• Restorative Dentistry and Endodontics
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• v.48 no.1
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• pp.8.1-8.8
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• 2023

Objectives: This study was designed to evaluate the parameters of bonding performance to root dentin, including push-out bond strength and dentinal tubular biomineralization, of a hydraulic bioceramic root-end filling material premixed with dimethyl sulfoxide (Endocem MTA Premixed) in comparison to a conventional powder-liquid-type cement (ProRoot MTA). Materials and Methods: The root canal of a single-rooted premolar was filled with either ProRoot MTA or Endocem MTA Premixed (n = 15). A slice of dentin was obtained from each root. Using the sliced specimen, the push-out bond strength was measured, and the failure pattern was observed under a stereomicroscope. The apical segment was divided into halves; the split surface was observed under a scanning electron microscope, and intratubular biomineralization was examined by observing the precipitates formed in the dentinal tubule. Then, the chemical characteristics of the precipitates were evaluated with energy-dispersive X-ray spectroscopic (EDS) analysis. The data were analyzed using the Student's t-test followed by the Mann-Whitney U test (p < 0.05). Results: No significant difference was found between the 2 tested groups in push-out bond strength, and cohesive failure was the predominant failure type. In both groups, flake-shaped precipitates were observed along dentinal tubules. The EDS analysis indicated that the mass percentage of calcium and phosphorus in the precipitate was similar to that found in hydroxyapatite. Conclusions: Regarding bonding to root dentin, Endocem MTA Premixed may have potential for use as an acceptable root-end filling material.

• Journal of the Korea Institute of Building Construction
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• v.24 no.1
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• pp.23-34
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• 2024

This research aims to assess the flexural bonding efficacy of polymer-cement composites(PCCs) in mending cracks within reinforced concrete(RC) structures. The study involved infilling PCCs into cement mortar cracks of varying dimensions, followed by evaluations of enhancements in flexural adhesion and strength. The findings indicate that the flexural bond performance of PCCs in crack repair is influenced by the cement type, polymer dispersion, and the polymer-to-binder ratio. Specifically, the use of ultra-high early strength cement combined with silica fume resulted in an up to 19.0% improvement in flexural bond strength compared to the application of ordinary Portland cement with silica fume. It was observed that the augmentation in flexural strength of cement mortar filled with PCCs was significantly more dependent on the depth of the crack rather than the width. Furthermore, PCCs not only acted as repair agents but also as reinforcement materials, enhancing the flexural strength to a certain extent. Consequently, this study concludes that PCCs formulated with ultra-high early strength cement, various polymer dispersions, silica fume, and a high polymer-to-binder ratio ranging from 60% to 80% are highly effective as maintenance materials for crack filling in practical settings.

• Polymer(Korea)
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• v.39 no.1
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• pp.1-5
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• 2015

The effects of zeolite on the thermal stability of poly(vinyl chloride) (PVC) were investigated by the static thermal stability test, pyrolysis experiment and ultraviolet spectrum. The results showed that the porous zeolite could absorb hydrogen chloride (HCl), which suppressed the catalysis of HCl on thermal degradation of PVC, thus improved the thermal stability of PVC. The oxidizing acid which was loaded on zeolite had oxidated on the double bond that formed during the dehydrochlorination of PVC. This process could prohibit the growth of the conjugated polyene and improved the color of PVC. Hence, zeolite might be possible to come up with a high performance thermal stabilizer.

• Journal of the Korean Chemical Society
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• v.60 no.6
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• pp.410-414
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• 2016

The anharmonic frequency of a local OH stretching mode of a water monomer and dimer was calculated using various levels of density functional theory. The quantum chemical potential energy curves as a function of the OH bond distance were calculated, and they were fitted with the Morse potential function to analytically obtain the fundamental transition frequency. By comparing those values with the frequencies similarly calculated using an ab initio quantum chemical method, the coupled cluster theory including both single and double excitations with the perturbative inclusion of triple excitation in the complete basis limit, the accuracy of various density functional methods in the calculation of anharmonic vibration frequency of water molecules was assessed. For a water monomer, X3LYP and B3LYP methods give the best accuracy, whereas for a water dimer, B972, LCBLYP, ${\omega}B97X$, ${\omega}B97$ methods show the best performance.

