• Journal of Photoscience
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• 제8권1호
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• pp.9-12
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• 2001

The photoisomerization behavior of benzylideneacetophenones, known as chalcones, was studied. We synthesized the chalcone derivatives that have ether groups at 4 and 4＇ positions. Due to the electron donating ability of the ether oxygen, the bond order of the single bond between two phenyl ring of the chalcone strengthened, which eventually increased the rotational barrier of the single bond. The rotational barrier of the single bond is about 20-22 kcal/mole. Thermal recovery of this process took about 1 min. The UV-visible spectra of these chromophores exhibit two characteristic absorption peaks at 276 nm and 340 nm. The relative intensity of the peaks varies depending on the alkyl chain length of the substituent. Photo-irradiation with the 365 nm light monotonously decreases the 340 nm peak. However, the photo-irradiation with 254 nm light induce two competing processes and produced rather complicated absorption profile.

• Proceedings of the Korea Concrete Institute Conference
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.635-638
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• 2004

External bonding of steel plates has been used to strengthen deficient reinforced-concrete structures since the 1960s. In recent years, fiber-reinforcde polymer(FRP) plates have been increasingly used to replace steel plates due to their superior properties. This paper is concerned with anchorage failure due to crack propagation parallel to the boned plated near or along the adhesive/concrete interface, staring from the critically stressed position toward the anchored end of the plates. Factor of bond-slip interface model is average bond stress, effective length, slip volume and fracture energy. The aim of the present paper is to provide a comprehensive assessment of bond-slip interface model with concrete and CFRP plates.

• Structural Engineering and Mechanics
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• 제19권3호
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• pp.337-346
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• 2005

The paper reports on a study of bond strength between reduced-water-content concrete and tensile reinforcement in spliced mode. Three different diameters (12, 16 and 22 mm) of tensile steel were spliced in the constant moment zone, where there were two bars of same size in tension. For each diameter of reinforcement, a total of nine beams ($1900{\times}270{\times}180mm$) were tested, of which three beams were with no axial force (positive bending) and the other six beams were with axial force (combined bending). The splice length was selected so that bars would fail in bond, splitting the concrete cover in the splice region, before reaching the yield point. It was found that there was a considerable size effect in the experimental results, i.e., as the diameter of the reinforcement reduced the bond strength and the deflection recorded at the midspan increased significantly, whilst the stiffness of the beams reduced. It was also found for all reinforcement sizes that higher bond strength and stiffness were obtained for beams tested in combined bending than that of the beams tested in positive bending only.

• Bulletin of the Korean Chemical Society
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• 제12권2호
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• pp.182-188
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• 1991

The reactions of aniline with benzyl and phenacyl compounds are studied by the AM1 method. Two types of modeling were adopted: Cation-neutral, in which a proton is attached to the leaving group F and anion-neutral model, in which aniline was replaced by phenoxide with Cl as the leaving group. The cation-neutral model represented the reactvery well, reproducing the various solution-phase experimental results. In the benzyl system, the ${\pi}$-electrons of the two rings (X-ring in the nucleophile and Y-ring in the substrate) interact conjugatively in the transition state (TS) resulting in a bond contraction of the $C_{\alpha}-C_{Y1}$ bond (benzylic effect), whereas in the phenacyl system the ${\pi}$ electrons of the X-ring delocalizes more efficiently into the carbonyl group than into the Y-ring (resonance shunt effect) with a bond contraction of the $C_{\alpha}-C_{\beta}$ bond. The bond contraction in the benzylic effect was substantially greater than that in the resonance shunt effect. The TS was rather loose for benzyl while it was tighter for phenacyl system. Various bond length changes with substituents in the TS were, however, found to be irregular.

• Journal of the Korea Concrete Institute
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• 제28권6호
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• pp.723-731
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• 2016

In pretensioned concrete members, a certain bond length from the end of the member is required to secure the effective prestress in the strands, which is defined as the transfer length. However, due to the complex bond mechanism between strands and concrete, most transfer length models based on the deterministic approach have uncertainties and do not provide accurate estimations. Therefore, in this study, Adaptive Neuro-Fuzzy Inference System (ANFIS), a Neuro-Fuzzy System, is introduced to reduce the uncertainties and to estimate the transfer length more accurately in pretensioned concrete member. A total of 253 transfer length test results have been collected from literatures to train ANFIS, and the trained ANFIS algorithm estimated the transfer length very accurately. In addition, a design equation was proposed to calculate the transfer length based on parametric studies and dimensional analyses. Consequently, the proposed equation provided accurate results on the transfer length which are comparable to the ANFIS analysis results.

• Computers and Concrete
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• 제21권3호
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• pp.249-259
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• 2018

