^{\circ}C$ storage, specimens underwent 2,000 thermocycles, and then, shear bond strengths were measured (1 mm/min). An adhesive remnant index (ARI) score was calculated. The data were analyzed using one-way analysis of variance and the Bonferroni test (p = 0.05). Results: Surface treatment with primers resulted in increased shear bond strength. The SU group showed the highest shear bond strength followed by the ZP, ZL, MZ, and CO groups, in that order. The median ARI scores were as follows: CO = 0, MZ = 0, ZP = 0, ZL = 0, and SU = 3 (p < 0.05). Conclusions: Within this experiment, zirconia primer can increase the shear bond strength of bracket bonding. The highest shear bond strength is observed in SU group, even when no primer is used.

Pullout Bond Characteristics of Untensioned Prestressing Strand (인장을 가하지 않은 PS강연선의 인발 부착특성)

  • Ha, Sang-Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.5
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    • pp.101-108
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    • 2008
  • The primary objective of this research is a study on the pullout bond characteristics of untensioned prestressing strand in concrete. The bond characteristics of untensioned prestressing strand in concrete differs from that of deformed reinforcing bar. In order to use and design untensioned prestressing strand as deformed reinforcing bar, a study for bond characteristics of the untensioned prestressing strand was progressed. Major test variables are embedment length ($10d_b{\sim}60d_b$), concrete cover (45mm, 70mm, 100m) and diameter of strands. (12.7mm : SWPC7, 9.3mm : SWPC7A) As a results, these showed that average bond stress was decreased as a growing the embedment length, and then showed that the bond performance of untensioned prestressing strand was improved if embedment length was above 60$60d_b$.

INFLUENCE OF ARTIFICIAL SALIVA CONTAMINATION ON BONDING OF DENTIN ADHESIVES TO DENTIN (인공타액 오염이 수종 상아질접착제와 상아질간의 결합에 미치는 영향)

  • Ryu, Mee-Ae;Yang, Kyu-Ho;Oh, Won-Mann
    • Restorative Dentistry and Endodontics
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    • v.17 no.2
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    • pp.383-397
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    • 1992
  • The purpose of this study was to evaluate the influence of artificial saliva contamination on bonding of several dentin adhesives to dentin. Sixty - three human molar teeth extracted within a month were used. Each tooth was sectioned longitudinally in a buccolingual direction to obtain 126 specimens. These specimens were randomly divided into three groups and were treated by Scotchbond 2, Gluma and All bond. Each group was subdivided into three subgroups; normal group not contaminated with artificial saliva, contaminated with artificial saliva and dried group, and contaminated with artificial saliva and washed and dried group. Enamel/dentin bonding agent(Dental Adhesive of Scotchbond 2) was applied and light cured on the treated dentin surfaces. Thereafter P - 50 were cured on them, and specimens were stored in $37^{\circ}C$ artificial saliva for 24 hours before measuring shear bond strength. Shear bond strengths were determined using an universal testing machine with cross head speed 1mm/min and SEM examinations were conducted to evaluate the resin - dentin interface and degree of penetrating resin string into the dentinal tubules. The following results were obtained. 1. Normal groups not contaminated with artificial saliva showed greater shear bond strength than any other group contaminated with artificial saliva(P<0.01). 2. The shear bond strengths showed no significant difference between washed groups with distilled water and not washed groups after contamination with artificial saliva(P>0.05). 3. In normal groups, the shear bond strength of A group was significantly greater than in any other group(P<0.01). 4. In Sand G groups, fractures after shear bond strength tests occured adhesively on resintooth interface in all specimens. But in A groups, fracture of the normal group occured cohesively in dentin and fracture of the contaminated groups occured adhesively and cohesively. 5. On SEM examination, the number of resin strings penetrated into dentinal tubules were the greatest in normal groups, followed by, in descending order, washed groups and not washed groups after contamination with artificial saliva.

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Full Geometry Optimizations of Bond-Stretch Isomers of C202+ Fullerene Dication by the Hybrid Density Functional B3LYP Methods

  • Lee, Ji-Hyun;Lee, Chang-Hoon;Park, Sung-S.;Lee, Kee-Hag
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.277-280
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    • 2011
  • We studied the relative stability and atomic structure of five $C_{20}^{2+}$ isomers obtained by two-electron ionization of a $C_{20}$ cage (the smallest fullerene). All the isomers are bond-stretch isomers, i.e., they differ in bond length. In particular, in one of the isomers with Ih symmetry, all the bond lengths are equal. Full geometry optimizations of the dipositive ion $C_{20}^{2+}$ were performed using the hybrid density functional (B3LYP/6-31G(d)) methods. All isomers were found to be true minima by frequency analysis at the level of B3LYP/6-31G(d) under the reinforced tight convergence criterion and a pruned (99,590) grid. The zero-point correction energy for the cage bond-stretch isomers was in the increasing order $D_{2h}<C_{2h}<C_2<T_h<I_h$ of $C_{20}^{2+}$. The energy difference among the isomers of cage dipositive ions was less than that among neutral cage isomers. Our results suggest that these isomers show bond-stretch isomerism and that they have an identical spin state and an identical potential energy curve. Although the predominant electronic configurations of the isomers are similar, the frontier orbital characteristics are different, implying that we could anticipate an entirely different set of characteristic chemical reactions for each type of HOMO and LUMO.