• Journal of the Korea Concrete Institute
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• v.16 no.4 s.82
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• pp.573-579
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• 2004

For the fast construction and replacement of bridges in urban area, a prefabricated bridge system can be an excellent alternative. Details of prefabricated slabs for PSC girders were developed and static tests on shear connections were conducted to propose design equations of the shear connection. Stirrups and stud connectors were used as shear connectors and non-shrink mortar was used for the filling material in shear pockets for shear connectors. Stirrups and studs were fabricated to insert embedded nut-type devices in PSC girders. Shear strength of the shear connection considering chemical bond, friction and mechanical connectors was evaluated and empirical equations were suggested. Due to the mechanical connectors, ultimate slip capacity of the shear connection was sufficient for shear load redistribution, and suggested details of the shear connection showed good performance in terms of strength and ductility.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2001.11a
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• pp.70-75
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• 2001

There is a problem to be solved for improvement of durability and safety for concrete When the waterproofing and anticorrosive work of main concrete are design, the material a of construction need to be correctly applied to appropriate circumstance conditions. Epoxy mostly been used for concrete water tank structure. Lately, lots of subjects on adaption res in mortar for waterproofing and anticorrosive are under discussion. Then, we attempt to approach by evaluating and comparing every capabilities with waterproofing materials in this experiment. Capability evaluation items include the bond age and curing conditions, the bond strength after accelerated weathering test and fret impact resistance, a mount of water, seepage quan Through the experiment analysis, we found that waterproofingtity, drinking water chemicals resistance. and anticorrosive resin mortar used with glass fiber cloth, inorgar material is dominantly superior to other waterproofing materials. According to this paper, we suggest the resin mortar as a new surface treatment material water tank structure.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.203-208
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• 1999

The purpose of this study is to examine the bond properties of polymer cement mortar. Generally, cement mortar using polymer has been used that recovering the deteriorative concrete structure performance. In this case, it is very important problem to become a monolithic construction by bonding property. In this study, it is evaluated with other properties that adhesion strength between polymer cement mortar and concrete substrate. And polymer cement mortar was compared with plain cement mortar by scanning electron microscope.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.543-546
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• 2005

The development and maintenance of a sound bond are an essential requirements of concrete repair and replacement. The bond property of a bonded overlay to its substrate concrete during the lifetime is one of the most important performance requirements which should be quantified This study was performed to investigate the characteristics of adhesive strength for overlay concrete. Three different removal methods of deteriorated concrete such as chip-patch, mill-patch and water-jet were varied in this study. According to the adhesive strength of pull- off test, case III using water-jet was measured $2\~3$ times higher than that of chip-patch or mill-patch.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.61-64
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• 2005

Recently to repair the structure of deteriorated concrete, LMC rehabilitation method is introduced. however, this method has the possible risks of brittle failure depending on bond performance of the interface. the prediction of interfacial behavior becomes essential to protect the failure. all of the studies which have been done about this field are only about material property such as strength, durability, bond. there is not enough data and studies about structural behavior and numerical analysis. therefore, in this study A flexural nonlinear analysis model of ABAQUS was proposed to predict the load-deflection response, interfacial stress, and ultimate strength. The parameter study showed that overlay thickness was a main influencing factor to the behavior of RC beam overlayed by LMC.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05b
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• pp.63-66
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• 2011

The aim of this study is to estimate the field applicability of PBFM to replace in-site soil with pile backfill used to replace the existing cement paste. As results, the flowability, segregation and bleeding, and bond strength of PBFM was a good performance than that of the existing cement paste. But the skin friction of pile by Pile Driving Analyzer (PDA) and compressive strength was slightly decreased than that of the existing cement paste. However, as pile backfill materials, and in terms of economics and environment, the applicability of PBFM is considered very effective.