The use of recycled aggregate in concrete is gaining much attention due to the growing need for sustainability in construction. In the present study, Self Compacting Concrete (SCC) is made using both natural and recycled aggregate (crushed recycled concrete aggregate from building demolished waste) and performance of recycled aggregate based SCC for the bond behaviour of reinforcement is evaluated. The major factors that influence the bond like concrete compressive strength (Mix-A, B and C), diameter of bar ($D_b=10$, 12 and 16 mm) and embedment length of bar ($L_d=2.5Db$, $5D_b$ and full depth of specimen) are the parameters considered in the present study in addition to type of aggregates (natural and recycled aggregates). The mix proportions of Natural Aggregate SCC (NASCC) are arrived based on the specifications of IS 10262. The mix proportions also satisfy the guidelines of EFNARC. In case of Recycled Aggregate SCC (RASCC), both the natural coarse and fine aggregates are replaced 100% by volume with that of recycled aggregates. These mixes are also evaluated for fresh properties as per EFNARC. The hardened properties like compressive strength, split tensile strength and flexural strength are also determined. The pull-out test is conducted as per the specifications of IS 2770 (Part-1) for determining the bond strength of reinforcement. Bond stress versus slip curves were plotted and a typical comparison of RASCC is made with NASCC. The fracture energy i.e., area under the bond stress slip curve is determined. With the use of recycled aggregates, reduction in maximum bond stress is noticed whereas, the normalised maximum bond stress is higher in case of recycled aggregates. Based on the experimental results, regression analysis is conducted and an equation is proposed to predict the maximum bond stress of RASCC. The equation is in good agreement with the experimental results. The available models in the literature are made use to predict the maximum bond stress and compare the present results.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.215-220
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• 2002

The structures of 1-fluorosilatrane and the silatranyl cation were calculated by Hartree-Fock (HF), Mofller-Plesset second order (MP2), and various density functional theory (DFT) methods using many different basis sets, demonstrating that the Si-N bonds in two species are quite different. The N${\rightarrow}$Si bond distance of 1-fluorosilatrane from the hybrid DFT calculations $({\sim}2.32{\AA})$ using the Perdew-Wang correlation functional agrees with the gas phase experimental value $(2.324{\AA})$, while other functionals yield larger distances. The MP2 bond distance (2.287${\AA}$ with 6-311$G^{\ast}$) is shorter, and the HF one (2.544 ${\AA}$ with 6-311$G^{\ast}$) larger than those of DFT calculations. The MP2 bond distance is in good agreement with experiment indicating that the electron correlations are crucial for the correct description of the N${\rightarrow}$Si interaction. The silatranyl cation is a stable local minimum on the potential energy surface in all methods employed suggesting that the cation could be a reaction intermediate. The Si-N bond length for the cation is about 1.87 ${\AA}$ for all calculations tested implying that the Si-N bond is mainly conventional. Bonding characteristics of the Si-N bond in two species derived from the natural bond orbital analysis support the above argument based on calculated bond lengths.

• Journal of the Korea Concrete Institute
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• 제25권2호
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• pp.217-224
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• 2013

Design provisions for the development length of headed bars in ACI 318-08 include concrete compressive strength and yield strength of headed bars as design parameters but do not consider the effects of transvers reinforcement. In addition, they have very strict limitation for clear spacing and material strengths because these provisions were developed based on limited tests. In this study, splice tests using SD600 headed bars with $2d_b$ clear spacing and transverse reinforcement were conducted. Test results show that unconfined specimens failed due to prying action and bottom cover concrete prematurely spalled. The contribution of head bearing on the anchorage strength is only 15% on average implying that unconfined specimens failed before the head bearing was not sufficiently developed. Confined specimens with stirrups placed along whole splice length have enhanced strengths in bearing as well as bond because the stirrups prevented prying action and improved bond capacity. Bond failure occurred in locally confined specimens where stirrups were placed only at the ends of splice length. The stirrups at ends of splice lengths can prevent prying action but the bond capacity did not increase. From regression analysis of test results, an equation to predict anchorage strength of headed bars was developed. The proposed equation consists of bond and bearing contributions and includes transverse reinforcement index. The average ratio of tests to predictions is 1.0 with coefficient of variation of 6%.

• Geomechanics and Engineering
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• 제14권3호
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• pp.233-240
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• 2018

Pullout tests are usually employed to determine the ultimate bearing capacity of reinforced soil, and the load-displacement curve can be obtained easily. This paper presents an analytical solution for predicting the full-range mechanical behavior of a buried planar reinforcement subjected to pullout based on a bi-linear bond-slip model. The full-range behavior consists of three consecutive stages: elastic stage, elastic-plastic stage and debonding stage. For each stage, closed-form solutions for the load-displacement relationship, the interfacial slip distribution, the interfacial shear stress distribution and the axial stress distribution along the planar reinforcement were derived. The ultimate load and the effective bond length were also obtained. Then the analytical model was calibrated and validated against three pullout experimental tests. The predicted load-displacement curves as well as the internal displacement distribution are in closed agreement with test results. Moreover, a parametric study on the effect of anchorage length, reinforcement axial stiffness, interfacial shear stiffness and interfacial shear strength is also presented, providing insights into the pullout behaviour of planar reinforcements of MSE structures.

• Structural Engineering and Mechanics
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• 제41권3호
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• pp.379-393
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• 2012

Of the various methods of splicing reinforcing bar in reinforced concrete structure, mortar-filled sleeve reinforcement splice offers diverse benefits, not only in terms of structural performance but also for the construction process. Consequently, after the mortar-filled sleeve splices have been developed in recent years, research and development on these splices has been actively carried out, in order to evaluate its macro structural performance, such as its strength and stiffness, with the aim of enabling this system to be applied to construction in the field as early as possible. However, to make a proper evaluation on the overall structural performance of the mortar-filled sleeve reinforcing bar splice, it is of critical importance to understand the lateral confining action of the sleeve, which is known to affect the bond strength between the embedded bar and mortar in the sleeve. Accordingly, in this study, an experiment of monotonic loading and cyclic loading was conducted with a full-sized mortar-filled sleeve splice attaching strain gauges on the sleeve surface with experimental variables such as development length of bar, etc. Based on the test results, the effect of the lateral confining action of the sleeve was analyzed and considered in terms of the bond strength between the bar and mortar in this splice.