• Title/Summary/Keyword: Boiling Point

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Effects of Boliing, Steaming, and Chemical Treatment on Solid Wood Bending of Quercus acutissima Carr. and Pinus densiflora S. et. Z. (자비(煮沸), 증자(蒸煮) 및 약제처리(藥劑處理)가 상수리나무와 소나무의 휨가공성(加工性)에 미치는 영향(影響))

  • So, Won-Tek
    • Journal of the Korean Wood Science and Technology
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    • v.13 no.1
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    • pp.19-62
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    • 1985
  • This study was performed to investigate: (i) the bending processing properties of silk worm oak (Quercus acutissima Carr.) and Korean red pine (Pinus densiflora S. et Z.) by boiling and steaming treatments; (ii) the effects of interrelated factors - sapwood and heartwood, annual ring placement, softening temperature and time, moisture content. and wood defects on bending processing properties; (iii) the changing rates of bending radii after release from a tension strap, and (iv) the improving methods of bending process by treatment with chemicals. The size of specimens tested was $15{\times}15{\times}350mm$ for boiling and steaming treatments and $5{\times}10{\times}200mm$ for treatments with chemicals. The specimens were green for boiling treatments and dried to 15 percent for steaming treatments. The specimens for treatments with chemicals were soaked in saturated urea solution, 35 percent formaldehyde solution, 25 percent polyethylene glycol -400 solution, and 25 percent ammonium hydroxide solution for 5 days and immediately followed the bending process, respectively. The results obtained were as follows: 1. The internal temperature of silk worm oak and Korean red pine by boiling and steaming time was raised slowly to $30^{\circ}C$ but rapidly from $30^{\circ}C$ to $80-90^{\circ}C$ and then slowly from $80-90^{\circ}C$ to $100^{\circ}C$. 2. The softening time required to the final temperature was directly proportional to the thickness of specimen. The time required from $25^{\circ}C$ to $100^{\circ}C$ for 15mm-squared specimen was 9.6-11.2 minutes in silk worm oak and 7.6-8.1 minutes in Korean red pine. 3. The moisture content (M.C.) of specimen by steaming time was increased rapidly first 4 minutes in the both species, and moderately from 4 to 20 minutes and then slowly and constantly in silk worm oak, and moderately from 4 to 15 minutes and then slowly and constantly in Korean red pine. The M.C. of 15mm-squared specimen in 50 minutes of steaming was increased to 18.0 percent in the oak and 22.4 percent in the pine from the initial conditioned M.C. of 15 percent The rate of moisture adsorption measured was therefore faster in the pine than in the oak. 4. The mechanical properties of the both species were decreased significantly with the increase of boiling rime. The decrement by the boiling treatment for 60 minutes was measured to 36.6-45.0 percent in compressive strength, 12.5-17.5 percent in tensile strength, 31.6-40.9 percent in modulus of rupture, and 23.3-34.6 percent in modulus of elasticity. 5. The minimum bending radius (M.B.R.) of sapwood and heartwood was 60-80 mm and 90 mm in silk worm oak, and 260 - 300 mm and 280 - 300 mm in Korean red pine, respectively. Therefore, the both species showed better bending processing properties in sapwood than in heartwood. 6. The M.B.R. of edge-grained and flat-grained specimen in suk worm oak was 60-80 mm, but the M.B.R. in Korean red pine was 240-280 mm and 260-360 mm, respectively. Comparing the M.B.R. of edge-grained with flat-grained specimen, in the pine the edge-grained showed better bending processing property than the flat-grained. 7. The bending processing properties of the both species were improved by the rising of softening temperature from $40^{\circ}C$ to $100^{\circ}C$. The minimum softening temperature for bending was $90^{\circ}C$ in silk worm oak and $80^{\circ}C$ in Korean red pine, and the dependency of softening temperature for bending was therefore higher in the oak than in the pine. 8. The bending processing properties of the both species were improved by the increase of softening time as well as temperature, but even after the internal temperature of specimen reaching to the final temperature, somewhat prolonged softening was required to obtain the best plastic conditions. The minimum softening time for bending of 15 mm-squared silk worm oak and Korean red pine specimen was 15 and 10 minutes in the boiling treatment, and 30 and 20 minutes in the steaming treatment, respectively. 9. The optimum M.C. for bending of silk worm oak was 20 percent, and the M.C. above fiber saturation point rather degraded the bending processing property, whereas the optimum M.C. of Korean red pine needed to be above 30 percent. 10. The bending works in the optimum conditions obtained as seen in Table 24 showed that the M.B.R. of silk worm oak and Korean red pine was 80 mm and 240 mm in the boiling treatment, and 50 mm and 280 mm in the steaming treatment, respectively. Therefore, the bending processing property of the oak was better in the steaming than in the boiling treatment, but that of the pine better in the boiling than in the steaming treatment. 11. In the bending without a tension strap, the radio r/t of the minimum bending radius t to the thickness t of silk worm oak and Korean red pine specimen amounted to 16.0 and 21.3 in the boiling treatment, and 17.3 and 24.0 in the steaming treatment, respectively. But in the bending with a tension strap, the r/t of the oak and the pine specimen decreased to 5.3 and 16.0 in t he boiling treatment, and 3.3 and 18.7 in the steaming treatment, respectively. Therefore, the bending processing properties of the both species were significantly improved by the strap. 12. The effect of pin knot on the degradation of bending processing property was very severe in silk worm oak by side, e.g. 90 percent of the oak specimens with pin knot on the concave side were ruptured when bent to a 100 mm radius but only 10 percent of the other specimens with pin knot on the convex side were ruptured. 13. The changing rate in the bending radius of specimen bent to a 300 mm radius after 30 days of exposure to room temperature conditions was measured to 4.0-10.3 percent in the boiling treatment and 13,0-15.0 percent in the steaming treatment. Therefore, the degree of spring back after release was higher in the steaming than in the boiling treatment. And the changing rate of moisture-proofing treated specimen by expoxy resin coating was only -1.0.0 percent. 14. Formaldehyde, 35 percent solution, and 25 percent polyethylene glycol-400 solution found no effect on the plasticization of the both species, but saturated urea solution and 25 percent ammonium hydroxide solution found significant effect in comparison to non-treated specimen. But the effect of the treatment with chemicals alone was inferior to that of the steaming treatment, and the steaming treatment after the treatment with chemicals improved 10-24 percent over the bending processing property of steam-bent specimen. 15. Three plasticity coefficients - load-strain coefficient, strain coefficient, and energy coefficient - were evaluated to be appropriate for the index of bending processing property because the coefficients had highly significant correlation with the bending radius. The fitness of the coefficients as the index was good at load-strain coefficient, energy coefficient, and strain coefficient, in order.

