• Journal of the Korean Chemical Society
• /
• v.46 no.6
• /
• pp.523-527
• /
• 2002

Partition coefficient related composition of LPG are studied. Analysed sulfur compounds are ethyl mer-captan,n-propyl mercaptan and n-butyl mercaptan. The composition of liquid phase and gas phase in LPG are deter-mined by gas chromatography. The partition coefficient to related the boiling point of sulfur compounds, the temperature and the compositions of solvents, determined by using MLR(multiple linear regression) of SAS is follows; Kpc= $0.61222({\pm}0.6578)-0.04670({\pm}0.000959)Bp+0.26984(\pm0.06504)C4+0.003803(^{\circ}ae0.0019993)Tk,$ N=24, F=14.851, $R^2_{adj}$=0.6437. The boiling points of sulfur compounds at atmospheric pressure and the compositions of LPG effect mostly on partition coefficients. It is presumed that the gas odor elevating effects should be increased, where being on high tem-perature and larger amounts of n-butane.

• Journal of ILASS-Korea
• /
• v.19 no.1
• /
• pp.1-8
• /
• 2014

Liquefied petroleum gas (LPG) is regarded as an alternative fuel for spark ignition engine due to similar or even higher octane number. In addition, LPG has better fuel characteristics including high vaporization characteristic and low carbon/hydrogen ratio leading to a reduction in carbon dioxide emission. Recently, development of LPG direct injection system started to improve performance of vehicles fuelled with LPG. However, spray characteristics of LPG were not well understood, which is should be known to develop injector for LPG direct injection engines. In this study, effects of operation condition including ambient pressure, temperature, and injection pressure on spray properties of n-butane were evaluated and compared to gasoline in a multi-hole injector. As general characteristics of both fuels, spray penetration becomes smaller with an increase of ambient pressure as well as a reduction in the injection pressure. However, it is found that evaporation of n-butane was faster compared to gasoline under all experimental condition. As a result, spray penetration of n-butane was shorter than that of gasoline. This result was due to higher vapor pressure and lower boiling point of n-butane. On the other hand, spray angle of both fuels do not vary much except under high ambient temperature conditions. Furthermore, spray shape of n-butane spray becomes completely different from that of gasoline at high ambient temperature conditions due to flash boiling of n-butane.

• Journal of ILASS-Korea
• /
• v.13 no.3
• /
• pp.117-125
• /
• 2008

The correlations for the prediction of maximum liquid-phase penetration in diesel spray are reviewed in this study. The existing models developed for the prediction of maximum liquid-phase penetration can be categorized as the zero-dimensional (empirical) model, the multi-dimensional model and the other model. The existing zero-dimensional model can be classified into four groups and the existing multidimensional models can be classified into three groups. The other model includes holistic hydraulic and spray model. The maximum liquid-phase penetration is mainly affected by nozzle diameter, fuel volatility, injection pressure, ambient gas pressure, ambient gas density and fuel temperature. In the case of empirical correlations incorporated with spray angle, the predicted results will be different according to the selection of correlation for spray angle. The research for the effect of boiling point temperatures on maximum liquid-phase penetration is required. In the case of multidimensional model, there exist problems of the grid and spray sub-models dependency effects.

• Journal of ILASS-Korea
• /
• v.4 no.1
• /
• pp.27-33
• /
• 1999

An experimental study has been conducted to clarify the effect of vapor on droplet evaporation. Droplets of water, ethanol, n-hexadecane and n-heptane were exposed in air stream. Temperature, pressure, and flow velocity in the ambient air are 470K, 1 atm, and 2m/s, respectively. Measurements are carried out for the wide range of water vapor concentration$(0%\sim40%)$. To obtain the time histories of droplet diameter, suspended droplet in hot and humid air stream was synchronized with a back flash light, and enlarged droplet images were taken on a CCD camera. With the vapor concentration increasing, the evaporation rate constant of water droplet decrease slightly and the droplet of ethanol and n-heptane increase actively. The evaporation rate constant of n-hexadecane which has higher boiling point than water increases within around 30% of the concentration.

