• Title/Summary/Keyword: Blue-light-emitting polymer

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Synthesis and Characterization of Poly[9,10-diphenylanthracene-4$^\prime$, 4$^\prime^\prime$-ylenevinylene-3,6-(N-2-ethylhexyl)carbazole]

  • Kim, Yun Mi;Park, Gi Min;Gwon, Sun Gi
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.975-978
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    • 2001
  • A novel poly[9,10-diphenylanthracene-4',4"-ylenevinylene-3,6-(N-2-ethyl hexyl)carbazole] containing alternate diphenylanthracene and carbazole unit was synthesized by the Wittig reaction. The obtained polymer was soluble in common organic solvents and thermally stable up to 380 $^{\circ}C.$ The polymer gives rise to bright blue fluorescence both in solution and in thin solid films. The light emitted from the device (ITO/polymer/Al) was greenish-blue in color and clearly visible in daylight.

The Investigation of Photolithographic Patterning Method for Polymer Light Emitting Diodes (PLEDs) (고분자 전기 발광 다이오드(PLEDs)를 위한 포토리소그라피 패터닝 방법에 관한 연구)

  • Kim, Mi-Kyung;Lee, Jeong-Ik;Kim, Duck-Il;Hwang, Chi-Sun;Yang, Yong-Suk;Oh, Ji-Young;KoPark, Sang-He;Chu, Hye-Yong;Kim, Suk-Kyung;Hwang, Do-Hoon;Lee, Hyung-Jong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.106-108
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    • 2004
  • We have investigated the photolithographic patterning method of light emitting polymer film for polymer light emitting diodes (PLED). Blue light emitting polymers based on polyfluorene, which can be cured photochemically to yield an insoluble form, have been synthesized using Ni(0) mediated Yamamoto polymerization. The relationship between patterning property and several variables such as the intensity of the exposed UV light, the concentrations of additives, has been studied by using optical microscope analysis, UV/visible spectroscopy, and photoluminescence. We have successfully fabricated PLEDs composed of the patterned emissive layer and their electroluminescence property has been also investigated. In this presentation, the detailed photolithographic patterning method and its application for polymer light emitting display will be discussed.

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White Light-Emitting Diodes Using Conjugated Polymer Blends

  • Hwang, Do-Hoon;Park, Moo-Jin;Kim, Suk-Kyung;Lee, Chang-Hee;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.585-587
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    • 2004
  • We report the characterization of white light emitting devices fabricated using conjugated polymer blends. Blue emissive poly[9,9-bis(4'-n-octyloxyphenyl) fluorene-2,7-diyl-co-10-(2'-ethylhexyl)phenothiazine-3,7-diyl] [poly(BOPF-co-PTZ)] and red emissive poly(2-(2'-ethylhexyloxy)-5-methoxy-1,4-phenylenevinylene) (MEH-PPV) were employed in the blends. The inefficient energy transfer between these blue and red light emitting polymers (previously deduced from the PL spectra of the blend films) enables the production of white light emission through control of the blend ratio. The PL and EL emission spectra of the blend systems were found to vary with the blend ratio. The EL devices were fabricated in the ITO/PEDOT/blend/LiF/Al configuration and white light emission was obtained for one of the tested blend ratios.

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A Novel Polymer Host for Highly Efficient Solution-Processed Blue Organic Light-Emitting Diode

  • Jou, Jwo-Huei;Lin, Cheng-Wei;Lai, I-Ming;Wang, Wei-Ben;Chiu, Chuan-Huan;Grigalevicius, Saulius;Wu, Chung-Chih
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.803-805
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    • 2009
  • A highly efficient blue organic light-emitting diode (OLED) was fabricated by using a novel polymer host, poly[3-(carbazol-9-ylmethyl)-3-methyloxetane]. The resultant solution-processed device showed a markedly high efficiency of 29.7 lm/W at 100 cd/$m^2$ by doping 24 wt% blue dye bis(3,5-difluoro-2-(2-pyridyl)-phenyl-(2-carboxy pyridyl) iridium (III).

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Study of White Polymer Light Emitting Diode with Blending Method

  • Shin, Byong-Wook;Lee, Sung-Youp;Lee, Eui-Wan;Lee, Hyeong-Rag
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1461-1463
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    • 2007
  • In this study, we report the luminescent properties of white polymer light emitting diode (WPLED) fabricated by soluble methods with poly-fluorenebased polymers blends which emit blue and yellow light. A device structure of ITO/PEDOT:PSS/Emissive Layer (EML)/Al was employed.