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Development of Cryogenic Test Rig for Ball-Bearing and Evaluation of the Performance of the Prototype Ball-Bearing of Turbo pump (극저온 환경용 볼베어링 시험장치 개발 및 터보펌프용 볼베어링 시제품의 성능평가)

  • Jo, Jun Hyeon;Rhim, Yoon Chul;Lee, Sungchul;Kim, Choong Hyun
    • Tribology and Lubricants
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    • v.28 no.4
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    • pp.167-172
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    • 2012
  • The turbo pump of a liquid rocket engine is composed of three main parts: the oxidizer pump, fuel pump, and turbine. Liquid oxygen ($LO_X$) is the working fluid in the cryogenic environment in the oxidizer pump, but tests are usually performed using liquid nitrogen ($LN_2$), which has a boiling point similar to that of $LO_X$ but is comparatively safer and easier to use for the test. In this study, a bearing test rig is developed and its performance is evaluated using a cryogenic ball bearing with $LN_2$ as the working fluid. Verifying the performance of the bearing test rig is crucial for ensuring correct working of the turbo pump unit in the liquid rocket engine. A stable test rig for the bearing in a cryogenic environment makes the bearing technology enhance its reliability. The test results show that the system operates stably and the requirement of performance time of 500 s is met. The test results of temperature, motor speed, and torque are discussed. The developed cryogenic bearing test rig is expected to help in widening knowledge and expanding research on ball bearings in the future.