The Bond Behavior between Deformed bars and Recycled Fine Aggregate Concrete according to Bar Position. (철근 위치에 따른 이형철근과 순환잔골재 콘크리트의 부착거동)

  • You, Young-Chan;Jang, Yong-Heon;Lee, Min-Jung;Yun, Hyun-Do;Choi, Ki-Sun;Lee, Do-Heun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1089-1092
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    • 2008
  • The bond behavior between concrete and reinforcement is a important requirement for reinforced concrete constructions. For practical application, it is very important to study bond behavior of reinforcing bars in recycled fine aggregate concrete. Therefore, pull-out test in order to investigate the bond behavior between recycled fine aggregate concrete and deformed bars was performed. Recycled fine aggregate concrete replacement ratios (i.e., 0% and 100%) and positions of deformed bars (i.e., vertical and horizontal position) were considered as variables in this study. Test results were compared with the bond strength requirement recommended by CEB-FIP code. Based on the test results, It was found that the bond strength between the recycled fine aggregate concrete and deformed bars were influenced by both recycled fine aggregate concrete replacement ratios and positions of deformed bars. The reduction of bonded area at the soffit of horizontal reinforcement caused by concrete bleeding was observed in H type specimen. So, Only V type and HB specimen satisfied the bond strength requirement recommended by CEB-FIP code.

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Tensile Bond Characteristics between Underwater Coating Materials and Concrete Substrate (수중코팅제와 콘크리트 모재 간의 인장 부착 특성)

  • Kim, Min Ook;Jeong, Yeonung;Kang, Sung-Hoon;Moon, Juhyuk;Yi, Jin-Hak
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.30 no.6
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    • pp.298-305
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    • 2018
  • In this study, we investigated the tensile bond characteristics of underwater coating materials, in order to obtain useful information in support of repair work for marine and coastal concrete structures. Test variables included type of underwater coating, surface conditions of the concrete substrate, and environmental conditions. Pull-off tensile bond strength was measured at 24 h after applying underwater coatings to concrete substrates, in compliance with the procedures specified in ASTM C1583. Failure modes (coating, interface, and parent concrete) for each coating were identified through visual inspection, and comparisons were made based on measured bond strength. The tensile bond strength decreased underwater compared to that under dry conditions, while no significant effect of surface roughness on the measured bond strength was observed in underwater tests. Key aspects that need to be considered regarding selection and use of underwater coating materials for marine and coastal concrete structures were discussed.

Bond-Slip Model for CFRP Sheet-Concrete Adhesive Joint (탄소섬유쉬트-콘크리트 부착이음의 부착 모델)

  • Cho, Jeong-Rae;Cho, Keunhee;Park, Young-Hwan;Park, Jong-Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.2A
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    • pp.285-292
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    • 2006
  • In this study, a method determining the local bond-slip model from pure shear test results of CFRP sheet-concrete adhesive joints is proposed and local bond-slip models are presented. Adhesive joints with a specific bond-slip model, which is assumed as multi-linear curve in order to represent arbitary function, are solved numerically. The difference between the solution and test results are minimized for finding the bond-slip model. The model with bilinear curve is also optimized to verify the improvement of multi-linear model. The selected test results are ultimate load-adhesive length curves from a series of adhesive joints and load-displacement curves for each joint. The optimization problem is formulated by physical programming, and the optimized bond-slip model is found using genetic algorithm.

Experimental Study on Adfreeze Bond Strength Between Frozen Sand and Aluminium with Varying Freezing Temperature and Vertical Confining Pressure (동결온도와 수직구속응력 변화에 따른 모래와 알루미늄 재료의 접촉면에서 작용하는 동착강도 실험 연구)

  • Ko, Sung-Gyu;Choi, Chang-Ho
    • Journal of the Korean Geotechnical Society
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    • v.27 no.9
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    • pp.67-76
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    • 2011
  • Bearing capacity of pile foundations in cold region is dominated by adfreeze bond strength between surrounding soil and pile perimeter. Adfreeze bond strength is considered to be the most important design parameter for foundations in cold region. Many studies in last 50 years have been conducted to analyze characteristics of adfreeze bond strength. However, most studies have been performed under constant temperature and normal stress conditions in order to analyze affecting factors like soil type, pile material, loading speed, etc. In this study, both freezing temperature and normal stress acting on pile surface were considered to be primary factors affecting adfreeze bond strength, while other factors such as soil type, pile material and loading speed were predefined. Direct shear box was used to measure adfreeze bond strength between Joomoonjin sand and aluminium because it is easy to work for various roughness. Test was performed with temperatures of > $0^{\circ}C$, $-1^{\circ}C$, $-2^{\circ}C$, $-5^{\circ}C$, and $-10^{\circ}C$ and vertical confining pressures of 1atm, 2atm, and 3atm. Based on the test results, the effects of temperature and vertical stress on adfreeze bond strength were analyzed. The test results showed that adfreeze bond strength increases with decreased temperature and increased vertical stress. It was also noted that two types of distinct sections exist, owing to the rate of increase of adfreeze bond strength along the change of freezing temperature: 1)rapidly increasing section and 2)gradually decreasing section. In addition, the results showed that a main factor affecting adfreeze bond strength switches from friction angle to adhesion as freezing temperature decreases.

Molecular analysis of c-terminus structure for elucidating the stabilization effect of site-specific immobilization

  • Baek, Seung-Pil;Yu, Yeong-Jae
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.886-889
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    • 2001
  • C-terminus specific immobilization often results in a increased structural stability resistant to various denaturation factors. In order to elucidate the immobilization effect on the c-terminus in molecular level, we made over 200 protein data set from Protein Data Bank(PDB), analyzed c-terminus structure of each protein, and investigated the structural relationship with the stabilizing factors such as hydrogen bond, ion pairs, cation pi, disulfide bond, solvation free energy, surface area, flexibility and so on.

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