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Development of an alignment free mask patterning as a new fabrication method for high efficiency white organic light-emitting diodes

  • Joo, Chul-Woong;Jeon, Soon-Ok;Yook, Kyoung-Soo;Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.752-754
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    • 2009
  • High efficiency white organic light emitting diodes were fabricated by using an alignment free mask patterning method. Only red/green emission without any blue emission was observed in the red/green patterned region and blue emission was emitted in other area. A combination of the red/green and blue emission gave a high efficiency white emission. A maximum current efficiency of 30.7 cd/A and a current efficiency of 25.9 cd/A at 1000 cd/$m^2$ were obtained with a color coordinate of (0.38, 0.45).

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Preparation and Characterization of Blue-Emitting Polymer/Dielectric Nanolayer Nanocomposites (청색발광 고분자/절연 나노층 나노 복합체의 제조 및 특성화)

  • 박종혁;박오옥;김재경;유재웅;김영철
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.7-10
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    • 2003
  • Blue-light-emitting peiymer/dielectric nanolayer nanocomposites were prepared by the solution intercalation method and employed in electroluminescent device. Their photoluminescence and electroluminescence characteristics suggested that the nanolayers isolate the polymer chains and hinder the formation of excimers and aggregates. By reducing the excimer formation and its deleterious effects on emission efficiency, both the color purity and the luminescence stability were improved. Furthermore, the dielectric nanolayers have an aspect ratio of about 500 and therefore act as efficient barriers to oxygen and moisture diffusion, which produced a dramatic increase in the device stability.

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Electroluminescence Characteristics of Blue Light Emitting Copolymer Containing Perylene and Triazine Moieties in the Side Chain (페릴렌과 트리아진기를 측쇄로 가지는 청색 발광 공중합체의 전기발광 특성)

  • Lee Chang Ho;Ryu Seung Hoon;Oh Hwan Sool;Oh Se Young
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.367-373
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    • 2004
  • Novel non-conjugated blue light-emitting copolymers containing perylene and triazine moieties as light emitting and electron transporting units, respectively in the polymer side chain were synthesized. The resulting copolymers were soluble in most organic solvents such as chlorobenzene, THF, chloroform and benzene. The single-layered electroluminescence (EL) device consisting of indium tin oxide (ITO) /copolymer/aluminium (Al) exhibited a maximum external quantum efficiency ($0.003\%$) and a good carrier balance when the triazine content was $30\%$. In particular, the device emitted blue light (479 nm) corresponding to the emission of perylene moiety. The drive voltage was observed at 5 V and the CIE coordinate was x=0.16, y=0.17.

Synthesis and Characterization of 1,2,4-Oxadiazole-Based Deep-Blue and Blue Color Emitting Polymers

  • Agneeswari, Rajalingam;Tamilavan, Vellaiappillai;Hyun, Myung Ho
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.513-517
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    • 2014
  • Two donor-acceptor-donor monomers such as 3,5-bis(4-bromophenyl)-1,2,4-oxadiazole (BOB) and 3,5-bis(5-bromothiophen-2-yl)-1,2,4-oxadiazole (TOT) incorporating electron transporting and hole blocking 1,2,4-oxadiazloe moiety were copolymerized with light emitting fluorene derivative via Suzuki polycondensation to afford two new polymers, PFBOB and PFTOT, respectively. The optical studies for polymers PFBOB and PFTOT revealed that the band gaps are 3.10 eV and 2.72 eV, respectively, and polymer PFBOB exhibited a deep-blue emission while polymer PFTOT showed blue emission in chloroform and as thin film. The photoluminescence quantum efficiencies (${\Phi}_f$) of polymers PFBOB and PFTOT in chloroform calculated against highly blue emitting 9,10-diphenylanthracene (DPA, ${\Phi}_f=0.90$) were 1.00 and 0.44, respectively.

The Investigation of Photolithographic Patterning Method for Polymer Light Emitting Diodes

  • Kim, Mi-Kyung;Lee, Jeong-Ik;Kim, Duck-Il;Oh, Ji-Young;Hwang, Chi-Sun;KoPark, Sang-He;Yang, Yong-Suk;Chu, Hye-Yong;Kim, Suk-Kyung;Hwang, Do-Hoon;Lee, Hyung-Jong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.592-594
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    • 2004
  • We have investigated the photolithographic patterning method of light emitting polymer film for polymer light emitting diodes (PLEDs). Blue light emitting polymers based on polyfluorene, which can be cured photochemically to yield an insoluble form, have been synthesized using Ni(0) mediated Yamamoto polymerization. The relationship between patterning property and several variables such as the intensity of the exposed UV light, the concentrations of additives, has been studied by using optical microscope analysis, UV/visible spectroscopy, and photoluminescence. We have successfully fabricated PLEDs composed of the patterned emissive layer and their electroluminescence property has been also investigated. In this presentation, the detailed photolithographic patterning method and its application for polymer light emitting display will be discussed.

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