Effect of Marangoni flow on Surface Roughness and Packing Density of Inkjet-printed Alumina Film by Modulating Ink Solvent Composition

  • Jang, Hun-Woo;Kim, Ji-Hoon;Kim, Hyo-Tae;Yoon, Young-Joon;Kim, Jong-Hee;Hwang, Hae-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.99-99
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    • 2009
  • Two different micro-flows during the evaporation of ink droplets were achieved by engineering both surface tension gradient and compositional gradient across the ink droplet: (1) Coffee-ring generating flow resulting from the outward flow inside the ink droplet & (2) Marangoni flow leading to the circulation flow inside the ink droplet. The surface tension gradient and the compositional gradient in the ink droplets were tailored by mixing two different solvents with difference surface tension and boiling point. In order to create the coffee-ring generating flow (outward flow), a single-solvent system using N,N-dimethylformamide with nano-sized spherical alumina particles was formulated, Marangoni flow (circulation flow) was created in the ink droplets by combining N,N-dimethylformamide and fotmamide with the spherical alumina powders as a co-solvent ink system. We have investigated the effect of these two different flows on the formation of ceramic films by inkjet printing method, The packing density of the ceramic films printed with two different ink systems (single- and co-solvent systems) and their surface roughness were characterized. The dielectric properties of these inkjet-printed ceramic films such as dielectric constant and dissipation factor were also studied in order to evaluate the feasibility of their application to the electronic ceramic package substrate.

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Contribution of thermal-hydraulic validation tests to the standard design approval of SMART

  • Park, Hyun-Sik;Kwon, Tae-Soon;Moon, Sang-Ki;Cho, Seok;Euh, Dong-Jin;Yi, Sung-Jae
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1537-1546
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    • 2017
  • Many thermal-hydraulic tests have been conducted at the Korea Atomic Energy Research Institute for verification of the SMART (System-integrated Modular Advanced ReacTor) design, the standard design approval of which was issued by the Korean regulatory body. In this paper, the contributions of these tests to the standard design approval of SMART are discussed. First, an integral effect test facility named VISTA-ITL (Experimental Verification by Integral Simulation of Transients and Accidents-Integral Test Loop) has been utilized to assess the TASS/SMR-S (Transient and Set-point Simulation/Small and Medium) safety analysis code and confirm its conservatism, to support standard design approval, and to construct a database for the SMART design optimization. In addition, many separate effect tests have been performed. The reactor internal flow test has been conducted using the SCOP (SMART COre flow distribution and Pressure drop test) facility to evaluate the reactor internal flow and pressure distributions. An ECC (Emergency Core Coolant) performance test has been carried out using the SWAT (SMART ECC Water Asymmetric Two-phase choking test) facility to evaluate the safety injection performance and to validate the thermal-hydraulic model used in the safety analysis code. The Freon CHF (Critical Heat Flux) test has been performed using the FTHEL (Freon Thermal Hydraulic Experimental Loop) facility to construct a database from the $5{\times}5$ rod bundle Freon CHF tests and to evaluate the DNBR (Departure from Nucleate Boiling Ratio) model in the safety analysis and core design codes. These test results were used for standard design approval of SMART to verify its design bases, design tools, and analysis methodology.

Comparisons of Volatile Compounds Extracted from Pinus densiflora by Headspace Analysis (Headspace법에 의한 솔향의 분석)

  • 이미정;정은주;이신조;조지은;이양봉;조현종;윤정로
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.1
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    • pp.26-31
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    • 2002
  • Volatile compounds from three parts of needles, sprouts and twigs in Pinus densiflora were extracted by solid phase microextraction (SPME) and dynamic headspace analysis (DHA). separated by gas chromatography, and identified by using mass selective detecter and Kovat's retention index. The amounts of monoterpenes isolated by SPME and DHA were 66.7% and 14.3% in needles, 90.6% and 0.7% in sprouts, and 90.6% and 1.2% in twings, respectively. The amounts of sesquiterpenes detected only by SPME were 25.8% in needles, 4.4% in twings and 1.5% in sprouts. And the amounts of oxygenated terpenes isolated by SPME and DHA were 4.7% and 79.0% in sprouts, 3.7% and 70.4% in twigs, and 1.0% and 50.7% in needles, respectively. The kinds of volatile compounds isolated by SPME were similar to those by solvent extraction, but the number of compounds identified to hate a boiling point below 5$0^{\circ}C$ by UHA was larger than that of SPME.