• Journal of Advanced Marine Engineering and Technology
• /
• v.25 no.3
• /
• pp.588-594
• /
• 2001

The aim of this paper is to develop the low temperature vacuum dryer, with low initial investments and operating costs, easy operating method and trouble-free operation Usally operations just below atmospheric pressure, as with direct dryers, but some are built for vacuum operation with pressure as low 50 mmHg abs. The lowers the boiling point to $39^{\circ}C$ The experimental data of quantitative analysis for using practically were obtained by the constant drying rate period and reducing drying rate period according to the temperature of hot water which is the experimental parameters of present experiment. As the results, it took about 20 hours for material to reach about 18% of the final moisture content is order to store products for a long time about 450% of the early moisture content at the beginning of drying and maximum drying rate comes to about 0.30 kg/m2hr at about 350% of the moisture content.

• Journal of Physiology & Pathology in Korean Medicine
• /
• v.18 no.6
• /
• pp.1548-1551
• /
• 2004

studied on the physicochemistrical property of the clean active water depositting on the ceramic stone by the mineral-Oriental medicine. The results are as follows. The cluster of the clean active water is observed 53-66.5㎐ for contral water. The clean active water is observed 7.2 ph and 1.3330 refractive index for contral water. In the chemical experimental test by ICP, the clean active water is observed 102℃ in boiling point and 4.8㎎/100g V.E for 0㎎g/100g of contral water. In the antibiotic experimentation, an anion, the dimintion index of bacilli, radiation degree and radiate energy of the clean active water increased for contral water. And in the deodorization experimentation, the clean active water is observed 95% deodorization index.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.21 no.3
• /
• pp.126-133
• /
• 2013

Recently, it was reported that complaints about problems being experienced with the performance of vehicles operating on autogas in Korea. The problem was being assumed due to contaminants in LPG and an oily material which was being deposited in vaporizer, injector in LPG fuel system. This study is focused on the analysis of contaminant of automobile parts on LPG fuel system. The sampling points of contaminants are injectors, fuel filters, vaporizer in automobile equipment and it was also investigated by GC-MS, ICP-AES, SIMDIS and EDS. According to results, it was presumed that this contaminants had been analyzed plasticizers with hydrocarbons with high boiling point, Fe from steel corrosion, greases from gas station.

• Journal of the Korean Applied Science and Technology
• /
• v.6 no.2
• /
• pp.45-51
• /
• 1989

Allyl aliphatic carboxylates were synthesized by azotropic reaction with benzene between allyl alcohol and capric acid, lauric acid, myristic acid, palmitic acid or stearic acid respectively. allyl aliphatic carboxylates oligomers were prepared from polymerization giving allyl aliphatic carvboxylates in the presence of potassium persulfate in methanol, and the ${\alpha}-sulfonation$ of these five allyl aliphatic carboxylates oligomers were carried by direct addition of dry sulfur trioxide. Especially, molecular weights of fatty acid alylester oligomers and their sodium salts of ${\alpha}-sulfo$ fatty acid allylester oligomers were measured by boiling point method.

• Tribology and Lubricants
• /
• v.29 no.2
• /
• pp.117-123
• /
• 2013

Dimethyl ether (DME) has a high cetane number that is suitable for diesel fuel. DME does not contain sulfur or nitrogen, and is an oxygenated fuel so it produces no particulate matter when combusted and is environmentally friendly. DME fuel for diesel engines show excellent material properties such as a lower volumetric heating value, lower boiling point, lower lubricity, and stronger solvent effect than light oil. This study experimentally examined a lubricity improver (LI) for dimethyl ether. A diesel LI based on biodiesel and fatty acid methyl ester was tested among DME LI candidates. The long-term storage stability and physical properties of the optimum LI for DME were determined.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1996.10a
• /
• pp.34-39
• /
• 1996

There is much recent interests in applying membrane separation technologies, especially for organic liquid and vapor separation or removing dissolved organics from water. Pervaporation separation can separate azeotropic mixtures and mixtures close to boiling point, and it has a potential for energy saving process instead of distillation. Removal of chlorinated oraganics from water is other measure application for pervaporation separation. Contaminated pollutant must be removed from water, and a pervaporation can effectively remove the pollutant. Air pollution by organic vapor recently became serious enviromncntal problem, and removing organic vapor from air is important application of the membrane technology.