• Bulletin of the Korean Chemical Society
• /
• 제14권6호
• /
• pp.740-743
• /
• 1993

By considering both electron-electron and electron-lattice interactions, the effect of charge transfer on the bond structure and electronic states of $C_{60}$ is studied without configuration limitation. The results show that the electron-electron interaction does not eliminate the layer structure of the bond distortion and the self-trapping of transferred electrons. For charged ${C_{60}}^{2-}$, there exist two localized electronic states, which possess laminar wave functions, and four nonequivalent groups of carbon atoms, which induce a fine-structure in the NMR spectrum line.

• 한국공간구조학회논문집
• /
• 제21권2호
• /
• pp.57-66
• /
• 2021

This study develops finite element models for seismically-deficient reinforced concrete building frame retrofitted using fiber-reinforced polymer jacketing system and validates the finite element models with full-scale dynamic test for as-built and retrofitted conditions. The bond-slip effects measured from a past experimental study were modeled using one-dimensional slide line model, and the bond-slip models were implemented to the finite element models. The finite element model can predict story displacement and inter-story drift ratio with slight simulation variation compared to the measured responses from the full-scale dynamic tests.

• 구강회복응용과학지
• /
• 제18권3호
• /
• pp.225-233
• /
• 2002

This study was aimed to evaluate the effects of ultrasonic vibration on margin types and cements by comparing bond strength of cemented crown. In this study, margins of each metal die, which were chamfer, shoulder and shoulder with bevel, were prepared using computer milling machine. Specimens were cemented with zinc phosphate cement or resin cement. The specimens were divided by the finish line and cement used, ultrasonic vibration. I made total 84 specimens. All specimens were divided into two groups. One group was not vibrated, the other group was subjected to ultrasonic vibration for 12 minutes. Tensile bond strength was measured using Universial testing machine. The changes of bond strength in groups were statistically analyzed by t-test or One-way ANOVA. The results were as follows : 1. Ultrasonic instrumentation diminished the bond strength of crown cemented with zinc phosphate cement and resin cement after 12 minutes application. 2. In case of zinc phosphate cement, the bond strength of a vibrated group was showed significantly decreased(p<0.05). In vibrated groups with zinc phosphate cement, shoulder with bevel exhibit a significant difference to chamfer and shoulder(p<0.05) 3. Resin cement was more resistant to ultrasonic vibration than zinc phosphate cement and showed no significant differences according to ultrasonic vibration and margin type. In conclusion, These results revealed that zinc phosphate cement was most affected and resin cement was the least affected by ultrasonic vibration. Especially shoulder with bevel design was most affected in zinc phosphate cement groups. we should consider these results and be taken in the application of ultrasonic vibration to any teeth restored with crowns.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2006년도 춘계 학술발표회 논문집
• /
• pp.1008-1013
• /
• 2006

Ground anchor method is widely used in the large scale deep excavation of urban area to support a retained wall. Excavation using the ground anchor as a supporting system near a building have many difficulties due to the limitation of construction space. This method can not be applied to the site with the insufficient space from the retained wall to the boundary line. In this case, soil improvement at the anchor bond zone can be used to secure the frictional resistance of ground anchor within the boundary. Through this method, the bond length of anchor can be shortened considerably. This paper deals with the case study on the ground excavation adjacent to a building. The object field is Yongsan Park Tower Construction Site. In this site, the enlarged anchor with soil improvement was applied to solve the problem due to the limitation of construction space. According to the results of field test and monitoring, the anchor with soil improvement is very effective to secure the frictional resistance at the anchor bond zone.

• 대한치과기공학회지
• /
• 제41권2호
• /
• pp.71-80
• /
• 2019

Purpose: In this study, to evaluate the effect of oxide changes on the shear bond strength according to the composition of Ni-Cr alloys for porcelain fused matal crown, T-4 alloys, Zeroy alloys and Zeroy-X alloys were selected. Methods: 20 specimens were fabricated using selected Ni-Cr alloys and porcelain powders. A Ni-Cr alloy having a diameter of 5 mm and a height of 25 mm was produced and the metal surface was polished. Porcelain powder was fired on the polished metal surface to a diameter of 5 mm and a height of 3 mm. The experiment group consisted of three groups, T-4(TNA), Zeroy(ZNA) and Zeroy-X(ZXA). The fabricated specimens were mounted on a jig of a universal testing machine(UTM) and fracture strength was measured by applying a shear force at a UTM crosshead speed of 0.5 mm/min. The fracture strength was calculated as the bond strength between the porcelain and the alloy. The surface of the fractured alloy was analyzed by X-ray diffraction(XRD) and scanning electron microscopy(SEM), and the components of the oxide were measured by energy dispersive X-ray spectroscopy(EDX) line profile method. Results: In SEM, XRD and EDX analysis, yttrium tended to increase the mechanical and chemical bonding forces. The shear bond strength of ZXA group containing yttrium showed the highest value at 27.53 MPa. Conclusion: Based on the results of this study, it is considered that the yttrium-added Ni-Cr alloy is clinically acceptable in porcelain shear bond strength.