Analysis of Students' Responses on the Items of Chemistry II in the College Scholastics Ability Test (대학수학능력시험 화학II 문항에 대한 학생들의 응답 분석)

  • Hong, Mi-Young;Jeon, Kyung-Moon;Yi, Bum-Hong;Lee, Yang-Rak
    • Journal of The Korean Association For Science Education
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    • v.22 no.1
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    • pp.204-213
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    • 2002
  • In this study, the students' responses on the items of chemistry II in the College Scholastics Ability Test (CSAT) implemented for the past 3 years since 1999 was investigated. The number of applicants and mean score of chemistry II, average percent correct by contents and inquiry process, and the items with high and/or low percent correct are analysed and discussed. The percentage of applicants for natural science track is reduced each year. However, more than 25% of natural science track applied to chemistry II, which ranked second to biology II. The mean score of chemistry II was increased in 2001 along with those of other subjects. There is no difference in average percent correct either by contents or inquiry process. Students performed generally poor at solving test items relating to 'colligative properties of solution' such as 'boiling point elevation' or 'osmotic pressure', and very well at solving test items relating to 'reaction rates'. Educational implications are discussed.

A Case of Metal Fume Fever Associated with Copper Fume in a Welder (용접공에서 발생한 구리흄에 의한 금속열 1례)

  • Lim, Hyun-Sul;Cheong, Hae-Kwan
    • Journal of Preventive Medicine and Public Health
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    • v.31 no.3 s.62
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    • pp.414-423
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    • 1998
  • Metal fume fever has been known as an occupational disease is induced by intense inhalation of fresh metal fume with a particle size smaller than $0.5{\mu}m\;to\;1{\mu}m$. The fumes originate from heating metals beyond their boiling point, as happens, for example, in welding operations. Oxidation usually accompanies this process. In most cases, this syndrome is due to exposure to zinc oxide fumes; however, other metals like copper, magnesium, cadmium, manganese, and antimony are also reported to produce such reactions. Authors report a case of metal fume fever suspected to be associated with copper fume inhalation. The patient was a 42-year-old male and was a smoker. He conducted inert gas tungsten arc welding on copper-coated materials without safety precautions such as a protective mask and adequate ventilation. Immediately after work, he felt metallic taste in his mouth. A few hours after welding, he developed headache, chilling sensation, and chest discomfort. He also complained of myalgia, arthralgia, feverish sensation, thirst, and general weakness. Symptoms worsened after repeated copper welding on the next day and subsided gradually following two weeks. Laboratory examination showed a transient increase of neutrophil count, eosinophilia, elevated erythrocyte sedimentation rate, and positive C-reactive proteinemia. Blood and urine copper level was also increased compared to his wife. Before this episode, he experienced above complaints several times after welding with copper materials but welding of other metals did not produce any symptoms. It was suggested that copper fume would have induced metal fume fever in this case. Further investigations are needed to clarify their pathogenic mechanisms.

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Effect of Heating Time on Contents of Amino Acids and Related Compounds in the Muscle Extract of Snakehead (가열시간별 가물치육 엑스중의 아미노산 및 그 관련화합물의 변화)

  • HAN Young-Sil;KIM Kyung-Jin;PYEUN Jae-Hyeung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.2
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    • pp.141-146
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    • 1986
  • As a fundamental study of fresh water fish on a suitable cooking method and on flavor components from the view point of food science, changes in the free amino acid composition of the muscle extracts of snakehead (Channa argus) during heating in boiling water were investigated. The muscle extract of raw fish was featured a very high content of glycine, taurine, glutamic acid and histidine, and a large amount of urine was also determined in the extract; the former four components comprised about $53\%$ of the total free amino acids. The total extractable nitrogen was greatly increased with the heating time till 120 minutes of heating, while it gradually decreased thereafter. The apparently increased components on heating of 120 minutes were taurine, glycine, alanine, hydroxyproline, and ${\beta}$-aminoisobutyric acid, etc. including urea. After hydrolysis of the extracts, some of the amino acids were increased, the content of ethanolamine, lysine, 1-methyl histidine, phenylalanine, glutamic acid and taurine, etc. were apparently increased.