• 한국의류학회지
• /
• 제40권6호
• /
• pp.1010-1024
• /
• 2016

This study identifies the influence of on/off-line acquaintances' recommendation messages on fashion product attitude and purchase intention on the online purchase of fashion products in two-sided word of mouth situations as well as compares the difference in influence according to bond-base with equidistance. This study was conducted for one month on university students in their 20s who were believed to be active in smartphone use. Out of the collected 174 copies of the questionnaire, 162 copies were used for analysis. The questionnaire was classified into online and offline recommendation messages of an acquaintance. We present two-sided fashion product reviews made similar to the type found in an actual shopping mall web-site. As for analysis, confirmatory factory analysis, structural equation modeling, and multi-group analysis were conducted using AMOS 19.0. The analysis results are as follows. First, on/off-line acquaintances' recommendation messages had significant influences on product attitude in the situation where two-sided reviews on fashion products were presented; however, those messages did not influence purchase intention. Recommendation messages positively increased product attitude and enhanced purchase intention if acquaintances' recommendation messages were mediated between on/off-line acquaintances' recommendation messages and purchase intention. Consequently, a mediating effect on product attitude was revealed. Second, there was no difference between online acquaintances and offline acquaintances in terms of the influence of acquaintances' recommendation messages on product attitude and purchase intention, in the situation where two-sided reviews were presented on online fashion products. Therefore, no control effect according to the type of acquaintance was confirmed.

• Elastomers and Composites
• /
• 제51권1호
• /
• pp.63-67
• /
• 2016

Poly(ethylene-co-vinyl acetate) (EVA) was pyrolyzed to eliminate acetic acid of VA unit using off-line pyrolysis, and the deacetylated EVA was analyzed infrared spectroscopy (IR) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). EVA film for deacetylation was prepared by solution casting on aluminum foil and it was pyrolyzed at low temperature of $300^{\circ}C$ in the off-line pyrolysis apparatus. After deacetylation, carbon-carbon double bond (C=C) was formed by 1,2-elimination of the VA unit in the EVA backbone. Most of C=C bonds were trans-1,4-unit and 1,2-unit was also observed. Presence of the 1,2-unit in deacetylated EVA indicates that terminal or branch VA units exist in the raw EVA. Py-GC/MS chromatogram of deacetylated EVA displayed much smaller acetic acid and much more abundant other pyrolysis products than that of raw EVA, which means that the pyrolysis efficiency and separation condition were improved.

• Journal of Welding and Joining
• /
• 제18권3호
• /
• pp.51-59
• /
• 2000

Sink roll has been used in molten 55%Al-Zn alloy bath of continuous galvanizing line for sinking and stabilizing working steel strip in molten metal bath. In the process, the sink roll body inevitably build up dross compounds and pitting on the sink roll surface during 55%Al-Zn alloy coated strip production, and the life time of the sink roll is shorten by build up dross compounds and pitting. The present study examined the application of thermally sprayed ceramic coatings method on sink roll body for improving erosion resistance at molten 55% Al-Zn pool. In this experiment, the stainless steels such as STS 316L and STS 430F were used as the substrate materials. The CoNiCr and WE-Co powder were selected as bond coating materials. Moreover $Al_2O_3-ZrO_2-SiO_2 and ZrO_2-SiO_2$ powders selected as the top coating materials. Appearances of the specimens before and after dipping to molten 55%Al-Zn pool were compared and analyzed. As a result of this study, STS430F of substrate, WC-Co of bond spray coatings, $ZrO_2-SiO_2$ power of top spray coatings is the best quality in erosion resistance test at molten 55%Al-Zn pool

• 분석과학
• /
• 제9권4호
• /
• pp.355-363
• /
• 1996

인도네시아 Manado만의 Sulawesi에서 채집한 KB cancer cell line에 대해 in vitro로 활성을 가지고 있는 것으로 추정되는 해면 Luffariella sp.로부터 Aaptamine(1) 및 Demethyl(oxy)aaptamine(2)을 분리하였다. 이들 화합물의 화학구조는 $^1H-$, $^{13}C-NMR$, $^1H-^{13}C$(1 bond) heteronuclear multiple quantum coherence spectroscopy(HMQC), electron ionization mass spectroscopy(EIMS), UV 및 IR에 의해 밝혔다.

• 대한화학회지
• /
• 제19권3호
• /
• pp.149-155
• /
• 1975

플라스틱 결정체인 피발산의 temperature-dependent wide-line NMR line width, second monent 및 spin-lattice relaxation times 의 결과는 이 결정체의 특이한 운동학적 성질 및 수소결합에 기인된 것으로 해석된다. 이 분자의 운동학적 성질은 $C_3-C_3'$ reorientation 및 self-diffusion 으로 구성 되었음을 확인했다. Wide-line NMR 연구결과는 또한 Pople-Karasz 융해설과 비교검토되었고, 이 이론과의 차이점은 피발산의 수소결합에 기인되었음을 알아냈다.