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Biodiesel Production Using Castor Oil and Quality Analysis (피마자유로부터 바이오디젤 생산을 위한 물성 분석)

  • Kim, Deogkeun;Lee, Joonpyo;Park, Soonchul;Lee, Jinsuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.176.2-176.2
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    • 2011
  • 피마자유(Castor oil)는 합성수지, 그리스, 유압용 오일, 윤활기유 등의 다양한 용도로 쓰이는 오일로서 점도가 높고 무색에서 황갈색을 띈다. 피마자유 추출은 압착 착유 또는 용매 추출로 얻게 되며 본 실험에 사용된 오일은 압착 착유한 것으로 매우 진한 갈색을 띄는 정제전 오일을 이용하였다. 실험에 사용된 피마자유의 초기 산가는 1mgKOH/g 이하로 낮은 유리지방산 함량을 보였으며 수분은 0.3%로 전이에스테르화 반응을 위해서는 수분 증발이 필요했다. 피마자유의 바이오디젤 생산을 위해 진행된 물성 분석 항목은 산가, 수분, 인함량, 황함량, 점도, 고형물이며 원료유와 그 바이오디젤에 대해 각각 물성 분석을 실시하였다. 피마자유의 가장 큰 특징은 다른 식물성 오일과는 다르게 오일이 알코올에 녹는 특성이 있으며 이런 이유로 전이에스테르화 반응 후 바이오디젤과 글리세롤이 분리되지 않는 문제점을 갖고 있다. 피마자유를 이용해 제조한 바이오디젤, 즉 지방산메틸에스터의 함량을 분석한 결과 약 90%의 메틸에스터화 반응 전환율을 나타내었으나 국내외 품질규격상의 탄소수 C14~C24:0의 지방산 에스터(fatty acid methyl esters)로 검출되는 바이오디젤의 함량은 10% 미만으로 나타났으며 나머지 90%는 라이신올레익산메틸에스터(ricinoleic acid methyl ester)로 분석되었다. 따라서, 기존의 대두유, 유채유, 팜유, 폐식용유로부터 제조한 바이오디젤과 물성이 매우 상이하고 특히 끊는점(boiling point)과 점도가 높아 경유 대체연료로는 활용이 불가능할 것으로 판단된다. 하지만 기존의 다양한 용도의 오일로 사용하기 위해 정제하는 과정에서 전체 착유 오일중의 약 10%만을 선택적으로 분리하여 바이오디젤 원료로 활용하는 방안은 가능할 것으로 판단된다.

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Characteristics of Icing Phenomenon with Droplet of an Injector for Liquid Phase LPG Injection System (LPG 액상분사식 인젝터에서 후적에 의한 아이싱 특성 연구)

  • Park, Cheol-Woong;Kim, Chang-Up;Choi, Kyo-Nam;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.9-16
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    • 2007
  • Since the liquid phase LPG injection(LPLI) system has an advantage of higher power and lower emission characteristics than the mixer type fuel supply system, many studies and applications have been conducted. However, the heat extraction, due to the evaporation of liquid fuel, causes not only a dropping of LPG fuel but also icing phenomenon that is a frost of moisture in the air around the nozzle tip. Because both lead to a difficulty in the control of accurate air fuel ratio, it can result in poor engine performance and a large amount of HC emissions. The experimental investigation was carried out on the bench test rig in this study. It was found that n-butane, that has a relatively high boiling point($-0.5^{\circ}C$), was a main species of droplet composition and also found that the droplet problem was improved by the use of a large inner to outer bore ratio nozzle whose surface roughness is smooth. The icing phenomena were decreased when the an engine head temperature was increased, although a large amount of icing deposit was still observed in the case of $87^{\circ}C$. Also, it was observed that the icing phenomenon is improved by using anti-icing bushing.